CN102891331A - Multifunctional water tank for cold boot of fuel cell - Google Patents

Multifunctional water tank for cold boot of fuel cell Download PDF

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Publication number
CN102891331A
CN102891331A CN2012103589112A CN201210358911A CN102891331A CN 102891331 A CN102891331 A CN 102891331A CN 2012103589112 A CN2012103589112 A CN 2012103589112A CN 201210358911 A CN201210358911 A CN 201210358911A CN 102891331 A CN102891331 A CN 102891331A
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China
Prior art keywords
water tank
end socket
hydrogen
main body
fuel cell
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CN2012103589112A
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CN102891331B (en
Inventor
甘全全
李丹
秦连庆
江洪春
侯中军
孙德尧
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Sunrise Power Co Ltd
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Sunrise Power Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

The invention discloses a multifunctional water tank for cold boot of a fuel cell. The multifunctional water tank comprises an end socket front cover, an end socket, a water tank main body and a tail gas collecting end socket. The multifunctional water tank is characterized in that the end socket front cover is provided with an air intake pipe bushing hole and a hydrogen intake pipe; the end socket is provided with at least two hydrogen intake holes, wherein a hydrogen feeding pipe which is fixedly connected with the hydrogen intake hole is arranged at one side of the end socket, and an air intake pipe which is matched with the air intake pipe bushing hole is arranged at one side of the end socket; a catalysis pipe corresponding to the hydrogen intake pipe is arranged in the water tank main body, a catalyst is arranged at the inner side of the pipe wall of the catalysis pipe, at least one heating rod is also arranged in the water tank main body, and the water tank main body is respectively provided with a cooling liquid inlet and a cooling liquid outlet; and the end socket front cover, the end socket, the water tank main body and the tail gas collecting end socket are fixedly connected in sequence. The multifunctional water tank disclosed by the invention is simple in structure and convenient to use, is connected to a circulating main pipeline of a fuel cell system in series and achieves the functions of cooling liquid storage, auxiliary heating, tail gas treatment and the like.

Description

A kind of multipurpose water tank for the fuel cell cold start-up
Technical field
The present invention relates to a kind of water tank, specifically a kind of multipurpose water tank for the fuel cell cold start-up.
Background technology
The advantages such as that fuel cell has is pollution-free, high energy ratio, high efficiency, automobile industry is all being actively pushed forward the commercialization process of fuel cell car at present, but also exist various challenges, as: the infrastructure construction problems such as the accumulating of reliability, durability, cost and hydrogen fuel and filling etc.One of except these problems, fuel battery engines cold start-up ability also is restriction FCV(fuel cell car) significant challenge of commercial applications.For finishing the fuel cell pile Cold Start, special temperature is lower than-20 ℃ Cold Start, generally all needs to use the mode of assistant starting to finish.This process mainly realizes that by following three kinds of modes fuel cell heats up:
1, hydrogen or methyl alcohol are directly burnt or be catalytically converted into heat, and conduction is to the circulatory system or directly finish this process in pile inside;
2, have externally fed mode or fuel cell self generating to supply with heating wire, heating circulation system or air system reach the whole purpose that heats up;
3, improve the compression ratio of air feeding unit such as air compressor machine, realize the intake air temperature increase, thereby finish auxiliary heating pile process.
The problem that exists is that using single temperature-rising method in same system is the toggle speed that is unfavorable for system; In addition, all there is the problem that does not take full advantage of engine operation waste heat in three kinds of temperature-rising methods more than enumerating; Have, often face a problem when using catalysis method to process fuel cell hydrogen tail row, the air of namely sneaking into can't cool off the used heat that produces in the catalytic process, and this processes for follow-up tail exhaust body is dangerous and disadvantageous.Therefore, how to realize under the fuel cell freezing point starting fast, and to alleviate as much as possible or eliminates the low-temperature circulating startup be a urgent problem to the damage of fuel cell.
Summary of the invention
According to the technical problem of above-mentioned proposition, and provide a kind of multipurpose water tank for the fuel cell cold start-up.Water tank is mainly used in storing circulation fluid in fuel cell system, to system carry out that solution replenishes, bubble discharging etc.The present invention fully utilizes above three kinds of temperature-rising methods by the redesign to original water tank, increases its function, has solved fuel cell in the not enough problem of the external heating power of Cold Start.Simultaneously, can also be as the hydrogen tail discharge gas treatment at this water tank of fuel cell normal operating phase, making wherein, density of hydrogen is lower than the explosion limit value.
The technological means that the present invention adopts is as follows:
A kind of multipurpose water tank for the fuel cell cold start-up comprises that end socket protecgulum, end socket, water tank main body and tail row collect end socket, and it is characterized in that: described end socket protecgulum is provided with air inlet canister aperture and hydrogen gas pipe; Described end socket is provided with at least two hydrogen gas holes, and a side of described end socket is provided with the hydrogen snorkel that is fixedly connected with described hydrogen gas hole, and the opposite side of described end socket is provided with the air intake duct that is complementary with described air inlet canister aperture; Be provided with the catalysing tube corresponding with described hydrogen snorkel in the described water tank main body, the tube wall inboard of described catalysing tube is provided with can be with the catalyst of hydrogen and oxygen catalytic reaction Cheng Shui, also be provided with at least one heating rod in the described water tank main body, be respectively equipped with cooling fluid entrance and cooling liquid outlet on the described water tank main body; Described end socket protecgulum, described end socket, described water tank main body and described exhaust collection end socket are fixedly connected sequentially.
The caliber of described hydrogen snorkel is less than the caliber of described catalysing tube.
Catalyst in the described catalysing tube is at least platinum black, palladium, rhodium and alloy thereof, Pt/c, Cu xFe 3-xO 4In a kind of.
The mouth of pipe of described hydrogen snorkel is the sharp-mouth type mouth of pipe.
Water tank main body of the present invention is used for storing cooling fluid, and participates in the circulation of cooling system.Catalysing tube in being arranged on the interior hydrogen snorkel of end socket and being arranged on the water tank main body is corresponding one by one, the caliber of hydrogen snorkel is less than the caliber of catalysing tube, the air velocity of hydrogen flow rate outside the hydrogen snorkel in the hydrogen snorkel, the port of export at the hydrogen snorkel, because the speed difference of hydrogen and air and is finished H so that large quantity of air together is involved in the catalysing tube in catalysing tube 2+ O 2→ H 2The catalytic reaction of O produces simultaneously water and emits heat.
Air intake duct of the present invention is connected with the air tail row pipeline of fuel cell system; The hydrogen gas pipe links to each other with the hydrogen tail discharge mouth of fuel cell system; In the circulatory system that cooling fluid entrance on the water tank main body and cooling liquid outlet are connected on fuel cell system; Heating rod can power taking and control from fuel cell system.
Compare than prior art, the function that the present invention has not only kept original water tank namely stores cooling fluid, liquid level shows, has also increased the auxiliary function that heats up and the function of diluting tail row density of hydrogen in fuel cell cold-starting process.Take full advantage of the heat that system produces, from reclaiming fuel cell system high temperature air, catalytic way recovery fuel cell system hydrogen tail discharge energy and three directions of electric heating, accelerate the temperature rise speed of systemic circulation liquid.Air behind the process fuel cell reaction and hydrogen are mixed into and carry out catalytic reaction in the water tank main body, because the flow of air much larger than the flow of hydrogen, air and hydrogen mixing, can effectively reduce density of hydrogen after the reaction; In addition, reacted content of oxygen in air is lower, can make with the mixed concentration of hydrogen by control to be lower than again the hydrogen explosion limting concentration; And the water tank main body is owing to adopt tube shell type structure, the temperature of the heating rod in the water tank main body can be effectively controlled, thereby the temperature in the catalysing tube also can be effectively controlled, and also can not cause because gathering strength the ignite situation of hydrogen cause danger of high temperature to occur even work at normal temperatures.
The present invention is highly integrated, and is simple in structure, high without rotatable components and reliability, and the present invention can extensively promote in power station and the field such as vehicle-mounted for the foregoing reasons, and possesses preferably application prospect.
Description of drawings
The present invention is further detailed explanation below in conjunction with the drawings and specific embodiments.
Fig. 1 is structural representation of the present invention.
Fig. 2 is explosive view of the present invention.
Fig. 3 is the end view of end socket of the present invention.
Fig. 4 is the schematic diagram of water tank main body of the present invention.
Among the figure: 1, end socket protecgulum 11, air inlet canister aperture 12, hydrogen gas pipe 2, end socket 21, air intake duct 22, hydrogen gas hole 23, hydrogen snorkel 3, water tank main body 31, catalysing tube 32, cooling fluid entrance 33, cooling liquid outlet 34, heating rod 4, tail row collect end socket
Embodiment
As shown in Figure 1 and Figure 2, a kind of multipurpose water tank for the fuel cell cold start-up, comprise that end socket protecgulum 1, end socket 2, water tank main body 3 and tail row collect end socket 4, described end socket protecgulum 1 is provided with air inlet canister aperture 11 and hydrogen gas pipe 12, described air inlet canister aperture 11 is arranged on the front block surface of described end socket protecgulum 1, and described hydrogen gas pipe 12 is arranged on the sidewall of described end socket protecgulum 1; In the present embodiment, described end socket 2(is as shown in Figure 3) be provided with and be circular a plurality of hydrogen gas hole 22 of arranging, one side of described end socket 2 is provided with the hydrogen snorkel 23 that is fixedly connected with described hydrogen gas hole 22, and the mouth of pipe of described hydrogen snorkel 23 is the sharp-mouth type mouth of pipe.The opposite side of described end socket 2 is provided with the air intake duct 21 that is complementary with described air inlet canister aperture 11, is provided with sealing ring between described air intake duct 21 and the described air inlet canister aperture 11, thus the air-tightness of assurance device; Described water tank main body 3(is as shown in Figure 4) in be provided with the catalysing tube 31 corresponding with described hydrogen snorkel 23, catalysing tube 31 has preferably heat conductivility, can be fast the cooling fluid in the thermal energy transfer feed-tank main body 3 that produces in the catalytic reaction, can be fast the cooling fluid in the high temperature air heat transferred water tank main body; The tube wall inboard of described catalysing tube 31 is attached with can be with the catalyst of hydrogen and oxygen catalytic reaction Cheng Shui, and described catalyst is at least platinum black, palladium, rhodium and alloy thereof, Pt/c, Cu xFe 3-xO 4In a kind of, namely catalyst can be that in above-mentioned one or more are mixed and uses, in the present embodiment, what catalyst was selected is platinum black.The caliber of described hydrogen snorkel 23 is less than the caliber of described catalysing tube 31, in use, the flow velocity of hydrogen is greater than the flow velocity of air, hydrogen enters the air winding mixing that reaches hydrogen and air in the catalysing tube 31 by the sharp-mouth type mouth of pipe of hydrogen snorkel 23 front ends, wherein, hydrogen derives from tail row hydrogen, and air derives from the fuel cell high temperature air of recovery; Also be provided with 5 heating rods 34 in the described water tank main body 3, described heating rod 34 can be heating wire, electric ceramic etc., the heating wire that heating rod 34 adopts by tungsten filament system in the present embodiment; Be respectively equipped with cooling fluid entrance 32 and cooling liquid outlet 33 on the described water tank main body 3, cooling fluid entrance 32 and cooling liquid outlet 33 are connected on respectively in the circulatory system of fuel cell system, play the effect of recycling heat; Described end socket protecgulum 1 is welded and fixed with described end socket 2, and described end socket 2 is fixed with described water tank main body 3 bolts, and described water tank main body 3 is fixed with described exhaust collection end socket 4 bolts, and bearing is equipped with sealing ring, the air-tightness of assurance device.
The above; only be the better embodiment of the present invention; but protection scope of the present invention is not limited to this; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to replacement or change according to technical scheme of the present invention and inventive concept thereof, all should be encompassed within protection scope of the present invention.

Claims (4)

1. multipurpose water tank that is used for the fuel cell cold start-up, comprise that end socket protecgulum (1), end socket (2), water tank main body (3) and tail row collect end socket (4), it is characterized in that: described end socket protecgulum (1) is provided with air inlet canister aperture (11) and hydrogen gas pipe (12); Described end socket (2) is provided with at least two hydrogen gas holes (22), one side of described end socket (2) is provided with the hydrogen snorkel (23) that is fixedly connected with described hydrogen gas hole (22), and the opposite side of described end socket (2) is provided with the air intake duct (21) that is complementary with described air inlet canister aperture (11); Be provided with the catalysing tube (31) corresponding with described hydrogen snorkel (23) in the described water tank main body (3), the tube wall inboard of described catalysing tube (31) is provided with can be with the catalyst of hydrogen and oxygen catalytic reaction Cheng Shui, also be provided with at least one heating rod (34) in the described water tank main body (3), be respectively equipped with cooling fluid entrance (32) and cooling liquid outlet (33) on the described water tank main body (3); Described end socket protecgulum (1), described end socket (2), described water tank main body (3) and described exhaust collection end socket (4) are fixedly connected sequentially.
2. a kind of multipurpose water tank for the fuel cell cold start-up according to claim 1, it is characterized in that: the caliber of described hydrogen snorkel (23) is less than the caliber of described catalysing tube (31).
3. a kind of multipurpose water tank for the fuel cell cold start-up according to claim 1 is characterized in that: the catalyst in the described catalysing tube (31) is at least platinum black, palladium, rhodium and alloy thereof, Pt/c, Cu xFe 3-xO 4In a kind of.
4. a kind of multipurpose water tank for the fuel cell cold start-up according to claim 1 and 2, it is characterized in that: the mouth of pipe of described hydrogen snorkel (23) is the sharp-mouth type mouth of pipe.
CN201210358911.2A 2012-09-24 2012-09-24 Multifunctional water tank for cold boot of fuel cell Active CN102891331B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110435414A (en) * 2019-08-20 2019-11-12 芜湖同优汽车科技有限公司 Hydrogen energy source car tail calandria structure
CN110869586A (en) * 2018-04-23 2020-03-06 赛峰航空助推器股份有限公司 Hydraulic system for lubrication of turbojet engine

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1496589A (en) * 2000-10-30 2004-05-12 Multifunction energy system operable as fuel cell, reformer or thermal plant
US20090130511A1 (en) * 2007-11-19 2009-05-21 Microcell Corporation Fuel Cell Module
CN202905875U (en) * 2012-09-24 2013-04-24 新源动力股份有限公司 Multifunctional water tank used for cold start of fuel cell

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1496589A (en) * 2000-10-30 2004-05-12 Multifunction energy system operable as fuel cell, reformer or thermal plant
US20090130511A1 (en) * 2007-11-19 2009-05-21 Microcell Corporation Fuel Cell Module
CN202905875U (en) * 2012-09-24 2013-04-24 新源动力股份有限公司 Multifunctional water tank used for cold start of fuel cell

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110869586A (en) * 2018-04-23 2020-03-06 赛峰航空助推器股份有限公司 Hydraulic system for lubrication of turbojet engine
CN110869586B (en) * 2018-04-23 2022-07-12 赛峰航空助推器股份有限公司 Hydraulic system for lubrication of turbojet engine
CN110435414A (en) * 2019-08-20 2019-11-12 芜湖同优汽车科技有限公司 Hydrogen energy source car tail calandria structure
CN110435414B (en) * 2019-08-20 2024-05-14 芜湖同优科技股份有限公司 Tail pipe arrangement structure of hydrogen energy automobile

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