CN106698342A - Equipment for producing hydrogen by alcohol and water - Google Patents
Equipment for producing hydrogen by alcohol and water Download PDFInfo
- Publication number
- CN106698342A CN106698342A CN201710089037.XA CN201710089037A CN106698342A CN 106698342 A CN106698342 A CN 106698342A CN 201710089037 A CN201710089037 A CN 201710089037A CN 106698342 A CN106698342 A CN 106698342A
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- CN
- China
- Prior art keywords
- hydrogen
- pipe
- water
- gas
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N5/00—Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy
- F01N5/02—Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy the devices using heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B63/00—Adaptations of engines for driving pumps, hand-held tools or electric generators; Portable combinations of engines with engine-driven devices
- F02B63/04—Adaptations of engines for driving pumps, hand-held tools or electric generators; Portable combinations of engines with engine-driven devices for electric generators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Abstract
The invention relates to equipment for producing hydrogen by alcohol and water. A helical first heating coil is wound on the outer wall of a tail gas exhaust pipe; one end of a first liquid conveying pipe is communicated and connected with an oil tank, the other end is communicated and connected with the first heating coil, and a first liquid conveying pump and a first solenoid valve are mounted on the first liquid conveying pipe; a first three-way pipe is connected to the tail gas exhaust pipe, a first gas distributing solenoid valve is mounted on the first three-way pipe, two gas outlets of the first three-way pipe are respectively communicated and connected with a first gas outlet pipe and a second gas outlet pipe, a helical second heating coil is wound on the first gas outlet pipe, a housing is fixed on the second gas outlet pipe, and a reforming catalyst is placed in the housing; one end of a second liquid conveying pipe is communicated and connected with the oil tank, the other end is communicated and connected with the housing, and a second liquid conveying pump and a second solenoid valve are mounted on the second liquid conveying pipe. The equipment provided by the invention has the benefits that the alcohol and the water are completely converted to the hydrogen for storage by utilizing an alcohol-rich hydrogen engine, and the stored hydrogen is used for supplement to a fuel cell electric vehicle; a metal hydrogen absorbing material is adopted for the purification of the hydrogen, and the production efficiency is high.
Description
Technical field：
The present invention relates to hydrogen producer technical field, setting for hydrogen manufacturing is carried out using alcohol and water more specifically to a kind of
It is standby.
Background technology：
CN105329853A discloses a kind of Portable movable hydrogen making machine based on methanol-water hydrogen manufacturing, and it is by burner
Mode allow alcohol water vapor to the heating of alcohol water, the alcohol and water of vaporization is then carried out into catalyzing manufacturing of hydrogen into the reformer chamber of constant temperature again,
First alcohol and water is converted into reformer chamber the mixture of hydrogen, methane, carbon monoxide and carbon dioxide, by by film purifying hydrogen
Technology by Hydrogen Separation out.Its weak point is：1st, its mode of heating uses the burner, whole machine must to configure automatically controlled setting
It is standby, and its main part does not produce electric energy, it is necessary to be furnished with extraneous power supply in hydrogen production process.2nd, it uses film purified hydrogen
Gas technology, and the service life of film is limited, it is necessary to periodic inspection changes film.
ZL201520019763.0 discloses a kind of thermal effect alcohols generating set high, and it is sent out using alcohol hydrogen-rich engine
Electricity, its main purpose is to generate electricity, and electrical power storage to be got up charged to electric motor car, although also produce some hydrogen, but it is produced
Hydrogen finally or be used for generate electricity.This complete equipment cannot be fuel cell electric vehicle hydrogen make-up.
The content of the invention：
The purpose of the present invention and provides a kind of alcohol water hydrogen equipment aiming at the deficiency of prior art, and it is to utilize
Alcohol hydrogen-rich engine becomes hydrogen storage completely by alcohol and water, and the hydrogen for storing is used to be mended to fuel cell electric vehicle
It is flushed with hydrogen gas., using the electric energy and heat energy of the generation of alcohol hydrogen-rich engine to alcohol and water heatable catalytic, the purifying of hydrogen uses metal for it
Hydrogen-absorbing material, its production efficiency is high.
Technology solution of the invention is as follows：
Alcohol water hydrogen equipment, including engine and generator, driven by engine electrical power generators, fuel tank and engine
Fuel electronics nozzle is mutually connected by inflow pipeline, and fuel electronics nozzle is mutually connected with the inlet manifold of engine, starts equipment
There is exhaust pipe, the mixture equipped with alcohol and water in fuel tank；
Be wound with spiral helicine first heating coil on the outer wall of exhaust pipe, first liquid pushing tube one end connect fuel tank,
The other end is mutually connected with the first heating coil, and the first liquid-feeding pump and the first magnetic valve are provided with the first liquid pushing tube；Tail gas is vented
The first three-way pipe is connected with pipe, first point of pneumoelectric magnet valve, two gas outlets of the first three-way pipe are installed on the first three-way pipe
The first escaping pipe and the second escaping pipe being connected respectively, spiral helicine second heating coil being wound with the first escaping pipe, second goes out
Case is fixed with tracheae, reforming catalyst is placed with case, second liquid pushing tube one end connects fuel tank, the other end with case phase
Connect, the second liquid-feeding pump and the second magnetic valve are installed on the second liquid pushing tube；
The electrical power storage that generator is produced is fixed with electric heating sheets and is placed with weight in batteries in catalytic reforming room
Whole catalyst, batteries provide electric energy to electric heating sheets；The gas produced in the gas and case that are produced in catalytic reforming room
Into in heat exchanger, the cooling gas in heat exchanger out enter in low pressure gas bomb；
Low pressure gas bomb is mutually connected by pipeline with the second three-way pipe, and two gas outlets of the second three-way pipe connect respectively
One inhales hydrogen production device and second inhales the suction hydrogen air inlet of hydrogen production device, and second point of pneumoelectric magnet valve is provided with the second three-way pipe；
The structure of the first suction hydrogen production device and the second suction hydrogen production device is identical, and the structure of the first suction hydrogen production device is：Set on tank body
There are suction hydrogen air inlet, waste gas outlet and hydrogen outlet, water pipe is passed through and be fixed on tank body, the water in tank body from tank body
Metal hydrogen-absorbing material is fixed with the outer wall of tube portion, cold water or hot water are led in water pipe；First inhales hydrogen production device and second inhales hydrogen dress
The hydrogen outlet put connects hydrogen storage tank by pipeline, and the gas in waste gas outlet connects inlet manifold by pipeline.
Lead to running water in second heating coil, hot water connects water pipe by pipeline in the second heating coil.
Temperature sensor is mounted in the catalytic reforming room and case, the temperature signal of temperature sensor is conveyed to control
Cabinet processed, switch board controls electric heating sheets heating according to temperature signal, and switch board controls first point of pneumoelectric magnet valve according to temperature signal
Work, switch board controls second point of pneumoelectric magnet valve, the first liquid-feeding pump, the first magnetic valve, the second liquid-feeding pump and second magnetic valve work
Make.
The beneficial effects of the present invention are：
It is to become hydrogen storage completely by alcohol and water using alcohol hydrogen-rich engine, the hydrogen for storing be used for
Fuel cell electric vehicle hydrogen make-up.It is using the electric energy and heat energy of the generation of alcohol hydrogen-rich engine to alcohol and water heatable catalytic, hydrogen
The purifying of gas uses metal hydrogen-absorbing material, and its production efficiency is high.
Brief description of the drawings：
Fig. 1 is structural representation of the invention；
Fig. 2 is the structural representation of the first suction hydrogen production device part；
In figure：1st, engine；2nd, generator；3rd, fuel tank；4th, the first heating coil；5th, the first liquid-feeding pump；6th, the first electromagnetism
Valve；7th, batteries；8th, catalytic reforming room；9th, heat exchanger；10th, low pressure gas bomb；11st, the first three-way pipe；12nd, first point of pneumoelectric
Magnet valve；13rd, the first escaping pipe；14th, the second escaping pipe；15th, the second heating coil；16th, case；17th, the second liquid-feeding pump；18th,
Two magnetic valves；19th, the second three-way pipe；20th, first inhales hydrogen production device；21st, second inhales hydrogen production device；22nd, second point of pneumoelectric magnet valve；23、
Hydrogen storage tank；24th, switch board.
Specific embodiment：
Embodiment：As shown in Fig. 1,2, alcohol water hydrogen equipment, including engine 1 and generator 2, engine 1 drives to be sent out
Motor 2 is generated electricity, and fuel tank 3 is connected with the fuel electronics nozzle 1a of engine 1 by inflow pipeline 3-1 phases, fuel electronics nozzle 1a
Inlet manifold 1b phases with engine 1 are connected, and engine 1 has exhaust pipe 1c, the mixing equipped with alcohol and water in fuel tank 3
Thing；
Spiral helicine first heating coil 4 is wound with the outer wall of exhaust pipe 1c, first liquid pushing tube 3-2 one end connects
The fuel tank 3, other end is mutually connected with the first heating coil 4, and the first liquid-feeding pump 5 and the first electromagnetism are provided with the first liquid pushing tube 3-2
Valve 6；The first three-way pipe 11 is connected with exhaust pipe 1c, first point of pneumoelectric magnet valve 12 is installed on first three-way pipe 11, the
Two gas outlets of one three-way pipe 11 connect the first escaping pipe 13 and the second escaping pipe 14 respectively, are wound with the first escaping pipe 13
Spiral helicine second heating coil 15, is fixed with case 16 in the second escaping pipe 14, reforming catalyst 82 is placed with case 16,
Second liquid pushing tube 3-3 one end connects the fuel tank 3, other end and is mutually connected with case 16, and the second liquor charging is provided with the second liquid pushing tube 3-3
The magnetic valve 18 of pump 17 and second；
The electrical power storage that generator 2 is produced is fixed with electric heating sheets 81 and puts in batteries 7 in catalytic reforming room 8
Reforming catalyst 82 is equipped with, batteries 7 provide electric energy to electric heating sheets 81；The gas and case produced in catalytic reforming room 8
The gas produced in 16 enters in heat exchanger 9, and the cooling gas in heat exchanger 9 out enter in low pressure gas bomb 10；
Low pressure gas bomb 10 is mutually connected by pipeline with the second three-way pipe 19, two gas outlets difference of the second three-way pipe 19
The suction hydrogen air inlet 201 of the first suction hydrogen production device 20 and the second suction hydrogen production device 21 is connected, second point is provided with the second three-way pipe 20
Pneumoelectric magnet valve 22；
First suction hydrogen production device 20 is identical with the structure that second inhales hydrogen production device 21, and the structure of the first suction hydrogen production device 20 is：Tank body
Suction hydrogen air inlet 201, waste gas outlet 202 and hydrogen outlet 203 are provided with 200, water pipe 204 is passed through and solid from tank body 200
It is scheduled on tank body 200, metal hydrogen-absorbing material 205 is fixed with the outer wall of the water pipe sections in tank body 200, in water pipe 204
Logical cold water or hot water；The hydrogen outlet 203 that first suction hydrogen production device 20 and second inhales hydrogen production device 21 connects hydrogen storage by pipeline
Tank 23, the gas in waste gas outlet 202 connects inlet manifold 1b by pipeline.
Lead to running water in second heating coil 15, hot water connects water pipe 204 by pipeline in the second heating coil 15.
Temperature sensor, the temperature signal conveying of temperature sensor are mounted in the catalytic reforming room 8 and case 16
To switch board 24, switch board 24 controls electric heating sheets 81 to heat according to temperature signal, and switch board 24 is according to temperature signal control the
One point of pneumoelectric magnet valve 12 works, and switch board 24 controls second point of pneumoelectric magnet valve 22, the first liquid-feeding pump 5, first magnetic valve 6, second
The magnetic valve 18 of liquid-feeding pump 17 and second works.
Operation principle：, at 500 DEG C or so, it can be by the first heating for the temperature of tail gas in the exhaust pipe 1c of engine 1
Alcohol and water vaporization in coil pipe 4, the steam of the alcohol and water vaporized in the first heating coil 4 enters catalytic reforming room 8, in constant temperature
Under the conditions of the steam of alcohol and water is carried out into the gas mixture that catalytic reforming obtains hydrogen, methane, carbon monoxide and carbon dioxide.
The gas mixture of hydrogen, methane, carbon monoxide and carbon dioxide enters in heat exchanger 9, and heat exchanger 9 is changed for gas-liquid
Hot device, the gas mixture of the hydrogen of high temperature, methane, carbon monoxide and carbon dioxide is changed into the mixing of low temperature by cooling water
Gas enters in low pressure gas bomb 10.
Second point of pneumoelectric magnet valve 22 first closes the hydrogen inlet 201 of the second suction hydrogen production device 21, opens first and inhales hydrogen production device
20 hydrogen inlet 201, the mixed gas of the low temperature in low pressure gas bomb 10 enter in the first suction hydrogen production device 20, now, water
Lead to cold water in pipe 204, after the most of hydrogen in the mixed gas of low temperature is absorbed by metal hydrogen-absorbing material 205, open waste gas
Outlet 202, the predominantly gas mixture of methane, carbon monoxide and carbon dioxide in waste gas outlet 202 out and few
The hydrogen of amount, they enter the fuel again of engine 1 by inlet manifold 1b.To logical heat in the first water pipe 204 for inhaling device 20
Water, hydrogen enters in hydrogen storage tank 23 from hydrogen outlet 203 and preserves in metal hydrogen-absorbing material 205.Device 20 is inhaled first
The gas of middle entrance reach it is a certain amount of after, allow second point of pneumoelectric magnet valve 22 to close the first hydrogen inlet 201 for inhaling hydrogen production device 20,
The second hydrogen inlet 201 for inhaling hydrogen production device 21 is opened, allows the second suction hydrogen production device 21 to repeat the first action for inhaling hydrogen production device 2.
The first escaping pipe 13 and the second escaping pipe 14 is opened or closed by first point of pneumoelectric magnet valve 12 to adjust case
16 middle temperature, close to constant temperature, the alcohol and water entered in such case 16 can be vaporized simultaneously the temperature allowed in case 16, in weight
The gas mixture of hydrogen, methane, carbon monoxide and carbon dioxide is produced in the presence of whole catalyst 82 in case 16, this
Mixed gas enter in heat exchanger 9.
It makes full use of the energy that engine is produced to complete hydrogen manufacturing work, and the amounts of hydrogen of production is big, hydrogen storage tank 23
The hydrogen that purity is 85% can be obtained, then through being filtrated to get high-purity hydrogen, the hydrogen of high-purity is in fuel cell electric vehicle
Fuel cell electric vehicle hydrogenation is given in hydrogenation stations.
Claims (3)
1. alcohol water hydrogen equipment, including engine (1) and generator (2), engine (1) drive generator (2) to generate electricity, fuel tank
(3) fuel electronics nozzle (1a) with engine (1) is mutually connected by inflow pipeline (3-1), fuel electronics nozzle (1a) with hair
The inlet manifold (1b) of motivation (1) is mutually connected, and engine (1) is equipped with alcohol and water with exhaust pipe (1c) in fuel tank (3)
Mixture, it is characterised in that：
Spiral helicine first heating coil (4) is wound with the outer wall of exhaust pipe (1c), the first liquid pushing tube (3-2) one end leads to
Connected tank (3), the other end are mutually connected with the first heating coil (4), and the first liquid-feeding pump (5) is provided with the first liquid pushing tube (3-2)
With the first magnetic valve (6)；The first three-way pipe (11) is connected with exhaust pipe (1c), is provided with the first three-way pipe (11)
One point of pneumoelectric magnet valve (12), two gas outlets of the first three-way pipe (11) connect the first escaping pipe (13) and the second escaping pipe respectively
(14) spiral helicine second heating coil (15), is wound with the first escaping pipe (13), the second escaping pipe is fixed with cover on (14)
Shell (16), is placed with reforming catalyst (82) in case (16), the second liquid pushing tube (3-3) one end connect fuel tank (3), the other end with
Case (16) is mutually connected, and the second liquid-feeding pump (17) and the second magnetic valve (18) are provided with the second liquid pushing tube (3-3)；
The electrical power storage that generator (2) is produced is fixed with electric heating sheets (81) in batteries (7) in catalytic reforming room (8)
And reforming catalyst (82) is placed with, batteries (7) provide electric energy to electric heating sheets (81)；Produced in catalytic reforming room (8)
Gas and case (16) in produce gas enter heat exchanger (9) in, the cooling gas in heat exchanger (9) out enter low pressure
In gas bomb (10)；
Low pressure gas bomb (10) is mutually connected by pipeline with the second three-way pipe (19), two gas outlets point of the second three-way pipe (19)
The first suction hydrogen production device (20) and second is not connected and inhales suction hydrogen air inlet (201) of hydrogen production device (21), pacify on the second three-way pipe (20)
Equipped with second point of pneumoelectric magnet valve (22)；
First suction hydrogen production device (20) is identical with the structure that second inhales hydrogen production device (21), and the structure of the first suction hydrogen production device (20) is：Tank
It is provided with suction hydrogen air inlet (201), waste gas outlet (202) and hydrogen outlet (203) on body (200), water pipe (204) is from tank body
(200) passed through in and be fixed on tank body (200), metal suction is fixed with the outer wall of the water pipe sections in tank body (200)
Hydrogen material (205), leads to cold water or hot water in water pipe (204)；First inhales hydrogen production device (20) and second inhales the hydrogen of hydrogen production device (21)
Outlet (203) connects hydrogen storage tank (23) by pipeline, and the gas in waste gas outlet (202) connects inlet manifold by pipeline
(1b)。
2. alcohol water hydrogen equipment according to claim 1, it is characterised in that：Lead to originally in second heating coil (15)
Water, hot water connects water pipe (204) by pipeline in the second heating coil (15).
3. alcohol water hydrogen equipment according to claim 1, it is characterised in that：In catalytic reforming room (8) and case (16)
Temperature sensor is mounted on, the temperature signal of temperature sensor is conveyed to switch board (24), and switch board (24) is believed according to temperature
Number control electric heating sheets (81) heating, switch board (24) controls the work of first point of pneumoelectric magnet valve (12), control according to temperature signal
Cabinet (24) controls second point of pneumoelectric magnet valve (22), the first liquid-feeding pump (5), the first magnetic valve (6), second liquid-feeding pump (17) and second
Magnetic valve (18) works.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710089037.XA CN106698342A (en) | 2017-02-20 | 2017-02-20 | Equipment for producing hydrogen by alcohol and water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710089037.XA CN106698342A (en) | 2017-02-20 | 2017-02-20 | Equipment for producing hydrogen by alcohol and water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106698342A true CN106698342A (en) | 2017-05-24 |
Family
ID=58911913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710089037.XA Pending CN106698342A (en) | 2017-02-20 | 2017-02-20 | Equipment for producing hydrogen by alcohol and water |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106698342A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111188701A (en) * | 2018-11-15 | 2020-05-22 | 杭州醇电科技有限公司 | Methanol fuel power assembly system |
| CN111336038A (en) * | 2018-12-18 | 2020-06-26 | 杭州醇电科技有限公司 | Low-temperature cold start method for methanol engine |
| CN113036191A (en) * | 2021-02-03 | 2021-06-25 | 陕西嘉杰能源集团有限公司 | Hydrogen preparation and power generation system |
| CN114033595A (en) * | 2021-11-25 | 2022-02-11 | 南方科技大学 | Methanol hydrogen production power generation equipment and starting device and starting method thereof |
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| CN104564438A (en) * | 2015-01-12 | 2015-04-29 | 浙江新久能源科技有限公司 | High-thermal-efficiency alcohol generator unit |
| CN105261775A (en) * | 2015-11-03 | 2016-01-20 | 上海合既得动氢机器有限公司 | Water-to-hydrogen charging device for electric automobile |
| CN205535725U (en) * | 2016-01-21 | 2016-08-31 | 樊品良 | High -efficient alcohols steam generator |
| CN206872423U (en) * | 2017-02-20 | 2018-01-12 | 樊品良 | Alcohol water hydrogen equipment |
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| CN101111963A (en) * | 2004-12-28 | 2008-01-23 | 株式会社杰士汤浅 | Independent hydrogen producing system |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111188701A (en) * | 2018-11-15 | 2020-05-22 | 杭州醇电科技有限公司 | Methanol fuel power assembly system |
| CN111336038A (en) * | 2018-12-18 | 2020-06-26 | 杭州醇电科技有限公司 | Low-temperature cold start method for methanol engine |
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| CN114033595A (en) * | 2021-11-25 | 2022-02-11 | 南方科技大学 | Methanol hydrogen production power generation equipment and starting device and starting method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20170524 |