CN102888975A - Novel environment-friendly floor tile and manufacturing method thereof - Google Patents
Novel environment-friendly floor tile and manufacturing method thereof Download PDFInfo
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- CN102888975A CN102888975A CN2011102000695A CN201110200069A CN102888975A CN 102888975 A CN102888975 A CN 102888975A CN 2011102000695 A CN2011102000695 A CN 2011102000695A CN 201110200069 A CN201110200069 A CN 201110200069A CN 102888975 A CN102888975 A CN 102888975A
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Abstract
The invention relates to a novel environment-friendly floor tile and a manufacturing method thereof. The manufacturing method comprises the following steps: firstly, supplying multiple bottom fiber layers containing environment-friendly water-base resins, and then placing top abrasion-resisting layers made of thermoplastic polyurethane on the top surfaces of the multiple bottom fiber layers, and hotly pressing and jointing, thereby utilizing the environment-friendly water-base resins to bond the multiple bottom fiber layers with the top abrasion-resisting layers. The novel environment-friendly floor tile manufactured according to the manufacturing method has the characteristics of light weight, high abrasion resistance, and the like. Besides, the environment-friendly materials, such as fibers, thermoplastic polyurethanes, and the like, are adopted for bonding, so that the manufacturing method has innovation and novelty and meets the healthy and environment-friendly requirements.
Description
Technical field
The present invention relates to a kind of floor tile and preparation method thereof, particularly relate to a kind of novel environment-friendly type floor tile and preparation method thereof.
Background technology
Because indoor decoration collocation and surface management need easily, the laying of floor tile is very general, and the design of general floor tile mainly contains with ceramic tile or the plasticity floor tile made by plastics (PVC) material, and its price is different because of unlike material and size.
In the prior art, general plastic floor tile all contains halogen, or contains organic volatile substance, not environmental protection.Moreover, in the past so-called environment-friendly type plastic floor tile or adopt Lauxite, or modified cyanurotriamide resin, phenolic resins etc., these resins have toxicity in various degree, do not meet the health demand of society.For instance, in TaiWan, China patent announcement I280998, disclose a kind of plastic floor tile method of strengthening wearing face of making, this plastic floor tile as shown in Figure 1.At first, take at least a polyvinyl chloride (PVC) base plate 10 and a top layer glued membrane 12, the two is fitted again, wherein there is the wear-resisting glue that one deck applies in advance on glued membrane 12 surfaces in top layer, and top layer glued membrane 12 is fitted with PVC base plate 10 with the one side that does not have wear-resisting glue.After PVC base plate 10 and top layer glued membrane 12 synthesized, the reusable heat pressure roller rolled, and then cuts to make plastic floor tile.From then on technology as can be known, although can reach better wear-resisting effect, this routine polyvinyl chloride (PVC) base plate has the existence of halogen, still not environmental protection.Therefore, the present invention ties up to for above-mentioned puzzlement, proposes a kind of novel environment-friendly type floor tile and preparation method thereof, to solve the known problem that is produced.
Summary of the invention
The technical problem to be solved in the present invention is, a kind of novel environment-friendly type floor tile and preparation method thereof is provided, it is different from general plastic floor tile technology, and uses the environment-friendly materials of water-base resin, fibrage and thermoplastic polyurethane (TPU), to meet the health demand of society.In addition, utilize high-wearing feature and the high skid resistance of thermoplastic polyurethane, can increase the application life of floor tile.
For reaching above-mentioned purpose, the invention provides a kind of novel environment-friendly type floor tile, comprise a multi-layered soles fibrage that includes the first environment-friendly type water-base resin, and the end face of bottom fiber layer is provided with the top wearing layer that a material is thermoplastic polyurethane, and it mutually combines with the multi-layered soles fibrage that includes environment-friendly type aqueous resin.
The invention provides a kind of preparation method of novel environment-friendly type floor tile, a multi-layered soles fibrage that includes the first environment-friendly type water-base resin at first is provided.Then, be a top wearing layer of thermoplastic polyurethane with material, place on the fibrolaminar end face of multi-layered soles, and give the hot pressing applying, top wearing layer and the multi-layered soles fibrage that includes the first environment-friendly type water-base resin are mutually combined, just finish making.
Novel environment-friendly type floor tile of the present invention and preparation method thereof, at first, the multi-layered soles that includes environment-friendly type aqueous resin fibrage is provided, then, be the top wearing layer of thermoplastic polyurethane with material, place on the fibrolaminar end face of multi-layered soles, and give the hot pressing applying, make the multi-layered soles fibrage utilize environment-friendly type aqueous resin and top wearing layer to mutually combine.The novel environment-friendly type floor tile that the present invention makes not only has the characteristics such as light weight, high-wearing feature, in addition, fits because adopting the environment-friendly materials such as fiber and thermoplastic polyurethane, and this manufacture method meets the demand of health environment-friendly.In addition, also can set up end wearing layer, its material is thermoplastic polyurethane or polyethylene (PE), utilizes high-wearing feature and the high skid resistance of thermoplastic polyurethane, also can increase the application life of floor tile.
Below in conjunction with accompanying drawing novel environment-friendly type floor tile of the present invention and preparation method thereof is described further.
Description of drawings
Fig. 1 is the structure sectional view of prior art plastic floor tile;
Fig. 2 is the structure sectional view of the first embodiment of the present invention;
Fig. 3 a to 3b is each step structure sectional view of making the first embodiment of the present invention;
Fig. 4 a to 4b is fibrolaminar each the step schematic diagram of making multi-layered soles of the present invention;
Fig. 5 is the structure sectional view of the second embodiment of the present invention;
Fig. 6 a to 6b is each step structure sectional view that the present invention makes the second embodiment;
Fig. 7 a to 7b is that the present invention makes fibrolaminar each the step schematic diagram of decoration.
Description of reference numerals:
10-polyvinyl chloride base plate; 12-top layer glued membrane; 14-the first environment-friendly type water-base resin; 16-multi-layered soles fibrage; 17-multi-layer fiber layer; 18-top wearing layer; Wearing layer at the bottom of the 20-; 22-the second environment-friendly type aqueous resin; 24-decorates fibrage; 26-fibrillation decorative layer.
The specific embodiment
Below in conjunction with accompanying drawing, embodiment and experimental data, be described in more detail with other technical characterictic and advantage the present invention is above-mentioned.
Embodiment 1, as shown in Figure 2, in the first embodiment, the environment-friendly type floor tile comprises a multi-layered soles fibrage 16 that includes the first environment-friendly type water-base resin 14, wherein multi-layered soles fibrage 16 comprises the multi-layer fiber layer 17 that absorption has the first environment-friendly type water-base resin 14, and this multi-layer fiber layer 17 comprises the composite bed of at least one ply of paper, at least one lumber layer or at least one cork layer or above-mentioned ply of paper, lumber layer and cork layer; The first environment-friendly type water-base resin 14 is take thermoplastic polyurethane (TPU) glue as example, and it comprises, and to account for the gross weight percentage concentration be 25～50% polyaminoester emulsion, account for 5～15% odium stearate, account for 20～40% water, account for 1～10% glycerine and account for 0～10% polyvinyl alcohol.On the end face of multi-layered soles fibrage 16, being provided with material is the top wearing layer 18 of thermoplastic polyurethane, and multi-layered soles fibrage 16 utilizes the first environment-friendly type water-base resin 14 to mutually combine with top wearing layer 18.Because thermoplastic polyurethane glue is not the non-environmental protection type resin that belongs to prior art, and uses the environmental-protecting material of thermoplastic polyurethane and multi-layered soles fibrage 16, also break away from conventional plastic floor tile technology category, can reach environmental protection and healthy requirement.In addition, the thermoplastic polyurethane of top wearing layer 18 not only has high skid resistance, compares again general polyvinyl chloride (PVC) material, and high 5～10 times abrasion resistance can increase application life of floor tile.In the bottom surface of multi-layered soles fibrage 16, being provided with material is the end wearing layer 20 of thermoplastic polyurethane or polyethylene (PE), with protection multi-layered soles fibrage 16.Multi-layered soles fibrage 16 is to utilize environment-friendly type aqueous resin 14 to mutually combine with end wearing layer 20.
If when laying floor tile, ground belongs to smooth earth, then can omit end wearing layer 20, equally can reach above-mentioned effect.
The preparation method of embodiment 1 described product is shown in Fig. 3 a to 3b.At first shown in Fig. 3 a, provide the multi-layered soles fibrage 16 that includes the first environment-friendly type water-base resin 14.Then, shown in Fig. 3 b, end wearing layer 20, the multi-layered soles fibrage 16 that includes the first environment-friendly type water-base resin 14 and top wearing layer 18 are sequentially from bottom to top placed, and give hot pressing and fit, end wearing layer 20 and top wearing layer 18 and the multi-layered soles fibrage 16 that includes the first environment-friendly type water-base resin 14 are mutually combined, just finish making.
In addition, also can in the step shown in Fig. 3 b, omit end wearing layer 20, only top wearing layer 18 be placed the end face of bottom fiber layer 16, and give the hot pressing applying, top wearing layer 18 is mutually combined with the multi-layered soles fibrage 16 that includes the first environment-friendly type water-base resin 14 get final product.
The preparation method of multi-layered soles fibrage 16 below is described, shown in Fig. 4 a to 4b.At first, shown in Fig. 4 a, multi-layer fiber layer 17 is immersed in the first environment-friendly type water-base resin 14, both adsorb combination.Then, shown in Fig. 4 b, oven dry multi-layer fiber layer 17 to obtain multi-layered soles fibrage 16, can carry out follow-up making thus.
Embodiment 2, as shown in Figure 5.This embodiment 2 and embodiment 1 difference have been to include the decoration fibrage 24 of the second environment-friendly type aqueous resin 22 more, it is located between multi-layered soles fibrage 16 and the top wearing layer 18, and top wearing layer 18 mutually combines with multi-layered soles fibrage 16 with the decoration fibrage 24 that includes the second environment-friendly type aqueous resin 22.Wherein, the surface of decorating fibrage 24 has layout, and decorates fibrage 24 and more comprise the fibrillation decorative layer 26 that absorption has the second environment-friendly type aqueous resin 22, and this fibrillation decorative layer 26 is ply of paper, lumber layer or cork layer; The composition of the second environment-friendly type aqueous resin 22 is identical with the composition of the first environment-friendly type water-base resin 14, take thermoplasticity aqueous polyurethane glue as example, it comprises the polyaminoester emulsion that accounts for gross weight percentage concentration 25～50%, account for 5～15% odium stearate, account for 20～40% water, account for 1～10% glycerine and account for 0～10% polyvinyl alcohol at this.
Similarly, embodiment 2 also can omit end wearing layer 20, equally can reach the purpose of environment protection health, has simultaneously high-wearing feature.
The preparation method of embodiment 2 described products is shown in Fig. 6 a to 6b.At first shown in Fig. 6 a, provide the multi-layered soles fibrage 16 that includes the first environment-friendly type water-base resin 14.Then, shown in Fig. 6 b, end wearing layer 20, the multi-layered soles fibrage 16 that includes the first environment-friendly type water-base resin 14, the decoration fibrage 24 that includes the second environment-friendly type aqueous resin 22 and top wearing layer 18 are sequentially from bottom to top placed, and give hot pressing and fit, top wearing layer 18 and the decoration fibrage 24 and the end wearing layer 20 that include the multi-layered soles fibrage 16 of the first environment-friendly type water-base resin 14 and include the second environment-friendly type aqueous resin 22 are mutually combined, namely finish making.
In addition, also can be in the step of Fig. 6 b, omit end wearing layer 20, the decoration fibrage 24 that only will include the multi-layered soles fibrage 16 of the first environment-friendly type water-base resin 14 and include the second environment-friendly type aqueous resin 22 is sequentially from bottom to top placed with top wearing layer 18, and give hot pressing and fit, top wearing layer 18 is mutually combined with the decoration fibrage 24 that includes the multi-layered soles fibrage 16 of the first environment-friendly type water-base resin 14 and include the second environment-friendly type aqueous resin 22 get final product.
Because the preparation method of multi-layered soles fibrage 16 had been narrated in embodiment 1, shown in Fig. 4 a to 4b, did not repeat them here.
Shown in Fig. 7 a to 7b, the preparation method of fibrage 24 is decorated at last explanation.At first, shown in Fig. 7 a, fibrillation decorative layer 26 is immersed in the second environment-friendly type aqueous resin 22, make both adsorb combination.Then, shown in Fig. 7 b, oven dry fibrillation decorative layer 26 to obtain decorating fibrage 24, can carry out follow-up making.
In sum, the present invention not only uses environmental-protecting material, to reach the requirement of environmental protection, more by the material characteristic with thermoplastic polyurethane, satisfies the requirement of floor tile high-wearing feature.
Above-described embodiment is described preferred embodiment of the present invention; be not that scope of the present invention is limited; design under the prerequisite of spirit not breaking away from the present invention; various distortion and improvement that those of ordinary skills make technical scheme of the present invention all should fall in the definite protection domain of claims of the present invention.
Claims (25)
1. novel environment-friendly type floor tile comprises:
One multi-layered soles fibrage, it includes the first environment-friendly type water-base resin; And
One top wearing layer, its material are thermoplastic polyurethane (TPU), and are located on the fibrolaminar end face of described multi-layered soles, mutually combine with this multi-layered soles fibrage that includes the first environment-friendly type water-base resin.
2. novel environment-friendly type floor tile as claimed in claim 1, it is characterized in that: described the first environment-friendly type water-base resin is thermoplastic polyurethane glue.
3. novel environment-friendly type floor tile as claimed in claim 2 is characterized in that: described thermoplastic polyurethane glue comprises that to account for the gross weight percentage concentration be 25～50% polyaminoester emulsion, account for 5～15% odium stearate, account for 20～40% water, account for 1～10% glycerine and account for 0～10% polyvinyl alcohol.
4. novel environment-friendly type floor tile as claimed in claim 1 is characterized in that: described multi-layered soles fibrage also comprises the multi-layer fiber layer that absorption has described first ring guarantor type water-base resin.
5. novel environment-friendly type floor tile as claimed in claim 1, it is characterized in that: described multi-layer fiber layer also comprises the composite bed of at least one ply of paper, at least one lumber layer or at least one cork layer or this ply of paper, this lumber layer and this cork layer.
6. novel environment-friendly type floor tile as claimed in claim 1, it is characterized in that: also comprise one and decorate fibrage, it is located between described multi-layered soles fibrage and the described top wearing layer, this decoration fibrage includes the second environment-friendly type aqueous resin, and this top wearing layer mutually combines with this decoration fibrage and the multi-layered soles fibrage that include this second environment-friendly type aqueous resin.
7. novel environment-friendly type floor tile as claimed in claim 6, it is characterized in that: the described second environment-friendly type aqueous resin is thermoplastic polyurethane glue.
8. novel environment-friendly type floor tile as claimed in claim 7 is characterized in that: described thermoplastic polyurethane glue comprises that to account for the gross weight percentage concentration be 25～50% polyaminoester emulsion, account for 5～15% odium stearate, account for 20～40% water, account for 1～10% glycerine and account for 0～10% polyvinyl alcohol.
9. novel environment-friendly type floor tile as claimed in claim 6 is characterized in that: described decoration fibrage also comprises the fibrillation decorative layer that absorption has described the second environment-friendly type aqueous resin.
10. novel environment-friendly type floor tile as claimed in claim 9, it is characterized in that: described fibrillation decorative layer is ply of paper, lumber layer or cork layer.
11. novel environment-friendly type floor tile as claimed in claim 6 is characterized in that: the fibrolaminar surface of described decoration has layout.
12. novel environment-friendly type floor tile as claimed in claim 1 is characterized in that: also comprise an end wearing layer, it is located at the fibrolaminar bottom surface of described multi-layered soles, mutually combines with the multi-layered soles fibrage that includes described the first environment-friendly type water-base resin.
13. novel environment-friendly type floor tile as claimed in claim 12 is characterized in that: the material of wearing layer of the described end is thermoplastic polyurethane or polyethylene (PE).
14. the preparation method of a novel environment-friendly type floor tile comprises the following step:
The multi-layered soles fibrage that includes the first environment-friendly type water-base resin is provided; And
Be the top wearing layer of thermoplastic polyurethane (TPU) with material, place on the fibrolaminar end face of this multi-layered soles, and give hot pressing and fit, this top wearing layer and this multi-layered soles fibrage that includes this first environment-friendly type water-base resin are mutually combined.
15. the preparation method of novel environment-friendly type floor tile as claimed in claim 14 is characterized in that: described the first environment-friendly type water-base resin is thermoplastic polyurethane glue.
16. the preparation method of novel environment-friendly type floor tile as claimed in claim 15 is characterized in that: described thermoplastic polyurethane glue comprises that to account for the gross weight percentage concentration be 25～50% polyaminoester emulsion, account for 5～15% odium stearate, account for 20～40% water, account for 1～10% glycerine and account for 0～10% polyvinyl alcohol.
17. the preparation method of novel environment-friendly type floor tile as claimed in claim 14 is characterized in that: the fibrolaminar preparation method of described multi-layered soles comprises the following step:
One multi-layer fiber layer is immersed in described the first environment-friendly type water-base resin, and both adsorb combination; And
Dry this multi-layer fiber layer, to obtain this multi-layered soles fibrage.
18. the preparation method of novel environment-friendly type floor tile as claimed in claim 17 is characterized in that: described multi-layer fiber layer also comprises the composite bed of at least one ply of paper, at least one lumber layer or at least one cork layer or this ply of paper, this lumber layer and this cork layer.
19. the preparation method of novel environment-friendly type floor tile as claimed in claim 14, it is characterized in that: described top wearing layer and described multi-layered soles fibrage are being given the hot pressing applying, make in the step that this top wearing layer and this multi-layered soles fibrage that includes this first environment-friendly type water-base resin mutually combine, more can be with this multi-layered soles fibrage, the decoration fibrage and this top wearing layer that include the second environment-friendly type aqueous resin are sequentially from bottom to top placed, and give hot pressing and fit, this top wearing layer and this multi-layered soles fibrage that includes this decoration fibrage of this second environment-friendly type aqueous resin and include this first environment-friendly type water-base resin are mutually combined.
20. the preparation method of novel environment-friendly type floor tile as claimed in claim 19 is characterized in that: the described second environment-friendly type aqueous resin is thermoplastic polyurethane glue.
21. the preparation method of novel environment-friendly type floor tile as claimed in claim 20 is characterized in that: described thermoplastic polyurethane glue comprises that to account for the gross weight percentage concentration be 25～50% polyaminoester emulsion, account for 5～15% odium stearate, account for 20～40% water, account for 1～10% glycerine and account for 0～10% polyvinyl alcohol.
22. the preparation method of novel environment-friendly type floor tile as claimed in claim 21 is characterized in that: the fibrolaminar preparation method of described decoration comprises the following step:
One fibrillation decorative layer is immersed in the described second environment-friendly type aqueous resin, and both adsorb combination; And
Dry this fibrillation decorative layer, to obtain described decoration fibrage.
23. the preparation method of novel environment-friendly type floor tile as claimed in claim 22 is characterized in that: described fibrillation decorative layer is ply of paper, lumber layer or cork layer.
24. the preparation method of novel environment-friendly type floor tile as claimed in claim 14, it is characterized in that: described top wearing layer and described multi-layered soles fibrage are being given the hot pressing applying, make in the step that this top wearing layer and this multi-layered soles fibrage that includes this first environment-friendly type water-base resin mutually combine, also comprise an end wearing layer, described multi-layered soles fibrage and described top wearing layer are sequentially from bottom to top placed, and give the hot pressing applying, this top wearing layer and this end wearing layer and this multi-layered soles fibrage are mutually combined.
25. the preparation method of novel environment-friendly type floor tile as claimed in claim 24 is characterized in that: the material of wearing layer of the described end is thermoplastic polyurethane or polyethylene (PE).
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| CN2011102000695A CN102888975A (en) | 2011-07-18 | 2011-07-18 | Novel environment-friendly floor tile and manufacturing method thereof |
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| CN2011102000695A CN102888975A (en) | 2011-07-18 | 2011-07-18 | Novel environment-friendly floor tile and manufacturing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104708978A (en) * | 2013-12-17 | 2015-06-17 | 科森复合材料股份有限公司 | Sheet decoration structure and production method thereof |
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| WO2000061362A1 (en) * | 1999-04-14 | 2000-10-19 | Mitsui Chemicals, Inc. | Laminate |
| CN1362326A (en) * | 2000-12-27 | 2002-08-07 | 三井化学株式会社 | Laminated product with surface protective layer |
| CN101220252A (en) * | 2008-01-25 | 2008-07-16 | 中北大学 | Solid glue stick and method for producing the same |
| CN101509313A (en) * | 2009-03-17 | 2009-08-19 | 万利环宇（福建）贸易有限公司 | Thermoplastic polyurethane floor tile and technique for producing the same |
-
2011
- 2011-07-18 CN CN2011102000695A patent/CN102888975A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000061362A1 (en) * | 1999-04-14 | 2000-10-19 | Mitsui Chemicals, Inc. | Laminate |
| CN1362326A (en) * | 2000-12-27 | 2002-08-07 | 三井化学株式会社 | Laminated product with surface protective layer |
| CN101220252A (en) * | 2008-01-25 | 2008-07-16 | 中北大学 | Solid glue stick and method for producing the same |
| CN101509313A (en) * | 2009-03-17 | 2009-08-19 | 万利环宇（福建）贸易有限公司 | Thermoplastic polyurethane floor tile and technique for producing the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104708978A (en) * | 2013-12-17 | 2015-06-17 | 科森复合材料股份有限公司 | Sheet decoration structure and production method thereof |
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Application publication date: 20130123 |