CN102888171A - Scratch-resistant metal anti-rust paint and preparation method thereof - Google Patents
Scratch-resistant metal anti-rust paint and preparation method thereof Download PDFInfo
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- CN102888171A CN102888171A CN2012103407769A CN201210340776A CN102888171A CN 102888171 A CN102888171 A CN 102888171A CN 2012103407769 A CN2012103407769 A CN 2012103407769A CN 201210340776 A CN201210340776 A CN 201210340776A CN 102888171 A CN102888171 A CN 102888171A
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- 239000003973 paint Substances 0.000 title claims abstract description 48
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 title abstract description 4
- 239000002184 metal Substances 0.000 title abstract description 4
- 230000003678 scratch resistant effect Effects 0.000 title abstract 3
- 239000002994 raw material Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- 239000006185 dispersion Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000004576 sand Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 11
- 238000004537 pulping Methods 0.000 claims description 11
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Diphosphoinositol tetrakisphosphate Chemical compound OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 238000003801 milling Methods 0.000 claims description 6
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 5
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000012188 paraffin wax Substances 0.000 claims description 5
- 239000004584 polyacrylic acid Substances 0.000 claims description 5
- 229920000193 polymethacrylate Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 5
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 5
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 abstract description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000005477 standard model Effects 0.000 description 1
Abstract
The invention discloses scratch-resistant metal anti-rust paint and a preparation method thereof. The scratch-resistant metal anti-rust paint is prepared from slurrying raw materials and paint mixing raw materials; a paint film formed by the anti-rust paint has high hardness, scratch resistance, strong adhesion, salt fog resistance, saline resistance, acid-base resistance, water resistance, and oil resistance; the anti-rust paint can be used on the surface of an old paint film repeatedly; the damage to the paint film can be avoided; and ultra strong toughness of the paint film can be guaranteed. The service life of the common paint film is 8 to 10 years.
Description
Technical field
The present invention relates to a kind of metallic anti-rust paint, specifically a kind of damage resistant metallic anti-rust paint.
Background technology
Various mechanical means appearances all need apply the layer of metal lacquer, and one side increases attractive in appearance, on the other hand dustproof rust resistance and corrosion resistance; Rust-inhibiting paint of the prior art produces poisonous, harmful in a large number volatile gases because containing a large amount of volatile organic solvents, polluted air and infringement human health.The ubiquity weather resistance is not good, easily comes off, inadaptable complicated, severe environment.
Summary of the invention
The invention provides a kind of damage resistant metallic anti-rust paint and preparation method thereof, have good mechanical stability, snappiness and surface hardness, good weatherability.
Technical scheme of the present invention is:
A kind of damage resistant metallic anti-rust paint is characterized in that being made by the feed composition of following ingredients weight parts:
Pulping raw material:
Aluminium scrap powder 3-8, propylene glycol phenylate 1-3, tripropylene glycol methyl ether 5-10, paraffin wax emulsions 1-2, anti-sedimentation agent 3300S 1-2, flow agent BYK-300 1-2, polyacrylic acid sodium salt SN-5000 3-5, dispersion agent LBD-1 1-2, defoamer SPA202 1-2, nano-calcium carbonate 10-15, modified Nano diatomite 5-10, modified soluble nano silicone colloidal sol 5-10;
The paint raw material:
Polyvinylpyrrolidone 10-15, epoxy emulsion 25-30, myo-Inositol hexaphosphate 20-25, sodium polymethacrylate 3-5, Wickenol 116 3-5, fatty alcohol-polyoxyethylene ether 1-2, propylene glycol 50-60,1-phenoxy group-2-propyl alcohol 10-15,2-amino-2-methyl-1-propanol 1-2, Sodium hexametaphosphate 99 1-2;
Modified Nano diatomite prepares by the following method:
(1), diatomite adds (0.8～1.2) g/L potassium permanganate solution and soaked 2-3 hour, pulls out, is washed to neutrality, the sodium radio-phosphate,P-32 solution of putting into again 2-5% soaked, at 60-80 ℃ of lower stirring reaction 3-4 hour;
(2), in soak solution, add 3-4% sodium laurylsulfate, 1-2% Di(dioctylpyrophosphato) ethylene titanate, 2-3% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20-25% ferrophosphorus powder that is equivalent to diatomite weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) oven dry is pulverized, and makes nanometer powder;
Modified soluble nano silicone colloidal sol prepares by the following method:
The water-soluble nano grade silica sol adds 4-5% nano-carbon powder, 3-5% ferric oxide, is mixed and heated to 50-60 ℃, cooling after 30-40 minute.
The metallic anti-rust paint that described anti-outdoor water drenches is characterized in that being made by the feed composition of following ingredients weight parts:
Pulping raw material:
Aluminium scrap powder 6, propylene glycol phenylate 2, tripropylene glycol methyl ether 5, paraffin wax emulsions 2, anti-sedimentation agent 3300S 1, flow agent BYK-300 1, polyacrylic acid sodium salt SN-5000 5, dispersion agent LBD-1 2, defoamer SPA202 1, nano-calcium carbonate 10, modified Nano diatomite 10, modified soluble nano silicone colloidal sol 10;
The paint raw material:
Polyvinylpyrrolidone 10, epoxy emulsion 25, myo-Inositol hexaphosphate 25, sodium polymethacrylate 5, Wickenol 116 3, fatty alcohol-polyoxyethylene ether 1, propylene glycol 60,1-phenoxy group-2-propyl alcohol 15,2-amino-2-methyl-1-propanol 1, Sodium hexametaphosphate 99 2.
The preparation method of the metallic anti-rust paint that described anti-outdoor water drenches is characterized in that may further comprise the steps:
(1), slurrying: pour pulping raw material into batching kettle and mix, then mixed pulping raw material is transported in the high-speed dispersing kettle and stirs, disperse 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after the dispersion is transported to carries out the wet type sand milling in the sand mill, disperse, obtain slurry, the slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add the paint raw material in the slurry that makes, then be transported in the high-speed dispersing kettle and stir, disperse, being transported to of component carried out wet type sand milling, dispersion after disperseing in the sand mill, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) paint vehicle that makes is transported to vibrating filter and filters and screen, fineness≤40um, the product after then will filtering is packed, warehouse-in.
The paint film that rust-inhibiting paint of the present invention forms has hardness height, damage resistant, strong adhesion, and salt spray resistance, salt water resistance, acid and alkali-resistance, water-fast, oil resistant are reusable at old coating surface, can not cause the paint film damage, superpower paint film flexibility etc.The general paint film life-span can reach 8-10.
Embodiment
The metallic anti-rust paint that anti-outdoor water drenches, made by the feed composition of following ingredients weight parts (kilogram):
Pulping raw material:
Aluminium scrap powder 6, propylene glycol phenylate 2, tripropylene glycol methyl ether 5, paraffin wax emulsions 2, anti-sedimentation agent 3300S 1, flow agent BYK-300 1, polyacrylic acid sodium salt SN-5000 5, dispersion agent LBD-1 2, defoamer SPA202 1, nano-calcium carbonate 10, modified Nano diatomite 10, modified soluble nano silicone colloidal sol 10;
The paint raw material:
Polyvinylpyrrolidone 10, epoxy emulsion 25, myo-Inositol hexaphosphate 25, sodium polymethacrylate 5, Wickenol 116 3, fatty alcohol-polyoxyethylene ether 1, propylene glycol 60,1-phenoxy group-2-propyl alcohol 15,2-amino-2-methyl-1-propanol 1, Sodium hexametaphosphate 99 2;
Modified Nano diatomite prepares by the following method:
(1), diatomite adds the 0.8g/L potassium permanganate solution and soaked 2 hours, pulls out, is washed to neutrality, put into again 5% sodium radio-phosphate,P-32 solution and soak, 60-70 ℃ of lower stirring reaction 4 hours;
(2), in soak solution, add 3% sodium laurylsulfate, 2% Di(dioctylpyrophosphato) ethylene titanate, 2% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20% ferrophosphorus powder that is equivalent to diatomite weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) oven dry is pulverized, and makes nanometer powder;
Modified soluble nano silicone colloidal sol prepares by the following method:
The water-soluble nano grade silica sol adds 5% nano-carbon powder, 3% ferric oxide, and mix and blend is heated to 50-60 ℃, cooling after 30-40 minute.
The preparation method of the metallic anti-rust paint that anti-outdoor water drenches:
(1), slurrying: pour pulping raw material into batching kettle and mix, then mixed pulping raw material is transported in the high-speed dispersing kettle and stirs, disperse 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after the dispersion is transported to carries out the wet type sand milling in the sand mill, disperse, obtain slurry, the slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add the paint raw material in the slurry that makes, then be transported in the high-speed dispersing kettle and stir, disperse, being transported to of component carried out wet type sand milling, dispersion after disperseing in the sand mill, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) paint vehicle that makes is transported to vibrating filter and filters and screen, fineness≤40um, the product after then will filtering is packed, warehouse-in.
Metallic anti-rust paint performance index of the present invention:
1, paint film color and outward appearance: smooth smooth, color conformance with standard model and aberration scope
2, (23 ± 1 ℃ are coated with-4 viscometers to viscosity, S): 80-120
3, fineness≤50
4, time of drying (25 ℃): surface drying 25-30min, do solid work 48h
5, snappiness mm≤2
6, hardness 〉=2H
7, high temperature resistant (130 ℃) 〉=450h
8, shock-resistance 50
9, salt spray resistance (120h level) 〉=2
10, water tolerance (29 ± 1 ℃ of 240h): non-foaming, do not come off
11, oil resistant (90# gasoline, 56h): non-foaming, do not come off
12, alkali resistance (GB/T9755-2001): by 48 hours
13, artificial weathering ageing resistance (GB/T9755-2001): by 1000 hours.
Claims (3)
1. damage resistant metallic anti-rust paint is characterized in that being made by the feed composition of following ingredients weight parts:
Pulping raw material:
Aluminium scrap powder 3-8, propylene glycol phenylate 1-3, tripropylene glycol methyl ether 5-10, paraffin wax emulsions 1-2, anti-sedimentation agent 3300S 1-2, flow agent BYK-300 1-2, polyacrylic acid sodium salt SN-5000 3-5, dispersion agent LBD-1 1-2, defoamer SPA202 1-2, nano-calcium carbonate 10-15, modified Nano diatomite 5-10, modified soluble nano silicone colloidal sol 5-10;
The paint raw material:
Polyvinylpyrrolidone 10-15, epoxy emulsion 25-30, myo-Inositol hexaphosphate 20-25, sodium polymethacrylate 3-5, Wickenol 116 3-5, fatty alcohol-polyoxyethylene ether 1-2, propylene glycol 50-60,1-phenoxy group-2-propyl alcohol 10-15,2-amino-2-methyl-1-propanol 1-2, Sodium hexametaphosphate 99 1-2;
Modified Nano diatomite prepares by the following method:
(1), diatomite adds (0.8～1.2) g/L potassium permanganate solution and soaked 2-3 hour, pulls out, is washed to neutrality, the sodium radio-phosphate,P-32 solution of putting into again 2-5% soaked, at 60-80 ℃ of lower stirring reaction 3-4 hour;
(2), in soak solution, add 3-4% sodium laurylsulfate, 1-2% Di(dioctylpyrophosphato) ethylene titanate, 2-3% vinyl three ('beta '-methoxy oxyethyl group) silane, the 20-25% ferrophosphorus powder that is equivalent to diatomite weight, high speed dispersion 4200-4500 rev/min, 20-30 minute;
(3) oven dry is pulverized, and makes nanometer powder;
Modified soluble nano silicone colloidal sol prepares by the following method:
The water-soluble nano grade silica sol adds 4-5% nano-carbon powder, 3-5% ferric oxide, is mixed and heated to 50-60 ℃, cooling after 30-40 minute.
2. the metallic anti-rust paint that drenches of anti-outdoor water according to claim 1 is characterized in that being made by the feed composition of following ingredients weight parts:
Pulping raw material:
Aluminium scrap powder 6, propylene glycol phenylate 2, tripropylene glycol methyl ether 5, paraffin wax emulsions 2, anti-sedimentation agent 3300S 1, flow agent BYK-300 1, polyacrylic acid sodium salt SN-5000 5, dispersion agent LBD-1 2, defoamer SPA202 1, nano-calcium carbonate 10, modified Nano diatomite 10, modified soluble nano silicone colloidal sol 10;
The paint raw material:
Polyvinylpyrrolidone 10, epoxy emulsion 25, myo-Inositol hexaphosphate 25, sodium polymethacrylate 5, Wickenol 116 3, fatty alcohol-polyoxyethylene ether 1, propylene glycol 60,1-phenoxy group-2-propyl alcohol 15,2-amino-2-methyl-1-propanol 1, Sodium hexametaphosphate 99 2.
3. the preparation method of the metallic anti-rust paint that drenches of anti-outdoor water according to claim 1 is characterized in that may further comprise the steps:
(1), slurrying: pour pulping raw material into batching kettle and mix, then mixed pulping raw material is transported in the high-speed dispersing kettle and stirs, disperse 50-60 minute, rotating speed 3200-3500 rev/min, slurrying component after the dispersion is transported to carries out the wet type sand milling in the sand mill, disperse, obtain slurry, the slurry mesh-of-grind is less than or equals 40 microns;
(2) paint: add the paint raw material in the slurry that makes, then be transported in the high-speed dispersing kettle and stir, disperse, being transported to of component carried out wet type sand milling, dispersion after disperseing in the sand mill, obtains paint vehicle; Again with 3200-3600 rev/min of high speed dispersion 40-50min;
(3) paint vehicle that makes is transported to vibrating filter and filters and screen, fineness≤40um, the product after then will filtering is packed, warehouse-in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210340776.9A CN102888171B (en) | 2012-09-15 | 2012-09-15 | A kind of Scratch-resistant metal anti-rust paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210340776.9A CN102888171B (en) | 2012-09-15 | 2012-09-15 | A kind of Scratch-resistant metal anti-rust paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102888171A true CN102888171A (en) | 2013-01-23 |
| CN102888171B CN102888171B (en) | 2016-04-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210340776.9A Active CN102888171B (en) | 2012-09-15 | 2012-09-15 | A kind of Scratch-resistant metal anti-rust paint and preparation method thereof |
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| Country | Link |
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| CN (1) | CN102888171B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589204A (en) * | 2013-10-09 | 2014-02-19 | 芜湖中集瑞江汽车有限公司 | Antirust epoxy paint and preparation method thereof |
| CN114197454A (en) * | 2021-12-17 | 2022-03-18 | 广东劲拓建设工程有限公司 | Construction device and construction method for building foundation cast-in-place pile |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041760A (en) * | 2007-04-25 | 2007-09-26 | 沈阳市航达科技有限责任公司 | Aqueous anticorrosion paint and preparation method thereof |
| CN101781506A (en) * | 2010-02-04 | 2010-07-21 | 复旦大学 | self-cleaning epoxy resin anti-fog coating |
| CN102181219A (en) * | 2011-04-12 | 2011-09-14 | 厦门大学 | Water-based anticorrosive coating of nano montmorillonite and polypyrrole complex and preparation method thereof |
| KR20110135069A (en) * | 2010-06-10 | 2011-12-16 | 엘지이노텍 주식회사 | Anti-fog coating layer and manufacturing method of the same |
-
2012
- 2012-09-15 CN CN201210340776.9A patent/CN102888171B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041760A (en) * | 2007-04-25 | 2007-09-26 | 沈阳市航达科技有限责任公司 | Aqueous anticorrosion paint and preparation method thereof |
| CN101781506A (en) * | 2010-02-04 | 2010-07-21 | 复旦大学 | self-cleaning epoxy resin anti-fog coating |
| KR20110135069A (en) * | 2010-06-10 | 2011-12-16 | 엘지이노텍 주식회사 | Anti-fog coating layer and manufacturing method of the same |
| CN102181219A (en) * | 2011-04-12 | 2011-09-14 | 厦门大学 | Water-based anticorrosive coating of nano montmorillonite and polypyrrole complex and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589204A (en) * | 2013-10-09 | 2014-02-19 | 芜湖中集瑞江汽车有限公司 | Antirust epoxy paint and preparation method thereof |
| CN114197454A (en) * | 2021-12-17 | 2022-03-18 | 广东劲拓建设工程有限公司 | Construction device and construction method for building foundation cast-in-place pile |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102888171B (en) | 2016-04-06 |
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