CN102875122B - Production method for attapulgite fly ash insulation board - Google Patents

Production method for attapulgite fly ash insulation board Download PDF

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Publication number
CN102875122B
CN102875122B CN2012104163600A CN201210416360A CN102875122B CN 102875122 B CN102875122 B CN 102875122B CN 2012104163600 A CN2012104163600 A CN 2012104163600A CN 201210416360 A CN201210416360 A CN 201210416360A CN 102875122 B CN102875122 B CN 102875122B
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China
Prior art keywords
fly ash
attapulgite
heat preservation
insulation board
preservation plate
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Expired - Fee Related
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CN2012104163600A
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Chinese (zh)
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CN102875122A (en
Inventor
李学东
许庆华
许盛英
李文娟
周浩
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Rugao Fan Chuan Trading Co., Ltd.
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XUYI COUNTY DONGQIANG NEW BUILDING MATERIALS FACTORY
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Publication of CN102875122A publication Critical patent/CN102875122A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

The invention discloses a production method for an attapulgite fly ash insulation board. The key points of the technical scheme provided by the invention are that the production method comprises the following steps of: stirring and pressing an accessory of the attapulgite fly ash insulation board to form semi-finished products of the attapulgite fly ash insulation board with different shapes; and conveying the semi-finished products to a tunnel kiln for sintering to obtain a finished product of the attapulgite fly ash insulation board. The accessory of the attapulgite fly ash insulation board consists of high-viscosity attapulgite clay powder, attapulgite clay tailing powder, volcaniclastic rock mixture, fly ash, bentonite tailing powder, diatomite tailing powder and straw powder. The attapulgite fly ash insulation board has the characteristics of favorable flatness, light weight, earthquake resistance, heat insulating, energy saving, sound and heat insulation, fire resistance, flame retardance and reduction of house building load. A large amount of various wastes are adopted in the accessory of the attapulgite fly ash insulation board disclosed by the invention, and thus the improvement on the recycling rate is facilitated and wastes are changed into valuables; and in addition, the occupied land can be reduced, the environment is protected and purified and energy sources are saved. The attapulgite fly ash insulation board is suitable for constructing wall bodies of various buildings.

Description

The production method of Attapulgite fly ash heat preservation plate
Technical field
The present invention relates to building material field, be specifically related to a kind of production method of Attapulgite fly ash heat preservation plate.
Background technology
Mineral Resources in China 80% is intergrowth mineral, and a large amount of valuable resources retain among mine tailing, and tailings impoundment need to take a large amount of soils.A lot of Tailings Dams exceed the time limit or excess load is used, and even violation operation, make Tailings Dam have great potential safety hazard, and people's property and the life security of surrounding area caused to serious threat.
Attapulgite clay, except containing attapulgite, often contains the mineral such as montmorillonite, kaolinite, hydromica, sepiolite, quartz, opal and carbonate.
The volcanoclastic rock that also has with the symbiosis of attapulgite clay ore deposit, volcanoclastic rock is mostly on the upper strata in attapulgite clay ore deposit, the thickness of the volcanoclastic rock ore bed on upper strata, some attapulgite clays mining area is up to tens of rice, attapulgite clay is in recovery process, the volcanoclastic rock on upper strata, attapulgite clay mining area is abandoned as waste, investigate factually, the volcanoclastic rock that 1 ton of attapulgite clay of every exploitation produces has more than 30 tons, by the output of producing 150000 tons per year, calculate, the volcanoclastic rock produced is up to 4,500,000 tons, all can be utilized for many years, whole mining area is the volcanoclastic rock mixture of again piling up everywhere, cause the serious wasting of resources and financial loss.
Flyash is to receive the thin ash of catching in the flue gas from coal combustion, flyash is also the main solid waste that coal-burning power plant discharges, be one of industrial residue that the current discharge capacity of China is larger, along with the development of power industry, the flyash quantity discharged of coal-burning power plant increases year by year.A large amount of flyash does not add processing, will produce airborne dust, atmosphere pollution; If enter water system, can cause river to silt up, toxic chemical substance wherein also can work the mischief to human body and biology.
Summary of the invention
The objective of the invention is to overcome weak point in prior art, a kind of production method of Attapulgite fly ash heat preservation plate is provided.
The production method of Attapulgite fly ash heat preservation plate: the batching of Attapulgite fly ash heat preservation plate, through stirring, is pressed into to difform Attapulgite fly ash heat preservation plate work in-process, is transported to the finished product that tunnel kiln sintering becomes the Attapulgite fly ash heat preservation plate.The batching of Attapulgite fly ash heat preservation plate is comprised of the sticky attapulgite clay powder of height, attapulgite clay mine tailing, volcanoclastic rock mixture, flyash, wilkinite mine tailing, diatomite mine tailing and straw powder.
Attapulgite clay be a kind of layer of chain-like structure containing Shuifu County's zeopan clay mineral, attapulgite clay soil property exquisiteness, water-absorbent is strong, tool viscosity and plasticity-when wet, be conducive to the bonding between raw material, and can improve intensity and the porosity of Attapulgite fly ash heat preservation plate.
High sticky attapulgite clay powder refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, the suspension cup is placed on homogenizer, under the rotating speed of 11000 rev/mins, stir 20 minutes, to pour in the beaker of 250ml through the high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to be tested its suspension, tested viscosity value>=2200 into mPasthe attapulgite clay powder be high sticky attapulgite clay powder, the height that the present invention selects glues attapulgite clay powder particles fineness≤0.074 millimeter.
Attapulgite clay can mix in recovery process a certain amount of rubble and earth, can't be sieved, and as a kind of mine tailing, abandons, and causes a large amount of wastings of resources, and the present invention selects the attapulgite clay mine tailing after pulverizing, particle fineness≤0.149 millimeter.
Volcanoclastic rock is the rock of the transitional type between magma lava and sedimentogeneous rock, wherein the composition more than 50% is comprised of the material of pyroclastic flow ejection, and these tephras are mainly the lava of premature coagulation on volcano, the rock formation that passage is burst on every side when volcanic eruption.The volcanoclastic rock mixture comprises landwaste, brilliant bits, glassiness bits, slurry bits, volcanic block, volcanic gravel and volcanic ash, volcanoclastic rock can increase the intensity of Attapulgite fly ash heat preservation plate, the present invention selects the volcanoclastic rock mixture after pulverizing, particle fineness≤3.0 millimeter.
The flyash main component is silicon-dioxide, aluminium sesquioxide, ferric oxide, calcium oxide and unburnt carbon, do not fire charcoal and be loose porous form more, can increase the porosity of Attapulgite fly ash heat preservation plate and reduce energy consumption, the present invention selects the flyash after pulverizing, particle fineness≤0.25 millimeter.
Wilkinite has plasticity-and agglutinating value(of coal), and the wilkinite mine tailing that the present invention selects is distributed in the lower floor in attapulgite clay ore deposit mostly, is difficult to carry out independent exploitation, quality is also poor, major part is abandoned in the mine tailing district, and the present invention selects the wilkinite mine tailing after pulverizing, particle fineness≤0.25 millimeter.
Diatomite is fine and smooth, loose, light weight, porous, specific surface area is large, and space is regular distribution, stable chemical nature, it is a kind of natural nano aperture amorphous silicon material, but diatomite is made a low multiple use, most products come from one-level soil, and two, three grades of soil are discarded in a large number, caused serious waste of resources, also polluted environment, the present invention selects the diatomite mine tailing after pulverizing, particle fineness≤0.25 millimeter.
Stalk is the general name of ripe farm crop cauline leaf (fringe) part, is often referred to wheat, paddy rice, corn, potato class, oil plant, cotton, sugarcane and other farm crop remainder after the results seed.It is in order to increase the porosity of Attapulgite fly ash heat preservation plate that the present invention adopts straw powder, the Attapulgite fly ash heat preservation plate is in roasting process, and the straw burning in warming plate is ashes, forms a large amount of micropores, the present invention selects the straw powder after pulverizing, particle fineness≤1.0 millimeter.
The present invention is achieved by following technical proposals:
1, the production method of Attapulgite fly ash heat preservation plate: (1) the batching of Attapulgite fly ash heat preservation plate is added in the two shaft pugmill mixer moved and stirs, be transported to after stirring in pressing machine, be pressed into difform Attapulgite fly ash heat preservation plate work in-process; (2) work in-process are sent into to dry in room and carried out nature and dry, be transported to the tunnel furnace roasting after half-finished water ratio≤15%; (3) be divided into three phases in roasting process: the first stage maturing temperature is controlled at 30~300 ℃, and roasting time is controlled at 3~6 hours; The subordinate phase maturing temperature is controlled at 300~800 ℃, and roasting time is controlled at 4~12 hours; The phase III maturing temperature is controlled at 800~1150 ℃, and roasting time is controlled at 3~8 hours; (4) naturally cooling after sintering, be packaged as the finished product of Attapulgite fly ash heat preservation plate;
The batching of described Attapulgite fly ash heat preservation plate is comprised of following component by weight percentage: high sticky attapulgite clay powder 2~15%, attapulgite clay mine tailing 5~25%, volcanoclastic rock mixture 5~25%, flyash 5~35%, wilkinite mine tailing 5~15%, diatomite mine tailing 2~10%, straw powder 2~10% and water 10~35%;
Describedly be pressed into difform Attapulgite fly ash heat preservation plate work in-process, refer to the Attapulgite fly ash heat preservation plate work in-process that need to be pressed into square, rectangle, trilateral, ellipse, trapezoidal, quincunx or rhombus according to design;
Described half-finished water ratio per-cent is weight ratio.
Be divided into three phases in Attapulgite fly ash heat preservation plate roasting process, be conducive to slowly improve maturing temperature, guarantee the quality of product.
The Attapulgite fly ash heat preservation plate has that planeness is good, the characteristics of light weight antidetonation, heat preservation energy-saving, sound-insulating and heat-insulating, fire protection flame retarding and reduction building construction load.
In the batching of Attapulgite fly ash heat preservation plate, the various wastes of a large amount of employing, not only be conducive to improve resource utilization, turns waste into wealth, and can also reduce land occupation, and protection and environment purification are saved the energy, reduce production costs, and increase economic efficiency.
The Attapulgite fly ash heat preservation plate is applicable to the wall construction of various buildings .
Embodiment
Below in conjunction with embodiment, the invention will be further described:
1, the production method of Attapulgite fly ash heat preservation plate: (1) the batching of Attapulgite fly ash heat preservation plate is added in the two shaft pugmill mixer moved and stirs, be transported to after stirring in pressing machine, be pressed into difform Attapulgite fly ash heat preservation plate work in-process; (2) work in-process are sent into to dry in room and carried out nature and dry, be transported to the tunnel furnace roasting after half-finished water ratio≤15%; (3) be divided into three phases in roasting process: the first stage maturing temperature is controlled at 30~300 ℃, and roasting time is controlled at 6 hours; The subordinate phase maturing temperature is controlled at 300~800 ℃, and roasting time is controlled at 10 hours; The phase III maturing temperature is controlled at 800~1150 ℃, and roasting time is controlled at 5 hours; (4) naturally cooling after sintering, be packaged as the finished product of Attapulgite fly ash heat preservation plate;
The batching of described Attapulgite fly ash heat preservation plate is comprised of following component by weight percentage: high sticky attapulgite clay powder 8%, attapulgite clay mine tailing 16%, volcanoclastic rock mixture 16%, flyash 20%, wilkinite mine tailing 6%, diatomite mine tailing 4%, straw powder 2% and water 28%;
Describedly be pressed into difform Attapulgite fly ash heat preservation plate work in-process, refer to according to design and need to be pressed into foursquare Attapulgite fly ash heat preservation plate work in-process.

Claims (1)

1. the production method of an Attapulgite fly ash heat preservation plate, it is characterized in that, (1) the batching of Attapulgite fly ash heat preservation plate is added in the two shaft pugmill mixer moved and stirs, be transported to after stirring in pressing machine, be pressed into difform Attapulgite fly ash heat preservation plate work in-process; (2) work in-process are sent into to dry in room and carried out nature and dry, be transported to the tunnel furnace roasting after half-finished water ratio≤15%; (3) be divided into three phases in roasting process: the first stage maturing temperature is controlled at 30~300 ℃, and roasting time is controlled at 3~6 hours; The subordinate phase maturing temperature is controlled at 300~800 ℃, and roasting time is controlled at 4~12 hours; The phase III maturing temperature is controlled at 800~1150 ℃, and roasting time is controlled at 3~8 hours; (4) naturally cooling after sintering, be packaged as the finished product of Attapulgite fly ash heat preservation plate;
The batching of described Attapulgite fly ash heat preservation plate is comprised of following component by weight percentage: high sticky attapulgite clay powder 2~15%, attapulgite clay mine tailing 5~25%, volcanoclastic rock mixture 5~25%, flyash 5~35%, wilkinite mine tailing 5~15%, diatomite mine tailing 2~10%, straw powder 2~10% and water 10~35%;
Describedly be pressed into difform Attapulgite fly ash heat preservation plate work in-process, refer to the Attapulgite fly ash heat preservation plate work in-process that need to be pressed into square, rectangle, trilateral, ellipse, trapezoidal, quincunx or rhombus according to design;
The sticky attapulgite clay powder of described height refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, the suspension cup is placed on homogenizer, under the rotating speed of 11000 rev/mins, stir 20 minutes, to pour in the beaker of 250ml through the high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to be tested its suspension, tested viscosity value>=2200 into mPasthe attapulgite clay powder be high sticky attapulgite clay powder, the height of selecting glues attapulgite clay powder particles fineness≤0.074 millimeter.
CN2012104163600A 2012-10-27 2012-10-27 Production method for attapulgite fly ash insulation board Expired - Fee Related CN102875122B (en)

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CN104788117A (en) * 2015-02-15 2015-07-22 宁夏黑金科技有限公司 High-strength microcrystal foaming fireproof thermal-insulation plate produced by using attapulgite, coal gangue and graphite, and production process thereof
CN105801078A (en) * 2016-03-10 2016-07-27 于博骞 Fly ash environment-friendly composite wallboard and production method thereof
CN108164193A (en) * 2018-01-04 2018-06-15 童彬原 A kind of environmental protection integrated board and preparation method thereof

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JP5232984B2 (en) * 2007-07-04 2013-07-10 荒木窯業株式会社 Porous brick and method for producing the same
CN102515837B (en) * 2011-11-10 2013-04-17 许庆华 Spherical attapulgite bed silt ceramsites
CN102515633B (en) * 2011-11-10 2013-04-17 许庆华 Baking-free cylindrical attapulgite river bottom mud ceramisites

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Owner name: RUGAO FANCHUAN TRADING CO., LTD.

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Address after: 226500, No. 8, Changjiang East Road, Changjiang Town, Rugao, Jiangsu, Nantong

Patentee after: Rugao Fan Chuan Trading Co., Ltd.

Address before: 211700 Huaian city goussen Mo Jian village in Jiangsu province Xuyi County Township

Patentee before: Xuyi County Dongqiang New Building Materials Factory

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CF01 Termination of patent right due to non-payment of annual fee