CN102870794A - Sterilization composition for preventing rice sheath blight disease - Google Patents

Sterilization composition for preventing rice sheath blight disease Download PDF

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Publication number
CN102870794A
CN102870794A CN2012104012795A CN201210401279A CN102870794A CN 102870794 A CN102870794 A CN 102870794A CN 2012104012795 A CN2012104012795 A CN 2012104012795A CN 201210401279 A CN201210401279 A CN 201210401279A CN 102870794 A CN102870794 A CN 102870794A
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China
Prior art keywords
thifluzamide
albendazole
sheath blight
rice sheath
blight disease
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CN2012104012795A
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Chinese (zh)
Inventor
吉沐祥
缪康
赵来成
束兆林
王莉莉
吴祥
邵春
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Zhenjiang Institute of Agricultural Sciences Jiangsu Hilly Area
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Zhenjiang Institute of Agricultural Sciences Jiangsu Hilly Area
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Priority to CN2012104012795A priority Critical patent/CN102870794A/en
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Abstract

The invention belongs to the field of pesticide, and particularly relates to a sterilization composition for preventing a rice sheath blight disease. The sterilization composition includes effective ingredients of thifluzamide and albendazole, and the mass ratio of the thifluzamide to the albendazole is (1:20) to (20:1). The sterilization composition disclosed by the invention has good control effect on the banded sclerotial blight of the rice, and has the following significant effects and advantages that 1, the sterilization effect is improved after the thifluzamide and the albendazole are mixed, and the use dosage is reduced; 2, agent characteristics are subjected to complementary advantages after the thifluzamide and the albendazole are mixed, and drug use of a peasant is facilitated; and 3, the thifluzamide and the albendazole have a little of poison without residue and have significance in resistance and comprehensive treatment of a disease.

Description

Prevent and treat the bactericidal composition of rice sheath blight disease
Technical field
The invention belongs to pesticide field, specifically a kind of bactericidal composition of preventing and treating rice sheath blight disease.
Background technology
Control paddy rice rice sheath blight disease mainly relies on chemical agent in the at present agricultural production, existing common fungicide jinggangmeisu and triazole type medicament are (such as Difenoconazole, propiconazole, azoles is pure, alkene azoles alcohol etc.) pesticide resistance is in various degree arranged, in the production by increasing the bactericide property of medicine, according to incompletely statistics, annual medicament for preventing and treating rice sheath blight disease reaches tons up to ten thousand, this has not only caused serious paddy field ecotope and water pollution, and directly increased the residual of toxic chemical substance in the rice, human health is threatened, and the excessive use of triazole type medicament can suppress fertility, affect Rice Heading, easily produce " luxuriant neck " phenomenon, produce at present some the external imported products such as the single preparation of thifluzamide (full fringe) that are using, cost is too high, the peasant can not accept, and reuses for a long time and can develop immunity to drugs.Therefore, " good quality and high output ' with " safety " become contradiction very outstanding in the Rice Production.
Thifluzamide also claims thifluzamide, and English common name Trifluzamide belongs to the thiazole amide bactericide, has strong interior conductivity and the long lasting effect of inhaling.Thifluzamide is the succinate dehydrogenase inhibitor, because fluorine-containing, its competitiveness in biochemical pathway is very strong, in case be combined with regard to difficult recovery with substrate or enzyme.Thifluzamide has special efficacy to the fungus-caused disease of Basidiomycetes such as banded sclerotial blight, damping off etc., and the pathomycetes such as Rhizoctonia, Puccinia, Ustilago, Tilletia, corticium, nuclear cavity Pseudomonas are also all had good preventive effect.
Albendazole also claims albendazole, and English common name Albendazole is a kind of wide spectrum systemic fungicide of efficient, low toxicity, has protection and therapeutic action, and the pathogen spore germination is had stronger inhibitory action.Its main mechanism is similar to Benzimidazole fungicides.Fungicidal spectrum is wider, and the crop pest that especially multiple basidiomycetes and imperfect fungus is caused is effective, and also effective to some bacterial diseases.
Have not yet to see be used to what prevent and treat crop pest and comprise thifluzamide and albendazole bactericidal composition.
Summary of the invention
Technical problem to be solved by this invention is that a kind of bactericidal composition of preventing and treating rice sheath blight disease of preventing and treating rice sheath blight disease, reduction pathogen pesticide resistance, reducing drug cost that can be used in is provided.
Bactericidal composition active ingredient of preventing and treating rice sheath blight disease of the present invention is thifluzamide and albendazole, the mass ratio of thifluzamide and albendazole is at 1:20 ~ 20:1, preferred proportion is at 1:10 ~ 10:1, the mass percentage content of active ingredient in preparation is 1% ~ 60%, be preferably 15% ~ 60%, all the other are to allow in the agricultural chemicals to use and the acceptable auxiliary element.Under better formula, rice sheath blight disease controlling is reached preferably effect.
The present composition can be prepared into by the method that oneself knows any one formulation that is fit to agricultural use, and reasonable formulation is suspending agent, aqueous emulsion, wetting powder, water dispersible granules.
The auxiliary agent that uses in the composition of the present invention comprises that solvent, dispersant, stabilizing agent, antifreezing agent, thickener etc. reach other and be of value to the known substance that active ingredient is stablized and drug effect is brought into play in preparation, all be various compositions commonly used in the pesticidal preparations or that permission is used, be not particularly limited, concrete composition and consumption require to determine by test according to prescription.
Composition of the present invention also can use with other compound with weeding, desinsection or bactericidal property, also can mix use with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Bactericidal composition of the present invention has good preventive effect to the banded sclerotial blight of paddy rice, and has following remarkable result and advantage: the one, after thifluzamide and albendazole are mixed, improved bactericidal effect, and lowered using dosage; The 2nd, after thifluzamide and albendazole were mixed, the medicament characteristic had obtained mutual supplement with each other's advantages, made things convenient for peasant's medication; The 3rd, thifluzamide and albendazole be mixed rear little poison, noresidue, significant to resistance and the comprehensive regulation of disease.
Embodiment
In the embodiment of the invention, thifluzamide proportionings different from albendazole are to rice sheath blight disease toxicity test result such as following table:
Figure BDA00002276957100031
As can be seen from the table, thifluzamide and albendazole are mixed, and in mass ratio is the scope of 1:10~10:1, rice sheath blight disease are all shown as synergistic effect.Thifluzamide and albendazole are mixed and have reasonability and feasibility.
The present composition can be prepared into by the method that oneself knows any one formulation that is fit to agricultural use, comprises suspending agent, aqueous emulsion, wetting powder, water dispersible granules; The auxiliary agent that uses comprises that dispersant, wetting agent, emulsifier, antifreezing agent, thickener etc. reach other and be of value to the known substance that active ingredient is stablized and drug effect is brought into play in preparation, all is the various compositions of commonly using or allow use in the pesticidal preparations, is not particularly limited; The carrier that the present composition comprises can make fixing or liquid, can use any usually in preparation desinsection, bactericidal composition used any carrier all can use.
Surfactant can be wetting agent, dispersant or emulsifier, and they can be ionic or nonionic.Wetting agent is natural products wetting agent and cationic wetting agent, such as Tea Saponin, silkworm excrement, bay alcohol radical sodium sulphate, sodium dodecyl benzenylsulfonate, pull open in powder etc. one or more; Dispersant is industrial by-products and anionic dispersing agent, for example lignosulfite, lignin and derivative sulfonate thereof, one or more in the bitter edible plant and alkyl bitter edible plant methyl alcohol condensate sulfonates, the alkylsulfonate: emulsifier mainly comprises nonionic emulsifier such as polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fat glue, ethoxylated castor oil and anionic emulsifier etc.
Thickener has natural and synthetic, such as water-soluble high-molecular compound and water-soluble resin gum Arabic, xanthans, methylcellulose, carboxymethyl cellulose etc.; Antifreezing agent requires resistance to frost good, and volatility is low and little to active ingredient solvability, and commonly used have ethylene glycol, propane diols, a glycerine etc.; Defoamer comprises organic silicone, C8-10 fatty alcohol, CIO-20 representative examples of saturated aliphatic carboxylic and ester class thereof, ester one ether type compound etc., organic silicone commonly used and ester-ether type defoamer.
Suitable solid carrier comprises natural sticking scholar, silicate, magnesium silicate, Magnesiumaluminumsilicate, alumina silicate, calcium carbonate, calcium sulphate, ammonium sulfate, synthetic hydrated silica and synthetic calcium silicates or alumina silicate.The solid carrier that is particularly suitable for pulvis comprises the rock dust of natural formation, for example attapulgite, bentonite, montmorillonite, diatomite; Synthetic mineral matter and microdispersed silicic acid or the aluminium oxide of grinding.
Suitable liquid-carrier comprises water and organic solvent.Water can be used as solvent or thinner, and organic solvent also can be as auxiliary cosolvent or stabilization additives, and suitable organic solvent comprises aromatic hydrocarbons, for example toluene, dimethylbenzene, benzene Fluhyzon and chlorinated aromatic hydrocarbons, chloro aliphatic hydrocarbon, aliphatic hydrocarbon.Particularly suitable be polar solvent, for example isopropyl alcohol of alcohols, butanols, ethylene glycol, cyclohexanol, ketone such as acetone, MEK, cyclohexanone, dimethyl formamide, dimethyl sulfoxide (DMSO) and N monomethyl adjoin pyrrolidone.Different liquid mixtures often are suitable for.
In order to understand better invention essence, the below describes the technology contents of invention in detail with example, but the purposes of preventing and treating of the present invention is not limited to this.Percentage in the following example is the mass percent in the preparation.
Embodiment 1:15% thifluzamide albendazole suspending agent
Figure BDA00002276957100051
By the prescription requirement, take water as medium, former medicine, dispersant, suspending agent and antifreezing agent etc. are joined mix in the batching kettle, after ball mill or just pulverizing of clipper, porphyrize in the sand milling still is made suspending agent, through after the assay was approved, carrying out metering, distributing, packaging is finished product.
Use 20~30 g/acres of this mixtures to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 84.3%~89.2% behind the medicine.
Embodiment 2:35% thifluzamide albendazole suspending agent
Figure BDA00002276957100052
Figure BDA00002276957100061
By the prescription requirement, take water as medium, former medicine, dispersant, suspending agent and antifreezing agent etc. are joined mix in the batching kettle, after ball mill or just pulverizing of clipper, porphyrize in the sand milling still is made suspending agent, through after the assay was approved, carrying out metering, distributing, packaging is finished product.
Use 20~30 g/acres of this mixtures to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 75.7%~83.7% behind the medicine.
Embodiment 3:44% thifluzamide albendazole suspending agent
Figure BDA00002276957100062
By the prescription requirement, take water as medium, former medicine, dispersant, suspending agent and antifreezing agent etc. are joined mix in the batching kettle, after ball mill or just pulverizing of clipper, porphyrize in the sand milling still is made suspending agent, through after the assay was approved, carrying out metering, distributing, packaging is finished product.
Use 30-40 g/acre of this mixture to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 74.6%~85.2% behind the medicine.
Embodiment 4:30% thifluzamide albendazole wetting powder
Figure BDA00002276957100071
By the prescription requirement, mix pulverize by Roughpulverizer after, enter airslide disintegrating mill and fully be pulverized and mixed, through after the assay was approved, automatically be packaged to be wetting powder.
Use 30-40 g/acre of this mixture to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 73.6%~83.3% behind the medicine.
Embodiment 5:45% thifluzamide albendazole wetting powder
Figure BDA00002276957100072
By the prescription requirement, mix pulverize by Roughpulverizer after, enter airslide disintegrating mill and fully be pulverized and mixed, through after the assay was approved, automatically be packaged to be wetting powder.
Use 20-30 g/acre of this mixture to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 80.4%~91.2% behind the medicine.
Agent is drawn in the aqueous dispersion of embodiment 6:45% thifluzamide albendazole
By the prescription requirement, former medicine, dispersant, wetting agent, disintegrant, filler etc. are mixed through air-flow crushing become wetting powder, then add suitable quantity of water and carry out granulation and obtain water dispersible granules.
Use 20~30 g/acres of this mixtures to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 83.5%-~92.4% behind the medicine.
Agent is drawn in the aqueous dispersion of embodiment 7:60% thifluzamide albendazole
Figure BDA00002276957100082
By the prescription requirement, former medicine, dispersant, wetting agent, disintegrant, filler etc. are mixed through air-flow crushing become wetting powder, then add suitable quantity of water and carry out granulation and obtain water dispersible granules.
Use 10~20 g/acres of this mixtures to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 87.7%-~92.6% behind the medicine.
Embodiment 8:20% thifluzamide albendazole aqueous emulsion
Figure BDA00002276957100091
By the prescription requirement, take water as medium, the auxiliary agents such as former medicine, emulsifier, dispersant are joined in the batching kettle, mix through high-speed shearing machine and make aqueous emulsion, through after the assay was approved, carrying out metering, distributing, packaging is finished product.
Use 30~40 g/acres of this mixtures to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 82.4%%-~84.4% behind the medicine
Embodiment 9:30% thifluzamide albendazole aqueous emulsion
Figure BDA00002276957100092
By the prescription requirement, take water as medium, the auxiliary agents such as former medicine, emulsifier, dispersant are joined in the batching kettle, mix through high-speed shearing machine and make aqueous emulsion, through after the assay was approved, carrying out metering, distributing, packaging is finished product.
Use 30~40 g/acres of this mixtures to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 82.6%%-~87.8% behind the medicine
Comparative example 1
30% thifluzamide suspending agent
Figure BDA00002276957100101
By the prescription requirement, take water as medium, former medicine, dispersant, suspending agent and antifreezing agent etc. are joined mix in the batching kettle, after ball mill or just pulverizing of clipper, porphyrize in the sand milling still is made suspending agent, through after the assay was approved, carrying out metering, distributing, packaging is finished product.
Use 20~30 g/acres of this agent to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 86.2%~95.1% behind the medicine.
Comparative example 2
20% albendazole suspending agent
Figure BDA00002276957100102
Figure BDA00002276957100111
By the prescription requirement, take water as medium, former medicine, dispersant, suspending agent and antifreezing agent etc. are joined mix in the batching kettle, after ball mill or just pulverizing of clipper, porphyrize in the sand milling still is made suspending agent, through after the assay was approved, carrying out metering, distributing, packaging is finished product.
Use 80~100 g/acres of this agent to be watered even spraying and prevent and treat rice sheath blight disease, 14 days control efficiency reach 70.6%~85.3% behind the medicine.
By upper embodiment and comparative example as can be known, thifluzamide and albendazole are mixed, and have the notable synergistic effect.

Claims (5)

1. bactericidal composition of preventing and treating rice sheath blight disease, it is characterized in that: its active ingredient is thifluzamide and albendazole, thifluzamide and albendazole mass ratio are 1:20~20:1.
2. the bactericidal composition of preventing and treating rice sheath blight disease according to claim 1 is characterized in that: thifluzamide and albendazole mass ratio are 1:10 ~ 10: 1.
3. the bactericidal composition of preventing and treating rice sheath blight disease according to claim 1 and 2 is characterized in that: the mass percentage content of its active ingredient in preparation is between 1% ~ 60%, and all the other are to allow in the agricultural chemicals to use and the acceptable auxiliary element.
4. the bactericidal composition of preventing and treating rice sheath blight disease according to claim 3, it is characterized in that: its formulation is suspending agent, aqueous emulsion, wetting powder or water dispersible granules.
5. the purposes of a bactericidal composition claimed in claim 1 is characterized in that: be used for preventing and treating rice sheath blight disease.
CN2012104012795A 2012-10-19 2012-10-19 Sterilization composition for preventing rice sheath blight disease Pending CN102870794A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105076179A (en) * 2015-09-04 2015-11-25 广东中迅农科股份有限公司 Pesticide composition containing albendazole and iprodione
CN105123723A (en) * 2015-09-09 2015-12-09 江苏省绿盾植保农药实验有限公司 Bactericidal composition containing boscalid and albendazole
CN106818801A (en) * 2017-03-02 2017-06-13 贵州道元生物技术有限公司 The bactericide for preventing and treating rice sheath blight disease is compounded with rosickyite azoles and thifluzamide
CN106942248A (en) * 2017-04-12 2017-07-14 江苏金凤凰农化有限公司 A kind of composition and application process that rice sheath blight disease is treated based on guaiacol
CN107232215A (en) * 2017-05-31 2017-10-10 句容市农业技术推广中心 A kind of composition pesticide for preventing and treating rice blast

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101755825A (en) * 2009-11-23 2010-06-30 陈章艳 Bactericide composition containing thifluzamide
CN101828564A (en) * 2010-06-02 2010-09-15 陕西上格之路生物科学有限公司 Agricultural sterilizing composite containing thifluzamide
CN101828559A (en) * 2010-06-02 2010-09-15 陕西上格之路生物科学有限公司 Agricultural sterilizing composite containing thifluzamide
CN101856026A (en) * 2010-05-27 2010-10-13 浙江省桐庐汇丰生物化工有限公司 Pyrimidine nucleotide antibiotic and trifluzamide combined bactericide
CN102657186A (en) * 2012-04-24 2012-09-12 杭州宇龙化工有限公司 Bactericidal composition containing thifluzamide and prothioconazole
CN102669160A (en) * 2012-04-28 2012-09-19 广东中迅农科股份有限公司 Sterilization composite containing thifluzamide and flusilazole
CN102771486A (en) * 2012-08-16 2012-11-14 林宝峰 Sterilization composition used for preventing and controlling rice sheath blight disease

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101755825A (en) * 2009-11-23 2010-06-30 陈章艳 Bactericide composition containing thifluzamide
CN101856026A (en) * 2010-05-27 2010-10-13 浙江省桐庐汇丰生物化工有限公司 Pyrimidine nucleotide antibiotic and trifluzamide combined bactericide
CN101828564A (en) * 2010-06-02 2010-09-15 陕西上格之路生物科学有限公司 Agricultural sterilizing composite containing thifluzamide
CN101828559A (en) * 2010-06-02 2010-09-15 陕西上格之路生物科学有限公司 Agricultural sterilizing composite containing thifluzamide
CN102657186A (en) * 2012-04-24 2012-09-12 杭州宇龙化工有限公司 Bactericidal composition containing thifluzamide and prothioconazole
CN102669160A (en) * 2012-04-28 2012-09-19 广东中迅农科股份有限公司 Sterilization composite containing thifluzamide and flusilazole
CN102771486A (en) * 2012-08-16 2012-11-14 林宝峰 Sterilization composition used for preventing and controlling rice sheath blight disease

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105076179A (en) * 2015-09-04 2015-11-25 广东中迅农科股份有限公司 Pesticide composition containing albendazole and iprodione
CN105076179B (en) * 2015-09-04 2018-05-18 广东中迅农科股份有限公司 A kind of composition pesticide containing rosickyite azoles and iprodione
CN105123723A (en) * 2015-09-09 2015-12-09 江苏省绿盾植保农药实验有限公司 Bactericidal composition containing boscalid and albendazole
CN106818801A (en) * 2017-03-02 2017-06-13 贵州道元生物技术有限公司 The bactericide for preventing and treating rice sheath blight disease is compounded with rosickyite azoles and thifluzamide
CN106942248A (en) * 2017-04-12 2017-07-14 江苏金凤凰农化有限公司 A kind of composition and application process that rice sheath blight disease is treated based on guaiacol
CN107232215A (en) * 2017-05-31 2017-10-10 句容市农业技术推广中心 A kind of composition pesticide for preventing and treating rice blast

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Application publication date: 20130116