CN102863861B - Water-borne on rust coating and preparation method thereof - Google Patents
Water-borne on rust coating and preparation method thereof Download PDFInfo
- Publication number
- CN102863861B CN102863861B CN201210377753.5A CN201210377753A CN102863861B CN 102863861 B CN102863861 B CN 102863861B CN 201210377753 A CN201210377753 A CN 201210377753A CN 102863861 B CN102863861 B CN 102863861B
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- Prior art keywords
- rust
- water
- preparation
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- acrylate emulsion
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- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title abstract description 26
- 239000011248 coating agent Substances 0.000 title abstract description 13
- 238000000576 coating method Methods 0.000 title abstract description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 29
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000003973 paint Substances 0.000 claims description 29
- 238000006116 polymerization reaction Methods 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 238000004581 coalescence Methods 0.000 claims description 15
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid group Chemical group C(C(=O)O)(=O)O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 14
- 239000000049 pigment Substances 0.000 claims description 14
- 230000001131 transforming effect Effects 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 12
- 230000008719 thickening Effects 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 239000004160 Ammonium persulphate Substances 0.000 claims description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 7
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 7
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical class CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 7
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical group OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims description 5
- 239000001263 FEMA 3042 Substances 0.000 claims description 5
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims description 5
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 5
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 claims description 5
- 229940033123 tannic acid Drugs 0.000 claims description 5
- 235000015523 tannic acid Nutrition 0.000 claims description 5
- 229920002258 tannic acid Polymers 0.000 claims description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 claims description 3
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical class OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims description 2
- 239000010408 film Substances 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 abstract description 11
- 239000010959 steel Substances 0.000 abstract description 11
- 230000015572 biosynthetic process Effects 0.000 abstract description 6
- 239000012528 membrane Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 230000007246 mechanism Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 238000012216 screening Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 229910052742 iron Inorganic materials 0.000 description 10
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- -1 phenolic aldehyde Chemical class 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 230000003405 preventing effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210377753.5A CN102863861B (en) | 2012-09-30 | 2012-09-30 | Water-borne on rust coating and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201210377753.5A CN102863861B (en) | 2012-09-30 | 2012-09-30 | Water-borne on rust coating and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN102863861A CN102863861A (en) | 2013-01-09 |
CN102863861B true CN102863861B (en) | 2014-12-24 |
Family
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Family Applications (1)
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CN201210377753.5A Active CN102863861B (en) | 2012-09-30 | 2012-09-30 | Water-borne on rust coating and preparation method thereof |
Country Status (1)
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CN (1) | CN102863861B (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104031482A (en) * | 2013-03-06 | 2014-09-10 | 山西鑫山生物工程集团有限公司 | Environment friendly persimmon base membrane |
CN103483937B (en) * | 2013-09-26 | 2016-01-20 | 无锡阳工机械制造有限公司 | A kind of rust-inhibiting paint |
CN103938196B (en) * | 2014-04-16 | 2016-09-14 | 武汉科迪奥电力科技有限公司 | A kind of structural steel aqueous band rust treatment fluid and preparation method thereof in situ |
CN103897510B (en) * | 2014-04-22 | 2016-05-11 | 西南大学 | Water-based antirusting paint operable with rust and preparation method thereof |
CN104046149B (en) * | 2014-07-01 | 2016-04-06 | 国家电网公司 | A kind of waterborne rusted paint and preparation method thereof |
CN104530878A (en) * | 2014-11-20 | 2015-04-22 | 马鞍山市金韩涂料制造有限公司 | Environmental-friendly rust conversion and prevention paint |
CN105925092A (en) * | 2016-06-24 | 2016-09-07 | 无锡伊佩克科技有限公司 | Waterborne over-rust coating for steel and preparation method thereof |
CN106747654B (en) * | 2016-11-25 | 2019-04-19 | 深圳大学 | A kind of concrete protectant, concrete protection film and preparation method thereof |
CN108329767A (en) * | 2018-03-13 | 2018-07-27 | 泰州市杰诚新材料有限公司 | A kind of water nano Corrosion resisting paint without need of cleaning rust |
CN112625528B (en) * | 2020-12-19 | 2022-08-30 | 常州市武进吉丹洗涤剂有限公司 | Water-based rapid rust removing and preventing agent suitable for steel surface |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1709931A (en) * | 2004-06-18 | 2005-12-21 | 何一军 | Method for preparing anti-bacteria, water-proof and anti-ageing nano propyl-phenyl emulsion |
CN101921516A (en) * | 2009-10-28 | 2010-12-22 | 北京航空航天大学 | Aqueous antiseptic transparent coating suitable for steel surface and preparation method thereof |
-
2012
- 2012-09-30 CN CN201210377753.5A patent/CN102863861B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1709931A (en) * | 2004-06-18 | 2005-12-21 | 何一军 | Method for preparing anti-bacteria, water-proof and anti-ageing nano propyl-phenyl emulsion |
CN101921516A (en) * | 2009-10-28 | 2010-12-22 | 北京航空航天大学 | Aqueous antiseptic transparent coating suitable for steel surface and preparation method thereof |
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Publication number | Publication date |
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CN102863861A (en) | 2013-01-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
ASS | Succession or assignment of patent right |
Owner name: HEFEI HUAQING FANGXING SURFACE TECHNOLOGY CO., LTD Free format text: FORMER OWNER: HEFEI HUAQING METAL SURFACE TREATMENT CO., LTD. Effective date: 20121221 |
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C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20121221 Address after: 230088 Room 101, Huaqing research and development building, Yulan Avenue electromechanical zone, Hefei hi tech Zone, Anhui Applicant after: HEFEI HUAQING FANGXING SURFACE TECHNOLOGY Co.,Ltd. Address before: 230088 C-211 room, Science Park, National University, Mount Huangshan Road, Anhui, Hefei Applicant before: Hefei Huaqing Metal Surface Treatment Co.,Ltd. |
|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address |
Address after: 230088 Floor 1, Building 4, No. 1666, Ningxi Road, High tech Zone, Hefei, Anhui Patentee after: Hefei Huaqing High tech Surface Technology Co.,Ltd. Address before: 230088 Room 101, Huaqing R & D building, Yulan Avenue electromechanical Industrial Park, high tech Zone, Hefei City, Anhui Province Patentee before: HEFEI HUAQING FANGXING SURFACE TECHNOLOGY Co.,Ltd. |
|
CP03 | Change of name, title or address |