CN110452567A - A kind of selfreparing anticorrosive paint and preparation method for seawater hypersaline environment - Google Patents

A kind of selfreparing anticorrosive paint and preparation method for seawater hypersaline environment Download PDF

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Publication number
CN110452567A
CN110452567A CN201910802357.4A CN201910802357A CN110452567A CN 110452567 A CN110452567 A CN 110452567A CN 201910802357 A CN201910802357 A CN 201910802357A CN 110452567 A CN110452567 A CN 110452567A
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seawater
weight
parts
anticorrosive paint
phosphate
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CN201910802357.4A
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林芬
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林芬
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular

Abstract

The invention belongs to the technical fields of anticorrosive paint, provide a kind of selfreparing anticorrosive paint and preparation method for seawater hypersaline environment.This method is using containing hydrogen silicone oil, lime aluminium salt, polyamide micro mist, hydroxyethyl methacrylate as raw material, self repairing agent is made, then it is uniformly dispersed with phosphate modified acrylic acid ester emulsion, silicone acrylic emulsion, magnesium silicate, pyrroles, phosphate, coalescing agent, levelling agent, deionized water, the selfreparing anticorrosive paint for seawater hypersaline environment is made.It is compared with the traditional method; the anticorrosive paint of preparation of the invention; the dense coating with physics, chemical double protection can be generated in seawater hypersaline environment; and then can it is long-term it is resistance to live chloride ion corrosion; antiseptic property is excellent; metal material, concrete in effective protection seawater, have a extensive future.

Description

A kind of selfreparing anticorrosive paint and preparation method for seawater hypersaline environment
Technical field
The invention belongs to the technical fields of anticorrosive paint, provide a kind of selfreparing anti-corrosion painting for seawater hypersaline environment Material and preparation method.
Background technique
Marine corrosion is the corrosion that component occurs in marine environment.In this corrosive environment, seawater itself is a kind of Strong corrosive medium, while wave, wave, tide, stream generate low frequency toward combined stress and impact to metal component, concrete pier etc. again, In addition marine microorganism, aufwuch and their metabolite etc. all generate direct or indirect accelerated corrosion to corrosion process Effect.Therefore marine anticorrosion is particularly important.
However, the existing anticorrosive paint used in seawater with high salt is mostly resisted using barrier property and compactness is increased The etch of seawater.But due to washing away for a long time, coating can gradually be corroded, and eventually lead to anti-corrosion failure.
Self-healing coatings are expected to promote seawater corrosion prevention performance.Existing self-healing coatings are mainly using design embedding in the coating Film forming matter or sustained release reactant, to realize the purpose of selfreparing.However such coatings is due to being protected from environmental, it is difficult To reach good reaction environment, repair ability is weaker.Especially in some rugged environments, such as peracid, high-alkali, ring with high salt In border, coating self-reparing capability is difficult to ensure.Therefore, the corrosion resistance for improving selfreparing anticorrosive paint, is closed extensively by people Note.
At present both at home and abroad in anticorrosive paint filtering technique, especially achieved in terms of the coating of resistance to marine corrosion centainly at Effect.Wherein a kind of preparation method (Chinese invention patent application number of Marine Antifouling Paint is illustrated in old equality human hair 201510507708.0) polyvinyl chloride, xylene formaldehyde resin, zinc citrate, epoxy resin, are first taken, is added in solvent, is stirred It mixes, then neoprene, lecithin, sodium sulfoxylate formaldehyde, chlorinated paraffin is added in the resulting mixture, stirring, finally in gained Rutile type titanium white, dispersing agent, blanc fixe, butyl acetate, polymethyl methacrylate, solvent are added in mixture, Stirring, grind to get.In addition, a great waves have invented a kind of ocean nanometer anticorrosion coating (Chinese invention patent application number 201410411565.9), be prepared from the following raw materials in parts by weight: 1~5 parts by weight of mica powder, talcum powder, 1~5 parts by weight, 1~5 parts by weight of zinc powder, 1~5 parts by weight of titanium dioxide, 1~5 parts by weight of aluminium powder, 5~15 parts by weight of epoxy resin, plasticizer 5~8 Parts by weight, 1~5 parts by weight of levelling agent, 1~5 parts by weight of epoxy reinforcing agent, 10~15 parts by weight of defoaming agent, 8~15 weight of diluent Measure part, 1~5 parts by weight of alkaline water absorbing agent, 10~15 parts by weight of rust resisting pigment, 5~10 parts by weight of crack resistence pigment.
As it can be seen that anticorrosive paint in the prior art is when with component in Yu Haiyang, corrosion-inhibiting coating the shortcomings that there are easy damageds, Affect application of the anticorrosive paint under seawater hypersaline environment.
Summary of the invention
For seawater Anticorrosion with high salt, the present invention proposes a kind of selfreparing anticorrosive paint for seawater hypersaline environment And preparation method, the anti-corrosion for seawater hypersaline environment can be effectively improved.
To achieve the above object, specific technical solution of the present invention is as follows:
A kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment with containing hydrogen silicone oil, lime aluminium salt, is gathered Amide micro mist, hydroxyethyl methacrylate be raw material, self repairing agent is made, then with phosphate modified acrylic acid ester emulsion, silicon Acrylic emulsion, magnesium silicate, pyrroles, phosphate, coalescing agent, levelling agent, deionized water are uniformly dispersed, and selfreparing anti-corrosion is made and applies Sandwich-like composite photo-catalyst is made in material, and specific step is as follows for preparation:
(1) it by containing hydrogen silicone oil, lime aluminium salt, polyamide micro mist, hydroxyethyl methacrylate mixed grinding, is uniformly dispersed, Self repairing agent is made；
(2) by self repairing agent made from step (1) and phosphate modified acrylic acid ester emulsion, silicone acrylic emulsion, magnesium silicate, pyrrole It coughs up, the mixing of phosphate, coalescing agent, levelling agent, deionized water, is uniformly dispersed, the selfreparing for seawater hypersaline environment is made Anticorrosive paint.
Preferably, step (1) containing hydrogen silicone oil is Methyl Hydrogen Polysiloxane Fluid.
Preferably, step (1) the lime aluminium salt is calcium oxide and sodium metaaluminate mixture, wherein calcium oxide 40~60 Parts by weight, 40~60 parts by weight of sodium metaaluminate.
Preferably, the parts by weight of each raw material are in step (1), 8~12 parts by weight of containing hydrogen silicone oil, 35~40 weight of lime aluminium salt Measure part, 12~16 parts by weight of polyamide micro mist, 32~45 parts by weight of hydroxyethyl methacrylate.
Preferably, the solid content of step (2) the phosphate modified acrylic acid ester emulsion is 30~50%.
Preferably, the solid content of step (2) described silicone acrylic emulsion is 40~60%.
Preferably, step (2) phosphate is at least one of magnesium phosphate, aluminum phosphate, trbasic zinc phosphate, ferric phosphate.
Preferably, step (2) coalescing agent is at least one of propandiol butyl ether, propylene glycol methyl ether acetate.
Preferably, step (2) levelling agent is dimethyl silicone polymer, at least one in polymethylphenylsiloxane Kind.
Preferably, the parts by weight of each raw material are 10~13 parts by weight of self repairing agent, phosphate modified propylene in step (2) 20~23 parts by weight of acid esters lotion, 18~21 parts by weight of silicone acrylic emulsion, 6~8 parts by weight of magnesium silicate, 5~7 parts by weight of pyrroles, phosphorus 10~12 parts by weight of hydrochlorate, 1~3 parts by weight of coalescing agent, 1~2 parts by weight of levelling agent, 11~22 parts by weight of deionized water.
Lime aluminium salt method is that one kind is reacted by chloride ion in feeding lime and aluminium salt, with water, generates precipitating, in turn The method for effectively removing chloride ion.The present invention passes through containing hydrogen silicone oil and lime aluminium salt, polyamide micro mist, hydroxyethyl methacrylate Grinding, is uniformly dispersed, obtains self repairing agent；Using lime aluminium salt under hypersaline environment with the chloride ion slow reaction in seawater, It interacts with other compositions, and then coating is densified, and then improve the corrosion resistance of coating.Methyl Hydrogen Polysiloxane Fluid is easily crosslinked Form waterproof membrane；Hydroxyethyl methacrylate ethylene linkage containing polymerism and activity hydroxy, easy homopolymerization form barrier film, promote anticorrosion Performance.
The present invention also provides the selfreparing anti-corrosions for seawater hypersaline environment that a kind of above-mentioned preparation method is prepared Coating.The selfreparing anticorrosive paint is to grind containing hydrogen silicone oil and lime aluminium salt, polyamide micro mist, hydroxyethyl methacrylate, Be uniformly dispersed, obtain self repairing agent, the self repairing agent be used for seawater corrosion prevention coating, can under hypersaline environment with the chlorine in seawater Ion slow reaction, coating is densified, so that its selfreparing under seawater hypersaline environment forms fine and close coating, to reach Long-acting selfreparing corrosion-resistant purpose.Generation has the coating of physics, chemical double protection, can long-term resistance to firmly chloride ion corruption Erosion, is effectively protected metal material, concrete etc. in seawater.
The present invention provides a kind of selfreparing anticorrosive paints and preparation method for seawater hypersaline environment, with the prior art It compares, the feature and excellent effect protruded is:
1. anticorrosive paint prepared by the present invention, the antiseptic property in seawater hypersaline environment is excellent, has a extensive future.
2. preparation method of the invention passes through containing hydrogen silicone oil and lime aluminium salt, polyamide micro mist, hydroxyethyl methacrylate Grinding, be uniformly dispersed, obtain self repairing agent, be used for seawater corrosion prevention coating, can under hypersaline environment with the chloride ion in seawater Slow reaction densifies coating, so that its selfreparing under seawater hypersaline environment forms fine and close coating, to reach long-acting Selfreparing corrosion-resistant purpose.
3. preparation method of the invention can generate the coating with physics, chemical double protection in hypersaline environment, Can it is long-term it is resistance to live chloride ion corrosion, metal material, the concrete etc. being effectively protected in seawater.
Specific embodiment
In the following, the present invention will be further described in detail by way of specific embodiments, but this should not be interpreted as to the present invention Range be only limitted to example below.Without departing from the idea of the above method of the present invention, according to ordinary skill The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
9kg containing hydrogen silicone oil, 37kg lime aluminium salt, 13kg polyamide micro mist, 41kg hydroxyethyl methacrylate are mixed and ground Mill, is uniformly dispersed, and self repairing agent is made, wherein lime aluminium salt is calcium oxide and sodium metaaluminate mixture, wherein calcium oxide 18kg, sodium metaaluminate 19kg；Then the phosphate modified acrylate cream for being 38% by 11kg self repairing agent and 21kg solid content Liquid, the silicone acrylic emulsion that 20kg solid content is 48%, 7kg magnesium silicate, 6kg pyrroles, 11kg magnesium phosphate, 2kg propandiol butyl ether, 1kg Dimethyl silicone polymer, the mixing of 14kg deionized water, are uniformly dispersed, and the selfreparing anti-corrosion painting for seawater hypersaline environment is made Material.
Test method:
Corrosion resistance test coating conditions: by coating even application produced by the present invention on tinplate, front and back sides and Side whole brushing paint is brushed with a thickness of 135 μm, after spontaneously drying 7 days, is soaked in simulation high concentration seawater and carries out anti-corrosion Experiment；Simulate high concentration artificial seawater are as follows: sodium chloride content 50g/L；Content of magnesium chloride 7g/L；Sulfuric acid content of magnesium 4g/L；Sulphur Sour calcium content 6g/L；Temperature is 60 DEG C；It is taken out when impregnating 7 days, 15 days, observes coating conditions.
The data obtained is as shown in table 1.
Embodiment 2
9kg containing hydrogen silicone oil, 36kg lime aluminium salt, 13kg polyamide micro mist, 42kg hydroxyethyl methacrylate are mixed and ground Mill, is uniformly dispersed, and self repairing agent is made, wherein lime aluminium salt is calcium oxide and sodium metaaluminate mixture, wherein calcium oxide 18kg, sodium metaaluminate 18kg；Then the phosphate modified acrylate cream for being 35% by 11kg self repairing agent and 21kg solid content Liquid, the silicone acrylic emulsion that 19kg solid content is 45%, 6kg magnesium silicate, 6kg pyrroles, 10kg aluminum phosphate, 2kg propylene glycol monomethyl ether acetic acid Ester, 1kg polymethylphenylsiloxane, the mixing of 17kg deionized water, are uniformly dispersed, the selfreparing for seawater hypersaline environment are made Anticorrosive paint.
Test method and embodiment 1 are consistent, and the data obtained is as shown in table 1.
Embodiment 3
11kg containing hydrogen silicone oil, 38kg lime aluminium salt, 15kg polyamide micro mist, 36kg hydroxyethyl methacrylate are mixed and ground Mill, is uniformly dispersed, and self repairing agent is made, wherein lime aluminium salt is calcium oxide and sodium metaaluminate mixture, wherein calcium oxide 20kg, sodium metaaluminate 18kg；Then the phosphate modified acrylic acid for being 45% by 10~13kg self repairing agent and 22kg solid content Ester lotion, the silicone acrylic emulsion that 20kg solid content is 55%, 8kg magnesium silicate, 5~7kg pyrroles, 11kg trbasic zinc phosphate, 2kg propylene glycol fourth Ether, 2kg dimethyl silicone polymer, the mixing of 15kg deionized water, are uniformly dispersed, and are made anti-for the selfreparing of seawater hypersaline environment Rotten coating.
Test method and embodiment 1 are consistent, and the data obtained is as shown in table 1.
Embodiment 4
8kg containing hydrogen silicone oil, 35kg lime aluminium salt, 12kg polyamide micro mist, 45kg hydroxyethyl methacrylate are mixed and ground Mill, is uniformly dispersed, and self repairing agent is made, wherein lime aluminium salt is calcium oxide and sodium metaaluminate mixture, wherein calcium oxide 18kg, sodium metaaluminate 17kg；Then the phosphate modified acrylate cream for being 30% by 10kg self repairing agent and 20kg solid content Liquid, the silicone acrylic emulsion that 18kg solid content is 40%, 6kg magnesium silicate, 5~7kg pyrroles, 10kg ferric phosphate, 1kg propylene glycol monomethyl ether vinegar Acid esters, 1kg dimethyl silicone polymer, the mixing of 22kg deionized water, are uniformly dispersed, the selfreparing for seawater hypersaline environment are made Anticorrosive paint.
Test method and embodiment 1 are consistent, and the data obtained is as shown in table 1.
Embodiment 5
12kg containing hydrogen silicone oil, 40kg lime aluminium salt, 16kg polyamide micro mist, 32kg hydroxyethyl methacrylate are mixed and ground Mill, is uniformly dispersed, and self repairing agent is made, wherein lime aluminium salt is calcium oxide and sodium metaaluminate mixture, wherein calcium oxide 20kg, sodium metaaluminate 20kg；Then the phosphate modified acrylate cream for being 50% by 13kg self repairing agent and 23kg solid content Liquid, the silicone acrylic emulsion that 21kg solid content is 60%, 8kg magnesium silicate, 7kg pyrroles, 12kg magnesium phosphate, 3kg propandiol butyl ether, 2kg Dimethyl silicone polymer, the mixing of 11kg deionized water, are uniformly dispersed, and the selfreparing anti-corrosion painting for seawater hypersaline environment is made Material.
Test method and embodiment 1 are consistent, and the data obtained is as shown in table 1.
Comparative example 1
In dope preparing process, it is not added with lime aluminium salt, other preparation conditions and embodiment 1 are consistent.
Test method and embodiment 1 are consistent, and the data obtained is as shown in table 1.
Table 1:

Claims (10)

1. a kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment, which is characterized in that with containing hydrogen silicone oil, stone Grey aluminium salt, polyamide micro mist, hydroxyethyl methacrylate be raw material, self repairing agent is made, then with phosphate modified acrylic acid Ester lotion, silicone acrylic emulsion, magnesium silicate, pyrroles, phosphate, coalescing agent, levelling agent, deionized water are uniformly dispersed, and are made and review one's lessons by oneself Multiple anticorrosive paint, is made sandwich-like composite photo-catalyst, specific step is as follows for preparation:
(1) it by containing hydrogen silicone oil, lime aluminium salt, polyamide micro mist, hydroxyethyl methacrylate mixed grinding, is uniformly dispersed, is made Self repairing agent；
(2) by self repairing agent made from step (1) and phosphate modified acrylic acid ester emulsion, silicone acrylic emulsion, magnesium silicate, pyrroles, Phosphate, coalescing agent, levelling agent, deionized water mixing, are uniformly dispersed, the selfreparing anti-corrosion for seawater hypersaline environment are made Coating.
2. a kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment according to claim 1, feature Be: step (1) containing hydrogen silicone oil is Methyl Hydrogen Polysiloxane Fluid.
3. a kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment according to claim 1, feature Be: step (1) the lime aluminium salt is calcium oxide and sodium metaaluminate mixture, wherein 40~60 parts by weight of calcium oxide, inclined aluminium Sour 40~60 parts by weight of sodium.
4. a kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment according to claim 1, feature Be: the parts by weight of each raw material are in step (1), 8~12 parts by weight of containing hydrogen silicone oil, 35~40 parts by weight of lime aluminium salt, polyamides 12~16 parts by weight of amine micro mist, 32~45 parts by weight of hydroxyethyl methacrylate.
5. a kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment according to claim 1, feature Be: the solid content of step (2) the phosphate modified acrylic acid ester emulsion is 30~50%, and the solid content of silicone acrylic emulsion is 40 ~60%.
6. a kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment according to claim 1, feature Be: step (2) phosphate is at least one of magnesium phosphate, aluminum phosphate, trbasic zinc phosphate, ferric phosphate.
7. a kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment according to claim 1, feature Be: step (2) coalescing agent is at least one of propandiol butyl ether, propylene glycol methyl ether acetate.
8. a kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment according to claim 1, feature Be: step (2) levelling agent is at least one of dimethyl silicone polymer, polymethylphenylsiloxane.
9. a kind of preparation method of the selfreparing anticorrosive paint for seawater hypersaline environment according to claim 1, feature Be: the parts by weight of each raw material are in step (2), 10~13 parts by weight of self repairing agent, phosphate modified acrylic acid ester emulsion 20 ~23 parts by weight, 18~21 parts by weight of silicone acrylic emulsion, 6~8 parts by weight of magnesium silicate, 5~7 parts by weight of pyrroles, phosphate 10~12 Parts by weight, 1~3 parts by weight of coalescing agent, 1~2 parts by weight of levelling agent, 11~22 parts by weight of deionized water.
10. the selfreparing anti-corrosion for seawater hypersaline environment that any one of claim 1~9 preparation method is prepared applies Material.
CN201910802357.4A 2019-08-28 2019-08-28 A kind of selfreparing anticorrosive paint and preparation method for seawater hypersaline environment Pending CN110452567A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110343459A (en) * 2019-06-12 2019-10-18 苏州科技大学 A kind of selfreparing polyurethane water-proof paint, preparation method and application
CN110387100A (en) * 2019-08-01 2019-10-29 宁夏辰邦石油装备制造有限公司 A kind of bionic aquatic weed and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107556876A (en) * 2017-10-09 2018-01-09 江苏海晟涂料有限公司 A kind of ship Marine Antifouling Paint and preparation method thereof
CN108239458A (en) * 2017-12-19 2018-07-03 吉力水性新材料科技（珠海）有限公司 A kind of phosphate modified acrylic acid aqueous antirusting paint of salt fog resistance
CN108250347A (en) * 2017-12-19 2018-07-06 吉力水性新材料科技（珠海）有限公司 A kind of phosphate modified Acrylate Core-shell Emulsion of salt spray resistance

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107556876A (en) * 2017-10-09 2018-01-09 江苏海晟涂料有限公司 A kind of ship Marine Antifouling Paint and preparation method thereof
CN108239458A (en) * 2017-12-19 2018-07-03 吉力水性新材料科技（珠海）有限公司 A kind of phosphate modified acrylic acid aqueous antirusting paint of salt fog resistance
CN108250347A (en) * 2017-12-19 2018-07-06 吉力水性新材料科技（珠海）有限公司 A kind of phosphate modified Acrylate Core-shell Emulsion of salt spray resistance

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110343459A (en) * 2019-06-12 2019-10-18 苏州科技大学 A kind of selfreparing polyurethane water-proof paint, preparation method and application
CN110387100A (en) * 2019-08-01 2019-10-29 宁夏辰邦石油装备制造有限公司 A kind of bionic aquatic weed and preparation method thereof

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Application publication date: 20191115