CN102853176A - Thermoplastic plastic composite tube - Google Patents

Thermoplastic plastic composite tube Download PDF

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Publication number
CN102853176A
CN102853176A CN2012103612138A CN201210361213A CN102853176A CN 102853176 A CN102853176 A CN 102853176A CN 2012103612138 A CN2012103612138 A CN 2012103612138A CN 201210361213 A CN201210361213 A CN 201210361213A CN 102853176 A CN102853176 A CN 102853176A
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Prior art keywords
plastic tube
composite plastic
thermoplastic composite
tooth groove
overcoat
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CN2012103612138A
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CN102853176B (en
Inventor
李万利
袁长友
宋花平
刘进立
严为群
钱晓宇
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JIANGSU LIANGUAN HIGH-TECH Co Ltd
Oil Research Institute of General Logistic Department of PLA
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JIANGSU LIANGUAN HIGH-TECH Co Ltd
Oil Research Institute of General Logistic Department of PLA
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Priority to CN201210361213.8A priority Critical patent/CN102853176B/en
Publication of CN102853176A publication Critical patent/CN102853176A/en
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Abstract

The invention relates to a thermoplastic plastic composite tube, which comprises a thermoplastic plastic composite tube body and a joint. The joint comprises a core tube and a jacket, which are buckled on both ends of the tube body; the end of a tube body of the thermoplastic plastic composite tube is expanded in a radial direction, so that the inner diameter of the core tube is equal to the inner diameter of the tube body, an inner layer and an outer layer of the tail end of the end of the tube body are stripped, the expanded end of the tube body is buckled between a trapezoidal tooth groove outside the core tube and a trapezoidal tooth groove of the jacket; and the end of the core tube is a joint connecting part. The thermoplastic plastic composite tube has the advantages of firm joint buckling, good sealing property, high pressure resistance and drawing resistance, the inner diameter of the joint is equal to the inner diameter of the pipeline, and the fluid conveying resistance is reduced.

Description

A kind of thermoplastic composite plastic tube
Technical field
The thermoplastic pipe that the present invention relates to strengthen, the particularly thermoplastic composite plastic tube of fast demountable.
Background technique
Thermoplastic composite plastic tube since the nineties in last century abroad oil gas field progressively use, begin at home oil gas field the beginning of this century on probation, be mainly used in oil-gas gathering and transportation, water filling and notes alcohol.Now, the thermoplastic composite plastic tube application comprises ocean flexible pipe, hot spring delivery pipe; Oil, product oil, natural gas transport; Municipal administration plumbing, oily water, desalination of sea water; Mine water supply, air feed, draining, coal washing water, coal dust are carried; Chemical plant, steel mill's corrosive liquids are carried.
Composite pipe generally comprises three-decker: the inside liner of internal layer, middle enhancement layer, and outer field external protection.As the enhancement layer in mesosphere, can be formed by inorfil, organic fiber or steel fiber as required.As inside liner or the outer field external protection of internal layer, generally formed by elastomer (such as vulcanized rubber, thermoplastic elastomer (TPE)) or plastics (such as thermosetting plastics, thermoplastic).If the internal layer of composite pipe and skin all are thermoplastics, then this composite pipe is called as thermoplastic composite plastic tube.
Particularly, as the inside liner of internal layer, can be formed by high density polyethylene (HDPE) (HDPE), crosslinked polyethylene (PEX), ultra-high molecular weight polyethylene (UHMWPE), nylon (PA) and polyvinylidene fluoride (PVDF) etc.
As the enhancement layer in mesosphere, can mention such as organic fiber (such as aramid fiber, polyester fibre), inorfil (such as glass fibre, carbon fiber, basalt fibre) and steel fiber (such as steel wire) etc.
For the thermoplastic pipe of emergent delivering fuel etc., particularly importantly it has high on-the-spot dismounting performance, namely can connect fast and dismantle at the construction field (site).For with the thermoplastic pipe quick mounting, for the joint that is used for connecting and the Placement of joint and pipeline requirement is arranged.
At present, the common mode that is used for the thermoplastic pipe connection comprises following three kinds: (1) welding, for example hot melt connection, electric smelting connection or electric smelting-hot melt connect, and use the melting joint between two thermoplastic pipes, and it is lower that the joint that this Placement forms bears pressure; (2) withhold connection, the socket end of a metal pipe element is inserted the reinforced thermoplastics pipe, at metallic sheath of reinforced thermoplastics pipe overcoat, with mechanical means metallic sheath-reinforced thermoplastics pipe pipe end-tube spigot side pressure is tightly become joint, this Placement often can cause the connecting part internal diameter less than the thermoplastic pipe internal diameter at other positions, thereby the liquid resistance that causes carrying increases, and how to guarantee to seal and bear higher axial and radial load simultaneously also different; (3) clip directly is socketed, and outside, two connecting parts is provided with draw-in groove, directly is sheathed on the draw-in groove place by clip and connects, and shortcoming is that the clamp band type connector construction is long, weight is large, connecting bolt is many, can not the mechanization laying etc., relatively is fit to low pressure line and uses.
In addition, for above-mentioned Placement, also exist joint to connect the problems such as solidness is not high enough, installation rate is not fast.
Summary of the invention
In order to overcome the problems referred to above; the inventor has carried out with keen determination research; found that: for the thermoplastic composite plastic tube with inside liner, enhancement layer and external protection; for making internal diameter of tube body consistent with the joint internal diameter; resistance when reducing fluid by joint carries out the enlarging design, namely when withholding connection; with body heating tail end expander radially, its internal diameter is increased to identical with the internal diameter of joint first.In order to improve the intensity of enlarging transition position, caliber variation place of body end is provided with stiffening ring between body and overcoat behind expander, and stiffening ring is the annulus of varied in thickness, and stiffening ring is withheld simultaneously when joint is withheld; In order to improve axial load, i.e. anti-pull-out force adopts the mode of turning, divests the internal and external layer of body least significant end, and enhancement layer fiber such as steel wire floor are exposed, so that the groove of joint core pipe and overcoat when withholding can be tight with the pressing of enhancement layer fiber, increases anti-pull-out force; In order to improve the joint join strength, designed the stepped tooth groove, groove divides two-part, a part is withheld on the internal and external layer thermoplastic, a part is withheld and is being divested on the exposed enhancement layer fiber of internal and external layer, and groove is designed to the stepped tooth groove, to reduce the damage to internal and external layer thermoplastic and mesosphere fiber, the mutual interlock coupling of the stepped tooth groove of core pipe and overcoat, the degree of depth of groove, spacing and quantity change with body wall thickness and pressure increase.In order to increase the joint sealing performance, be provided with a special groove at the core pipe end, in put rubber seal, rubber seal is fixed simultaneously when joint is withheld.The core tube end is the joint joint, by it body is joined together to form pipeline.By using this structure, have extremely high anti-pull-out force between body and core pipe and the overcoat, the pipeline that is connected to form has extremely high bearing capacity, and can realize quick connection, and the internal diameter of the pipeline homogeneous that is connected to form, thereby finishes the present invention.
The object of the present invention is to provide following aspect:
(1) a kind of thermoplastic composite plastic tube, it comprises the thermoplastic composite plastic tube body, and in thermoplastic composite plastic tube body end, the core pipe has been withheld in inside, and overcoat and stiffening ring have been withheld in the outside, and the core bore is identical with the thermoplastic composite plastic tube internal diameter of tube body;
Wherein, the thermoplastic composite plastic tube body comprises: as the inside liner of internal layer, and as the enhancement layer in mesosphere, and as outer field external protection;
Thermoplastic composite plastic tube body end is by expander radially, the internal layer of the end of body end and outer being divested behind the expander, and the body end behind the expander is withheld between the stepped tooth groove of the stepped tooth groove of core pipe outside and overcoat;
The core tube end is the joint joint.
(2) thermoplastic composite plastic tube described in above-mentioned (1), wherein, the stepped tooth groove of core pipe outside and the stepped tooth groove of overcoat mate mutually.
(3) thermoplastic composite plastic tube described in above-mentioned (1) or (2), wherein, the enhancement layer fiber of the ends exposed of body end is crimped between the stepped tooth groove I of the stepped tooth groove I of core pipe outside and overcoat behind the expander, and the body end remaining part behind the expander is withheld between the stepped tooth groove II of the stepped tooth groove II of core pipe outside and overcoat.
(4) such as above-mentioned thermoplastic composite plastic tube described in each, wherein, caliber variation place of body end behind expander, between body and overcoat, be provided with stiffening ring, stiffening ring is the annulus of varied in thickness, and its internal surface and body connect airtight, and its outer surface and overcoat connect airtight.
(5) thermoplastic composite plastic tube described in above-mentioned (4), wherein, the stiffening ring outer surface arranges the stepped tooth groove, thereby connects airtight with overcoat.
(6) thermoplastic composite plastic tube described in above-mentioned (4) or (5) wherein, in thermoplastic composite plastic tube body inner end portion, begins variation place at caliber, is provided with rubber seal at body and core pipe connecting part.
(7) such as above-mentioned thermoplastic composite plastic tube described in each, wherein, in the thermoplastic composite plastic tube body, internal layer is the ultra high molecular polyethylene layer, and the mesosphere is steel wire floor, and is bonding by tackiness agent between internal and external layer and the mesosphere.
(8) such as above-mentioned thermoplastic composite plastic tube described in each, wherein, core pipe and overcoat are made by steel or aluminum alloy, and the core tube end is spigot-and-socket joint or trough formula joint.
(9) such as the manufacture method of above-mentioned thermoplastic composite plastic tube described in each, the method may further comprise the steps:
1. produce the thermoplastic composite plastic tube body;
2. thermoplastic composite plastic tube body and core pipe and overcoat and stiffening ring are withheld: thermoplastic composite plastic tube body end is heated, expander radially, divest thermoplastic internal layer and the outer thermoplastic layer of the end of body end behind the expander, the outside sheathed stiffening ring of caliber variation place of body end behind expander, body end behind the expander is withheld between the stepped tooth groove and stiffening ring of the stepped tooth groove of core pipe outside and overcoat, randomly, be provided with rubber seal at body and core pipe connecting part.
Have the following advantages according to thermoplastic composite plastic tube provided by the invention:
(1) stepped tooth groove, resistance to plucking take off, stiffening ring fastening-pressing type joint structure by using, and make the tensile strength of joint and body greater than the tensile strength of body itself, have solved the difficult problem that the heavy caliber high pressure multiunit tube joint is connected with body, have guaranteed use safety;
(2) adopt spigot-and-socket joint or trough formula joint, the convenient connection and dismounting, can significantly reduce labor intensity, improve the receipts speed of removing of laying;
(3) the joint internal diameter is identical with internal diameter of tube body, and the resistance when reducing fluid by joint is convenient emptying simultaneously;
(4) the body inside liner adopts ultra-high molecular weight polyethylene, smooth abrasion-proof, and transporting resistance is little, and quantity delivered under equal conditions improves approximately 30% than steel pipe;
(5) the body inside liner adopts ultra-high molecular weight polyethylene, has excellent oil resistance, and external protection adopts pipe stage polyethylene mixed ingredients, has excellent weather-proof aging, has improved working life and the storage life of body;
(6) joint adopts steel or aluminum alloy to make, and joint contacts with the earth, can in time the static charge that produces be dissipated to the earth during oil pipeline transportation; If the body enhancement layer adopts steel wire, steel wire is withheld with metal joint and is connected, and makes pipeline form the conductor of a UNICOM, more is conducive to the elimination of static charge, and Security is good.
Description of drawings
Fig. 1 illustrates according to thermoplastic composite plastic tube cross-sectional view of the present invention
Reference character:
1-core pipe
The stepped tooth groove I of 11-core pipe
The stepped tooth groove II of 12-core pipe
13-joint joint
The 2-overcoat
The stepped tooth groove I of 21-overcoat
The stepped tooth groove II of 22-overcoat
The 3-stiffening ring
4-thermoplastic composite plastic tube body
The 41-internal layer
The 42-mesosphere
43-is outer
The 5-rubber seal
Embodiment
The present invention is described in detail by exemplary embodiment below in conjunction with accompanying drawing.The features and advantages of the invention will become more clear, clear and definite along with these descriptions.
The identical same or analogous element of reference character presentation function in the accompanying drawing.
Here special-purpose word " exemplary " means " as example, embodiment or illustrative ".Here needn't be interpreted as being better than or being better than other embodiment as " exemplary " illustrated any embodiment.Although accompanying drawing unless otherwise indicated, needn't be drawn in proportion in embodiment's shown in the drawings various aspects.
According to the present invention, a kind of thermoplastic composite plastic tube is provided, it comprises the thermoplastic composite plastic tube body, in thermoplastic composite plastic tube body end, inside is crimped with the core pipe, and the outside is crimped with overcoat, and the core bore is identical with the thermoplastic composite plastic tube internal diameter of tube body;
Wherein, the thermoplastic composite plastic tube body comprises: as the inside liner of internal layer, and as the enhancement layer in mesosphere, and as outer field external protection;
Thermoplastic composite plastic tube body end is by expander radially, the internal layer of the end of body end and outer being divested behind the expander, and the body end behind the expander is crimped between the stepped tooth groove of the stepped tooth groove of core pipe outside and overcoat;
The core tube end is the joint joint.
In the thermoplastic composite plastic tube according to fast demountable of the present invention, the thermoplastic composite plastic tube body comprises at least three-decker from inside to outside: the inside liner 41 of internal layer, and the enhancement layer 42 in mesosphere, and outer field external protection 43, as shown in Figure 1.
As the inside liner of internal layer, extruded by ultra-high molecular weight polyethylene and to form, for example formed by the ultra-high molecular weight polyethylene of molecular weight between 1,000,000-5,000,000.As for the ultra-high molecular weight polyethylene extrusion method, such as can be referring to Chinese patent application 200610039727.6 and 200810019731.5 etc.
As the inside liner of internal layer, oil transportation mainly plays the oil resistant effect with the inside liner of composite pipe, because its oil resistance can prevent fuel to its corrosion and infiltration, thereby it is deteriorated to avoid pipeline integral body to be corroded.
As the enhancement layer in mesosphere, can be formed by inorganic or organic fiber.As inorfil, can mention such as steel wire, copper wire etc.As organic fiber, can mention such as aramid fibre, polyester fibre etc.In enhancement layer, inorfil or organic fiber twine mutually or net is knitted; In the situation that twine, winding direction can be identical or opposite.No matter be that namely enhancement layer can comprise one or more layers layer of fibers in the situation that winding still in the situation that net is knitted, as required, can arrange one or more layers layer of fibers, every layer of layer of fibers can be knitted by Filament-wound Machine or net and form.In the situation that enhancement layer can comprise the multi-layer fiber layer, can pass through adhesive bond between the layer of fibers.
In a preferred embodiment, enhancement layer is made of two fibre layers, and every layer of layer of fibers formed by steel wire winding, and the silk winding direction of two fibre layers is opposite, passes through adhesive bond between the two fibre layers.
As the enhancement layer in mesosphere, be mainly used in strengthening the anti-pressure ability that improves pipeline.Because Filament-wound Machine or the net of enhancement layer are woven on the inside liner, mainly bear the hydrodynamic pressure of the liquid of carrying, i.e. the stress that causes of interior pressure.According to the ability to bear of expectation, the enhancement layer of the expectation number of plies can be set.
As outer field external protection, can be formed by the organic material of rotproofness, such as formation such as thermoplastic such as polyethylene, nylon, PVDF.The effect of protective layer mainly is to provide protective, and the protection pipeline avoids being subject to the erosion of surrounding environment such as soil, seawater etc.
In the thermoplastic composite plastic tube body, between internal layer, mesosphere and the skin, can pass through adhesives.
One preferred embodiment in, the mesosphere is formed by steel wire.At this moment, internal layer and mesosphere can be by the polythene material adhesives.As the polythene material tackiness agent, mention such as chlorinated polypropylene modified adhesive, hot melt adhesive (such as ethene-vinyl acetate base polymer hot melt adhesive), SBS (SBS) adhesive, esters of acrylic acid adhesive and silicone adhesive sealant etc.By tackiness agent, steel-wire carcass and inside and outside layers of polyethylene closely are bonded together.
In thermoplastic composite plastic tube according to the present invention, each layer of thermoplastic composite plastic tube body can also contain other additives as required, as contain anti-static agent in internal layer.
About the production of thermoplastic composite plastic tube body, can extrude first internal layer, then in internal layer establishment, bonding mesosphere, then extrude skin in the mesosphere.
For expander is carried out in thermoplastic composite plastic tube body end, adopt and heat radially expander, rather than axial expander.During expander, need a side pipe end of body of enlarging to put into the baking oven preheating body, the deliquescing of pipe end parts of plastics moves to rapidly on the expander mould after a period of time, measures the size of putting into mould, the fixed tube body position, make the module of flaring die balanced, synchronously mobile in the other direction along centripetal force, thereby enlarge the inner chamber of pipe end, begin to cool down typing after reaching size requirement, the expander process has namely been finished in body end after the taking-up enlarging.
In preferred embodiment, descend for fear of increase the short-term bursting pressure value that causes owing to caliber, caliber variation place of body end behind expander, between body and overcoat, be provided with stiffening ring 3, stiffening ring is the annulus of varied in thickness, its internal surface and body connect airtight, and its outer surface and overcoat connect airtight.
Further preferably, the stiffening ring outer surface arranges the stepped tooth groove, thereby connects airtight with overcoat.
Overcoat is fixed on the enlarging transition position through after withholding compression with stiffening ring.Experiment showed, that stiffening ring is set effectively to be avoided descending owing to caliber increases the bursting pressure value that causes.
In the present invention, the metal tube of the integrated moulding of core pipe, its internal diameter is identical with internal diameter of tube body, and the outside is provided with the stepped tooth groove, and its end is designed to the joint joint.
The metal pipe box of the integrated moulding of overcoat, its inside is provided with the stepped tooth groove.
In the present invention, in order to improve Safety performance, adopted resistance to plucking to take off structure, divest the internal and external layer of body end tip behind the expander by for example turning, to strengthen steel wire floor exposes, when withholding, with directly withholding between the stepped tooth groove I 21 of the stepped tooth groove I 11 of core pipe afterbody and overcoat of the enhancing steel wire floor that exposes, under the radial compression force effect that when withholding, produces, so that it is compressed between overcoat and core pipe to strengthen steel wire floor, strengthen steel wire floor and be squeezed into waveform, enter in the stepped tooth groove of overcoat and core pipe, increase anti-pull-out force, improve Safety performance; Body end remaining part behind the expander is crimped between the stepped tooth groove II 22 of the stepped tooth groove II 12 of core pipe outside and overcoat, when withholding, the wall thickness of body is compressed between overcoat and core pipe, the internal layer of body is squeezed in the stepped tooth groove II that waveform enters the core pipe, the skin of body is squeezed in the stepped tooth groove II that waveform enters overcoat, so that pipe joint obtains larger anti-pull-out force, improved simultaneously sealability.
In preferred embodiment, the stepped tooth groove of core pipe outside and the stepped tooth groove of overcoat mate mutually, thereby body end behind the expander (the enhancement layer fiber and the unexposed part that comprise ends exposed) withheld between the stepped tooth groove of the stepped tooth groove of core pipe outside and overcoat.
Preferably, the stepped tooth groove of core pipe outside comprises stepped tooth groove I and stepped tooth groove II, the stepped tooth groove of overcoat comprises stepped tooth groove I and stepped tooth groove II, the enhancement layer fiber of the ends exposed of body end is crimped between the stepped tooth groove I of the stepped tooth groove I of core pipe outside and overcoat behind the expander, and the body end remaining part behind the expander is crimped between the stepped tooth groove II of the stepped tooth groove II of core pipe outside and overcoat.
Further preferably, stepped tooth groove II shape is identical, be evenly distributed, and stepped tooth groove I shape is different, distributing inhomogeneity, and other stepped tooth groove depths of stepped tooth groove I termination trench depth ratio are large, so that the enhancing steel wire floor that will expose is effectively withheld, further increase anti-pull-out force.
One preferred embodiment in, in thermoplastic composite plastic tube body inner end portion, begin variation place at caliber, be provided with rubber seal 5 at body and core pipe connecting part, the fluid of avoiding carrying infiltrates from the slit of junction point, corrodes.
In preferred embodiment, core pipe and overcoat are made by steel or aluminum alloy, so that enough intensity and impact resistances to be provided.Particularly preferably be formed from steel, this is because steel are firmer, and joint connects firmer, can bear stronger impact or larger pressure.
In thermoplastic composite plastic tube according to the present invention, as the core tube end, can be designed as joint joint commonly used, such as trough formula joint or flanged joint, also can be military spigot-and-socket joint, to improve connection, dismounting speed, make things convenient for mechanization to lay.
When the joint joint was symplex structure, such as trough formula joint or flanged joint, then used core tube end (being the joint joint) docking clip or bolt to be fixed and get final product this moment; When the joint joint was dissymmetrical structure, such as spigot-and-socket joint, the core tube end that will insert as faucet part this moment as the core tube end of socket section got final product.
The inventor finds through research and great many of experiments, according to thermoplastic composite plastic tube provided by the invention, can connect fast and efficiently at the construction field (site) and dismantle, be connected firmly between thermoplastic composite plastic tube body and core pipe and the overcoat, can bear extremely strong external pressure and interior pressure, the joint transition is mild, and fluid (such as gasoline, diesel oil, jet fuel) can not infiltrate from the slit and corrode, the internal diameter of the pipeline homogeneous that forms after connecting, the isostasy of the oil plant of carrying.
Abovely by preferred embodiment the present invention has been carried out exemplary explanation.What but need statement is; these embodiments only are to illustrative explanation of the present invention; protection scope of the present invention is not consisted of any restriction; in the situation that do not exceed the present invention's spirit and protection domain; those skilled in the art can carry out multiple improvement, replacement or modification to the technology of the present invention content and mode of execution thereof, and these all fall within the scope of protection of the present invention.

Claims (9)

1. thermoplastic composite plastic tube, it comprises thermoplastic composite plastic tube body and joint, and in thermoplastic composite plastic tube body end, the core pipe has been withheld in inside, overcoat and stiffening ring have been withheld in the outside, and the core bore is identical with the thermoplastic composite plastic tube internal diameter of tube body;
Wherein, the thermoplastic composite plastic tube body comprises: as the inside liner of internal layer, and as the enhancement layer in mesosphere, and as outer field external protection;
Thermoplastic composite plastic tube body end is by expander radially, the internal layer of the end of body end and outer being divested behind the expander, and the body end behind the expander is withheld between the stepped tooth groove of the stepped tooth groove of core pipe outside and overcoat;
The core tube end is the joint joint.
2. the thermoplastic composite plastic tube described in according to claim 1, wherein, the stepped tooth groove of core pipe outside and the stepped tooth groove of overcoat mate mutually.
3. the thermoplastic composite plastic tube described in according to claim 1 and 2, wherein, the enhancement layer fiber of the ends exposed of body end is crimped between the stepped tooth groove I of the stepped tooth groove I of core pipe outside and overcoat behind the expander, and the body end remaining part behind the expander is withheld between the stepped tooth groove II of the stepped tooth groove II of core pipe outside and overcoat.
4. according to the thermoplastic composite plastic tube described in above-mentioned each claim, wherein, caliber variation place of body end behind expander, between body and overcoat, be provided with stiffening ring, stiffening ring is the annulus of varied in thickness, and its internal surface and body connect airtight, and its outer surface and overcoat connect airtight.
5. the thermoplastic composite plastic tube described in according to claim 4, wherein, the stiffening ring outer surface arranges the stepped tooth groove, thereby connects airtight with overcoat.
6. according to claim 4 or the thermoplastic composite plastic tube described in 5, wherein, in thermoplastic composite plastic tube body inner end portion, begin variation place at caliber, be provided with rubber seal at body and core pipe connecting part.
7. according to the thermoplastic composite plastic tube described in above-mentioned each claim, wherein, in the thermoplastic composite plastic tube body, internal layer is the ultra high molecular polyethylene layer, and the mesosphere is steel wire floor, and is bonding by tackiness agent between internal and external layer and the mesosphere.
8. according to the thermoplastic composite plastic tube described in above-mentioned each claim, wherein, core pipe and overcoat are made by steel or aluminum alloy, and the core tube end is spigot-and-socket joint or trough formula joint.
9. according to the manufacture method of the thermoplastic composite plastic tube described in above-mentioned each claim, the method may further comprise the steps:
(1) produces the thermoplastic composite plastic tube body;
(2) thermoplastic composite plastic tube body and core pipe and sleeve pipe and stiffening ring are withheld: thermoplastic composite plastic tube body end is heated, expander radially, divest internal layer and the skin of the end of body end behind the expander, the outside sheathed stiffening ring of caliber variation place of body end behind expander, body end behind the expander is withheld between the stepped tooth groove and stiffening ring of the stepped tooth groove of core pipe outside and overcoat, randomly, be provided with rubber seal at body and core pipe connecting part.
CN201210361213.8A 2012-09-25 2012-09-25 Thermoplastic plastic composite tube Active CN102853176B (en)

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