CN102836099A - Activated carbon bead, facial cleanser comprising same and preparation methods thereof - Google Patents
Activated carbon bead, facial cleanser comprising same and preparation methods thereof Download PDFInfo
- Publication number
- CN102836099A CN102836099A CN2012103447766A CN201210344776A CN102836099A CN 102836099 A CN102836099 A CN 102836099A CN 2012103447766 A CN2012103447766 A CN 2012103447766A CN 201210344776 A CN201210344776 A CN 201210344776A CN 102836099 A CN102836099 A CN 102836099A
- Authority
- CN
- China
- Prior art keywords
- activated carbon
- weight
- carbon beads
- kernel
- bead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to an activated carbon bead with a particle diameter of 5-500 meshes. The activated carbon bead comprises an inner core with a weight percentage of 2-20, an activated carbon layer with a weight percentage of 40-95 and a shell with a weight percentage of 3-40 from inside to outside. The invention also relates to a facial cleanser comprising the activated carbon bead and preparation methods of the activated carbon bead and the facial cleanser. The activated carbon bead disclosed by the invention is a novel material developed by the Mentholatum company and has the following advantages that an activated carbon gentle bead wrapping technology is advanced and novel, and as much as 95 percent of activated carbon can be wrapped; the activated carbon gentle bead is added to the facial cleanser and the activated carbon can be rapidly released only by lightly massaging the face when the facial cleanser is in use; and the activated carbon is wrapped in the activated carbon gentle bead, is isolated from the external world and can be gradually released only when in use, so a superstrong adsorption and cleaning ability of the activated carbon is fully played, and the adsorption ability of the facial cleanser comprising the activated carbon bead is more than 8 times that of an ordinary activated carbon facial cleanser.
Description
Technical field
The present invention relates to cosmetic field, specifically, the present invention relates to activated carbon beads, comprise its facial milk cleanser and their method for preparing.
Background technology
Active carbon is a kind of porous carbon containing matter; It has highly developed hole structure, and the loose structure of active carbon provides a large amount of surface areas for it, can fully contact with impurity; Thereby given active carbon peculiar absorption property, made it be very easy to reach the purpose that absorbs collection impurity.Active carbon is widely used in aspects such as air cleaning, sewage disposal, food industry, pharmaceuticals industry, chemical industry.In recent years, at cosmetic industry, the scientific research personnel utilizes the superpower absorbability of active carbon, is applied in gradually in the cosmetics such as facial milk cleanser, bath gel, facial film, fancy soap.But technology all is that active carbon is ground into fine particle or powder at present, directly adds in the cosmetics.But because active carbon has superpower absorbability, it is saturated to absorb water easily, is difficult to give play to the actual absorbability of active carbon, and cleaning effect is general.
Summary of the invention
The objective of the invention is to overcome the defective of prior art, a kind of facial milk cleanser that has the activated carbon beads of superpower absorbability and comprise this activated carbon beads is provided.
In order to realize the object of the invention; The present invention provides a kind of activated carbon beads; The particle diameter of said activated carbon beads is the 5-500 order; From inside outwards comprise: the active carbon layer of the kernel of 2-20 weight %, 40-95 weight % and the shell of 3-40 weight % preferably, from inside outwards comprise: the active carbon layer of the kernel of 8 weight %, 84 weight % and the shell of 8 weight %.
In activated carbon beads of the present invention, said kernel is the neutral substance kernel, and active carbon and shell are coated on the said kernel successively.Preferably, said kernel is the sucrose kernel.
In activated carbon beads of the present invention, said shell is the semipermeability coating membrane, is preferably the coating membrane of the mixture of hydroxypropyl emthylcellulose and corn starch.
In the shell of activated carbon beads of the present invention, hydroxypropyl emthylcellulose content is 1-39 weight %, and the content of corn starch is 1-39 weight %, and preferably, hydroxypropyl emthylcellulose content is 2 weight %, and the content of corn starch is 6 weight %.
Preferably, the particle diameter of activated carbon beads of the present invention is the 10-100 order, more preferably the 20-40 order.
Preferably, the activated carbon beads in the activated carbon beads of the present invention is one or more in bamboo charcoal, Linesless charcoal and the coconut husk charcoal.
The present invention also provides a kind of method for preparing of activated carbon beads, and this method comprises:
1) sucrose is processed piller with as kernel;
2) add active carbon, said active carbon is coated on the said kernel, and
3) use the anhydrous alcohol solution of the mixture of hydroxypropyl emthylcellulose and corn starch to carry out coating, making particle diameter is 5-500 purpose activated carbon beads.
During activated carbon beads of the present invention, can use the conventional pellet processing machine that uses in this area in preparation, for example available from the pellet processing machine of Chongqing Seiko pharmaceutical machine Co., Ltd.After making activated carbon beads; Make that the particle diameter of activated carbon beads is the 5-500 order, from inside outwards comprise: the shell of the corn starch of the active carbon layer of the kernel of 2-20 weight %, 40-95 weight % and the hydroxypropyl emthylcellulose of 1-20 weight % and 2-20 weight %.
Like what use among this paper, term " particle diameter " is a notion known in the art.In this article, if no special instructions, particle diameter adopts sieve method to measure.
The present invention also provides a kind of facial milk cleanser, comprises: acceptable carrier and surplus are water on the cosmetic conduct and learning of the soap class of the described activated carbon beads of 0.1-20 weight %, 2-40 weight % or surfactant, 0.1-5 weight %.
Preferably, facial milk cleanser of the present invention comprises: the water of acceptable carrier and 67.5 weight % on the cosmetic conduct and learning of the soap class of the described activated carbon beads of 2 weight %, 30 weight % or surfactant, 0.5 weight %.
As used herein, term " acceptable carrier on the cosmetic conduct and learning " is the routine techniques term of knowing in the cosmetic field, and it generally includes essence, antiseptic etc.
Preferably, said soap class obtains through following method: make in lauric acid, myristic acid, Palmic acid and the stearic acid one or more, make with potassium hydroxide or sodium hydroxide saponification.
Preferably, said surfactant is one or more in lauryl alcohol sodium sulfate, lauryl alcohol ammonium sulfate, cocoyl CAB and the fatty acid distribution of coconut oil diglycollic amide.
In addition, the present invention also provides a kind of method for preparing of facial milk cleanser, and this method comprises: first Jiang Shui and soap class or surfactant add container; Stir and be heated to 80 ℃ make dissolving fully after, continue to stir 20-60 minute, be cooled to 35-40 ℃ then while stirring; Add acceptable carrier on the cosmetic conduct and learning, continue stirring and be cooled to 25-35 ℃, slowly add described activated carbon beads equably; And after slowly stirring, promptly get.Stop allotment afterwards, can not open stirring more later on, and require that fill finishes in 48 hours.
Facial milk cleanser of the present invention is used hard-core technologies such as modern parcel and slow release, earlier active carbon is wrapped in the gentle pearl, adds prescription again to process the gentle pearl facial milk cleanser of active carbon; It is saturated to avoid active carbon in prescription, to absorb water; Massage gently during use, active carbon discharges gradually, and moment siphons away deep layer oils and fats dirt as magnetic force; Thoroughly clean aging cutin, thereby give full play to the superpower absorbability of active carbon.It has advantage: the gentle pearl technique for packing of active carbon is advanced novel, can wrap up nearly 95% active carbon; The gentle pearl of active carbon is added to facial milk cleanser, and shell is hard during harsh products, is difficult for brokenly, mixes after 2 days, and shell begins to soften, and only need massage gently during use, and active carbon is released rapidly; Active carbon is wrapped in the gentle pearl of active carbon, is isolated from the outside, and has only when use just to discharge gradually, gives full play to the superpower absorption and the cleaning capacity of active carbon, and absorbability is more than 8 times of common active carbon facial milk cleanser.
The specific embodiment
Following examples are used to explain the present invention, but are not used for limiting scope of the present invention.
The preparation of embodiment 1 activated carbon beads of the present invention
Proportioning (weight %):
The preparation process:
1. sucrose is added pellet processing machine limit pot, be heated to 60 ℃, add an amount of anhydrous alcohol again and make solvent (being working fluid with dissolving saccharose is advisable), stirring and dissolving becomes the working fluid state.
2. open the rotating fluidized bed of pellet processing machine; Temperature is controlled at 60-80 ℃, and sucrose solution is sprayed into rotating fluidized bed through nozzle, and sucrose is the circular motion of turning round rope form along locular wall; Anhydrous alcohol forms steam with the bottom hot blast and discharges fluid bed, and sucrose forms the 400-800 purpose ball heart (kernel) gradually.
3. active carbon is added pellet processing machine limit pot, be heated to 60 ℃, add an amount of anhydrous alcohol again and make solvent (being advisable to disperse the being flow slurry), stirring and dissolving becomes mobile pulpous state.At the equidirectional active carbon slurry that sprays into of tangent line and the motion of the ball heart, the active carbon powder in the adding rotating fluidized bed is coated on the core by bag and by round as a ball, the thermal current that blows out from crack makes piller dry, makes 40-100 purpose active carbon ball.
4. hydroxypropyl emthylcellulose and corn starch are added pellet processing machine limit pot, be heated to 60 ℃, add an amount of anhydrous alcohol again and make solvent (being advisable to disperse the being flow slurry), stirring and dissolving becomes mobile pulpous state.Equidirectional hydroxypropyl emthylcellulose and the corn starch mixed pulp of spraying in tangent line and the motion of charcoal ball; Add the hydroxypropyl emthylcellulose in the rotating fluidized bed and the corn starch mixture is coated on the charcoal ball by bag and by round as a ball; The thermal current that blows out from crack makes piller dry; Thereby active carbon is rolled into activated carbon beads, and particle diameter is the 20-40 order.
5. rotary fluid bedside rotation limit is cooled to 30 ℃, stops the rotation and dries the blanking from the bottom.
The preparation of embodiment 2 activated carbon beads of the present invention
According to preparing activated carbon beads with embodiment 1 identical mode, difference is to adopt following proportioning, and final activated carbon beads particle diameter is the 80-100 order.
Proportioning (weight %):
The preparation of embodiment 3 activated carbon beads of the present invention
According to preparing activated carbon beads with embodiment 1 identical mode, difference is to adopt following proportioning, and final activated carbon beads particle diameter is the 60-80 order.
Proportioning (weight %):
The preparation of embodiment 4 pure activated carbon beads
According to preparing activated carbon beads with embodiment 1 identical mode, difference is to use the active carbon of identical weight to come sucrose, active carbon, hydroxypropyl emthylcellulose and corn starch in the alternate embodiment 1.
The preparation of embodiment 5 facial milk cleanser of the present invention
Prescription (weight %):
The preparation process:
1. purified water, lauryl alcohol sodium sulfate, glycol distearate, citric acid are added container, be heated to 75-80 ℃, stirring and dissolving is complete.
2. in container, add cocoyl CAB, fatty acid distribution of coconut oil diglycollic amide and sodium chloride, 10-50r/min stirs 10-15 minute to mix homogeneously, cooling.
3. be cooled to 50 ℃, add activated carbon beads and glycerol, 10-20r/min stirs 10-20 minute to mix homogeneously, continues cooling.
4. be cooled to 40 ℃, add antiseptic and essence, 10-20r/min stirs 10-20 minute to mix homogeneously, continues cooling.
5. be cooled to 30 ℃, allotment finishes.
The preparation of embodiment 6 facial milk cleanser of the present invention
Prescription (weight %):
Technology:
1. water: purified water, glycerol, 1,3 butylene glycol, EDTA-2Na, potassium hydroxide are added suitable vessel, mix, be heated to 75-80 ℃, subsequent use.
2. oil phase: lauric acid, myristic acid, Palmic acid, stearic acid, glycol distearate are added suitable vessel, be heated to 75-80 ℃, 10-20r/min stirs 20-30 minute to mix homogeneously, and is subsequent use.
3. water and oil phase are mixed, homogenizing 5-10 minute, stop homogenizing then, insulated and stirred 60 minutes begins to cool down then.
4. be cooled to 45 ℃, add activated carbon beads, 10-20r/min stirs 10-20 minute to mix homogeneously, continues cooling.
5. be cooled to 40 ℃, add antiseptic, essence, 10-20r/min stirs 10-20 minute to mix homogeneously, cooling.
6. be cooled to 32 ℃, allotment finishes.
The preparation of embodiment 7 facial milk cleanser of the present invention
According to preparing facial milk cleanser with embodiment 5 identical modes, difference is to use the activated carbon beads for preparing among the embodiment 1 of 20 weight %.
The preparation of embodiment 8 facial milk cleanser of the present invention
According to preparing facial milk cleanser with embodiment 6 identical modes, difference is to use the pure activated carbon beads of preparation among the embodiment 4 to replace the activated carbon beads of the present invention of preparation among the embodiment 1.
Test Example
Use the facial milk cleanser of embodiment 6 preparations and the facial milk cleanser of embodiment 8 preparations to clean face, during use, said facial milk cleanser is massaged gently, evenly be coated in face then, use clear water to wash facial milk cleanser off after about 2 minutes.Each facial milk cleanser that uses equal weight.
According to following (a) 5 grades of evaluation criterions, estimated the facial milk cleanser of facial milk cleanser and embodiment 8 preparations of embodiment 6 preparation by 10 members of expert group: (1) is clearly felt, (2) cleaning effect.According to following (b) 4 grades of criterions, use the average mark of the sample that obtains through 5 grades of evaluation criterions to judge.
For the facial milk cleanser of embodiment 6 preparations,
Find through (a) 5 grades of evaluation criterion tests:
The mark of salubrious sense is respectively: 4,4,4,4,4,4,4,3,4,4;
The mark of cleaning effect is respectively: 4,4,4,4,4,4,4,4,4,4;
Find according to (b) 4 grades of criterion tests:
The average mark of salubrious sense is 3.9, and effect is excellent;
The average mark of cleaning effect is 4.0, and effect is excellent.
For the facial milk cleanser of embodiment 8 preparations,
Find through (a) 5 grades of evaluation criterion tests:
The mark of salubrious sense is respectively: 2,1,1,2,3,1,1,3,2,1;
The mark of cleaning effect is respectively: 1,2,1,1,1,2,1,1,2,1;
Find according to (b) 4 grades of criterion tests:
The average mark of salubrious sense is 1.7, and effect is general;
The average mark of cleaning effect is 1.3, and effect is for poor.
This shows that the salubrious sense of facial milk cleanser of the present invention and cleaning effect are far superior to adopt the facial milk cleanser of conventional Preparation of Activated Carbon.
Claims (12)
1. an activated carbon beads is characterized in that, the particle diameter of said activated carbon beads is the 5-500 order, from inside outwards comprises: the active carbon layer of the kernel of 2-20 weight %, 40-95 weight % and the shell of 3-40 weight %.
2. activated carbon beads according to claim 1 is characterized in that, from inside outwards comprises: the active carbon layer of the kernel of 8 weight %, 84 weight % and the shell of 8 weight %.
3. activated carbon beads according to claim 1 and 2 is characterized in that said kernel is the neutral substance kernel, is preferably the sucrose kernel.
4. activated carbon beads according to claim 1 and 2 is characterized in that said shell is the semipermeability coating membrane, is preferably the coating membrane of the mixture of hydroxypropyl emthylcellulose and corn starch.
5. according to each described activated carbon beads in the claim 1 to 4, it is characterized in that the particle diameter of said activated carbon beads is the 20-40 order.
6. according to each described activated carbon beads in the claim 1 to 4, it is characterized in that said activated carbon beads is one or more in bamboo charcoal, Linesless charcoal and the coconut husk charcoal.
7. the method for preparing of an activated carbon beads, this method comprises:
1) sucrose is processed piller with as kernel;
2) add active carbon, said active carbon is coated on the said kernel, and
3) use the anhydrous alcohol solution of the mixture of hydroxypropyl emthylcellulose and corn starch to carry out coating, making particle diameter is 5-500 purpose activated carbon beads.
8. facial milk cleanser; It is characterized in that, comprise: 0.1-20 weight %'s is water according to acceptable carrier and surplus on the cosmetic conduct and learning of the soap class of each described activated carbon beads, 2-40 weight % in the claim 1 to 6 or surfactant, 0.1-5 weight %.
9. facial milk cleanser according to claim 8; It is characterized in that, comprise: the water of 2 weight % according to acceptable carrier and 67.5 weight % on the cosmetic conduct and learning of the soap class of each described activated carbon beads, 30 weight % in the claim 1 to 6 or surfactant, 0.5 weight %.
10. according to Claim 8 or 9 described facial milk cleanser, it is characterized in that said soap class obtains through following method: make in lauric acid, myristic acid, Palmic acid and the stearic acid one or more, make with potassium hydroxide or sodium hydroxide saponification.
11. according to Claim 8 or 9 described facial milk cleanser, it is characterized in that said surfactant is one or more in lauryl alcohol sodium sulfate, lauryl alcohol ammonium sulfate, cocoyl CAB and the fatty acid distribution of coconut oil diglycollic amide.
12. the method for preparing of a facial milk cleanser, this method comprises: first Jiang Shui and soap class or surfactant add container, stir and be heated to 80 ℃ make dissolving fully after; Continue to stir 20-60 minute, be cooled to 35-40 ℃ then while stirring, add acceptable carrier on the cosmetic conduct and learning; Continue to stir and be cooled to 25-35 ℃; Slowly add equably according to each described activated carbon beads in the claim 1 to 6, and after slowly stirring, promptly get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210344776.6A CN102836099B (en) | 2012-09-18 | 2012-09-18 | Activated carbon bead, facial cleanser comprising same and preparation methods thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210344776.6A CN102836099B (en) | 2012-09-18 | 2012-09-18 | Activated carbon bead, facial cleanser comprising same and preparation methods thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102836099A true CN102836099A (en) | 2012-12-26 |
| CN102836099B CN102836099B (en) | 2014-01-01 |
Family
ID=47364004
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210344776.6A Active CN102836099B (en) | 2012-09-18 | 2012-09-18 | Activated carbon bead, facial cleanser comprising same and preparation methods thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102836099B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104069026A (en) * | 2014-07-17 | 2014-10-01 | 广州丹奇日用化工厂有限公司 | Facial cleanser and preparation method |
| CN104921999A (en) * | 2015-06-24 | 2015-09-23 | 陈威宇 | Oil-control antioxidant cleanser |
| CN107095833A (en) * | 2016-02-23 | 2017-08-29 | 欧诗漫生物股份有限公司 | A kind of face cleaning composition |
| CN107095834A (en) * | 2016-02-23 | 2017-08-29 | 欧诗漫生物股份有限公司 | A kind of whitening cleansing milk |
| CN107625669A (en) * | 2017-10-13 | 2018-01-26 | 北京洛娃日化有限公司 | A kind of shower cream and preparation method |
| CN108606934A (en) * | 2016-12-12 | 2018-10-02 | 苏州朗力福保健品有限公司 | A kind of anti-blackhead mildy wash of man's multiple-effect and preparation method thereof |
| CN108743416A (en) * | 2018-07-08 | 2018-11-06 | 东莞市联洲知识产权运营管理有限公司 | A kind of activated carbon base face cleaning cosmetics and preparation method thereof that yolk ball is modified |
| CN109223700A (en) * | 2018-11-23 | 2019-01-18 | 谢树群 | A kind of facial cleanser formula with bactericidal effect |
| CN113116785A (en) * | 2021-05-08 | 2021-07-16 | 何平蓉 | Cleaning massage shower gel and preparation method thereof |
| CN113197826A (en) * | 2021-05-18 | 2021-08-03 | 何平蓉 | Massage type facial cleanser with high moisture retention, high cleaning power and low irritation and preparation method thereof |
| CN115532224A (en) * | 2022-09-20 | 2022-12-30 | 中国科学院上海高等研究院 | Vegetable gum coated active carbon for blood perfusion, preparation method and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022090433A1 (en) * | 2020-10-30 | 2022-05-05 | Da Volterra | Method for the manufacture of an adsorbent formulation |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1723877A (en) * | 2005-05-27 | 2006-01-25 | 徐建国 | Cleansing milk contg. bamboo charcoal |
| CN101327423A (en) * | 2008-08-01 | 2008-12-24 | 东南大学 | Spherical particle compound material containing active carbon and preparation technique thereof |
| CN101343083A (en) * | 2008-05-15 | 2009-01-14 | 复旦大学 | Magnetic carbon sphere of surface finished C8 alkyl chain, preparation and application thereof |
| CN102580678A (en) * | 2012-02-29 | 2012-07-18 | 福州大学 | Inorganic gelling active carbon particle with shell structure and preparation method thereof |
-
2012
- 2012-09-18 CN CN201210344776.6A patent/CN102836099B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1723877A (en) * | 2005-05-27 | 2006-01-25 | 徐建国 | Cleansing milk contg. bamboo charcoal |
| CN101343083A (en) * | 2008-05-15 | 2009-01-14 | 复旦大学 | Magnetic carbon sphere of surface finished C8 alkyl chain, preparation and application thereof |
| CN101327423A (en) * | 2008-08-01 | 2008-12-24 | 东南大学 | Spherical particle compound material containing active carbon and preparation technique thereof |
| CN102580678A (en) * | 2012-02-29 | 2012-07-18 | 福州大学 | Inorganic gelling active carbon particle with shell structure and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 胡迎春: "面部护理品", 《中国化妆品》 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104069026A (en) * | 2014-07-17 | 2014-10-01 | 广州丹奇日用化工厂有限公司 | Facial cleanser and preparation method |
| CN104921999A (en) * | 2015-06-24 | 2015-09-23 | 陈威宇 | Oil-control antioxidant cleanser |
| CN107095833A (en) * | 2016-02-23 | 2017-08-29 | 欧诗漫生物股份有限公司 | A kind of face cleaning composition |
| CN107095834A (en) * | 2016-02-23 | 2017-08-29 | 欧诗漫生物股份有限公司 | A kind of whitening cleansing milk |
| CN108606934A (en) * | 2016-12-12 | 2018-10-02 | 苏州朗力福保健品有限公司 | A kind of anti-blackhead mildy wash of man's multiple-effect and preparation method thereof |
| CN107625669A (en) * | 2017-10-13 | 2018-01-26 | 北京洛娃日化有限公司 | A kind of shower cream and preparation method |
| CN108743416A (en) * | 2018-07-08 | 2018-11-06 | 东莞市联洲知识产权运营管理有限公司 | A kind of activated carbon base face cleaning cosmetics and preparation method thereof that yolk ball is modified |
| CN108743416B (en) * | 2018-07-08 | 2021-04-27 | 江西登云健康美业互联有限公司 | Yolk ball modified activated carbon-based cleansing cosmetic and preparation method thereof |
| CN109223700A (en) * | 2018-11-23 | 2019-01-18 | 谢树群 | A kind of facial cleanser formula with bactericidal effect |
| CN113116785A (en) * | 2021-05-08 | 2021-07-16 | 何平蓉 | Cleaning massage shower gel and preparation method thereof |
| CN113197826A (en) * | 2021-05-18 | 2021-08-03 | 何平蓉 | Massage type facial cleanser with high moisture retention, high cleaning power and low irritation and preparation method thereof |
| CN115532224A (en) * | 2022-09-20 | 2022-12-30 | 中国科学院上海高等研究院 | Vegetable gum coated active carbon for blood perfusion, preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102836099B (en) | 2014-01-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102836099B (en) | Activated carbon bead, facial cleanser comprising same and preparation methods thereof | |
| JP5675459B2 (en) | Scrub agent for cleaning composition and cleaning composition | |
| KR20030075192A (en) | Delivery system having encapsulated porous carrier loaded with additives | |
| CN109464377B (en) | Biological antibacterial shower gel and preparation method thereof | |
| CN106904603A (en) | A kind of corrosion inhibiter microcapsules based on graphene roll and preparation method thereof | |
| CN103784339A (en) | Abrasive skin cleaning product free of emulsifier | |
| CN105886137A (en) | High-density low temperature quickly dissolved washing powder and preparation method thereof | |
| EP2185679A1 (en) | Encapsulated active ingredients for cleaning applications | |
| TWI257424B (en) | Detergent particle | |
| DE60320679T2 (en) | SOFTWARE, MECHANICALLY STABLE, ROBUST GRANULES | |
| CN102559422B (en) | Soapberry detergent and preparation method thereof | |
| CN101703540A (en) | Celeryseed extract pellets and preparation method thereof | |
| JP3071427B2 (en) | Enzyme particles | |
| CN113563987A (en) | Fabric combined antibacterial mite-killing nursing fragrance retaining agent and preparation method thereof | |
| JP6063726B2 (en) | Pigment granules | |
| TW202039811A (en) | Salt-sensitive particles | |
| CN105018250A (en) | Novel application of biologic cellulose in leather cleaner preparation | |
| JP6063725B2 (en) | Pigment granules | |
| CN114712325B (en) | Coated suspended particles, preparation method and application thereof | |
| CN108384673B (en) | Environment-friendly laundry detergent | |
| JP2005179530A (en) | Coated particle for detergent composition and detergent composition | |
| JPH06239733A (en) | Facial cleansing agent | |
| CN117731555A (en) | Body scrub cream integrating washing and caring and preparation method thereof | |
| CN117285993A (en) | Laundry effervescent tablet and preparation method thereof | |
| CN106566732A (en) | Phosphorus-free, fluorescent agent-free and preservative-free super-concentrated capsule granule laundry detergent, preparation method and use method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |