CN102828414A - Viscose rayon environment-friendly size for water-spraying weaving - Google Patents
Viscose rayon environment-friendly size for water-spraying weaving Download PDFInfo
- Publication number
- CN102828414A CN102828414A CN2012103508083A CN201210350808A CN102828414A CN 102828414 A CN102828414 A CN 102828414A CN 2012103508083 A CN2012103508083 A CN 2012103508083A CN 201210350808 A CN201210350808 A CN 201210350808A CN 102828414 A CN102828414 A CN 102828414A
- Authority
- CN
- China
- Prior art keywords
- sizing
- environment
- viscose rayon
- agent
- friendly size
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an environment-friendly size for viscose rayon sizing. The environment-friendly size is characterized by being prepared from the following components in proportion by weight: 75%-79% of de-ionized water, 18%-22% of PE (Poly Ethylene) particle size, 0.4%-0.6% of penetrating agent, 1%-2% of smoothing agent and 0.2%-0.4% of de-foaming agent. The invention further discloses a preparation method of the environment-friendly size and a sizing process thereof. The environment-friendly size for the viscose rayon sizing disclosed by the invention is moderate and safe, is made from the raw materials easy to obtain, and is not easy to drop, simple for desizing and good in biological degradability in a process of weaving the viscose rayon on a water-spraying weaving machine.
Description
Technical field
The present invention relates to the textile auxiliary field, be specifically related to a kind of viscose rayon sizing and use environment-friendly size.
Background technology
What the viscose rayon sizing generally used is the cotton starch size of using; Produce with air-jet loom and too big problem can not occur; But when loom is used into water jet looms instead, in the weaving process, during starch slurry weaves on the viscose rayon grey cloth destarch pre-treatment; Need put in order as desizing agent with NaOH or starch destarch enzyme, can produce a large amount of industrial wastewaters; Starch slurry on the viscose rayon, starch slurry can be met water and come off; The yarn sizing material comes off, and brute force descended suddenly when viscose glue people silk was met water, caused being easy to take place serious cracked ends, can not weave; For this reason, study that both environmental protection are prone to destarch and in the water spray weaving process difficult drop-off cause the viscose rayon of cracked ends to use slurry, be the technical barrier that China textile industry technical staff needs to be resolved hurrily.
Summary of the invention
To the problem that above-mentioned prior art exists, the present invention provides a kind of viscose rayon sizing to use environment-friendly size, on water jet looms, weaves difficult drop-off in the viscose rayon process, is prone to destarch.
For solving the problem that above-mentioned prior art exists, the technical scheme that the present invention takes is: a kind of viscose rayon sizing is used environment-friendly size, it is characterized in that the raw material weight ratio of said slurry is:
Deionized water: 75-79%,
PE particle slurry: 18-22%,
Bleeding agent: 4-6 ‰,
Smooth agent: 1-2%,
Antifoaming agent: 2-4 ‰.
Described PE particle slurry is the liquid polyester slurry, is processed by the terylene thread section, and can form serous coat on the warp thread surface during water jet looms is weaved has resistance to water; Said PE particle slurry is identical with the spun polyester thread composition, promptly all is polyester macromolecule, and according to the similar compatibility principle, this slurry has higher adhesion to polyester fiber, and is water insoluble in the weaving process, do not have the slurry phenomenon, reduces cracked ends; On the big molecule of sizing material polyester, introduce certain water-soluble monomer simultaneously, make it under the condition about 95 ℃, just can come off from yam surface, make things convenient for the destarch arrangement, slurry has biodegradability preferably, satisfies environmental requirement.
Said bleeding agent is fast penetrant T (Xingtai is contained and reached auxiliary agent Co., Ltd); It is diisooctyl succinate sodium sulfonate; Soluble in water, solution is oyster white, not anti-strong acid, highly basic, heavy metallic salt and reductant; Infiltration fast, evenly has good wetting, infiltration, emulsification, frothing capacity.
Said smooth agent is two amido functional group organic silicon emulsions (articles for use Co., Ltd is knitted in Dongguan too paj), and the adding of smooth agent can strengthen the intensity and the elasticity of yarn after the starching.
Said antifoaming agent is silicone defoaming agent JX8368 (the ten thousand one-tenth Environmental Protection Technology Co., Ltd in Guangzhou); This antifoaming agent can have good froth breaking in the slurry production process, press down bubble effect and acid and alkali-resistance, high temperature resistant, can not produce the quality that reaction influences starching because of breakdown of emulsion or with slurry.
A kind of viscose rayon sizing is with the preparation method of environment-friendly size:
A, add the deionized water of 35-45% in the agitated reactor, open steam valve,, add the PE particle slurry of 18-22%, constantly stir 45min simultaneously, it is fully dissolved when reactor temperature rises to 85-95 ℃;
Add the deionized water of the remaining 30-44% of prescription in B, the reaction system after steps A again, and constantly stirred 20 minutes, cool to 35 ℃;
Add the bleeding agent of 4-6 ‰, the smooth agent of 1-2% in C, the reaction system behind step B, stirred 20 minutes, slowly drip the antifoaming agent of 2-4 ‰ simultaneously, stir 30min, can.
A kind of viscose rayon sizing is with the sizing technique of environment-friendly size, and technological parameter is:
(1) slurry concentration of input slurries is 14%, and the rate of sizing is controlled at 5-7%;
(2) move back that to separate tension force be 0.15g/D, coiling tension is 0.2g/D;
(3) drying room temperature: 140 ℃ in first drying room, 140 ℃ in second drying room, the elongation of yarn is 0.8% between feeding roller and the starching roller, the elongation of yarn is 1.5% between drying room and the cylinder;
(4) 5 cylinder temperature are: 100-105 ℃, 105 ℃, 105 ℃, 98-102 ℃, 100 ℃.
Sizing of the present invention is used environment-friendly size, and technology is simple, in the process of preparation and use, does not all contain any harmful organic solvent, gentle safety; And the raw material of environment-friendly size of the present invention is easy to get, and is cheap, and the adhesiveness of slurry and fiber is good, the slurry phenomenon that can not fall in the weaving process, and the rate of sizing is merely 2/3 of polyacrylic slurry at 5-7%; Sizing technique is easy to operate, and the sizing bake out temperature is lower, and general sizing drying room temperature is 152 ℃, and this slurry only needs 130-140 ℃, preferred 135 ℃, can cut down the consumption of energy greatly; After the starching, smooth, wear-resisting, pliable and tough and the serous coat of the surface-coated one deck of viscose rayon organizine with certain intensity, the viscose rayon organizine can be weaved on water jet looms smoothly, has solved with water jet looms and has weaved the difficult problem that viscose rayon is done organizine; In back arrangement process, also be prone to destarch, biological degradability is good.
The specific embodiment
Below in conjunction with the specific embodiment the present invention is elaborated.
Embodiment 1
A kind of viscose rayon sizing is used environment-friendly size; The weight ratio of its raw material is: deionized water: 75.4%, and the liquid polyester slurry: 22%, diisooctyl succinate sodium sulfonate: 4 ‰; Two amido functional group organic silicon emulsions: 2%, silicone defoaming agent JX8368:2 ‰.
A kind of viscose rayon sizing is with the preparation method of environment-friendly size:
A, add 35% deionized water in the agitated reactor, open steam valve,, add 22% liquid polyester slurry, constantly stir 45min simultaneously, it is fully dissolved when reactor temperature rises to 95 ℃;
Add the deionized water of prescription remaining 40.4% in B, the reaction system after steps A again, and constantly stirred 20 minutes, cool to 35 ℃;
Add 4 ‰ diisooctyl succinate sodium sulfonate, two amido functional group organic silicon emulsions of 2% in C, the reaction system behind step B, stirred 20 minutes, slowly drip 2 ‰ silicone defoaming agent JX8368 simultaneously, stir 30min, can.
Embodiment 2
A kind of viscose rayon sizing is used environment-friendly size; The raw material weight ratio that it is characterized in that said slurry is: deionized water: 79%, and the liquid polyester slurry: 19%, diisooctyl succinate sodium sulfonate: 6 ‰; Two amido functional group organic silicon emulsions: 1%, silicone defoaming agent JX8368:4 ‰.
A kind of viscose rayon sizing is with the preparation method of environment-friendly size:
A, add 45% deionized water in the agitated reactor, open steam valve,, add 19% liquid polyester slurry, constantly stir 45min simultaneously, it is fully dissolved when reactor temperature rises to 85 ℃;
Add the deionized water of prescription remaining 34% in B, the reaction system after steps A again, and constantly stirred 20 minutes, cool to 35 ℃;
Add 6 ‰ diisooctyl succinate sodium sulfonate, two amido functional group organic silicon emulsions of 1% in C, the reaction system behind step B, stirred 20 minutes, slowly drip 4 ‰ silicone defoaming agent JX8368 simultaneously, stir 30min, can.
Embodiment 3
A kind of viscose rayon sizing is used environment-friendly size; The raw material weight ratio that it is characterized in that said slurry is: deionized water: 77.7%, and the liquid polyester slurry: 20%, diisooctyl succinate sodium sulfonate: 5 ‰; Two amido functional group organic silicon emulsions: 1.5%, silicone defoaming agent JX8368:3 ‰.
A kind of viscose rayon sizing is with the preparation method of environment-friendly size:
A, add 40% deionized water in the agitated reactor, open steam valve,, add 20% liquid polyester slurry, constantly stir 45min simultaneously, it is fully dissolved when reactor temperature rises to 90 ℃;
Add the deionized water of prescription remaining 37.7% in B, the reaction system after steps A again, and constantly stirred 20 minutes, cool to 35 ℃;
Add 5 ‰ diisooctyl succinate sodium sulfonate, two amido functional group organic silicon emulsions of 1.5% in C, the reaction system behind step B, stirred 20 minutes, slowly drip 3 ‰ silicone defoaming agent JX8368 simultaneously, stir 30min, can.
Embodiment 4
The prepared viscose rayon sizing of embodiment 1-3 is with the sizing technique of environment-friendly size, and its parameter is:
(1) slurry concentration of input slurries is 14%, and the rate of sizing is controlled at 7%;
(2) move back that to separate tension force be 0.15g/D, coiling tension is 0.2g/D;
(3) drying room temperature: 140 ℃ in first drying room, 140 ℃ in second drying room, the elongation of yarn is 0.8% between feeding roller and the starching roller, the elongation of yarn is 1.5% between drying room and the cylinder
(4) 5 cylinder temperature are: 105 ℃, 105 ℃, 105 ℃, 100 ℃, 100 ℃.
Embodiment 5
The prepared viscose rayon sizing of embodiment 1-3 is with the sizing technique of environment-friendly size, and its parameter is:
(1) slurry concentration of input slurries is 14%, and the rate of sizing is controlled at 5%;
(2) move back that to separate tension force be 0.15g/D, coiling tension is 0.2g/D;
(3) drying room temperature: 140 ℃ in first drying room, 140 ℃ in second drying room, the elongation of yarn is 0.8% between feeding roller and the starching roller, the elongation of yarn is 1.5% between drying room and the cylinder
(4) 5 cylinder temperature are: 100 ℃, 105 ℃, 105 ℃, 98 ℃, 100 ℃.
Claims (7)
1. a viscose rayon sizing is used environment-friendly size, it is characterized in that the raw material weight ratio of said slurry is:
Deionized water: 75-79%,
PE particle slurry: 18-22%,
Bleeding agent: 4-6 ‰,
Smooth agent: 1-2%,
Antifoaming agent: 2-4 ‰.
2. a kind of viscose rayon sizing according to claim 1 is used environment-friendly size, it is characterized in that: described PE particle slurry is the liquid polyester slurry.
3. use environment-friendly size according to claim 1 or 2 each described a kind of viscose rayon sizing, it is characterized in that: said bleeding agent is a fast penetrant T, i.e. diisooctyl succinate sodium sulfonate.
4. use environment-friendly size according to claim 1 or 2 each described a kind of viscose rayon sizing, it is characterized in that: said smooth agent is two amido functional group organic silicon emulsions.
5. use environment-friendly size according to claim 1 or 2 each described a kind of viscose rayon sizing, it is characterized in that: said antifoaming agent is silicone defoaming agent JX8368.
6. the preparation method of the described environment-friendly size of claim 1 comprises the steps:
A, add the deionized water of 35-45% in the agitated reactor, open steam valve,, add the PE particle slurry of 18-22%, constantly stir 45min simultaneously, it is fully dissolved when reactor temperature rises to 85-95 ℃;
Add the deionized water of the remaining 30-44% of prescription in B, the reaction system after steps A again, and constantly stirred 20 minutes, cool to 35 ℃;
Add the bleeding agent of 4-6 ‰, the smooth agent of 1-2% in C, the reaction system behind step B, stirred 20 minutes, slowly drip the antifoaming agent of 2-4 ‰ simultaneously, stir 30min, can.
7. the sizing technique of the prepared environment-friendly size of a claim 6, technological parameter is:
(1) slurry concentration of input slurries is 14%, and the rate of sizing is controlled at 5-7%;
(2) move back that to separate tension force be 0.15g/D, coiling tension is 0.2g/D;
(3) the drying room temperature is: 140 ℃ in first drying room, and 140 ℃ in second drying room, the elongation of yarn is 0.8% between feeding roller and the starching roller, the elongation of yarn is 1.5% between drying room and the cylinder;
(4) 5 cylinder temperature are: 100-105 ℃, 105 ℃, 105 ℃, 98-102 ℃, 100 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103508083A CN102828414A (en) | 2012-09-20 | 2012-09-20 | Viscose rayon environment-friendly size for water-spraying weaving |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103508083A CN102828414A (en) | 2012-09-20 | 2012-09-20 | Viscose rayon environment-friendly size for water-spraying weaving |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102828414A true CN102828414A (en) | 2012-12-19 |
Family
ID=47331709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103508083A Pending CN102828414A (en) | 2012-09-20 | 2012-09-20 | Viscose rayon environment-friendly size for water-spraying weaving |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102828414A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106065526A (en) * | 2016-07-05 | 2016-11-02 | 广东汇益纺织有限公司 | For improving penetrating agent and the using method of dark fine count fiber fabric color fastness |
| CN108004771A (en) * | 2017-11-14 | 2018-05-08 | 浙江玉帛纺织有限公司 | A kind of environment-friendly size auxiliary agent and preparation method and application |
| CN114032689A (en) * | 2021-12-15 | 2022-02-11 | 温州百德富新材料有限公司 | Water-based woven tape sizing slurry and preparation method thereof |
| CN114635218A (en) * | 2022-03-22 | 2022-06-17 | 嘉兴金亿帆纺织科技股份有限公司 | Production process of fine denier filament ultrathin fabric |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333792A (en) * | 1998-12-03 | 2002-01-30 | 伊斯曼化学公司 | Terephthalate-based sulfopolyesters |
| CN102079812A (en) * | 2010-11-16 | 2011-06-01 | 苏州瀚海化学有限公司 | Water-soluble copolyester and preparation method thereof |
-
2012
- 2012-09-20 CN CN2012103508083A patent/CN102828414A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333792A (en) * | 1998-12-03 | 2002-01-30 | 伊斯曼化学公司 | Terephthalate-based sulfopolyesters |
| CN102079812A (en) * | 2010-11-16 | 2011-06-01 | 苏州瀚海化学有限公司 | Water-soluble copolyester and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 洪仲秋: "纺织浆料助剂的功能及应用", 《棉纺织技术》 * |
| 王伟等: "津田驹KS-200型浆丝机上浆工艺实践", 《丝绸》 * |
| 王文彬等: "喷水织机浆料SP-6，SG-15及其上浆工艺", 《丝绸》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106065526A (en) * | 2016-07-05 | 2016-11-02 | 广东汇益纺织有限公司 | For improving penetrating agent and the using method of dark fine count fiber fabric color fastness |
| CN108004771A (en) * | 2017-11-14 | 2018-05-08 | 浙江玉帛纺织有限公司 | A kind of environment-friendly size auxiliary agent and preparation method and application |
| CN114032689A (en) * | 2021-12-15 | 2022-02-11 | 温州百德富新材料有限公司 | Water-based woven tape sizing slurry and preparation method thereof |
| CN114032689B (en) * | 2021-12-15 | 2023-12-26 | 温州百德富新材料有限公司 | Aqueous braid sizing slurry and preparation method thereof |
| CN114635218A (en) * | 2022-03-22 | 2022-06-17 | 嘉兴金亿帆纺织科技股份有限公司 | Production process of fine denier filament ultrathin fabric |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105887283B (en) | Regenerated polyester fiber fabric and its production technology | |
| CN102828414A (en) | Viscose rayon environment-friendly size for water-spraying weaving | |
| CN105603710A (en) | Environmentally-friendly desizing agent used for high-density polyester fabric and preparation method thereof | |
| CN104480755A (en) | Novel dyeing and finishing processing process for pure linen varieties | |
| CN107956041A (en) | A kind of glass fabric with high tenacity | |
| CN101736586B (en) | Special size composition for sizing hank yarns | |
| CN104328778B (en) | Fiberglass sand-fixing net and weaving method thereof | |
| CN204112047U (en) | Adopt the technological equipment of scouringing and bleaching in the continuous liquid of chemical & blended fabric open width of environmental auxiliary agent | |
| CN102277736B (en) | Highly-alkaliproof mercerizing and infiltrating refining agent | |
| CN103898752A (en) | Textile size applicable to high-count cotton fabrics | |
| CN204370111U (en) | Long filament one side velvet fabric | |
| CN107724082A (en) | A kind of destarch fabric production technology | |
| CN101892566B (en) | High-count and high-density pure linen grey cloth warp sizing method | |
| CN109403035A (en) | A kind of spinning sizing agent and preparation method thereof | |
| CN102321969B (en) | Green environment-friendly dyeing process for all-cotton fabrics | |
| CN103465487A (en) | Manufacturing method of weighing machine conveying belt | |
| CN108755139A (en) | A kind of preparation method of poplin cloth class close weave starching slurry | |
| CN102875826B (en) | Starch textile size, preparation method thereof and warp sizing method | |
| CN109183406A (en) | Environmentally friendly refining agent of a kind of weaving and preparation method thereof | |
| CN204370112U (en) | The two-sided velvet fabric of long filament | |
| CN105399891B (en) | A kind of water-soluble polymer for handling cotton warp thread and its application | |
| CN106381677A (en) | Desizing method of pine needle fine hair fabric | |
| CN114351483B (en) | Energy-saving and emission-reducing wet-process sizing process and application thereof in production of sizing and dyeing combination machine | |
| CN106381673A (en) | Desizing treatment method of cotton-terylene blended fabric | |
| CN106381681A (en) | Sizing technology of coral fleece fabric yarns |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20121219 |