CN102828070B - Protective coating material for boiler pipeline - Google Patents
Protective coating material for boiler pipeline Download PDFInfo
- Publication number
- CN102828070B CN102828070B CN201210305846.7A CN201210305846A CN102828070B CN 102828070 B CN102828070 B CN 102828070B CN 201210305846 A CN201210305846 A CN 201210305846A CN 102828070 B CN102828070 B CN 102828070B
- Authority
- CN
- China
- Prior art keywords
- coating material
- coated material
- protective coating
- boiler
- surplus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 36
- 239000011253 protective coating Substances 0.000 title abstract 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- 230000004888 barrier function Effects 0.000 claims description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims description 12
- 229910052719 titanium Inorganic materials 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 229910052748 manganese Inorganic materials 0.000 claims description 11
- 229910052758 niobium Inorganic materials 0.000 claims description 11
- 238000000034 method Methods 0.000 description 14
- 239000010936 titanium Substances 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 238000005260 corrosion Methods 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000000280 densification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910001080 W alloy Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005254 chromizing Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Landscapes
- Other Surface Treatments For Metallic Materials (AREA)
- Coating By Spraying Or Casting (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a protective coating material for a boiler pipeline. The protective coating material comprises the following components by weight percent: 12%-14% of Cr, 0.4%-0.6% of Mn, 2%-3% of Ti, 3%-5% of Al, 2%-4% of Si, 1%-2% of Nb, 8%-12% of Fe, 1%-3% of Co, 3%-5% of Mo, less than or equal to 0.025% of S, less than or equal to 0.035% of P and the balance of Ni.
Description
Technical field
The present invention relates to coated material preparation field, particularly a kind of boiler tubing barrier material.
Background technology
In coal-fired power plant, boiler in hot environment, is subject to flue gas or is suspended in ash content effect wherein for a long time, and the high temperature corrosion that can occur in various degree comprises high temperature oxidation, vitriol high temperature corrosion, sulphur corrosion, muriate high temperature corrosion etc.High-temperature high-pressure boiler " four pipes " the high temperature corrosion phenomenon of (being water wall tube, superheater tube, reheating pipe, economizer tube) and a series of serious consequences such as such as booster of bringing are therefrom power industry difficult problems anxious to be resolved always.
Adopting hot-spraying techniques to prevent boi1er tube is the effective means in a kind of prolonged boiler normal operation cycle.At home, the main sprayed protection technology adopting has at present: aluminium-plated protection, because the fusing point low of aluminium is 660.4 ℃, under low temperature environment, effect is pretty good, its creep strength is low, wear no resistance, the component such as high-temperature high-pressure boiler " four pipe " often need to bear certain abrasive action simultaneously, and these factors make the provide protection after aluminium-plated undesirable; Surfacing Ni-W alloy coat, although spray-welding coating combination is good, abrasion and corrosion is slight, and its technique weak point is that remelting temperature is too high, causes pipe deformation, and big area is used and is had any problem; Domestic also have the aluminising of employing, chromising to protect, but hot-dip process is generally only applicable to the coating of single-element composition, and the desired higher working temperature of the method (generally between 750-1100 ℃) all can produce certain impact for organize results and the performance of body material, and protection effect is not good enough.With abroad comparing, China starts late in the work aspect boi1er tube protection, lacks the bad working environments that is applicable to boiler running and the coated material simultaneously with good resistance to high temperature corrosion performance.
Publication number is that the application for a patent for invention of CN101260487A discloses a kind of titanium-containing high-chromium-nickel alloy, its composition consists of (weight percentage): 15%≤Cr≤25%, 1%≤Ti≤5%, 1%≤Si≤6%, 0 < C%≤0.20%, 20%≤Ni≤55%, 0.5%≤Re≤6%, 0 < Al≤6%, 0 < S≤0.035%, 0 < P≤0.035%, 0 < Mn≤0.2%, surplus is Fe.Although this patent has obtained certain improvement effect, its chrome content is higher, easily causes the bonding properties of its coating bad, after using after a while, easily peels off.
Summary of the invention
For the deficiencies in the prior art, one of object of the present invention is to provide a kind of boiler tubing barrier material, and this coated material has excellent anti-oxidant, sulfuration, nitrogenize and hydrogenation property, and strong with basal body binding force, the feature of long service life.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of boiler tubing barrier material, described coated material is comprised of following component by weight percentage: Cr:12%-14%, Mn:0.4%-0.6%, Ti:2%-3%, Al:3%-5%, Si:2%-4%, Nb:1%-2%, Fe:8%-12%, Co:1%-3%, Mo:3%-5%, S≤0.025%, P≤0.035%, surplus is Ni.
Preferably, described coated material is comprised of following component by weight percentage: Cr:12.5%-13.5%, Mn:0.45%-0.55%, Ti:2.3%-2.7%, Al:3.5%-4.5%, Si:2.5%-3.5%, Nb:1.3%-1.7%, Fe:9%-11%, Co:1.5%-2.5%, Mo:3.5%-4.5%, S≤0.025%, P≤0.035%, surplus is Ni.
Most preferably, described coated material is comprised of following component by weight percentage: Cr:13%, Mn:0.5%, Ti:2.5%, Al:4%, Si:3%, Nb:1.5%, Fe:10%, Co:2%, Mo:4%, S≤0.025%, P≤0.035%, surplus is Ni.
The present invention has following beneficial effect:
1) than prior art, reduced the content of Cr, the toughness of coating is increased, increase with the bonding force of matrix; But still assurance has the content of the Cr of enough erosion resistances.
2) Ti adding in coated material and Nb refinement the crystal grain of coated material, and in use, can form on surface one deck densification, in conjunction with firmly, the sull that can also automatically heal when damaged.
3) Cr, the Si that in coated material, add, Al can form intact densification and have with oxygen the oxide film (Cr of protectiveness when high temperature
2o
3, SiO
2, Al
2o
3), matrix is shielded;
4) in coated material, add appropriate Co and Mo, the resistance to elevated temperatures of material is improved.
5) optimization design the ratio of above-mentioned each component, make its various elements reach synergistic action technique effect, make coated material there is strong resistance to high temperature oxidation, high temperature resistance SO
2, H
2s, Na
2sO
4/ K
2sO
4deng the performance of dielectric corrosion.
Embodiment
Embodiment mono-
A kind of boiler tubing barrier material, described coated material is comprised of following component by weight percentage: Cr:12%, Mn:0.6%, Ti:2%, Al:5%, Si:2%, Nb:2%, Fe:8%, Co:3%, Mo:3%, S≤0.025%, P≤0.035%, surplus is Ni.
Embodiment bis-
A kind of boiler tubing barrier material, described coated material is comprised of following component by weight percentage: Cr:14%, Mn:0.4%, Ti:3%, Al:3%, Si:4%, Nb:1%, Fe:12%, Co:1%, Mo:5%, S≤0.025%, P≤0.035%, surplus is Ni.
Embodiment tri-
A kind of boiler tubing barrier material, described coated material is comprised of following component by weight percentage: Cr:12.5%, Mn:0.55%, Ti:2.3%, Al:4.5%, Si:2.5%, Nb:1.7%, Fe:9%, Co:2.5%, Mo:3.5%, S≤0.025%, P≤0.035%, surplus is Ni.
Embodiment tetra-
A kind of boiler tubing barrier material, described coated material is comprised of following component by weight percentage: Cr:13.5%, Mn:0.45%, Ti:2.7%, Al:3.5%, Si:3.5%, Nb:1.3%, Fe:11%, Co:1.5%, Mo:4.5%, S≤0.025%, P≤0.035%, surplus is Ni.
Embodiment five
A kind of boiler tubing barrier material, described coated material is comprised of following component by weight percentage: Cr:13%, Mn:0.5%, Ti:2.5%, Al:4%, Si:3%, Nb:1.5%, Fe:10%, Co:2%, Mo:4%, S≤0.025%, P≤0.035%, surplus is Ni.
Applicant's statement, the present invention illustrates detailed process equipment and process flow process of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and process flow process, do not mean that the present invention must rely on above-mentioned detailed process equipment and process flow process and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, and the selections of the equivalence replacement to the each raw material of product of the present invention and the interpolation of ancillary component, concrete mode etc., within all dropping on protection scope of the present invention and open scope.
Claims (3)
1. a boiler tubing barrier material, is characterized in that, described coated material is comprised of following component by weight percentage: Cr:12%-14%, Mn:0.4%-0.6%, Ti:2%-3%, Al:3%-5%, Si:2%-4%, Nb:1%-2%, Fe:8%-12%, Co:1%-3%, Mo:3%-5%, S≤0.025%, P≤0.035%, surplus is Ni.
2. a kind of boiler tubing barrier material as claimed in claim 1, is characterized in that, described coated material is comprised of following component by weight percentage: Cr:12.5%-13.5%, Mn:0.45%-0.55%, Ti:2.3%-2.7%, Al:3.5%-4.5%, Si:2.5%-3.5%, Nb:1.3%-1.7%, Fe:9%-11%, Co:1.5%-2.5%, Mo:3.5%-4.5%, S≤0.025%, P≤0.035%, surplus is Ni.
3. a kind of boiler tubing barrier material as claimed in claim 1 or 2, is characterized in that, described coated material is comprised of following component by weight percentage: Cr:13%, Mn:0.5%, Ti:2.5%, Al:4%, Si:3%, Nb:1.5%, Fe:10%, Co:2%, Mo:4%, S≤0.025%, P≤0.035%, surplus is Ni.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210305846.7A CN102828070B (en) | 2012-08-24 | 2012-08-24 | Protective coating material for boiler pipeline |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210305846.7A CN102828070B (en) | 2012-08-24 | 2012-08-24 | Protective coating material for boiler pipeline |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102828070A CN102828070A (en) | 2012-12-19 |
| CN102828070B true CN102828070B (en) | 2014-05-07 |
Family
ID=47331377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210305846.7A Active CN102828070B (en) | 2012-08-24 | 2012-08-24 | Protective coating material for boiler pipeline |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102828070B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108220857A (en) * | 2018-01-04 | 2018-06-29 | 西安热工研究院有限公司 | The anti-chlorine corrosion double-layer structure alloy coat of waste incinerator heating surface and preparation method |
| CN110284094B (en) * | 2019-07-04 | 2020-10-02 | 华北电力大学 | Preparation of high-temperature anticorrosive coating on boiler water-cooled wall and heat treatment synergistic enhancement technology of pipe matrix |
| CN115233136B (en) * | 2022-07-27 | 2024-06-18 | 西安热工研究院有限公司 | Anti-chlorine corrosion wear-resistant coating material, composite material and preparation method thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1037699C (en) * | 1995-05-09 | 1998-03-11 | 宝山钢铁(集团)公司 | Stainless corrosion-resistant conductive rolle rsleeve and making method thereof |
| JP4280898B2 (en) * | 2002-12-18 | 2009-06-17 | 住友金属工業株式会社 | Metal dusting metal material with excellent high temperature strength |
| DE10302989B4 (en) * | 2003-01-25 | 2005-03-03 | Schmidt + Clemens Gmbh & Co. Kg | Use of a heat and corrosion resistant nickel-chromium steel alloy |
| SE528807C2 (en) * | 2004-12-23 | 2007-02-20 | Siemens Ag | Component of a superalloy containing palladium for use in a high temperature environment and use of palladium for resistance to hydrogen embrittlement |
| JP4827047B2 (en) * | 2005-03-22 | 2011-11-30 | 国立大学法人九州工業大学 | Steel structure with corrosion resistance, wear resistance and heat crack resistance |
| EA022538B1 (en) * | 2008-12-01 | 2016-01-29 | Сэн-Гобэн Коутинг Солюшн | Coating for a device for shaping glass material |
| CN101798669B (en) * | 2009-02-06 | 2011-07-20 | 上海宝钢设备检修有限公司 | Method for thermally spraying protective coating on surface of copper plate of continuous casting crystallizer |
-
2012
- 2012-08-24 CN CN201210305846.7A patent/CN102828070B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN102828070A (en) | 2012-12-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103740983B (en) | High tough corrosion-resistant ageing strengthening type nickel-base alloy and direct aging heat treating method | |
| CN102808108B (en) | Method for preparing protective coating material of boiler tube | |
| CN102498225B (en) | Ni-based alloy material | |
| CN107042370B (en) | A kind of high-Cr Ni-base high-temperature alloy welding wire and preparation process | |
| CN103334055B (en) | Pipeline steel with resistance against carbon dioxide and hydrogen sulfide corrosion and preparation method thereof | |
| CN106893893B (en) | A kind of high-strength low expansion superalloy | |
| CN102828070B (en) | Protective coating material for boiler pipeline | |
| CN101260487A (en) | Spraying material prepared from titanium-containing high-chromium-nickel alloy and preparation method and application thereof | |
| CN104357751B (en) | A kind of valve two-phase stainless Steel material and preparation method thereof | |
| CN102286700B (en) | Sulfuric-acid-resistant dew point corrosion steel with tensile strength greater than or equal to 800Mpa grade and preparation method thereof | |
| CN105483495A (en) | Protective coating for boiler tube | |
| CN107755684A (en) | A kind of strong composite powder metallurgy material of wear resistant and impact resistant | |
| CN105506400A (en) | Aluminium alloy seamless steel tube | |
| KR20100114844A (en) | Acid-resistant steel material and low temperature member associated with exhaust gas of combustion·incineration facility | |
| CN107322180A (en) | A kind of biomass boiler anti-corrosion built-up welding Ni-based silk material and preparation method thereof | |
| CN106119691A (en) | A kind of ocean structure steel plate and manufacture method thereof | |
| CN105483469A (en) | High-toughness aluminium alloy steel pipe | |
| CN101538696A (en) | Hot spray wire for ultra supercritical boiler | |
| CN104775085A (en) | Corrosion-resistant iron-base alloy coating for thermal spraying and preparation method of alloy coating | |
| JPS61551A (en) | Heat resistant alloy having superior corrosion resistance in highly oxidizing and sulfurizing corrosive atmosphere | |
| CN102345086B (en) | Anti-oxidization and wear-resistance composite coating for four pipes of power plant boiler | |
| CN107641766A (en) | A kind of weathering steel for bridge structure | |
| CN103938033B (en) | A kind of mechanism multicomponent alloy material and preparation method thereof | |
| CN103060711B (en) | Method for preparing stainless steel for boiler | |
| CN109055866A (en) | A kind of corrosion resisting steel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: NINGBO SUNLIGHT MOTOR PARTS CO., LTD. Free format text: FORMER OWNER: ZHU XIAOYING Effective date: 20140410 |
|
| C14 | Grant of patent or utility model | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Dai Chufa Inventor before: Zhu Xiaoying |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: ZHU XIAOYING TO: DAI CHUFA Free format text: CORRECT: ADDRESS; FROM: 315181 NINGBO, ZHEJIANG PROVINCE TO: 315175 NINGBO, ZHEJIANG PROVINCE |
|
| GR01 | Patent grant | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20140410 Address after: Yinzhou District Lianfeng road 315175 Zhejiang city of Ningbo Province, No. 889 Applicant after: Ningbo Sunlight Motor Parts Co., Ltd. Address before: Yinzhou District Heng Jie Heng Jie Zhen Road 315181 No. 50 Zhejiang city of Ningbo Province Applicant before: Zhu Xiaoying |
|
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: 889 Lianfeng Middle Road, Gaoqiao Town, Haishu District, Ningbo City, Zhejiang Province Patentee after: NINGBO SUNLIGHT MOTOR PARTS Co.,Ltd. Address before: 315175 889 Luen Fung Road, Yinzhou District, Ningbo, Zhejiang Patentee before: NINGBO SUNLIGHT MOTOR PARTS Co.,Ltd. |