CN102827544A - Thermosetting water soluble resin antibacterial coating - Google Patents
Thermosetting water soluble resin antibacterial coating Download PDFInfo
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- CN102827544A CN102827544A CN2012103422241A CN201210342224A CN102827544A CN 102827544 A CN102827544 A CN 102827544A CN 2012103422241 A CN2012103422241 A CN 2012103422241A CN 201210342224 A CN201210342224 A CN 201210342224A CN 102827544 A CN102827544 A CN 102827544A
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- resin
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- thermoset
- water soluble
- soluble resin
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Abstract
The invention relates to a thermosetting water soluble resin antibacterial coating which comprises the components by weight percent: 5-15% of thermosetting organic resin, 0.1-0.5% of dryer, 25-30% of water-soluble modified resin, 3-5% of butanol, 2-6% of light calcium carbonate, 5-10% of precipitated barium sulphate, 2-8% of talcum powder, 5-15% of wet iron oxide red, 0.5-15% of antibacterial agent and 10-20% of deionized water. The thermosetting water soluble resin antibacterial coating has good water solubility and film-forming property, is low in price and free from toxin, harm and pollution, has good using performance, can be used for replacing various solvent based coatings, is good in antibacterial effect and can be used for surface coating of metal components.
Description
Technical field
The present invention relates to a kind of water soluble resin coating, relate in particular to a kind of thermoset water soluble resin antibiotic paint.
Background technology
Along with the progress and human attention to the living environment quality of science and technology, coatings industry just develops towards environment-friendly type, Water-borne modification direction, also for reducing or eliminating volatile organic compounds in the coating (VOC) effort.For realizing the Water-borne modification target of coating products, at first to resin be carried out Water-borne modification.The maximum solvent-borne type Synolac of output contains a large amount of volatile organic solvents on the market, in production, storage and transportation, exists inflammable and explosive dangerous hidden danger.
Summary of the invention
The objective of the invention is to overcome the deficiency of above-mentioned prior art, a kind of thermoset water soluble resin antibiotic paint is provided, can be used for the external coating of hardware.
Technical scheme: a kind of thermoset water soluble resin antibiotic paint, contain following composition: thermoset organic resin 5～15%, siccative 0.1～0.5% by weight percentage; Water-soluble modified resin 25～30%, butanols 3～5%, light calcium carbonate 2～6%; Process white 5～10%, talcum powder 2～8%, wet oxidation iron oxide red 5～15%; Antiseptic-germicide 0.5～15%, deionized water 10～20%.
Above-mentioned described thermoset water soluble resin antibiotic paint contains following composition: thermoset organic resin 10%, siccative 0.3% by weight percentage; Water-soluble modified resin 30%, butanols 4%, light calcium carbonate 5%; Process white 10%, talcum powder 8%, wet oxidation iron oxide red 10%; Antiseptic-germicide 10%, deionized water 12.7%.
Above-mentioned described thermoset organic resin is one of Synolac, vinyl resin, vibrin, urethane and their mixture.
Above-mentioned described water-soluble modified resin contains following composition by weight percentage: oleum lini 30%, MALEIC ANHYDRIDE 8%, petroleum resin 7%, catalyzer (PC) 0.01%, butanols 12%, organic amine 2%, ammoniacal liquor 6%, deionized water 35%.
It is that 0.01～1% weight and methylol substitution value are no less than 0.4 Walocel MT 20.000PV that above-mentioned described antiseptic-germicide contains silver content.
Beneficial effect: thermoset water soluble resin antibiotic paint provided by the invention; Have good water-solubility and film-forming properties; Cheap, nontoxic, harmless, pollution-free, also have good use properties and bacterinertness, can replace all kinds of SOLVENTS type coating; Good anti-bacterial effect can be used for the external coating of hardware.
Embodiment
Embodiment 1
1. thermoset water soluble resin antibiotic paint of the present invention; The preparation of said thermoset organic resin may further comprise the steps: select the thermoset organic resin; Make resin solidification and form solidified thermosetting resin, the solidified resin is processed the particle that granularity is not more than 20 microns.
2. thermoset water soluble resin antibiotic paint of the present invention, the preparation of said water-soluble modified resin: oleum lini 30%, petroleum resin 7% and MALEIC ANHYDRIDE 8% are mixed, stir, are heated to 170 ℃, add catalyzer (PC) 0.01%, continue to be heated to 210 ℃; Insulation reaction 1～1.5h when viscosity reaches 8～12s, cools, and adds organic amine 2%; Regulate pH=7.0～7.5 with ammoniacal liquor 6%, thin up is settlement separate then; Filter, discharging, subsequent use.
3. the preparation of thermoset water soluble resin antibiotic paint of the present invention: earlier thermoset organic resin 10%, water-soluble modified resin 30% and water are processed resin solution; Then siccative 0.3% is dissolved in butanols 4%, is added to again in the resin solution; Water is transferred to 2～4s with soltion viscosity; Then add light calcium carbonate 5%, process white 10%, talcum powder 8% and wet oxidation iron oxide red 10%, stir, add antiseptic-germicide 10% back and grind 3～4 times with sand mill, filter, discharging gets finished product.
Thermoset water soluble resin antibiotic paint provided by the invention, cheap, nontoxic, harmless, pollution-free, have good use properties and bacterinertness.
The above is the preferred embodiments of the present invention, but the present invention also is not limited to above only embodiment, on embodiment, does improvement slightly and also will be regarded as protection scope of the present invention.
Claims (5)
1. a thermoset water soluble resin antibiotic paint is characterized in that containing by weight percentage following composition: thermoset organic resin 5～15%, siccative 0.1～0.5%; Water-soluble modified resin 25～30%, butanols 3～5%, light calcium carbonate 2～6%; Process white 5～10%, talcum powder 2～8%, wet oxidation iron oxide red 5～15%; Antiseptic-germicide 0.5～15%, deionized water 10～20%.
2. thermoset water soluble resin antibiotic paint according to claim 1 is characterized in that containing by weight percentage following composition: thermoset organic resin 10%, siccative 0.3%; Water-soluble modified resin 30%, butanols 4%, light calcium carbonate 5%; Process white 10%, talcum powder 8%, wet oxidation iron oxide red 10%; Antiseptic-germicide 10%, deionized water 12.7%.
3. thermoset water soluble resin antibiotic paint according to claim 1 is characterized in that said thermoset organic resin is one of Synolac, vinyl resin, vibrin, urethane and their mixture.
4. thermoset water soluble resin antibiotic paint according to claim 1 is characterized in that said water-soluble modified resin contains following composition by weight percentage: oleum lini 30%, MALEIC ANHYDRIDE 8%; Petroleum resin 7%; Catalyzer (PC) 0.01%, butanols 12%, organic amine 2%; Ammoniacal liquor 6%, deionized water 35%.
5. thermoset water soluble resin antibiotic paint according to claim 1 is characterized in that it is that 0.01～1% weight and methylol substitution value are no less than 0.4 Walocel MT 20.000PV that said antiseptic-germicide contains silver content.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103422241A CN102827544A (en) | 2012-09-17 | 2012-09-17 | Thermosetting water soluble resin antibacterial coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103422241A CN102827544A (en) | 2012-09-17 | 2012-09-17 | Thermosetting water soluble resin antibacterial coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102827544A true CN102827544A (en) | 2012-12-19 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103422241A Pending CN102827544A (en) | 2012-09-17 | 2012-09-17 | Thermosetting water soluble resin antibacterial coating |
Country Status (1)
| Country | Link |
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| CN (1) | CN102827544A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103725174A (en) * | 2013-12-30 | 2014-04-16 | 河北晨阳工贸集团有限公司 | Water-based paint for wagon and preparation method thereof |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063118A (en) * | 1992-02-26 | 1992-07-29 | 沈阳市石油化工研究院 | Water soluble anti-rusting paint and preparation method |
| CN1129518A (en) * | 1994-10-18 | 1996-08-28 | 联合株式会社 | Anti-fungus agent |
| CN1388174A (en) * | 2001-05-30 | 2003-01-01 | 海洋化工研究院 | Water-thinned epoxy/acrylic amino resin emulsion and water-thinned baking paint with the emulsion as base material |
| CN1640968A (en) * | 2004-01-05 | 2005-07-20 | 重庆亿隆漆业有限公司 | Water-soluble acroleic-acid modified epoxy ester anti-rast paint |
| CN101864236A (en) * | 2010-07-02 | 2010-10-20 | 湖南湘江涂料集团有限公司 | Aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish |
-
2012
- 2012-09-17 CN CN2012103422241A patent/CN102827544A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063118A (en) * | 1992-02-26 | 1992-07-29 | 沈阳市石油化工研究院 | Water soluble anti-rusting paint and preparation method |
| CN1129518A (en) * | 1994-10-18 | 1996-08-28 | 联合株式会社 | Anti-fungus agent |
| CN1388174A (en) * | 2001-05-30 | 2003-01-01 | 海洋化工研究院 | Water-thinned epoxy/acrylic amino resin emulsion and water-thinned baking paint with the emulsion as base material |
| CN1640968A (en) * | 2004-01-05 | 2005-07-20 | 重庆亿隆漆业有限公司 | Water-soluble acroleic-acid modified epoxy ester anti-rast paint |
| CN101864236A (en) * | 2010-07-02 | 2010-10-20 | 湖南湘江涂料集团有限公司 | Aqueous acrylic modified epoxy ester primer-topcoat integrated anticorrosive baking finish |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103725174A (en) * | 2013-12-30 | 2014-04-16 | 河北晨阳工贸集团有限公司 | Water-based paint for wagon and preparation method thereof |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
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| PB01 | Publication | ||
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| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20121219 |