CN102808200A - Electrolysis recovery apparatus - Google Patents
Electrolysis recovery apparatus Download PDFInfo
- Publication number
- CN102808200A CN102808200A CN2011101412946A CN201110141294A CN102808200A CN 102808200 A CN102808200 A CN 102808200A CN 2011101412946 A CN2011101412946 A CN 2011101412946A CN 201110141294 A CN201110141294 A CN 201110141294A CN 102808200 A CN102808200 A CN 102808200A
- Authority
- CN
- China
- Prior art keywords
- container
- recovery device
- water
- electrolytic recovery
- rotating shaft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Abstract
A purpose of the invention is to provide an electrolysis recovery apparatus, wherein the apparatus is used for treating cleaning water in an electroplating process, extracting precious metals in the cleaning water, removing cyanide, and reducing water treatment cost. The electrolysis recovery apparatus of the invention comprises a container, wherein a rotation shaft is arranged on the middle part of a bottom plate of the container in a penetration manner, the upper part of the rotation shaft is provided with one or a plurality of metal plates adopted as a cathode, the container is further provided with a metal object adopted as an anode, the side wall of the container is provided with a water inlet and a water outlet, the lower part of the rotation shaft is connected with a power device, the cathode and the negative electrode of a power supply are connected, and the anode and the positive electrode of the power supply are connected. The electrolysis recovery apparatus of the present invention has characteristics of simple structure and small volume, and can be directly matchedly installed with an electroplating production line, such that metal ions in the cleaning water can be separated in time so as to provide a purification effect, cyanide ions in the water are reduced, and enterprise operation cost is reduced.
Description
Technical field
The invention belongs to technical field of waste water processing, specially refer to a kind of rinse water that is used for handling in the electroplating process, or electroplating effluent, take off the electrolytic recovery device of golden liquid.
Background technology
In plating line, contain toxic substances such as noble metal such as gold and cyanogen in its rinse water, therefore must could discharge after treatment, otherwise not only can cause the waste of noble metal, but also can cause serious environmental to pollute.Present rinse water treatment process is to handle through recovery and broken cyanide that ion exchange resin carries out noble metal, and is with high costs, and reusable edible not, and used resin can produce obnoxious flavour when reclaiming, and also can cause certain environmental pollution.
Summary of the invention
The objective of the invention is to propose a kind of electrolytic recovery device, be used for handling the rinse water in the electroplating process, extract noble metal wherein, and remove cyanogen content wherein simultaneously, reduce cost of water treatment.
Electrolytic recovery device of the present invention comprises a container; Run through in the middle part of the base plate of said container a rotating shaft is installed; The top of said rotating shaft is equipped with one or more metal sheets of useing negative electrode as; Also be provided with in the said container and use the anodic metal object as, the sidewall of said container has water-in and water outlet; The bottom of said rotating shaft links to each other with PWR PLT; Said negative electrode with link to each other with the negative pole of power supply, said anode links to each other with the positive pole of power supply.
According to electrolytic principle; After containing the rinse water entering container of precious metal ions such as gold, its metals ion can be attached to cathode surface under the effect of electrode, simultaneously because electric current itself have the effect of heating; Can heat rinse water, so just can crack the cyanogen in the water.Use after for some time, just can reclaim noble metal as long as change the metal sheet of useing negative electrode as.In addition, metal sheet can rotate under the effect of rotating shaft and PWR PLT, and the rinse water in the container is formed stirring action, accelerates the separation of metals ion.
Further, the said metal sheet of useing negative electrode as is that pure titanium metal is processed, and in electrolytic process, need not to add any electrolysis promotor, to the quality not influence fully of liquid bath water quality and product.
Further, said water-in is arranged at the bottom of wall of container, and said water outlet is arranged at the top of wall of container.Like this rinse water can be from the bottom to top overflow container gradually, can guarantee the metals ion in the rinse water is separated absorption in the process the inside of overflowing.
Further, said container is processed for the PVC material.Because rinse water is mordant, therefore adopt protection against corrosion, insulation, resistant to elevated temperatures PVC material is made container can guarantee safety.
Further, said PWR PLT are the buncher that is installed on the container below, and said buncher is connected with said rotating shaft through belt.To different rinse water, can control the velocity of separation of precious metal ion through the rotating speed of regulating buncher.
Further, the said anodic metal object of useing as is for around rotating shaft and use the metallic cylinder of the metal sheet of negative electrode as.Adopt metallic cylinder as anode, can enlarge the anodic area as much as possible, thereby improve the separation rate of precious metal ion.
Further, PL, the switch that is used for control electrode work, the PL that is used to indicate the PWR PLT working order that is used for the indicator electrode working order, the switch that is used to control PWR PLT work are installed on the said container outside wall.Above-mentioned switch and PL are set can be helped to control the carrying out of electrolysis work and observe working order.
Further, said water inlet is equipped with adverse current and suppresses valve, to prevent the aqueous reflux in the container.
Electrolytic recovery apparatus structure of the present invention is simple, and volume is little, can be directly and the supporting installation of plating line, and the metals ion in the rinse water is separated timely, play Water purification, reduce the cryanide ion in the rinse water simultaneously, reduce the cost of enterprise operation.
Description of drawings
Fig. 1 is the structural representation of electrolytic recovery device of the present invention.
The time dependent synoptic diagram of residual gold concentration when Fig. 2 is to use electrolytic recovery device of the present invention in the rinse water.
The synoptic diagram of the residual cyanogen concentration changes with time when Fig. 3 is to use electrolytic recovery device of the present invention in the rinse water.
Indicate among the figure: 1, container; 2, rotating shaft; 3, pure titanium metal plate; 4, metallic cylinder; 5, water-in; 6, water outlet; 7, belt; 8, buncher.
Embodiment
Contrast accompanying drawing below; Through the description to embodiment, the effect of mutual alignment between the shape of specific embodiments of the invention such as related each member, structure, the each several part and annexation, each several part and principle of work etc. are done further to specify.
Embodiment 1:
As shown in Figure 1; The electrolytic recovery device of present embodiment comprises the container 1 that a PVC material is processed; The base plate of container 1 middle part is run through a rotating shaft 2 being installed, and the top of rotating shaft 2 is equipped with four pure titanium metal plates 3 of useing negative electrode as, also is provided with in the container 1 around rotating shaft 2 and the metallic cylinder 4 of pure titanium metal plate 3 of useing negative electrode as to use anode as; The lower sidewall of container 1 has water-in 5, and top has water outlet 6; The bottom of rotating shaft 2 links to each other with a buncher 8 that is installed on the container below through belt 7; Pure titanium metal plate 3 with link to each other with the negative pole of power supply, metallic cylinder 4 links to each other with the positive pole of power supply; The switch that PL, the switch that is used for control electrode work, the PL that is used to indicate the PWR PLT working order that are used for the indicator electrode working order is installed on container 1 outer side wall, is used to control PWR PLT work (figure do not draw power supply, switch, PL).
Further, said water inlet is equipped with adverse current and suppresses valve, to prevent the aqueous reflux (adverse current of not drawing among the figure suppresses valve) in the container.
Like Fig. 2, shown in 3, after using the electrolytic recovery device of present embodiment, the growth that residual gold concentration in the rinse water and residual cyanogen concentration can be in time and significantly reducing.
In use, in the accumulator tank of plating line, wherein water pump will be installed by water inlet pipeline place with water outlet pipeline and water inlet pipe connection.Confirm whether reclaim liquid in the accumulator tank, can not start shooting when not reclaiming liquid then.
Concrete steps are following: A, open the pump operation switch; B: open electrode supply running switch; C: regulate motor speed as required; D: after using for some time, pull down and change the pure titanium metal plate 3 of useing negative electrode as, reclaim metal.
With a circuit board plant is example, and the gold-plated flow line of the soft board of this circuit board plant has been installed the electrolytic recovery device of two playscript with stage directions embodiment.Before the electrolytic recovery device was installed, draining weekly contained golden waste water 1600kg, contained gold amount 1200 grams, and every month near the 5kg flight of gold; Rinse water is changed once weekly at least, 500 yuan/ton of its broken cyanide expenses.
After using the electrolytic recovery device, reclaimed 5kg gold in every month, rinse water is by original changing into biweekly once in a week, and the broken cyanide expense reduces 2/3rds.
Through above-mentioned instance explanation, the electrolytic recovery device of present embodiment has reduced a large sum of running cost for enterprise really.
Claims (8)
1. electrolytic recovery device; It is characterized in that comprising a container; Run through in the middle part of the base plate of said container a rotating shaft is installed; The top of said rotating shaft is equipped with one or more metal sheets of useing negative electrode as, also is provided with in the said container to use the anodic metal object as, and the sidewall of said container has water-in and water outlet; The bottom of said rotating shaft links to each other with PWR PLT; Said negative electrode with link to each other with the negative pole of power supply, said anode links to each other with the positive pole of power supply.
2. electrolytic recovery device according to claim 1 is characterized in that the said metal sheet of useing negative electrode as is that pure titanium metal is processed.
3. electrolytic recovery device according to claim 1 and 2 is characterized in that said water-in is arranged at the bottom of wall of container, and said water outlet is arranged at the top of wall of container.
4. electrolytic recovery device according to claim 1 and 2 is characterized in that said container is PVC, and the PP material is processed.
5. electrolytic recovery device according to claim 1 and 2 is characterized in that said PWR PLT are the buncher that is installed on the container below, and said buncher is connected with said rotating shaft through belt.
6. electrolytic recovery device according to claim 1 and 2 is characterized in that the said anodic metal object of useing as is for around rotating shaft and use the metallic cylinder of the metal sheet of negative electrode as.
7. electrolytic recovery device according to claim 1 and 2 is characterized in that being equipped with on the said container outside wall PL, the switch that is used for control electrode work, the PL that is used to indicate the PWR PLT working order that is used for the indicator electrode working order, the switch that is used to control PWR PLT work.
8. electrolytic recovery device according to claim 1 and 2 is characterized in that said water inlet is equipped with adverse current and suppresses valve.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101412946A CN102808200A (en) | 2011-05-30 | 2011-05-30 | Electrolysis recovery apparatus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101412946A CN102808200A (en) | 2011-05-30 | 2011-05-30 | Electrolysis recovery apparatus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102808200A true CN102808200A (en) | 2012-12-05 |
Family
ID=47232067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101412946A Pending CN102808200A (en) | 2011-05-30 | 2011-05-30 | Electrolysis recovery apparatus |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102808200A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103215615A (en) * | 2013-04-10 | 2013-07-24 | 张登峰 | Noble metal recovering method |
| CN103922519A (en) * | 2014-04-18 | 2014-07-16 | 红板（江西）有限公司 | Process for recycling cyaniding gold plating liquid carried by board surface in PCB (Printed Circuit Board) industry |
| CN107777761A (en) * | 2017-11-08 | 2018-03-09 | 江门市蓬江区鑫浩源科技有限公司 | A kind of electrolytic cleaning processing unit |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5332814A (en) * | 1976-09-08 | 1978-03-28 | Sumitomo Metal Ind Ltd | Production of steel plate with excellent moldability used for steel pipe |
| CN2700345Y (en) * | 2004-04-21 | 2005-05-18 | 深圳市危险废物处理站 | Radiating type electrode electrolytic cell |
| CN2841681Y (en) * | 2005-11-11 | 2006-11-29 | 河南卡斯通科技有限公司 | Programme-controlled multi-anode, rotary cathode electrolytic tank |
| CN202099393U (en) * | 2011-05-30 | 2012-01-04 | 苏州市鼎尚海珍品有限公司 | Electrolytic recovery device |
-
2011
- 2011-05-30 CN CN2011101412946A patent/CN102808200A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5332814A (en) * | 1976-09-08 | 1978-03-28 | Sumitomo Metal Ind Ltd | Production of steel plate with excellent moldability used for steel pipe |
| CN2700345Y (en) * | 2004-04-21 | 2005-05-18 | 深圳市危险废物处理站 | Radiating type electrode electrolytic cell |
| CN2841681Y (en) * | 2005-11-11 | 2006-11-29 | 河南卡斯通科技有限公司 | Programme-controlled multi-anode, rotary cathode electrolytic tank |
| CN202099393U (en) * | 2011-05-30 | 2012-01-04 | 苏州市鼎尚海珍品有限公司 | Electrolytic recovery device |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103215615A (en) * | 2013-04-10 | 2013-07-24 | 张登峰 | Noble metal recovering method |
| CN103922519A (en) * | 2014-04-18 | 2014-07-16 | 红板（江西）有限公司 | Process for recycling cyaniding gold plating liquid carried by board surface in PCB (Printed Circuit Board) industry |
| CN107777761A (en) * | 2017-11-08 | 2018-03-09 | 江门市蓬江区鑫浩源科技有限公司 | A kind of electrolytic cleaning processing unit |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102808200A (en) | Electrolysis recovery apparatus | |
| CN202099393U (en) | Electrolytic recovery device | |
| CN202193854U (en) | Full automatic intelligent recoverer recovering silver from film developing waste liquid | |
| CN210826392U (en) | Electrolytic device for industrial production of 5N high-purity copper | |
| CN102108531A (en) | Impurity removing method for nickel electroplating solution and impurity removing equipment thereof | |
| CN204607581U (en) | A kind of acid-restoring plant of lead acid cell | |
| CN105645703A (en) | Electrochemical control device for controlling pH value of electrolyte for electro-kinetic remediation of heavy metal sludge | |
| CN203866076U (en) | Complex-breaking and chromium-removing device for tanning dyeing wastewater | |
| CN210657162U (en) | Device for electrodepositing copper on waste micro-etching solution | |
| CN103420438A (en) | Electroplating-rinse-water recycling and reusing method | |
| CN103101995A (en) | Novel electrolysis device | |
| CN207046914U (en) | A kind of heavy metal containing sewage ionization device | |
| CN202968216U (en) | Electrolytic dephosphorizing device | |
| CN202107584U (en) | Water-saving device for electroplating production line | |
| CN203033808U (en) | Electrochemical sewage treatment device | |
| CN208413941U (en) | A kind of roller ni plating apparatus with electrolyte tank | |
| CN104556498A (en) | System for treating low-concentration copper-containing waste water | |
| CN110683684B (en) | Electroplating copper-containing sewage treatment system and treatment process | |
| CN202705557U (en) | Electroplating device capable of recycling electroplate rinse liquid | |
| CN210886282U (en) | Plating bath liquid level control device | |
| CN216997718U (en) | Tank type feeding device | |
| CN203916441U (en) | Spent lye in a kind of LCD production process and acid mist treatment system | |
| CN213671094U (en) | Electrochemical device for treating contaminated soil | |
| CN202139094U (en) | Electroadsorption waste water desalting device | |
| CN212375077U (en) | Sewage treatment plant for environmental engineering |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C05 | Deemed withdrawal (patent law before 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20121205 |