CN102775762A - Anti-static resin composition - Google Patents
Anti-static resin composition Download PDFInfo
- Publication number
- CN102775762A CN102775762A CN2012102999158A CN201210299915A CN102775762A CN 102775762 A CN102775762 A CN 102775762A CN 2012102999158 A CN2012102999158 A CN 2012102999158A CN 201210299915 A CN201210299915 A CN 201210299915A CN 102775762 A CN102775762 A CN 102775762A
- Authority
- CN
- China
- Prior art keywords
- resin composition
- parts
- antistatic resin
- antistatic
- static
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 35
- 239000004033 plastic Substances 0.000 claims abstract description 15
- 229920003023 plastic Polymers 0.000 claims abstract description 15
- 230000003068 static effect Effects 0.000 claims abstract description 14
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 239000002985 plastic film Substances 0.000 claims abstract description 10
- 229920006255 plastic film Polymers 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 14
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000003851 corona treatment Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 229920005549 butyl rubber Polymers 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- CKQVRZJOMJRTOY-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O CKQVRZJOMJRTOY-UHFFFAOYSA-N 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000002216 antistatic agent Substances 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 abstract 1
- 239000008213 purified water Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000000428 dust Substances 0.000 description 3
- 239000004020 conductor Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000088 plastic resin Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an anti-static resin composition and belongs to the technical field of static prevention. The anti-static resin composition consists of the following substances in parts by weight: 100 to 150 parts of polyurethane, 10 to 20 parts of acrylonitrile-styrene copolymer, 5 to 40 parts of antistatic agent, 5 to 50 parts of adhesive, 50 to 160 parts of solvent and 50 to 160 parts of purified water. The anti-static resin composition is wide in raw material source and simple in preparation method, the prepared composition is used for coating the surface of the plastic film, and the static electricity of the plastic products is reduced, so that the surface resistance of the plastic products is reduced to 106 to 109ohm, and the harm generated by the surface resistance of the industrial plastic products is greatly eliminated.
Description
Technical field
The invention belongs to the antistatic technique field, be specifically related to a kind of antistatic resin composition.
Background technology
Static is a kind of electric charge that remains static, ubiquity in daily life and industry, and the static that in industrial production, produces often has very big hazardness, mainly comprises the harm that harm that static discharge causes and electrostatic attraction cause.The harm that static discharge causes comprises: cause the fault or the flase operation of electronics, cause EMI; Puncture unicircuit and accurate electronic component, perhaps impel component ageing, reduce the rate that manufactures a finished product; The high pressure electrostatic discharge causes electric shock, jeopardizes personnel safety; Production place at many inflammable explosive articles or dust, mist of oil very easily sets off an explosion and fire.The harm that electrostatic attraction causes comprises: the absorption dust, cause the pollution of unicircuit and semiconductor element, and reduce yield rate greatly; Make film or film take-up uneven; Film, CD mould dish and are infected with dust, influence quality; The paper rolling is uneven, register trouble, and soil pick-up is serious, even paper coheres influence production; Cause rhizoid to wave, twine harm such as flower breaks end, yarn is entangled with.
Existing Plastic Resin goods, the anti-static precautions of taking has: add tensio-active agent, increase the surface resistivity of product, but the surface resistivity of product receives the influence of environment easily, it is bigger to fluctuate; Add conductive material such as carbon black, product is easy to generate colour cast, influences transparency of products; The surface sputtering electro-conductive material, but its cost is high, is not suitable for scale operation.
Summary of the invention
The object of the present invention is to provide a kind of antistatic resin composition, coat surface of plastic products, solve present Plastic Resin goods and be prone to produce static, the uneven problem of coating.
A kind of antistatic resin composition is made up of the material of following parts by weight: urethane 100-150 part, acrylonitritrile-styrene resin 10-20 part, static inhibitor 5-40 part, tackiness agent 5-50 part, solvent 50-160 part, pure water 50-160 part.
Said static inhibitor is one or more among sodium laurylsulfonate, MGD, the cruel amine of oxyethyl group bay, glycerine-stearate, the nanometer SiO.
Said tackiness agent is Z 150PH, CMC 99.5, butyl rubber, vinyl acetate resin, vinyl resin or chlorinated rubber.
Said solvent is Virahol, normal hexane or ethanol.
The application of above-mentioned antistatic resin composition in preparation antistatic plastic film carried out corona treatment with the plastics film surface, is coated with antistatic resin composition then, and drying promptly can be made into.
Beneficial effect of the present invention: antistatic resin composition raw material sources of the present invention are wide, and the preparation method is simple, and the compsn of preparation is used for the coating plastic film surface, reduce the static of plastics, make the surface resistivity of plastics be reduced to 10
6-10
9Between the Ω, eliminated the harm that industrial plastic goods static is produced greatly.
Embodiment
Below in conjunction with specific embodiment the present invention is further specified.
Embodiment 1
A kind of antistatic resin composition is made up of the material of following parts by weight: 100 parts of urethane, 11 parts of acrylonitritrile-styrene resins, 5 parts of sodium laurylsulfonates, 8 parts of Z 150PH, 100 parts of Virahols, 50 parts of pure water.
The application of above-mentioned antistatic resin composition in preparation antistatic plastic film carried out corona treatment with the plastics film surface, is coated with antistatic resin composition then, and drying promptly can be made into, and the product surface resistance of processing is 10
7
Embodiment 2
A kind of antistatic resin composition is made up of the material of following parts by weight: 140 parts of urethane, 14 parts of acrylonitritrile-styrene resins, 10 parts of MGDs, 18 parts of CMC 99.5s, 60 parts of normal hexanes, 100 parts of pure water.
The application of above-mentioned antistatic resin composition in preparation antistatic plastic film carried out corona treatment with the plastics film surface, is coated with antistatic resin composition then, and drying promptly can be made into, and the product surface resistance of processing is 10
8
Embodiment 3
A kind of antistatic resin composition is made up of the material of following parts by weight: 150 parts of urethane, 11 parts of acrylonitritrile-styrene resins, 35 parts of the cruel amine of oxyethyl group bay, 40 parts of butyl rubbers, 60 parts of ethanol, 80 parts of pure water.
The application of above-mentioned antistatic resin composition in preparation antistatic plastic film carried out corona treatment with the plastics film surface, is coated with antistatic resin composition then, and drying promptly can be made into, and the product surface resistance of processing is 5x10
7
Embodiment 4
A kind of antistatic resin composition is made up of the material of following parts by weight: 130 parts of urethane, 20 parts of acrylonitritrile-styrene resins, 25 parts of glycerine-stearates, 25 parts of vinyl acetate resins, 130 parts of Virahols, 70 parts of pure water.
The application of above-mentioned antistatic resin composition in preparation antistatic plastic film carried out corona treatment with the plastics film surface, is coated with antistatic resin composition then, and drying promptly can be made into, and the product surface resistance of processing is 2x10
7
Embodiment 5
A kind of antistatic resin composition is made up of the material of following parts by weight: 125 parts of urethane, 15 parts of acrylonitritrile-styrene resins, 30 parts of nanometer SiO, 32 parts of vinyl resins, 100 parts of Virahols, 150 parts of pure water.
The application of above-mentioned antistatic resin composition in preparation antistatic plastic film carried out corona treatment with the plastics film surface, is coated with antistatic resin composition then, and drying promptly can be made into, and the product surface resistance of processing is 5x10
8
Embodiment 6
A kind of antistatic resin composition is made up of the material of following parts by weight: 130 parts of urethane, 15 parts of acrylonitritrile-styrene resins, 20 parts of nanometer SiO, 21 parts of chlorinated rubbers, 100 parts of Virahols, 150 parts of pure water.
The application of above-mentioned antistatic resin composition in preparation antistatic plastic film carried out corona treatment with the plastics film surface, is coated with antistatic resin composition then, and drying promptly can be made into, and the product surface resistance of processing is 3x10
8
Claims (5)
1. an antistatic resin composition is characterized in that, is made up of the material of following parts by weight: urethane 100-150 part; Acrylonitritrile-styrene resin 10-20 part, static inhibitor 5-40 part, tackiness agent 5-50 part; Solvent 50-160 part, pure water 50-160 part.
2. according to the said a kind of antistatic resin composition of claim 1, it is characterized in that said static inhibitor is one or more among sodium laurylsulfonate, MGD, the cruel amine of oxyethyl group bay, glycerine-stearate, the nanometer SiO.
3. according to the said a kind of antistatic resin composition of claim 1, it is characterized in that said tackiness agent is Z 150PH, CMC 99.5, butyl rubber, vinyl acetate resin, vinyl resin or chlorinated rubber.
4. according to the said a kind of antistatic resin composition of claim 1, it is characterized in that said solvent is Virahol, normal hexane or ethanol.
5. the application of the said antistatic resin composition of claim 1 in preparation antistatic plastic film is characterized in that, corona treatment is carried out on the plastics film surface, is coated with the described antistatic resin composition of claim 1 then, and drying promptly can be made into.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102999158A CN102775762B (en) | 2012-08-22 | 2012-08-22 | Anti-static resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102999158A CN102775762B (en) | 2012-08-22 | 2012-08-22 | Anti-static resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102775762A true CN102775762A (en) | 2012-11-14 |
| CN102775762B CN102775762B (en) | 2013-12-04 |
Family
ID=47120881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012102999158A Expired - Fee Related CN102775762B (en) | 2012-08-22 | 2012-08-22 | Anti-static resin composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102775762B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103204639A (en) * | 2013-04-19 | 2013-07-17 | 奇瑞汽车股份有限公司 | Preparation method of dustproof automobile glass |
| CN103232647A (en) * | 2013-05-10 | 2013-08-07 | 苏州工业园区方圆金属制品有限公司 | Reinforced acrylonitrile-styrenecopolymer (AS) plastic plate |
| CN105036570A (en) * | 2015-06-30 | 2015-11-11 | 四川航天五源复合材料有限公司 | Preparation technology of continuous basalt fiber sizing |
| CN106245154A (en) * | 2016-08-30 | 2016-12-21 | 甘木林 | A kind of antistatic porous nano fibrous material |
| CN107475760A (en) * | 2017-09-04 | 2017-12-15 | 苏州云舒新材料科技有限公司 | A kind of preparation method of antistatic film material |
| WO2020000934A1 (en) * | 2018-06-28 | 2020-01-02 | 浙江清华柔性电子技术研究院 | Method for surface treatment of silicone rubber |
| CN111978879A (en) * | 2019-05-24 | 2020-11-24 | 浙江欧仁新材料有限公司 | Solvent-resistant antistatic film |
| CN112521680A (en) * | 2020-12-24 | 2021-03-19 | 石家庄中汇药品包装有限公司 | Antistatic polyethylene bag and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105367868A (en) * | 2015-11-16 | 2016-03-02 | 无锡贺邦金属制品有限公司 | High-hardness plastic product |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0263590A2 (en) * | 1986-09-08 | 1988-04-13 | Mobil Oil Corporation | Water based coating composition and polymer film coated therewith |
| JP2001214079A (en) * | 2000-02-02 | 2001-08-07 | Daicel Chem Ind Ltd | Antistatic resin composition |
| CN102199335A (en) * | 2011-04-20 | 2011-09-28 | 合肥乐凯科技产业有限公司 | Antistatic compound and antistatic film containing same |
-
2012
- 2012-08-22 CN CN2012102999158A patent/CN102775762B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0263590A2 (en) * | 1986-09-08 | 1988-04-13 | Mobil Oil Corporation | Water based coating composition and polymer film coated therewith |
| JP2001214079A (en) * | 2000-02-02 | 2001-08-07 | Daicel Chem Ind Ltd | Antistatic resin composition |
| CN102199335A (en) * | 2011-04-20 | 2011-09-28 | 合肥乐凯科技产业有限公司 | Antistatic compound and antistatic film containing same |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103204639A (en) * | 2013-04-19 | 2013-07-17 | 奇瑞汽车股份有限公司 | Preparation method of dustproof automobile glass |
| CN103232647A (en) * | 2013-05-10 | 2013-08-07 | 苏州工业园区方圆金属制品有限公司 | Reinforced acrylonitrile-styrenecopolymer (AS) plastic plate |
| CN105036570A (en) * | 2015-06-30 | 2015-11-11 | 四川航天五源复合材料有限公司 | Preparation technology of continuous basalt fiber sizing |
| CN106245154A (en) * | 2016-08-30 | 2016-12-21 | 甘木林 | A kind of antistatic porous nano fibrous material |
| CN107475760A (en) * | 2017-09-04 | 2017-12-15 | 苏州云舒新材料科技有限公司 | A kind of preparation method of antistatic film material |
| WO2020000934A1 (en) * | 2018-06-28 | 2020-01-02 | 浙江清华柔性电子技术研究院 | Method for surface treatment of silicone rubber |
| US11713380B2 (en) | 2018-06-28 | 2023-08-01 | Institute Of Flexible Electronics Technology Of Thu, Zhejiang | Method for surface treatment of silicone rubber |
| CN111978879A (en) * | 2019-05-24 | 2020-11-24 | 浙江欧仁新材料有限公司 | Solvent-resistant antistatic film |
| CN111978879B (en) * | 2019-05-24 | 2022-05-06 | 浙江欧仁新材料有限公司 | Solvent-resistant antistatic film |
| CN112521680A (en) * | 2020-12-24 | 2021-03-19 | 石家庄中汇药品包装有限公司 | Antistatic polyethylene bag and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102775762B (en) | 2013-12-04 |
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Legal Events
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131204 |