CN103265807A - PU (Poly Urethane) sole antistatic agent - Google Patents
PU (Poly Urethane) sole antistatic agent Download PDFInfo
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- CN103265807A CN103265807A CN2013102110196A CN201310211019A CN103265807A CN 103265807 A CN103265807 A CN 103265807A CN 2013102110196 A CN2013102110196 A CN 2013102110196A CN 201310211019 A CN201310211019 A CN 201310211019A CN 103265807 A CN103265807 A CN 103265807A
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- antistatic agent
- quaternary ammonium
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- sole antistatic
- lithium
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Abstract
The invention discloses PU (Poly Urethane) sole antistatic agent. The PU sole antistatic agent comprises the following components in percentage by weight: 68%-88% of 1-ethyl-3-methyl imidazole ethyl sulfate, 12%-18% of a polyalcohol solvent, and 8%-12% of quaternary ammonium salt compounds containing silver or lithium ions. The preparation method of the PU sole antistatic agent comprises the following steps of: uniformly mixing the components according to the proportion; stirring for 2 hours-3hours at a high speed under the normal temperature; and stewing for 1-2 hours to obtain the product. The PU sole antistatic agent disclosed by the invention is scientific in formula, low in production cost, simple in preparation process and capable of strengthening the antistatic performances of the sole.
Description
Technical field:
The present invention relates to a kind of antistatic agent, relate in particular to PU sole antistatic agent.
Background technology:
The past sole most no natural materialss of material, so the phenomenon of its fricative static is not paid attention to by people.But along with the development of petrochemical complex, electron trade, macromolecular materials such as plastic, rubber and man-made fiber are come out one after another, and electrostatic problem more and more causes the attention of each side.Because footwear belong to the ionogen category mostly with macromolecular material, its resistivity is very big, and namely specific conductivity is very little, thus be easy to gather a large amount of electric charges, thus to such an extent as to bring harm for life, production life.
The harm of static refers to the infringement that static discharge causes the electrostatic sensitive product.The size of static hazard or the severity of static damage depend on the degree of accumulation of static electricity and the electrostatic sensitivity of electrostatic sensitive product.Electrostatic potential is more high, endangers more big; The electrostatic sensitivity of product is more big, the more easy harm that is subjected to static.
Being created in the industrial production of static is that inevitably its harm that causes mainly can be summed up as following two kinds of mechanism.The harm that one, static discharge cause: fault or flase operation that (1) causes electronics, cause electromagnetic interference; (2) puncture unicircuit and accurate electronic component, or impel component ageing, reduce and produce ratio defective product; (3) the high pressure static electricity discharge causes motor, crisis personnel safety; (4) at many inflammable explosive articles or dust.The production place of mist of oil very easily sets off an explosion and fire.Its two, the harm that electrostatic attraction causes: (1) electronic industry, absorption dust, cause the pollution of unicircuit and semiconductor element, reduce yield rate greatly; (2) film and plastics industry make film or film take-up uneven; Film, CD mould dish and are infected with dust, influence quality; (3) cause Printing industry, the paper rolling is uneven, register trouble, and soil pick-up is serious, even the paper bonding, and influence is produced; (4) textile industry causes rhizoid to wave, twine harm such as flower breaks end, yarn is entangled with.Therefore, produce have an electrostatic-proof function and can use with above-mentioned industry in anti-static shoes at the bottom of have great importance.
Summary of the invention:
The purpose of this invention is to provide a kind of novel PU sole antistatic agent, it can effectively reduce the static that the PU sole produces.
The present invention is achieved by the following technical solutions:
A kind of PU sole antistatic agent comprises following component by weight percentage:
1-ethyl-3-Methylimidazole sulfuric acid acetate salt 68%-88%;
Polyalcohols solvent 12%-18%;
The quaternary ammonium compound 8%-12% of argentiferous or lithium ion.
Preferred as technique scheme, described polyalcohols derivative solvent is sorbyl alcohol, N.F,USP MANNITOL is a kind of in the derivative of tetramethylolmethane.
Preferred as technique scheme, the quaternary ammonium compound of described argentiferous or lithium ion is the quaternary ammonium silver chloride, quaternary ammonium Sulfuric acid disilver salt, quaternary ammonium Silver Nitrate, quaternary ammonium lithium chloride, quaternary ammonium Lithium Sulphate, the one or more combination thing in the quaternary ammonium lithium nitrate.
Preferred as technique scheme, polyalcohols is as dispersion medium.
Beneficial effect of the present invention is: its scientific formulation, production cost is low, preparation technology is simple, strengthened the static electricity resistance of sole.
Embodiment:
In order to deepen the understanding of the present invention, the invention will be further described below in conjunction with embodiment, and this embodiment only is used for explaining the present invention, does not constitute the restriction to protection domain of the present invention.
Embodiment 1:
A kind of PU sole antistatic agent is made up of following composition mixing by weight percentage: 1-ethyl-3-Methylimidazole sulfuric acid acetate salt 74%, N.F,USP MANNITOL 15%, quaternary ammonium silver chloride 11%.
The preparation method of PU sole antistatic agent of the present invention after each above-mentioned component is mixed by proportioning, after high-speed stirring 2-3 hour, left standstill 1-2 hour under the normal temperature, namely got product.
Embodiment 2:
A kind of PU sole antistatic agent is made up of following composition mixing by weight percentage: 1-ethyl-3-Methylimidazole sulfuric acid acetate salt 77%, N.F,USP MANNITOL 12%, quaternary ammonium lithium chloride 11%.
Its preparation method is identical with embodiment one.
Embodiment 3:
A kind of PU sole antistatic agent is made up of following composition mixing by weight percentage: 1-ethyl-3-Methylimidazole sulfuric acid acetate salt 80%, N.F,USP MANNITOL 12%, quaternary ammonium lithium chloride 8%.
Its preparation method is identical with embodiment one.
Embodiment 4:
A kind of PU sole antistatic agent is made up of following composition mixing by weight percentage: 1-ethyl-3-Methylimidazole sulfuric acid acetate salt 79%, N.F,USP MANNITOL 12%, quaternary ammonium lithium chloride 9%.Its preparation method is identical with embodiment one.
Claims (4)
1. PU sole antistatic agent, it is characterized in that: by weight percentage, this PU sole antistatic agent comprises following component:
1-ethyl-3-Methylimidazole sulfuric acid acetate salt 68%-88%;
Polyalcohols solvent 12%-18%;
The quaternary ammonium compound 8%-12% of argentiferous or lithium ion.
2. PU sole antistatic agent according to claim 1, it is characterized in that: described how far the alcohol derivatives solvent is sorbyl alcohol, N.F,USP MANNITOL is a kind of in the derivative of tetramethylolmethane.
3. PU sole antistatic agent according to claim 1, it is characterized in that: the quaternary ammonium compound of described argentiferous or lithium ion is the quaternary ammonium silver chloride, the quaternary ammonium Sulfuric acid disilver salt, the quaternary ammonium Silver Nitrate, the quaternary ammonium lithium chloride, quaternary ammonium Lithium Sulphate, the one or more combination thing in the quaternary ammonium lithium nitrate.
4. PU sole antistatic agent according to claim 1, it is characterized in that: described polyalcohols is as dispersion medium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102110196A CN103265807A (en) | 2013-05-31 | 2013-05-31 | PU (Poly Urethane) sole antistatic agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102110196A CN103265807A (en) | 2013-05-31 | 2013-05-31 | PU (Poly Urethane) sole antistatic agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103265807A true CN103265807A (en) | 2013-08-28 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102110196A Pending CN103265807A (en) | 2013-05-31 | 2013-05-31 | PU (Poly Urethane) sole antistatic agent |
Country Status (1)
| Country | Link |
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| CN (1) | CN103265807A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106117887A (en) * | 2016-07-08 | 2016-11-16 | 浙江佳华精化股份有限公司 | A kind of Compositional type PVC antistatic additive and application thereof |
| CN107523039A (en) * | 2017-09-29 | 2017-12-29 | 淄博接地气健康科技有限公司 | Polyurethane shoe-sole and preparation method thereof |
| CN107625229A (en) * | 2017-09-29 | 2018-01-26 | 淄博接地气健康科技有限公司 | Add polyurethane shoe-sole of graphene composite material and preparation method thereof |
| CN108086054A (en) * | 2017-12-18 | 2018-05-29 | 温州市新丰装饰材料有限公司 | A kind of preparation method of antistatic glaxin release paper |
| CN108504065A (en) * | 2018-03-24 | 2018-09-07 | 徐州九龙电子工业有限公司 | A kind of antistatic mouse material and preparation method thereof |
| CN110054825A (en) * | 2019-04-30 | 2019-07-26 | 北京聚天骄新材料有限公司 | A kind of long-acting antistatic plastic master batch and preparation method thereof |
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| JPH04298518A (en) * | 1991-01-10 | 1992-10-22 | Kao Corp | Additive for production of polyurethane and production of polyurethane |
| JP3147909B2 (en) * | 1991-01-10 | 2001-03-19 | 花王株式会社 | Additive for polyurethane production and method for producing polyurethane |
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| CN102651981A (en) * | 2009-12-10 | 2012-08-29 | 巴斯夫欧洲公司 | Antistatic thermoplastic compositions |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106117887A (en) * | 2016-07-08 | 2016-11-16 | 浙江佳华精化股份有限公司 | A kind of Compositional type PVC antistatic additive and application thereof |
| CN106117887B (en) * | 2016-07-08 | 2018-12-18 | 浙江佳华精化股份有限公司 | A kind of Compositional type PVC antistatic agent and its application |
| CN107523039A (en) * | 2017-09-29 | 2017-12-29 | 淄博接地气健康科技有限公司 | Polyurethane shoe-sole and preparation method thereof |
| CN107625229A (en) * | 2017-09-29 | 2018-01-26 | 淄博接地气健康科技有限公司 | Add polyurethane shoe-sole of graphene composite material and preparation method thereof |
| CN107523039B (en) * | 2017-09-29 | 2020-05-19 | 山东接地气健康科技有限公司 | Polyurethane sole and preparation method thereof |
| CN108086054A (en) * | 2017-12-18 | 2018-05-29 | 温州市新丰装饰材料有限公司 | A kind of preparation method of antistatic glaxin release paper |
| CN108504065A (en) * | 2018-03-24 | 2018-09-07 | 徐州九龙电子工业有限公司 | A kind of antistatic mouse material and preparation method thereof |
| CN110054825A (en) * | 2019-04-30 | 2019-07-26 | 北京聚天骄新材料有限公司 | A kind of long-acting antistatic plastic master batch and preparation method thereof |
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Application publication date: 20130828 |