CN102774021A - Production process of light-colored static-conduction glass steel - Google Patents
Production process of light-colored static-conduction glass steel Download PDFInfo
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- CN102774021A CN102774021A CN2012102883950A CN201210288395A CN102774021A CN 102774021 A CN102774021 A CN 102774021A CN 2012102883950 A CN2012102883950 A CN 2012102883950A CN 201210288395 A CN201210288395 A CN 201210288395A CN 102774021 A CN102774021 A CN 102774021A
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Abstract
The invention provides a production process of light-colored static-conduction glass steel, relating to a production process of glass steel. The production process provided by the invention comprises the following steps of: adding static-conduction fibers and nanoscale static-conduction zinc oxide into resin of a surface gel-coated layer; adding various color pastes into the resin according to demands; and performing the processing procedures of preparing gel-coated resin and interlayer resin, coating the gel-coated layer, curing, laminating, coating the gel-coated layer in a brushing layer, and sizing on the mixture to obtain the light-colored static conduction glass steel. The glass steel produced by the method provided by the invention has the advantages that the surface resistance reaches 105 ohm/m, the conduction is uniform, and the construction operation is facilitated; and although the nanoscale static-conduction zinc oxide and the static-conduction fibers have no color covering power, a desired surface decoration effect can be realized by adding the color pastes.
Description
Technical field
The present invention relates to a kind of production technology of fiberglass, be specifically related to a kind of production technology of light-colored static conductive fiberglass.
Background technology
Fiberglass is a kind of traditional composite, is a kind of composite product that is composited by unsaturated polyester (UP) and glass fibre.Fibre glass product manufacture itself has high electrical insulation capability, is a kind of good insulating materials.Simultaneously also have excellent corrosion resisting performance and weather resistance, thus be widely used in outdoor and the abominable place of environment, some place such as gas station etc.; Need conducting electrostatic materials preferably; Need better weather ability and decay resistance again, traditional metal material and conventional glass steel have significant disadvantages, so the conductive and static glass steel product that has been born; The conventional glass steel is led the static product; It is led electrostatic efficiency and generally leads the static carbon black through interpolation and reach and lead electrostatic efficiency, and this technological major defect is: color is single, has only black a kind of; Carbon black adds difficult the dispersion, causes electrostatic efficiency inhomogeneous; After carbon black added, because granularity is less, the viscosity that causes resin paste easily sharply increased and makes resin paste and glass fiber impregnated difficulty.Tradition is led the fibre glass product manufacture of static, because the filler that adds is generally conductive black, because it has extremely strong covering power, so the product that forms is a black, color is single, is difficult to reach beautify outward appearance, the effect of classification and caution.
Summary of the invention
The production technology that the purpose of this invention is to provide a kind of light-colored static conductive fiberglass leads to solve prior art that electrostatic efficiency is poor, color is single is difficult to reach the problem of beautifying outward appearance, classification and warning function.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of production technology of light-colored static conductive fiberglass is led electrostatic fibre and nanoscale is led static zinc oxide through in surperficial gel coating resin resin, adding, and to add various mill bases as requested, and concrete processing step is following:
(1) preparation gel coating resin and interlayer resin: the nanoscale of leading electrostatic fibre and 5～15% mass content that in resin, adds 3～8% mass content is led static zinc oxide and is mixed with gel coating resin; And based on requiring to add various mill bases; Common stirring at low speed is until evenly, and is for use, in resin, adds a certain amount of conductive black simultaneously and is mixed with interlayer resin; Abundant stirring at low speed is until evenly, and is for use;
(2) brush gel coating resin: in the gel coating resin that step (1) obtains, add a certain amount of curing agent, at die surface brushing one deck gel coating resin, the gel coating resin of brushing is uniformly dispersed on die face then;
(3) solidify: treat spontaneous curing after brushing is accomplished or under 25 ℃～40 ℃, dry;
(4) lamination operation: treat after the initial set of ground floor gel coat that feel is soft and when sticking, on the ground floor gel coat, use interlayer resin to carry out the lamination operation, and be cured;
(5) brush gel coating resin: treat after the interlayer resin layer initial set of step (4) that feel is soft and when sticking; In the gel coating resin that step (1) obtains, add a certain amount of curing agent; Brushing one deck gel coating resin on the interlayer resin layer then, the gel coating resin of brushing is uniformly dispersed on interlayer resin;
(6) typing processing: after treating the gel coating resin curing of step (5), fibre glass product manufacture is carried out Surface Machining handle, thereby obtain light-colored static conductive fiberglass.
Via the light-colored static conductive fiberglass that above-mentioned production technology is processed, sheet resistance reaches 10
5Ohm/m.
Above-mentioned lead 4～5% mass content that the preferred addition of electrostatic fibre is a gel coating resin.
Above-mentioned nanoscale is led 8～10% mass content that the preferred addition of static zinc oxide is a gel coating resin.
The invention has the beneficial effects as follows: in the gel coating resin resin, add and a kind ofly nano levelly lead static zinc oxide and lead electrostatic fibre, make the sheet resistance of fiberglass reach 10
5Ohm/m, because the particle diameter of filler is big slightly, oil factor is lower, and the resin viscosity after the adding generally is no more than 50% of former gel coating resin resin viscosity, and disperses easily, and conduction evenly helps constructing operation; Nano levelly lead static zinc oxide and lead electrostatic fibre and do not have the color covering power, can be through adding the incrustation that mill base reach to be needed.
The specific embodiment
Example 1
(1) preparation gel coating resin and interlayer resin: the nanoscale of leading electrostatic fibre and 5% mass content that in resin, adds 3% mass content is led static zinc oxide; And based on requiring to add various mill bases; Common stirring at low speed is until evenly, and it is for use to obtain gel coating resin, in resin, adds a certain amount of conductive black simultaneously; Fully stirring at low speed is until evenly, and it is for use to obtain interlayer resin;
(2) brush gel coating resin: in the gel coating resin that step (1) obtains, add a certain amount of curing agent, at die surface brushing one deck gel coating resin, the gel coating resin of brushing is uniformly dispersed on die face then;
(3) solidify: treat spontaneous curing after brushing is accomplished or under 25 ℃～40 ℃, dry;
(4) lamination operation: treat after the initial set of ground floor gel coat that feel is soft and when sticking, on the ground floor gel coat, use interlayer resin to carry out the lamination operation, and be cured;
(5) brush gel coating resin: treat after the interlayer resin layer initial set of step (4) that feel is soft and when sticking; In the gel coating resin that step (1) obtains, add a certain amount of curing agent; Brushing one deck gel coating resin on the interlayer resin layer then, the gel coating resin of brushing is uniformly dispersed on interlayer resin;
(6) typing processing: after treating the gel coating resin curing of step (5), fibre glass product manufacture is carried out Surface Machining handle, thereby obtain light-colored static conductive fiberglass.
Via the light-colored static conductive fiberglass that above-mentioned production technology is processed, sheet resistance reaches 10
5Ohm/m.
Example 2
(1) preparation gel coating resin and interlayer resin: the nanoscale of leading electrostatic fibre and 15% mass content that in resin, adds 8% mass content is led static zinc oxide; And based on requiring to add various mill bases; Common stirring at low speed is until evenly, and it is for use to obtain gel coating resin, in resin, adds a certain amount of conductive black simultaneously; Fully stirring at low speed is until evenly, and it is for use to obtain interlayer resin;
(2) brush gel coating resin: in the gel coating resin that step (1) obtains, add a certain amount of curing agent, at die surface brushing one deck gel coating resin, the gel coating resin of brushing is uniformly dispersed on die face then;
(3) solidify: treat spontaneous curing after brushing is accomplished or under 25 ℃～40 ℃, dry;
(4) lamination operation: treat after the initial set of ground floor gel coat that feel is soft and when sticking, on the ground floor gel coat, use interlayer resin to carry out the lamination operation, and be cured;
(5) brush gel coating resin: treat after the interlayer resin layer initial set of step (4) that feel is soft and when sticking; In the gel coating resin that step (1) obtains, add a certain amount of curing agent; Brushing one deck gel coating resin on the interlayer resin layer then, the gel coating resin of brushing is uniformly dispersed on interlayer resin;
(6) typing processing: after treating the gel coating resin curing of step (5), fibre glass product manufacture is carried out Surface Machining handle, thereby obtain light-colored static conductive fiberglass.
Via the light-colored static conductive fiberglass that above-mentioned production technology is processed, sheet resistance reaches 10
5Ohm/m.
Example 3
(1) preparation gel coating resin and interlayer resin: the nanoscale of leading electrostatic fibre and 8% mass content that in resin, adds 4% mass content is led static zinc oxide; And based on requiring to add various mill bases; Common stirring at low speed is until evenly, and it is for use to obtain gel coating resin, in resin, adds a certain amount of conductive black simultaneously; Fully stirring at low speed is until evenly, and it is for use to obtain interlayer resin;
(2) brush gel coating resin: in the gel coating resin that step (1) obtains, add a certain amount of curing agent, at die surface brushing one deck gel coating resin, the gel coating resin of brushing is uniformly dispersed on die face then;
(3) solidify: treat spontaneous curing after brushing is accomplished or under 25 ℃～40 ℃, dry;
(4) lamination operation: treat after the initial set of ground floor gel coat that feel is soft and when sticking, on the ground floor gel coat, use interlayer resin to carry out the lamination operation, and be cured;
(5) brush gel coating resin: treat after the interlayer resin layer initial set of step (4) that feel is soft and when sticking; In the gel coating resin that step (1) obtains, add a certain amount of curing agent; Brushing one deck gel coating resin on the interlayer resin layer then, the gel coating resin of brushing is uniformly dispersed on interlayer resin;
(6) typing processing: after treating the gel coating resin curing of step (5), fibre glass product manufacture is carried out Surface Machining handle, thereby obtain light-colored static conductive fiberglass.
Via the light-colored static conductive fiberglass that above-mentioned production technology is processed, sheet resistance reaches 10
5Ohm/m.
Example 4
(1) preparation gel coating resin and interlayer resin: the nanoscale of leading electrostatic fibre and 10% mass content that in resin, adds 5% mass content is led static zinc oxide; And based on requiring to add various mill bases; Common stirring at low speed is until evenly, and it is for use to obtain gel coating resin, in resin, adds a certain amount of conductive black simultaneously; Fully stirring at low speed is until evenly, and it is for use to obtain interlayer resin;
(2) brush gel coating resin: in the gel coating resin that step (1) obtains, add a certain amount of curing agent, at die surface brushing one deck gel coating resin, the gel coating resin of brushing is uniformly dispersed on die face then;
(3) solidify: treat spontaneous curing after brushing is accomplished or under 25 ℃～40 ℃, dry;
(4) lamination operation: treat after the initial set of ground floor gel coat that feel is soft and when sticking, on the ground floor gel coat, use interlayer resin to carry out the lamination operation, and be cured;
(5) brush gel coating resin: treat after the interlayer resin layer initial set of step (4) that feel is soft and when sticking; In the gel coating resin that step (1) obtains, add a certain amount of curing agent; Brushing one deck gel coating resin on the interlayer resin layer then, the gel coating resin of brushing is uniformly dispersed on interlayer resin;
(6) typing processing: after treating the gel coating resin curing of step (5), fibre glass product manufacture is carried out Surface Machining handle, thereby obtain light-colored static conductive fiberglass.
Via the light-colored static conductive fiberglass that above-mentioned production technology is processed, sheet resistance reaches 10
5Ohm/m.
Claims (3)
1. the production technology of a light-colored static conductive fiberglass is characterized in that leading electrostatic fibre and nanoscale is led static zinc oxide through in surperficial gel coating resin resin, adding, and adds various mill bases as requested, and concrete processing step is following:
(1) preparation gel coating resin and interlayer resin: the nanoscale of leading electrostatic fibre and 5～15% mass content that in resin, adds 3～8% mass content is led static zinc oxide and is mixed with gel coating resin; And based on requiring to add various mill bases; Common stirring at low speed is until evenly, and is for use, in resin, adds a certain amount of conductive black simultaneously and is mixed with interlayer resin; Abundant stirring at low speed is until evenly, and is for use;
(2) brush gel coating resin: in the gel coating resin that step (1) obtains, add a certain amount of curing agent, at die surface brushing one deck gel coating resin, the gel coating resin of brushing is uniformly dispersed on die face then;
(3) solidify: treat spontaneous curing after brushing is accomplished or under 25 ℃～40 ℃, dry:
(4) lamination operation: treat after the initial set of ground floor gel coat that feel is soft and when sticking, on the ground floor gel coat, use interlayer resin to carry out the lamination operation, and be cured;
(5) brush gel coating resin: treat after the interlayer resin layer initial set of step (4) that feel is soft and when sticking; In the gel coating resin that step (1) obtains, add a certain amount of curing agent; Brushing one deck gel coating resin on the interlayer resin layer then, the gel coating resin of brushing is uniformly dispersed on interlayer resin;
(6) typing processing: after treating the gel coating resin curing of step (5), fibre glass product manufacture is carried out Surface Machining handle, thereby obtain light-colored static conductive fiberglass.
2. the production technology of light-colored static conductive fiberglass according to claim 1 is characterized in that leading 4～5% mass content that the electrostatic fibre addition is a gel coating resin.
3. the production technology of light-colored static conductive fiberglass according to claim 1 is characterized in that nanoscale leads 8～10% mass content that static zinc oxide addition is a gel coating resin.
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| CN201210288395.0A CN102774021B (en) | 2012-08-10 | 2012-08-10 | Production process of light-colored static-conduction glass steel |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937388A (en) * | 2014-04-22 | 2014-07-23 | 浙江倍斯特制冷科技有限公司 | Weather-resistant nano-composite gel coat and preparation method thereof |
| CN103963313A (en) * | 2014-04-18 | 2014-08-06 | 武汉共达材料科技有限公司 | Glass fiber reinforced plastics product with anti-static function and preparation method |
| CN107127983A (en) * | 2017-05-14 | 2017-09-05 | 南通德瑞森复合材料有限公司 | A kind of imitation gold plating glass reinforced plastic pipe preparation technology |
| CN107234859A (en) * | 2017-05-14 | 2017-10-10 | 南通德瑞森复合材料有限公司 | A kind of ornamental glass steel plate and construction technology |
| CN107415276A (en) * | 2017-05-14 | 2017-12-01 | 南通德瑞森复合材料有限公司 | A kind of graining fiberglass preparation technology |
Citations (2)
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|---|---|---|---|---|
| JPH0616846A (en) * | 1992-07-03 | 1994-01-25 | Hitachi Zosen Corp | Conductive fiber-reinforced synthetic resin |
| CN1338542A (en) * | 2000-08-23 | 2002-03-06 | 上海君江科技有限公司 | Permanently antistatic fire-retarding colour veneer |
-
2012
- 2012-08-10 CN CN201210288395.0A patent/CN102774021B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0616846A (en) * | 1992-07-03 | 1994-01-25 | Hitachi Zosen Corp | Conductive fiber-reinforced synthetic resin |
| CN1338542A (en) * | 2000-08-23 | 2002-03-06 | 上海君江科技有限公司 | Permanently antistatic fire-retarding colour veneer |
Non-Patent Citations (1)
| Title |
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| 谢永和，赵丽萍: "《渔船船体及船舶设备》", 31 August 2004, 北京市：海洋出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103963313A (en) * | 2014-04-18 | 2014-08-06 | 武汉共达材料科技有限公司 | Glass fiber reinforced plastics product with anti-static function and preparation method |
| CN103937388A (en) * | 2014-04-22 | 2014-07-23 | 浙江倍斯特制冷科技有限公司 | Weather-resistant nano-composite gel coat and preparation method thereof |
| CN103937388B (en) * | 2014-04-22 | 2016-01-20 | 浙江倍斯特制冷科技有限公司 | Nano combined gel coat of weather resistant and preparation method thereof |
| CN107127983A (en) * | 2017-05-14 | 2017-09-05 | 南通德瑞森复合材料有限公司 | A kind of imitation gold plating glass reinforced plastic pipe preparation technology |
| CN107234859A (en) * | 2017-05-14 | 2017-10-10 | 南通德瑞森复合材料有限公司 | A kind of ornamental glass steel plate and construction technology |
| CN107415276A (en) * | 2017-05-14 | 2017-12-01 | 南通德瑞森复合材料有限公司 | A kind of graining fiberglass preparation technology |
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| CN102774021B (en) | 2015-01-14 |
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