CN102765973A - Organic waste pyrolysis, carbonization and activation method and device thereof - Google Patents

Organic waste pyrolysis, carbonization and activation method and device thereof Download PDF

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Publication number
CN102765973A
CN102765973A CN2011101127400A CN201110112740A CN102765973A CN 102765973 A CN102765973 A CN 102765973A CN 2011101127400 A CN2011101127400 A CN 2011101127400A CN 201110112740 A CN201110112740 A CN 201110112740A CN 102765973 A CN102765973 A CN 102765973A
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China
Prior art keywords
heating
steam
heating drum
discharge
solenoid
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CN2011101127400A
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CN102765973B (en
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张大伟
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MISSISSIPPI INTERNATIONAL WATER (CHINA) CO Ltd
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MISSISSIPPI INTERNATIONAL WATER (CHINA) CO Ltd
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Priority to CN201110112740.0A priority Critical patent/CN102765973B/en
Priority to PCT/CN2012/075023 priority patent/WO2012149897A1/en
Publication of CN102765973A publication Critical patent/CN102765973A/en
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/312Preparation
    • C01B32/336Preparation characterised by gaseous activating agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/05Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/30Active carbon
    • C01B32/312Preparation
    • C01B32/318Preparation characterised by the starting materials
    • C01B32/324Preparation characterised by the starting materials from waste materials, e.g. tyres or spent sulfite pulp liquor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

An organic waste pyrolysis, carbonization and activation method comprises the following steps of: 1) conveying organic wastes which need processing into rotatable stainless steel heating equipment; 2) powering up a solenoid, and flipping and heating the organic wastes in the heating equipment by the use of an alternating magnetic field generated from the solenoid; 3) condensing steam generated by heating of the organic wastes into condensed water, and conveying combustible gas into a combustor of a steam boiler; 4) keeping heating, introducing steam and flue gas, and activating carbon generated by pyrolysis of the organic wastes so as to increase carbon pore; 5) stopping heating and discharging carbon; and 6) repeating step 1 to step 5. The invention also discloses a device for realizing the above method.

Description

A kind of with thermal decomposition of organic wastes, carbonization, activatory method and apparatus
Technical field
The present invention relates to a kind of method that thereby organic waste is prepared agriculture charcoal through pyrolysis way carbonization, activation.
The invention still further relates to a kind of device that is used to realize aforesaid method.
Background technology
2007 the world " agriculture charcoal " initiate conference and hold at New South Wales, Australia, various countries scientist and business circles have caused " agriculture charcoal " technical study and utilization shows great attention to.
" agriculture charcoal " is with organic raw material such as animal excrement, rice husk, Pericarppium arachidis hypogaeae, cornstalk, trees waste materials (Agrichar); The same residue of similar charcoal that under oxygen-free environment, forms behind the low temperature pyrogenation, the carbon in about 50% the organic raw material is retained in wherein.
The newest research results of Australia 5 rumba Agricultural Research Institute has been reconfirmed the great potential of " agriculture charcoal " technology.The researchist tests by the amount that the per hectare farmland applies 10 tons " agriculture charcoals ", and the result shows that " agriculture charcoal " can make the output of wheat increase by 3 times, makes the output of soybean increase more than 2 times.Simultaneously, they also use nitrogenous fertilizer and " agriculture charcoal " and nitrogenous fertilizer separately and are used for comparing test, find that output is basic identical.This explanation uses " agriculture charcoal " just can play the effect of increasing production the same with using nitrogenous fertilizer separately.
" agriculture charcoal " technology can also significantly reduce the discharging of greenhouse gases.The famous scientist's Tim Fu Lannarui of Australia points out that in the world, the greenhouse gases amount that soil discharges is more than 10 times of greenhouse gases that fossil-fueled produces.Through the gas that discharges in the soil is measured and contrasted, find that " agriculture charcoal " can significantly reduce the release of carbonic acid gas and nitrous oxide.And nitrous oxide is another kind of more serious greenhouse gases, and its effectiveness of making Greenhouse effect is 300 times of carbonic acid gas, and is sustainable 150 years in air.
The Australia 5 another one environmentalist Steve Ken Mubai of rumba Agricultural Research Institute point out that " agriculture charcoal " also brings another benefit for peasant and environment.Carbon in the forms such as farm crop remnants, mulching material and mixed fertilizer is unsettled in soil, in two to three years, will thoroughly decompose, and changes into carbonic acid gas.And " agriculture charcoal " is very stable in soil, and carbon wherein can keep the time of centuries.This means that use " agriculture charcoal " and the mixed fertilizer of equivalent, " agriculture charcoal " once just can push up decades, and mixed fertilizer will use every year, this can reduce peasant's expenditure undoubtedly.For environment, because unsettled, labile carbon is replaced by stable " agriculture charcoal ", the amount of carbon dioxide that soil discharges will significantly reduce.
The mankind produce a large amount of organic wastes every day in production, life process: the ight soil in cattle farm, poulty house; The rice husk of grain processing enterprise, Pericarppium arachidis hypogaeae; The agricultural crop straw that produces in the agricultural production process; Remaining bagasse in sugar enterprise's production process; The blue-green algae that the shallow lake Pollution abatement is salvaged ... or the like.Except moisture, also contain a large amount of organism in the above-mentioned organic waste, organic staple is a carbon.These organic waste water cut are big, complicated component, and the place disperses, if can not be in time, deal carefully with very easily smellyly, causes environmental pollution.
As everyone knows, with organic wastes such as animal excrement, rice husk, Pericarppium arachidis hypogaeae, agricultural crop straw, bagasse, blue-green algaes, can process agriculture charcoal (Agrichar) after pyrolysis under oxygen-free environment, carbonization, the activation.Make agriculture carbon realization suitability for industrialized production after whether can adopting a kind of device to make above-mentioned thermal decomposition of organic wastes, carbonization, activation, do not appear in the newspapers so far.
Summary of the invention
The object of the present invention is to provide a kind ofly with organic wastes such as animal excrement, rice husk, Pericarppium arachidis hypogaeae, agricultural crop straw, bagasse, blue-green algaes, pyrolysis under oxygen-free environment, carbonization, activation prepare the method for agriculture charcoal.
Another purpose of the present invention is to provide a kind of and is used for thermal decomposition of organic wastes, carbonization, activatory device.
Be to realize above-mentioned purpose, provided by the invention thermal decomposition of organic wastes, carbonization, activation are prepared the method for agriculture charcoal, key step comprises:
1) organic waste that will handle is transported in the heating installation of rotatable stainless steel;
2) to the solenoid energising, the alternating magnetic field that utilizes solenoid to produce stirs heat treated to the organic waste in the heating installation;
3) water vapor condensation of organic waste heating generation becomes water of condensation, and inflammable gas is transported to the burner of steam boiler;
4) continue heating, the carbon that importing steam and flue gas generate thermal decomposition of organic wastes carries out activation to increase the hole of carbon;
5) stop heating, discharge carbon;
6) repeating step 1 is to step 5.
Provided by the invention being used for wherein mainly comprises thermal decomposition of organic wastes, carbonization, activatory device:
One heating chamber; The heating drum that the interior metallic substance that 1000 ℃ of a magnetic conduction and abilities axially are installed of this heating chamber is processed; The outer wall of this heating drum and the top of heating chamber and both sides inwall are provided with a spacing; The heating drum inwall is equipped with many rows and turns over charging guide plate, is provided with spacing between per two row's stirring charging guide plates; Every row's stirring charging guide plate turns over charging guide plate by polylith to be formed, and every stirring charging guide plate is made up of a plane and an inclined-plane trilateral, and every row turns over the plane of charging guide plate for horizontal, and leg-of-mutton tip is towards the discharge port of heating drum;
At least one group of solenoid that produces alternating magnetic field is the semicircle arcuation, is installed in the heating drum bottom, is provided with the working clearance between the outer wall of solenoid and heating drum bottom; Solenoid electrically connects the power inverter that produces exchange current;
One end of heating drum is a conical shell, in this conical shell marker board is arranged, and the conical shell of heating drum is connected with an end of discharging cylinder.Be provided with the spiral charging guide plate in the discharging cylinder.Be connected with discharge chamber in the other end of this discharging cylinder passes the carrying roller chamber and discharge room extend into out feed bin, the vertical side of this discharge chamber and discharging cylinder offers drain hole, and the blowing flap is installed on this drain hole; This goes out the feed bin bottom and is provided with discharge port;
The interior transfer lime of one convey materials goes out the feed bin outer side wall certainly and axially is plugged in the discharging cylinder, and discharging mouth of pipe of transfer lime extends in the heating drum in this, and the space in this between inwall of transfer lime and discharging cylinder is a tapping channel; The charging mouth of pipe of transfer lime is through swivel joint difference connector material conveying device, steam, flue gas and pressurized air in being somebody's turn to do; There is feeding warehouse this device for transporting objects top;
The other end of heating drum is connected with head roll, and in head roll integral body was located between driving arrangement, interior installing drive device between driving arrangement was by forward and reverse rotation of the electric motor driving heating drum in this drive unit;
One steam discharge pipe axially is plugged in the head roll, and an end is connected on the heating drum, and the other end connects the mixed steam purifying processing device;
Described device, wherein, the two ends sidewall and the top of heating chamber are provided with the heat-insulation and heat-preservation material.
Described device, wherein, the topped one deck ceramic plate of the upper surface of solenoid.
Described device, wherein, discharge room and and the carrying roller chamber between be provided with a dividing plate; The discharge room top is provided with discharge room dedusting mouth, and this discharge room dedusting mouth top connects a dedust air duct, and this dedust air duct is connected with fly-ash separator; The discharge room bottom is provided with discharge gate; The corresponding nesting box in discharge room lower end.
Described device, wherein, the indoor carrying roller that supports the discharging cylinder that is provided with of carrying roller; Discharging cylinder outside is provided with backing ring, and this backing ring is supported on the carrying roller; This discharging cylinder outside is coated with the heat-insulation and heat-preservation material; The carrying roller and the thrust roller of head roll are installed between driving arrangement, and the head roll outside is equipped with backing ring and driving gear, and this backing ring is supported on the carrying roller, and its side towards driving gear contacts with the thrust roller; The pinion(gear) interlock of this driving gear and drive unit; This head roll outside is coated with the heat-insulation and heat-preservation material.
Described device, wherein, the power inverter complete installation between an electricinstallation in, both sides are provided with a plurality of air grating fence gates between this electricinstallation, and the fan of thermolysis wherein has been installed in the air grating fence gate of a side.
Described device, wherein, the top between driving arrangement is provided with dedusting mouth between driving arrangement, and dedusting mouth top is connected with dedust air duct between driving arrangement, and this dedust air duct is connected with fly-ash separator; There is metal door the outer side both sides between driving arrangement, and air grid is arranged at the bottom of metal door.
Described device, wherein, steam discharge pipe connects an end diameter of heating drum greater than the diameter that connects mixed steam purifying processing device one end; This steam discharge pipe is connected with
Figure BDA0000058871180000041
mixed steam purifying processing device through the steam discharge pipe swivel joint that is arranged on outside end plate between driving arrangement;
The diameter of the discharging mouth of pipe one end of interior transfer lime is greater than the diameter of the charging mouth of pipe one end.
Described device, wherein, steam is to be provided by steam boiler, the flue gas that flue gas produces when being the steam boiler burning, pressurized air is to be provided by compressed air tank.
The present invention can suitability for industrialized production scale with organic wastes such as animal excrement, rice husk, Pericarppium arachidis hypogaeae, agricultural crop straw, bagasse, blue-green algaes, can process agriculture charcoal (Agrichar) after pyrolysis under oxygen-free environment, carbonization, the activation.
Description of drawings
Fig. 1 is the structural representation of apparatus of the present invention;
Fig. 2 is the cross-sectional view of apparatus of the present invention;
Fig. 3 is the diagrammatic cross-section along A-A line among Fig. 2;
Fig. 4 is the intravital charging guide plate synoptic diagram that turns over of conically shaped of the present invention, and wherein Fig. 4 a is the sectional view of heating drum, and Fig. 4 b is the diagrammatic cross-section along B-B line among Fig. 4 a.
Description of symbols among the figure:
1-housing, 2-fly-ash separator, 3-cleaning shaft, 4-heat-accumulator tank SV, 5-heat-accumulator tank steam valve, 6-heat-accumulator tank pressure display and transmitter, 7-heat-accumulator tank, 8-heat-accumulator tank steam inlet, 9-heat-accumulator tank sewage draining exit, 10-steam boiler sewage draining exit, 11-steam boiler cap relief valve, 12-steam-pipe, 13-steam boiler SV, 14-steam boiler pressure display and transmitter, 15-flue gas mouth, 16-water supplement port, 17-water level gauge, 18-natural gas burner, 19-methane gas burner, 20-steam boiler, 21-feeding warehouse, 22-material transfer equipment, 23-material conveying pipe, 24-compressed air tank, 25-air outlet valve, 26-inlet mouth, the demonstration of 27-air pressure and transmitter, 28-pressurized air T-valve, 29-steam flue gas T-valve, 30-gas approach, 31-steam-in, 32-steam flue gas mixing tank, 33-air, 34-wheel, 35-nesting box, 36-discharge port, 37-go out in the feed bin, 38-blowing flap, 39-drain hole, 40-folding, 41-spiral charging guide plate, 42-inspection port, 43-steam flue gas mixed export, 44-materail tube swivel joint, 45-that transfer lime, 46-discharge chamber, 47-discharging cylinder, 48-heat-insulation and heat-preservation material, 49-dividing plate, 50-compressed air tank SV, 51-discharge room, 52-go out that feed bin TP, 53-dedusting mouth, 54-vent-pipe, 55-rolling ring, 56-carrying roller chamber, 57-tightness system, 58-dedust air duct, 59-metal shell, 60-head temperature transmitter, 61-heating chamber, 62-heating drum, 63-turn between charging guide plate, 64-steam discharge pipe, 65-head roll, 66-driving gear, 67-driving arrangement, TP, 91-ventilation barrier, 92-deslagging chamber door, 93-barrier air door, 94-electric equipment compartment TP, 95-solenoid TP, 96-fan, 97-chimney, 98-inflammable gas pipeline, 99-vapor pressure equilibrium valve, 100-steam-flow meter, 101-steam-pipe between 68-steam discharge pipe swivel joint, 69-mixed gas outlet, 70-mixture pipe, 71-combustible gas housing, 72-mixed steam purification apparatus, 73-spray water interface, 74-water port, 75-discharge fan, 76-base, 77-drive unit, 78-thrust roller, 79-carrying roller, 80-high-strength ceramic plate, 81-power inverter, 82-solenoid, 83-electricinstallation, Zhong Bu the 84-marker board, 85-conical shell, 86-deslagging chamber, 87-slag-drip opening, 88-blast inlet, 89-metal door, 90-.
Embodiment
Below in conjunction with accompanying drawing the present invention is described in detail.
Please combine Fig. 1 to Fig. 4.The inventive system comprises:
One heating chamber 61, the outside is a metal shell 59.One heating drum 62 axially is installed in this heating chamber, and heating drum 62 adopts high temperature resistant 310S stainless steel to make.Heating chamber 61 two ends sidewalls and top are heat-insulation and heat-preservation materials 48.The Lower Half of heating drum 62 is coated with the arc solenoid 82 of semicircular in shape; This solenoid 82 is at least one group (present embodiment and accompanying drawing are be example explain with 5 groups of solenoids), and the upper surface of solenoid 82 is coated with can resistant to elevated temperatures high-strength ceramic plate 80.Leave the working clearance between the Lower Half of heating drum 62 and the ceramic plate 80; This working clearance is meant that heating drum 62 does not contact friction with ceramic plate 80 generations when rotated; And heating drum 62 can receive the alternating magnetic field that solenoid 82 produces, and general clearance distance is located between the 1-5mm.If clearance distance is excessive, then the magneticline of force of solenoid 82 formation high-frequency alternating magnetic fields can't be through producing eddy current in heating drum 62 metallic objects; If too small, heating drum 62 and ceramic plate 80 produced contact friction and the damage solenoid apart from the gap.
Heating chamber 61 following is between electricinstallation 83; (power inverter effect of the present invention is to solenoid high-frequency alternating current to be provided 5 power inverters 81 that electrically connect 5 groups of solenoids 82 respectively to be installed in 83 between electricinstallation; Mainly form, belong to known technology) by rectifying circuit, inverter circuit, loop, rly., electric fan etc.
83 both sides have air grating fence gate 93 between electricinstallation; Wherein in the air grating fence gate 93 of a side fan 96 is installed; The corresponding power inverter 81 of each exhaust fan is measured working temperatures through the TP 94 between electricinstallation and is started exhaust fan 96 when too high and dispel the heat.
The rotating speed design of heating drum 62 is at 2-5r/min, and the distance of heating drum 62 outer walls and the heating chamber 61 both sides first halves and top inner wall is 300mm.One end of heating drum 62 is a conical shell 85, and marker board 84 is arranged in the conical shell 85, and conical shell 85 is connected with discharging cylinder 47.There are backing ring 55, heat-insulation and heat-preservation material 48 in discharging cylinder 47 outsides, with heating chamber 61, go out feed bin 51 connecting portions tightness system 57 is arranged.
The other end of discharging cylinder 47 passes between carrying roller 56, discharge room 51 extend into out in the feed bin 37 and is connected with discharge chamber 46.A drain hole 39 is arranged on discharge chamber 46 outer round surface; One blowing flap 38 is arranged on the drain hole 39; Blowing flap 38 is connected by a folding 40 with discharge chamber 46 walls, and the blowing flap can cover drain hole 39 after drain hole 39 forwards the top to along with discharge chamber 46, to avoid producing too many dust.
Going out feed bin 37 bottoms has discharge port 36, and outer side wall has inspection port 42, goes out feed bin TP 52, swivel joint 44.There is heat-insulation and heat-preservation material 48 outside that goes out feed bin 37.There is metal door 89 discharge room 51 both sides, and dedusting mouth 53 is arranged at the top.Dedusting mouth 53 is connected with dedust air duct 58.Slag-drip opening 87 is arranged at discharge room 51 bottoms.
Slag-drip opening 87 bottoms are deslagging chamber 86, and the dreg discharging box 35 of belt wheel 34 is arranged in the deslagging chamber 86, and deslagging chamber's 87 1 sides have deslagging chamber's door 92, can dreg discharging box 35 be pulled out.
Ventilation opening 88 is arranged at discharge room 51 inherent dividing plate 49 bottoms with carrying roller chamber 56.Carrying roller 79, vent-pipe 54 are arranged in the carrying roller chamber 56, and there is metal door 89 both sides.The blast inlet of vent-pipe 54 is positioned at carrying roller chamber 56 first halves.
The other end of heating drum 62 is connected with head roll 65.Head roll 65 is positioned between driving arrangement 67.There are backing ring 55, driving gear 66 in head roll 65 outsides.Backing ring 55 is seated on the carrying roller 79, and backing ring 55 contacts with thrust roller 78 towards a side of driving gear 66; The gear interlock of driving gear 66 and drive unit 77, there is heat-insulation and heat-preservation material 48 head roll 65 outsides.Carrying roller 79, thrust roller 78, drive unit 77 are installed in 67 between driving arrangement, dedusting mouth 53 is arranged at the top.Dedusting mouth 53 is connected with dedust air duct 58.67 outside end plates are equipped with swivel joint 68 between driving arrangement, and there is metal door 89 67 both sides between driving arrangement.Air grid 91 is arranged at the bottom of metal door 89.
Steam discharge pipe 64 is installed in the head roll 65, and steam discharge pipe 64 1 ends extend in the heating drum 62, the other end outside head roll 65 with driving arrangement between the vapor pipe swivel joint 68 installed on 67 outer walls be connected.Steam discharge pipe 64 stretches into heating drum 62 interior end diameters greater than the diameter that is connected an end with vapor pipe swivel joint 68.There is steam outlet 69 vapor pipe swivel joint 68 outer ends.Steam outlet 69 is connected with mixed steam purification apparatus 72 steam inlets through pipeline 70.Gas mixture purification apparatus 72 adopts spray column, and spray column is known equipment.Spray column has water-in 73, water outlet 74, steam inlet 70, combustible gas outlet 71.
One end of interior transfer lime 45 passes out feed bin 37, discharge chamber 46, discharging cylinder 47 and extend in the heating drum 62 (this end is referred to as the discharging mouth of pipe).The other end is connected (this end is referred to as the charging mouth of pipe) with the materail tube swivel joint 44 that goes out the installation of feed bin 37 outer walls.Interior transfer lime 45 and discharge chamber 46, the welding of discharging cylinder 47 contacts site.The interior transfer lime 45 discharging mouths of pipe (promptly stretching into an end of heating drum 62) diameter greater than with the charging mouth of pipe (promptly being connected an end) diameter with materail tube swivel joint 44, stop up when avoiding charging.Materail tube swivel joint 44 connects an outer transfer lime 23, and these outer transfer lime 23 the other ends are connected with device for transporting objects 22.There is feeding warehouse 21 device for transporting objects 22 tops.Device for transporting objects 22 adopts spiral pump, and spiral pump is known equipment.
Above-mentioned each parts can be installed on the base 76.
On the outer transfer lime 23 gas mixture T-valve 29 is installed, the two ends of gas mixture T-valve 29 are connected with outer transfer lime 23, and the other end is connected with the mixing gas port 43 of steam flue gas mixing tank 32 through pipeline.23 are equipped with pressurized air T-valve 28 on the outer transfer lime, and the two ends of pressurized air T-valve 28 are connected with outer transfer lime 23, and the other end is connected with the air outlet 25 of compressed air tank 24 through pipeline.
The gas approach 30 of steam flue gas mixing tank 32 is connected with steam boiler flue 97, with flue 97 junctions above smoke valve 50 is installed.The steam inlet 31 of steam flue gas mixing tank 32 is connected with the vapour outlet 5 of heat-accumulator tank 7.Steam flue gas mixing tank 32 adopts venturi tube, and venturi tube is a known device.
Heating drum 62 inwalls are equipped with many rows and turn over charging guide plate 63, and every row turns over charging guide plate 63 and turns over charging guide plate 63 by polylith and form; Two of every rows turn between the charging guide plate 63 has dilatation joint; Every is turned over charging guide plate 63 and is the trilaterals at 5 °~20 ° degree angles by a plane and inclined-plane, and the plane that wherein every row turns over charging guide plate 63 is for horizontally, and the trilateral tip of turning over charging guide plate 63 is towards going out feed bin 37.
Spiral charging guide plate 41 is installed in the discharging cylinder 47.Spiral charging guide plate 41 is left-handed 3 °~15 ° with the vertical angle of discharging cylinder 47.
The present invention is provided with steam boiler 20, and " agriculture charcoal " that its effect provides preparation carries out required steam of activation and flue gas, simultaneously the inflammable gas that produces in the thermal decomposition of organic wastes process is recycled.Form by parts such as steam valve 11, wash water valve 10, SV 13, water supplement port 16, water level gauge 17, pressure display and transmitter 14, natural gas burner 18, methane gas burner 19, exhanst gas outlet 15, chimneys 97.Steam valve 11 is connected with the steam inlet 8 of heat-accumulator tank 7 through pipeline 12.The vapour outlet of heat-accumulator tank 7 has steam valve 5, and steam valve 5 is connected with the steam inlet 31 of steam flue gas mixing tank 32 through pipeline.Heat-accumulator tank 7 is furnished with SV 4, pressure display and transmitter 6, wash water valve 9.
The present invention also is provided with compressed air tank 24, is used for raw material is blown in the heating drum.The inlet mouth 26 of compressed air tank 24 is connected with air 33 air outlets.Pressure display and transmitter 27 are arranged on the compressed air tank 24.
Dust removal installation 2 is connected with dedust air duct 58 through cleaning shaft 3.Dust removal installation 2 adopts known pulsed sack cleaner.
The operation of complete assembly of the present invention is controlled by housing 1.Housing 1 passes through the pilot circuit of power switch, temperature regulation button, power selection button, inside etc., realizes energy transformation, attemperation, device control etc., and housing 1 has following function:
1) measuring ability: oscillation signal detects, current detecting, and voltage detecting, goes out 83 temperature detection between feed bin 37 temperature detection, electricinstallation at vapor pressure detection, compressed air pressure detection, heating chamber 61 temperature detection, solenoid 82 temperature detection.Heating chamber 61 middle part temperature detection.
2) function: current control, vapor pressure control, compressed air pressure control, the control of heating chamber 61 temperature; The control of solenoid 82 temperature goes out the control of feed bin 37 temperature, 83 temperature control between electricinstallation, steam boiler 20 operation controls; The control of heating drum 62 rotating speeds, the control of heating drum 62 turning directions, material transfer equipment 22 operation controls, dust removal installation 2 operation controls; Discharge fan 75 operation controls, fan 96 controls, air 33 controls.
3) Presentation Function: heating chamber 61 temperature, heating chamber 61 middle part temperature go out feed bin 37 temperature, 83 temperature between electricinstallation; Solenoid 82 temperature, vapor pressure, drive unit 77 operations stop; Steam boiler 20 operations stop, and material transfer equipment 22 operations stop, dust removal installation 2 operations stop, and discharge fan 75 operations stop; Fan 96 operations stop, and air 33 operations stop heating drum 62 rotating speeds, discharge fan 75 rotating speeds.
4) defencive function: overtemperature prote, overcurrent protection, the under-voltage protection of voltage superpressure, leakage magnetic flux protection, steam overpressure protection.
Said apparatus of the present invention is used for animal excrement are processed agriculture charcoal (Agrichar) after pyrolysis under the oxygen-free environment, carbonization, activation schedule of operation is following:
(1) animal excrement that will process are transported in the feed storehouse 21;
(2) start discharge fan 75; Start dust removal installation 1;
(3) with adding the water level of softening water in the steam boiler 20 to regulation;
(4) starting air 33 inflates in compressed air tank 24;
(5) send water to gas mixture purification apparatus 72;
(6) pressurized air T-valve 28 is opened to material conveying pipe 23 connections, steam flue gas T-valve 29 is opened to material conveying pipe 23 connections;
(7) above-mentioned work ready after, start drive unit 77, heating drum 62 is seen from gas mixture purification apparatus 72 1 ends, turn round with 5r/min speed in the direction of the clock;
(8) start material transfer equipment 22, the animal excrement in the feeding warehouse 21 are got in the heating drum through material conveying pipe 23, pressurized air T-valve 28, steam flue gas T-valve 29, swivel joint 44, interior transfer lime 45.After animal excrement have been carried; The air outlet that pressurized air T-valve 28 is rotated to compressed air tank 24 is communicated with the material conveying pipe 23 of swivel joint 44 1 sides; Open air outlet valve 25; Animal excrement in the material conveying pipe 23 of swivel joint 44 1 sides are blown in the heating drum 62, close air outlet valve 25 then.The rotating speed of heating drum 62 is transferred to the running of 1~2r/min speed.
(9) send to power inverter 81.Produce high-frequency current through the electronic circuit board integral part in the power inverter 81; By rectifying circuit the alternating-current of 50HZ/60HZ is become volts DS; Convert volts DS to high-frequency current through pilot circuit again; Form high-frequency alternating magnetic fields through solenoid 82, when the magneticline of force in the magnetic field through the heating position metallic object of heating drum 62 in the electric current (being eddy current) of generation alternation, eddy current makes heating drum 62 iron molecule high speed random motions; Molecule run foul of each other, rub and produce heat energy make heating drum 62 itself voluntarily at a high speed heating heat up rapidly, and the heat energy that heating drum 62 is produced is passed to the animal excrement in the heating drum 62.
(10) animal excrement in heating drum 62 are being turned under the effect of charging guide plate 63 and are constantly being stirred, heat.When the temperature of heating chamber 61 was elevated to 200~250 ℃, the moisture start vaporizer in the heating drum 62 in the animal excrement generated water vapor.When the temperature of heating chamber 61 was elevated to 500~650 ℃, the organism in the organic waste in the heating drum 62 began to decompose, gasification, generates the gas that contains combustiblecomponentss such as methane, ethane, carbon monoxide.
(11) the mixing gas of water vapor and the gas formation that contains combustiblecomponents through vapor pipe 64, swivel joint 68, mixture pipe 70, gets in the mixed steam purification apparatus under the effect of discharge fan in the heating drum 62.The mixed steam purification apparatus is known products-spray column.Moisture in the mixed steam purification apparatus in the mixed steam becomes water of condensation after handling through spray, discharges through the water port 74 of mixed steam purification apparatus.Inflammable gas such as methane, ethane is transported to the methane gas burner 19 of steam boiler 20 in the mixed steam through combustible gas outlet 71, discharge fan 75, the combustible gas pipeline 98 of mixed steam evolution treatment facility.
(12) because the methane gas that produces in the thermal decomposition of organic wastes process is unstable; Therefore steam boiler need keep that burning things which may cause a fire disaster is arranged in the burner hearth all the time with natural gas burner; Be the methane gas igniting; Guarantee methane gas can be safely in the steam boiler burner hearth, burning reliably, avoid cutoff, detonation etc.When the inflammable gas shortage of heat that produces, replenish by natural gas burner, enough steam and flue gas are arranged when guaranteeing activation.
(13) when the temperature of heating chamber 61 reaches 650~750 ℃, steam flue gas T-valve is rotated to steam flue gas mixed gas outlet 43 be communicated with the material conveying pipe of swivel joint 44 1 sides; Valve on the chimney 97 50 is turned down, opened the steam valve 5 of heat-accumulator tank 7.Steam gets into steam flue gas mixing equipment 32 through steam-pipe 101, vapor pressure equilibrium valve 99, steam-flow meter 100, steam-in 31.The quantity of input steam and the ratio of the carbon in the heating drum 62 are 500~700m 3: 1t.Under the suction function that when vapour stream is crossed venturi tube, produces, flue gas gets into steam flue gas mixing equipment 32 from gas approach 30.Steam flue gas mixing equipment 32 steam-ins 31 are 1: 2 with the bore ratio of gas approach 30.Steam and flue gas mix the back and get in the heating drum from steam flue gas mixed gas outlet 43, swivel joint 44, interior transport pipe 45 in venturi tube, the carbon that thermal decomposition of organic wastes is generated carries out activation, increases the hole of carbon.The input of steam flue gas gas mixture was at first closed the power supply of power inverter 81 after 15~30 minutes.Steam off valve 5 when the temperature in the heating chamber 61 is reduced to 600~700 ℃.
(14) when the temperature in the heating chamber 61 drops to 200~300 ℃; At first stopping heating drum 62 rotates; Change heating drum 62 turning directions then, heating drum 62 is seen from gas mixture purification apparatus 72 1 ends, turn round with 5r/min speed counter clockwise.Carbon is pulled to the rear end of heating drum 62 in the heating drum 62 under the effect of turning over charging guide plate 63, gets into marker board 84; Under the effect of marker board 84, carbon gets into discharging cylinder 47; Under the effect of the spiral charging guide plate 41 in discharging cylinder 47, get into discharge chamber 46, be deposited in the bottom of discharge chamber 46; Below the drain hole 39 of discharge chamber 46 forwards at every turn; The drain hole 39 of discharge chamber 46 is down the time, and lid 38 is because the effect of gravity is opened downwards, and the carbon of discharge chamber 46 bottoms is emitted from drain hole 39; Get into out in the feed bin 37, the discharge port below going out feed bin 37 36 is discharged again.
(15) when heating drum 62 operation or discharging, have a spot of dust and get into out in the feed bin 37 from the drain hole 39 of heating drum 62, discharging cylinder 47, discharge chamber 46, be leaked to discharge room 51 from discharging cylinder 47 and the seals at that goes out between the feed bin 37 again.The dust that is leaked in the discharge room 51 will get into fly-ash separator 2 through dedusting mouth 53, dedust air duct 58, cleaning shaft 3.Being leaked to the slag-drip opening 87 of dust heavier in the discharge room 51 below discharge room 51 falls in the dreg discharging box 35 in the deslagging chamber 96.
(16) in operational process,, start fan 96 and dispel the heat if between electricinstallation 83 or the temperature of solenoid 82 when high.

Claims (10)

1. one kind with thermal decomposition of organic wastes, carbonization, activatory method, and key step comprises:
1) organic waste that will handle is transported in the heating installation of rotatable stainless steel;
2) to the solenoid energising, the alternating magnetic field that utilizes solenoid to produce stirs heat treated to the organic waste in the heating installation;
3) water vapor condensation that the organic waste heating is generated becomes water of condensation, and inflammable gas is transported to the burner of steam boiler;
4) continue heating, the carbon that importing steam and flue gas generate thermal decomposition of organic wastes carries out activation to increase the hole of carbon;
5) stop heating, discharge carbon;
6) repeating step 1 is to step 5.
2. one kind is used for thermal decomposition of organic wastes, carbonization, activatory device, wherein mainly comprises:
One heating chamber; The heating drum that the interior metallic substance that 1000 ℃ of a magnetic conduction and abilities axially are installed of this heating chamber is processed; The outer wall of this heating drum and the top of heating chamber and both sides inwall are provided with a spacing; The heating drum inwall is equipped with many rows and turns over charging guide plate, is provided with spacing between per two row's stirring charging guide plates; Every row's stirring charging guide plate turns over charging guide plate by polylith to be formed, and every stirring charging guide plate is made up of a plane and an inclined-plane trilateral, and every row turns over the plane of charging guide plate for horizontal, and leg-of-mutton tip is towards the discharge port of heating drum;
At least one group of solenoid that produces alternating magnetic field is the semicircle arcuation, is installed in the heating drum bottom, is provided with the working clearance between the outer wall of solenoid and heating drum bottom; Solenoid electrically connects the power inverter that produces exchange current;
One end of heating drum is a conical shell, in this conical shell marker board is arranged; The conical shell of heating drum is connected with an end of discharging cylinder.
Be provided with the spiral charging guide plate in the discharging cylinder.Be connected with discharge chamber in the other end of this discharging cylinder passes the carrying roller chamber and discharge room extend into out feed bin, the vertical side of this discharge chamber and discharging cylinder offers drain hole, and the blowing flap is installed on this drain hole; This goes out the feed bin bottom and is provided with discharge port;
The interior transfer lime of one convey materials goes out the feed bin outer side wall certainly and axially is plugged in the discharging cylinder, and discharging mouth of pipe of transfer lime extends in the heating drum in this, and the space in this between inwall of transfer lime and discharging cylinder is a tapping channel; The charging mouth of pipe of transfer lime is through swivel joint difference connector material conveying device, steam, flue gas and pressurized air in being somebody's turn to do; There is feeding warehouse this device for transporting objects top;
The other end of heating drum is connected with head roll, and in head roll integral body was located between driving arrangement, interior installing drive device between driving arrangement was by forward and reverse rotation of the electric motor driving heating drum in this drive unit;
One steam discharge pipe axially is plugged in the head roll, and an end is connected on the heating drum, and the other end connects the mixed steam purifying processing device.
3. device according to claim 2, wherein, the two ends sidewall and the top of heating chamber are provided with the heat-insulation and heat-preservation material.
4. device according to claim 2, wherein, the topped one deck ceramic plate of the upper surface of solenoid.
5. device according to claim 2, wherein, discharge room and and the carrying roller chamber between be provided with a dividing plate; The discharge room top is provided with discharge room dedusting mouth, and this discharge room dedusting mouth top connects a dedust air duct, and this dedust air duct is connected with fly-ash separator; The discharge room bottom is provided with discharge gate; The corresponding nesting box in discharge room lower end.
6. device according to claim 2, wherein, the indoor carrying roller that supports the discharging cylinder that is provided with of carrying roller; Discharging cylinder outside is provided with backing ring, and this backing ring is supported on the carrying roller; This discharging cylinder outside is coated with the heat-insulation and heat-preservation material.
7. device according to claim 2 wherein, is equipped with the carrying roller of head roll between driving arrangement, and the head roll outside is equipped with backing ring and driving gear, and this backing ring is supported on the carrying roller, the pinion(gear) interlock of this driving gear and drive unit; This head roll outside is coated with the heat-insulation and heat-preservation material.
8. device according to claim 2, wherein, the power inverter complete installation between an electricinstallation in, both sides are provided with a plurality of air grating fence gates between this electricinstallation, and the fan of thermolysis wherein has been installed in the air grating fence gate of a side.
9. device according to claim 2, wherein, the top between driving arrangement is provided with dedusting mouth between driving arrangement, and dedusting mouth top is connected with dedust air duct between driving arrangement, and this dedust air duct is connected with fly-ash separator; There is metal door the outer side both sides between driving arrangement, and air grid is arranged at the bottom of metal door.
10. device according to claim 2, wherein, steam discharge pipe connects an end diameter of heating drum greater than the diameter that connects mixed steam purifying processing device one end; This steam discharge pipe is connected with the mixed steam purifying processing device through the steam discharge pipe swivel joint that is arranged on outside end plate between driving arrangement;
The diameter of the discharging mouth of pipe one end of interior transfer lime is greater than the diameter of the charging mouth of pipe one end.
CN201110112740.0A 2011-05-03 2011-05-03 Organic waste pyrolysis, carbonization and activation method and device thereof Expired - Fee Related CN102765973B (en)

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PCT/CN2012/075023 WO2012149897A1 (en) 2011-05-03 2012-05-03 Method and device for preparing agricultural carbon by using an organic substance

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