CN102747616A - Polyacrylate emulsion printing paste adhesion preventer and preparation method thereof - Google Patents
Polyacrylate emulsion printing paste adhesion preventer and preparation method thereof Download PDFInfo
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- CN102747616A CN102747616A CN2012102537430A CN201210253743A CN102747616A CN 102747616 A CN102747616 A CN 102747616A CN 2012102537430 A CN2012102537430 A CN 2012102537430A CN 201210253743 A CN201210253743 A CN 201210253743A CN 102747616 A CN102747616 A CN 102747616A
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- antitack agent
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Abstract
The invention relates to polyacrylate emulsion printing paste adhesion preventer and a preparation method thereof and belongs to the technical field of screen printing. The polyacrylate emulsion printing paste adhesion preventer comprises at least two of silicon oil, mineral oil, animal and vegetable oil, PE-wax (polyethylene wax) and high-grade fatty acid ester. Components and proportion are regulated according to surface adhesion and internal adhesion difference in printing paste printed products, adhesion of the common polyacrylate emulsion printing paste printed products can be overcome effectively, and water resistance, heat resistance and the like are improved.
Description
Technical field
The present invention relates to a kind of polyacrylate dispersion stamp rubber cement antitack agent and preparation method thereof, belong to the screen printing technique field.
Background technology
COAT PRINTING is by means of adhesive coating to be adhered to the printing technology that fiber surface obtains required pattern.Modern age, COAT PRINTING originated in the Ardye system of nineteen thirty-seven Interchemical company, caused the attention of domestic and international colourist to COAT PRINTING, then was after the Aeramin F type textile printing pigment appearance of nineteen fifty-one Germany Bayer company.The sixties synthetic fiber development, the rise of petrochemical industry and the large-scale production of chemical fibre textile provide the opportune moment of displaying one's talent for the COAT PRINTING technology.Because COAT PRINTING technology is easy, there is not sewage discharge to pollute, eco-friendly superiority looms large, thereby develops very fastly, and the share that COAT PRINTING occupies in stamp market, the world increases year by year.Present global COAT PRINTING fabric accounts for whole PRINTED FABRIC more than 55%, and especially in the U.S., the COAT PRINTING proportion has much the trend that replaces dye printing up to 80%.The COAT PRINTING of various countries shared ratio in textiles is different, and the U.S. accounts for 80%, and West Europe accounts for 60 one 70%; India accounts for 60%, and Japan accounts for 30%, though China's textile coating stamp starting is later; But development is very fast; In recent years, the ratio of COAT PRINTING is also in rising trend, has surpassed 50% of total stamp amount so far.Along with improving constantly of living standards of the people; The consumer not only to garment material require increasingly high; And to indoor textile decoration with the requirement of cloth also progressively to middle and high shelves development, in order to adapt to different consumer demands, COAT PRINTING will be further developed.
Owing to have good film forming, adhesion strength, have heat-resisting, resistance to oxidation, weatherability simultaneously, not flavescence, biodegradable, advantages such as environmental protection, polyacrylate dispersion stamp rubber cement becomes rubber cement kind the most frequently used in the COAT PRINTING.But the characteristic of polyacrylate self molecular structure has the shortcoming of hot sticky cold crisp again, be difficult to again reach textiles particularly the printing quality of knitwear require: soft, the good springiness of comfortable feel; Good stretching resilience is arranged; Tack-free under the normal temperature; To extruding again after the stretching of stamp position, unclamp naturally under the normal temperature, do not stick together; The flower bit position is printed in doubling, cooling naturally after 70 ℃ * 24h * 5kg weight, and broken grade for performance requirement can cannot not drawn back stickingly in doubling flower position.For overcoming this shortcoming, people constantly release antiseized method.Such as the vitrification point that improves acrylate copolymer, form the soft nucleocapsid structure of Hard Roll, with modifications such as polyurethane, polysilane or the like, these methods all have certain effect to improving viscosity undoubtedly, but all will reduce some performance of product or raise the cost.The method that adds antitack agent is simple and easy to control, can change proportioning flexibly according to the actual conditions of polyacrylate dispersion stamp rubber cement, the polyacrylate dispersion stamp rubber cement that obtains suiting.Therefore, the method for interpolation antitack agent is the method for the most generally using.
At present the most frequently used antitack agent is a paraffin, floats over the surface of stamp with the form that is separated, and reaches anti-adhesion effects.But belong to brittle solid during paraffin low temperature, stretch and break easily, melt easily during high temperature, anti-adhesion effects reduces.
Disclosed antitack agent is one or more in stearic acid isooctyl, Tissuemat E, the different tridecanol fat of stearic acid, the mineral oil among the patent CN102286888A; Its consumption is the 1.5-2.5% of mass fraction; It has used synthetic wax in an embodiment, and effect is better, but the scope of application is narrower.
To above problem; The present invention provides a kind of polyacrylate dispersion stamp rubber cement antitack agent, goes for acrylic acid ester emulsion stamp rubber cement, polyacrylate/polyurethane polyureas acrylic acid ester emulsion stamp rubber cement, polyurethane polyureas acrylic acid ester emulsion stamp rubber cement system.It comprises silicone oil, mineral oils, vegetable oil, PE wax, with high-grade aliphatic ester at least two kinds.Such antitack agent has stable chemical performance, and feel is smooth, and ABRASION RESISTANCE is good, does not return stickingly, and water-fast advantage such as wash has solved the technical problem that exists in the use of above-mentioned polyacrylate dispersion stamp rubber cement effectively.
Summary of the invention
Goal of the invention of the present invention provides a kind of polyacrylate dispersion stamp rubber cement antitack agent; It comprises in the following material two or more: paraffin, silicone oil, mineral oils, vegetable and animals oils, PE wax and high-grade aliphatic ester, and described antitack agent to account for polyacrylate dispersion stamp rubber cement mass ratio be 1-8%.
Wherein, described paraffin is meant fusing point synthetic cured at 52-70 ° of C;
Described silicone oil comprises at least a in methyl-silicone oil, dimethicone, diethyl silicone oil, ethyl silicon oil, phenyl silicone oil, ethylphenyl silicone oil, methyl phenyl silicone oil, methyl trifluoro propyl silicone oil, the methyl ethylene silicone oil;
Described mineral oil is claimed slab oil, paraffin oil, mineral oil, White Mineral Oil, white oil, atoleine, Liquid Paraffin, white mineral oil again; Generally be the lightweight linear paraffin lube cut of getting molecular weight 250～450 in the crude oil, through acid-alkali refining, washing, drying, carclazyte absorption, add special deep refining such as antioxidant and make.Water white transparency oily viscous liquid, do not have under the room temperature smell tasteless, all very stable to acid, heat, light.Preferred flash-point is at medical grade linear paraffin oil and paraffin oil below 180.
Described vegetable and animals oils comprises at least a in haco oil, palm oil, corn oil, soybean oil, linseed oil, the castor oil.
Described PE wax is claimed macromolecule wax again, and fusing point is between 90-130 ℃.Can be divided into cracking process and synthetic method according to production method.The preferred PE wax of the present invention is the ethylene waxes shape oligomer of fusing point between 90-110 ℃.
Described high-grade aliphatic ester is meant by refining processing or structural formula such as C synthetic, semi-synthetic gained in oil, the coal
nH
2n ± 1COOC
mH
M ± 1One type of material of (n=16-20, m=4-16, m+n≤40), its fusing point is at-20～50 ° of C.Wherein, the preferred one type high-grade aliphatic ester of fusing point between-20～37 ℃.Concrete is butyl stearate, the different monooctyl ester of stearic acid, stearic acid isotridecanol, at least a in the different hexadecanol ester of stearic acid.
A kind of polyacrylate dispersion stamp rubber cement antitack agent provided by the invention can process emulsion and the solution dual mode adds in the stamp rubber cement, and wherein the solid content of antitack agent is 30-50% in the antitack agent emulsion, and the content of antitack agent is 100% in the antitack agent solution.
Antitack agent solution is made up of paraffin oil, high-grade aliphatic ester and silicone oil, and mass ratio is 8: 1: 1, and consumption is the 3-5% of polyacrylate dispersion stamp rubber cement quality.
The antitack agent emulsion is cured by paraffin, mineral oil, paraffin oil, PE, high-grade aliphatic ester is formed; Adopt compound emulsifying agent to process aqueous emulsion and use, paraffin, paraffin oil, mineral oil, PE mass ratio cured, high-grade aliphatic ester are 2: 4: 2 in the antitack agent emulsion: 1.5: 0.5.The consumption of antitack agent emulsion is the 6-10% of polyacrylate dispersion stamp rubber cement quality.
Goal of the invention of the present invention realizes through following technical scheme:
Implementation step does
1, printing model according to tabulating 1 test method down, is judged the viscosity of stamp rubber cement printing product;
Table 1. stamp position viscosity method of testing and performance
2 select to be fit to antitack agent in the step 1;
3 mix stamp rubber cement antitack agent by a certain percentage, are made as emulsion or mixed solution;
4 gently add the antitack agent for preparing in the stamp rubber cement while stirring, continue to be stirred to rubber cement and mix.
When this scheme also can be passed through preparation stamp rubber cement, together add properly mixed antitack agent and realize.
Wherein, the judgement or the mensuration of the viscosity of said stamp rubber cement printing product, can but be not limited to the listed method of implementation step 1 and realize;
When said polyacrylate dispersion stamp rubber cement printing product showed as 3 grades of viscosity, antitack agent was made up of paraffin oil, mineral oil, silicone oil, and mass ratio is 6: 3: 1, and consumption is the 2-4% of polyacrylate dispersion stamp rubber cement.
Printing product when polyacrylate dispersion stamp rubber cement; When showing 2 grades of viscosity, this antitack agent is made up of paraffin, paraffin oil, stearate and silicone oil, and mass ratio is 2: 6: 1: 1; Can be made into emulsion or solution and use, consumption is the 3-6% of polyacrylate dispersion stamp rubber cement.
Printing product when polyacrylate dispersion stamp rubber cement; When showing as 1 grade of viscosity; This antitack agent is cured by paraffin, paraffin oil, mineral oil, PE, high-grade aliphatic ester is formed, and their mass ratio is 2: 4: 2: 1.5: 0.5, consumption was the 4-8% of polyacrylate dispersion stamp rubber cement.
A kind of polyacrylate dispersion antitack agent provided by the present invention has following excellent effect:
1) anti-adhesion effects is good, particularly the low difficult antiseized emulsion of vitrification point.
2) applied widely, utilization flexibly, to pure third, phenylpropyl alcohol, vinegar the third, effectively antitack agent is different.
3) disperse rapidly safety and environmental protection;
4) feel is smooth, and look friction fastness has improvement;
5) do not return sticking;
6) stable chemical performance, anti-storage;
A kind of polyacrylate dispersion stamp rubber cement antitack agent provided by the present invention is applicable to polypropylene
Acid esters stamp rubber cement, polyacrylate/polyurethane stamp rubber cement, polyurethane stamp rubber cement system.
The specific embodiment
Below in conjunction with the specific embodiment the present invention is made further detailed description, but protection domain of the present invention is not limited to following embodiment.The judgement or the mensuration of the viscosity of stamp rubber cement printing product in following examples, can but be not limited to the listed method of table 1 and realize;
Washing fastness adopts grey classification scale to adopt UNI EN ISO105C06/99 as evaluation criteria method standard assay method, and AATCC61/69 and UNI EN20105794 are from C01-C05; 1; The colour fastness to perspiration test is according to GB/T3922; The color fastness to water test is carried out according to GB/T5713; The colorfastness to rubbing test is carried out according to GB/T3920;
Other carries out according to national textile product basic security technical specification GB18401-2010)
Embodiment 1
A kind of polyacrylate dispersion stamp rubber cement prepares, and next adds antitack agent as follows:
1, judges that by table 1 method the viscosity of the printing product of stamp rubber cement is 3 grades of viscosity.
2, select antitack agent to form by paraffin oil, mineral oil, silicone oil.Mass ratio is 6: 3: 1.
3, paraffin oil, mineral oil, silicone oil being formed by mass ratio is 6: 3: 1 mixed, and mechanical agitation breaks into the mixed liquor of homogeneous;
4, the stamp rubber cement is stirred on the limit, and the limit will be set by step 3 prepares, and 3.0% the antitack agent that quality is equivalent to stamp rubber cement quality gently adds wherein, continues to be stirred to rubber cement and mixes and get final product.
Comparative example 1-1
Antitack agent changed do emulsified wax, repeat above-mentioned steps.
Comparative example 1-2
Component (seeing the following form) preparation according to the described environmental protection stamp of patent CN102286888A claim 5 rubber cement.
| The acrylate emulsion polymer | 60 |
| Dispersant | 1.5 |
| Polyethylene glycol | 3 |
| Synthetic wax | 2.5 |
| Thickener | 5 |
| Titanium white powder | 28 |
Comparative example 1-3
Component (seeing the following form) preparation according to the described environmental protection stamp of patent CN102286888A claim 6 rubber cement.
| The acrylate emulsion polymer | 85 |
| Dihydroxylic alcohols | 5 |
| Polyethylene glycol | 3 |
| Synthetic wax | 2 |
| Thickener | 5 |
Compare with the comparative example, technical scheme provided by the present invention has not only overcome the sticking shortcoming of heat of stamp rubber cement, and the index at aspects such as COLOR FASTNESS also is not less than prior art simultaneously.Effect comparison is as shown in table 2:
Table 2 parameter comparison
Embodiment 2
A kind of polyacrylate dispersion stamp rubber cement prepares, and next adds antitack agent as follows:
1, judges that according to table 1 method the viscosity of the printing product of stamp rubber cement is 2 grades of viscosity.
2, select antitack agent to form by paraffin, paraffin oil, stearate and silicone oil.
3, with paraffin, paraffin oil, stearate and silicone oil by weight being 2: 6: 1: 1 mixed, mechanical agitation break into the mixed liquor of homogeneous;
4, the stamp rubber cement is stirred on the limit, and the limit is equivalent to stamp rubber cement quality 4.0% with quality, and 3 antitack agents that prepare gently add wherein set by step, continues to be stirred to rubber cement and mixes and get final product.
Comparative example 2-1
Antitack agent changed do emulsified wax, repeat above-mentioned steps.
Comparative example 2-2
Component (seeing the following form) preparation according to the described environmental protection stamp of patent CN102286888A claim 5 rubber cement.
| The acrylate emulsion polymer | 60 |
| Dihydroxylic alcohols | 1.5 |
| Polyethylene glycol | 3 |
| Synthetic wax | 2.5 |
| Thickener | 5 |
| Titanium white powder | 28 |
Comparative example 2-3
Component (seeing the following form) preparation according to the described stamp rubber cement of patent CN102286888A claim 6.
| The acrylate emulsion polymer | 85 |
| Dihydroxylic alcohols | 5 |
| Polyethylene glycol | 3 |
| Synthetic wax | 2 |
| Thickener | 5 |
Compare with the comparative example, technical scheme provided by the present invention has not only overcome the sticking shortcoming of stamp rubber cement heat, and the index at aspects such as COLOR FASTNESS also is not less than prior art simultaneously.Effect comparison is as shown in table 3:
Table 3 parameter comparison
Embodiment 3
A kind of polyacrylate dispersion stamp rubber cement prepares, and next adds antitack agent as follows:
1, judge that according to table 1 method the viscosity of the printing product of stamp rubber cement is 1 grade of viscosity, viscosity was obvious when particularly high-temperature pressurizing was loaded;
2, select that antitack agent is cured by paraffin, paraffin oil, mineral oil, PE, high-grade aliphatic ester is formed.
3, paraffin, paraffin oil, mineral oil, PE is cured, high-grade aliphatic ester is by weight being 2: 4: 2: 1.5: 0.5 mixed, mechanical agitation break into the mixed liquor of homogeneous;
4, the stamp rubber cement is stirred on the limit, and the limit is equivalent to 6.0% of stamp rubber cement quality with quality, and 3 antitack agents that prepare gently add wherein set by step, continues to be stirred to rubber cement and mixes and get final product.
Comparative example 3-1
Antitack agent changed do emulsified wax, repeat above-mentioned steps.
Comparative example 3-2
Component (seeing the following form) preparation according to the described environmental protection stamp of patent CN102286888A claim 5 rubber cement.
| The acrylate emulsion polymer | 60 |
| Dispersant | 1.5 |
| Polyethylene glycol | 3 |
| Synthetic wax | 2.5 |
| Thickener | 5 |
| Titanium white powder | 28 |
Comparative example 3-3
Component (seeing the following form) preparation according to the described stamp rubber cement of patent CN102286888A claim 6.
| The acrylate emulsion polymer | 85 |
| Dihydroxylic alcohols | 5 |
| Polyethylene glycol | 3 |
| Synthetic wax | 2 |
| Thickener | 5 |
Compare with the comparative example, technical scheme provided by the present invention has not only overcome the shortcoming of the hot sticky cold crisp of stamp rubber cement, and the index at aspects such as COLOR FASTNESS also is not less than prior art simultaneously.Effect comparison is as shown in table 4:
Table 4 parameter comparison
Claims (15)
1. a polyacrylate dispersion stamp rubber cement antitack agent is characterized in that, comprises in the following material two or more: paraffin, silicone oil, mineral oil, vegetable and animals oils, PE wax and high-grade aliphatic ester;
Wherein, described paraffin is meant fusing point synthetic cured at 52-70 ℃;
Described silicone oil comprises at least a in dimethicone, ethyl silicon oil, the ethylphenyl silicone oil;
Described mineral oil is meant that flash-point is at refining linear paraffin oil or paraffin oil below 180 ℃;
Described vegetable and animals oils comprises plunders at least a in haco oil, palm oil, corn oil, the soybean oil;
Described PE wax is meant that fusing point is 90-110 ℃ low molecular weight, narrow distribution Alathon;
Described high-grade aliphatic ester is meant butyl stearate, the different monooctyl ester of stearic acid, stearic acid isotridecanol, at least a in the different hexadecanol ester of stearic acid.
2. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 1 is characterized in that the mass ratio of described antitack agent and polyacrylate dispersion stamp rubber cement is 1%-8%.
3. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 1; It is characterized in that; Antitack agent can process emulsion and the solution dual mode adds in the stamp rubber cement; Wherein the content of antitack agent is 30-50% in the antitack agent emulsion, and the content of antitack agent is 100% in the antitack agent solution.
4. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 3 is characterized in that antitack agent solution is made up of paraffin oil, high-grade aliphatic ester and silicone oil.
5. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 4 is characterized in that the mass ratio of the paraffin oil in the antitack agent solution, high-grade aliphatic ester and silicone oil is 8: 1: 1.
6. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 3 is characterized in that the consumption of antitack agent solution is the 3-5% of polyacrylate dispersion stamp rubber cement quality.
7. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 3 is characterized in that, the antitack agent emulsion is cured by paraffin, mineral oil, paraffin oil, PE, high-grade aliphatic ester is formed.
8. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 7 is characterised in that paraffin, mineral oil, paraffin oil, PE mass ratio cured, high-grade aliphatic ester are 2: 4: 2 in the antitack agent emulsion: 1.5: 0.5.
9. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 3 is characterized in that the consumption of antitack agent emulsion is the 6-10% of polyacrylate dispersion stamp rubber cement quality.
10. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 1; It is characterized in that; When the printing product of polyacrylate dispersion stamp rubber cement showed 1 grade of viscosity, antitack agent was cured by paraffin, paraffin oil, mineral oil, PE, high-grade aliphatic ester is formed.
11. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 10; It is characterized in that; Paraffin, paraffin oil, mineral oil, PE ratio cured, high-grade aliphatic ester are 2: 4: 2: 1.5: 0.5, consumption was the 4-8% of polyacrylate dispersion stamp rubber cement.
12. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 1 is characterized in that when the printing product of polyacrylate dispersion stamp rubber cement, when showing 2 grades of viscosity, this antitack agent is made up of paraffin, paraffin oil, stearate and silicone oil.
13. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 12 is characterized in that the mass ratio of paraffin, paraffin oil, stearate and silicone oil group is 2: 6: 1: 1, consumption is the 3-6% of polyacrylate dispersion stamp rubber cement.
14. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 1 is characterized in that when said polyacrylate dispersion stamp rubber cement printing product showed as 3 grades of viscosity, antitack agent was made up of paraffin oil, mineral oil and silicone oil.
15. a kind of polyacrylate dispersion stamp rubber cement antitack agent as claimed in claim 14 is characterized in that the mass ratio of paraffin oil, mineral oil and silicone oil is 6: 3: 1, consumption is the 2-4% of polyacrylate dispersion stamp rubber cement.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104961867A (en) * | 2015-06-25 | 2015-10-07 | 合肥聚合辐化技术有限公司 | Anti-stick mucilage resin and preparation method thereof |
| CN107916584A (en) * | 2017-11-24 | 2018-04-17 | 陈石生 | Soft dry wet friction fastness improving agent |
| CN111676714A (en) * | 2020-06-23 | 2020-09-18 | 广州明诺新材料科技有限公司 | Digital printing dot imitating white adhesive cement and preparation method thereof |
| CN115058907A (en) * | 2022-07-29 | 2022-09-16 | 东莞长联新材料科技股份有限公司 | Bio-based printing water slurry and preparation method and application thereof |
| CN115142280A (en) * | 2022-08-03 | 2022-10-04 | 东莞长联新材料科技股份有限公司 | Water-based printing adhesive cement with anti-dyeing and anti-color-migration effects and preparation method and application thereof |
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| CN101948555A (en) * | 2010-09-30 | 2011-01-19 | 东莞长联新材料科技有限公司 | Acrylate-containing elastic emulsion, preparation method thereof and compounded printing binder |
| CN102286888A (en) * | 2011-07-12 | 2011-12-21 | 宏大研究院有限公司 | Environment-friendly printing mortar |
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| CN101948555A (en) * | 2010-09-30 | 2011-01-19 | 东莞长联新材料科技有限公司 | Acrylate-containing elastic emulsion, preparation method thereof and compounded printing binder |
| CN102286888A (en) * | 2011-07-12 | 2011-12-21 | 宏大研究院有限公司 | Environment-friendly printing mortar |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104961867A (en) * | 2015-06-25 | 2015-10-07 | 合肥聚合辐化技术有限公司 | Anti-stick mucilage resin and preparation method thereof |
| CN107916584A (en) * | 2017-11-24 | 2018-04-17 | 陈石生 | Soft dry wet friction fastness improving agent |
| CN111676714A (en) * | 2020-06-23 | 2020-09-18 | 广州明诺新材料科技有限公司 | Digital printing dot imitating white adhesive cement and preparation method thereof |
| CN115058907A (en) * | 2022-07-29 | 2022-09-16 | 东莞长联新材料科技股份有限公司 | Bio-based printing water slurry and preparation method and application thereof |
| CN115058907B (en) * | 2022-07-29 | 2023-11-17 | 东莞长联新材料科技股份有限公司 | Bio-based printing water slurry and preparation method and application thereof |
| CN115142280A (en) * | 2022-08-03 | 2022-10-04 | 东莞长联新材料科技股份有限公司 | Water-based printing adhesive cement with anti-dyeing and anti-color-migration effects and preparation method and application thereof |
| CN115142280B (en) * | 2022-08-03 | 2023-12-08 | 东莞长联新材料科技股份有限公司 | Water-based printing adhesive cement with anti-dyeing and anti-migration effects and preparation method and application thereof |
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Address after: 523400 Building 1, No. 733, Liaobu section, Shida Road, Liaobu Town, Dongguan City, Guangdong Province Patentee after: DONGGUAN CTL NEW MATERIAL TECHNOLOGY Co.,Ltd. Address before: 523419 Guangdong province Dongguan city Liaobu Town Village loose sand Industrial Zone Road Patentee before: DONGGUAN CTL NEW MATERIAL TECHNOLOGY Co.,Ltd. |