CN102732000A - 阻燃玻纤增强pa6/pa1010合金组合物及其制备方法 - Google Patents

阻燃玻纤增强pa6/pa1010合金组合物及其制备方法 Download PDF

Info

Publication number
CN102732000A
CN102732000A CN2012102474624A CN201210247462A CN102732000A CN 102732000 A CN102732000 A CN 102732000A CN 2012102474624 A CN2012102474624 A CN 2012102474624A CN 201210247462 A CN201210247462 A CN 201210247462A CN 102732000 A CN102732000 A CN 102732000A
Authority
CN
China
Prior art keywords
flame
glass fibre
strengthens
alloy composite
proof glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012102474624A
Other languages
English (en)
Inventor
郭建鹏
孟成铭
杨涛
陈晓东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Rizhisheng New Technology Development Co Ltd
Original Assignee
Shanghai Rizhisheng New Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Rizhisheng New Technology Development Co Ltd filed Critical Shanghai Rizhisheng New Technology Development Co Ltd
Priority to CN2012102474624A priority Critical patent/CN102732000A/zh
Publication of CN102732000A publication Critical patent/CN102732000A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/12—Making granules characterised by structure or composition
    • B29B9/14—Making granules characterised by structure or composition fibre-reinforced
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58—Component parts, details or accessories; Auxiliary operations
    • B29B7/72—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7461—Combinations of dissimilar mixers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/80—Component parts, details or accessories; Auxiliary operations
    • B29B7/88—Adding charges, i.e. additives
    • B29B7/90—Fillers or reinforcements, e.g. fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/12—Making granules characterised by structure or composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
    • B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
    • B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B29C2948/9259—Angular velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92885—Screw or gear
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895—Barrel or housing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

本发明涉及一种阻燃玻纤增强PA6/PA1010合金组合物及其制备方法，所述组合物包括以下重量百分比含量的各组分：PA620-41％，PA101020-41％，复配阻燃母粒0-15％，玻璃纤维20-40%，抗氧剂0.1-1％，润滑分散剂0.1-1％；所述组合物的制备方法包括如下步骤：按重量配比称取各组分，放入高混机中混合2～5分钟，出料，然后用双螺杆挤出机挤出造粒，加工温度在200～225℃，螺杆转数在30～40Hz。与现有技术相比，本发明的组合物具有高CTI值、低阻燃剂析出性、无卤环保、综合性能均衡等优势，可以广泛应用于接触器、漏电保护器、断路器外壳等电子电器领域的产品。

Description

阻燃玻纤增强PA6/PA1010合金组合物及其制备方法
技术领域
本发明涉及一种阻燃玻纤增强合金材料，具体涉及一种阻燃玻纤增强PA6/PA1010合金组合物及其制备方法。
背景技术
近年来，我国电子电气工业迅速发展，对高电绝缘阻燃增强工程塑料的需求日益增长，如低压真空接触器、断路器、漏电保护器、接插件、低压开关、薄壁电子电气元件等都需要用具有良好的综合力学性能、阻燃性能及电绝缘性能的工程塑料材料。在这一产品领域里，聚酰胺（PA）的用量最大。然而，由于阻燃剂的发展相对行业对材料日益提高的要求来说滞后，很多种阻燃剂加入到材料里会大大降低了材料的力学性能、电绝缘性能。例如，相比漏电起痕指数（CTI）从600V降到200V甚至更低，此外，随着欧盟RoHs和WEEE指令的实施，传统的溴系阻燃体系已不能满足此要求，同时某些阻燃剂的使用也会受到限制。随着技术的进步工程塑料国产化的进程也在加快。上海日之升新技术发展有限公司针对高CTI值、低阻燃剂析出性阻燃玻纤增强PA6/PA1010产品进行了深入的研究。所研制的高CTI值、低阻燃剂析出性、阻燃玻纤增强PA6/PA1010合金产品成功地替代了BASF等公司生产的同类产品，实现了该类产品的国产化，在被一些外资企业纳入原料国产化计划的同时，该材料也开始出口到欧美地区。
发明内容
本发明的目的在于克服上述现有技术存在的缺陷，提供一种阻燃玻纤增强PA6/PA1010合金组合物及其制备方法。本发明的组合物具有高CTI值、低阻燃剂析出性，无卤环保，综合性能均衡等优点，可以广泛应用于接触器、漏电保护器、断路器外壳等电子电器领域的产品。
本发明的目的是通过以下技术方案来实现的：
本发明涉及一种阻燃玻纤增强PA6/PA1010合金组合物，包括以下重量百分比含量的各组分：
Figure BDA00001894915700021
优选地，所述的PA6的特性粘度为2.4dL/g。
优选地，所述的PA1010的特性粘度为2.4dL/g，由癸二酸经缩聚制得。
优选地，所述的复配阻燃母粒是由我公司自行复配，由三种组分混合而成，具体包括以下重量百分比含量的各组分：除铁赤磷母粒：50%；防迁移剂：25%；高CTI助剂：25%。
优选地，所述玻璃纤维为表面经硅烷偶联剂处理的无碱玻璃纤维。
优选地，所述抗氧剂为受阻酚类抗氧剂。
优选地，所述的润滑分散剂为硅酮。
本发明还涉及一种前述的阻燃玻纤增强PA6/PA1010合金组合物的制备方法，具体为：将所述各组分按重量配比放入高混机中混合，出料，双螺杆挤出机挤出造粒，即可。
优选地，所述混合的时间为2～5分钟。
优选地，所述双螺杆挤出机的挤出温度为200～225℃，螺杆转数为30～40HZ。
与现有技术相比，本发明具有如下有益效果：
1、采用复配阻燃母粒体系，和传统的阻燃母粒相比，复配阻燃母粒体系有以下特点：1）综合力学性能更高；2)能将CTI从320V提高到660V；3）克服了普通红磷在一定条件下迁移的制品表面，然后红磷在氧气和水的作用下最终形成对金属制件有腐蚀性的磷系酸性物质的缺陷。
2、加入的抗氧剂为受阻酚类抗氧剂，可提高组合物在加工过程的抗氧化性能和使用过程中的抗老化性能。
3、采用硅酮作为润滑剂，提高材料加工流动性，降低摩擦系数，提高滑爽性，在特定的加工条件下采用分散性较好，停留时间短，剪切稍弱的组合，防止阻燃剂分解，从而保证了材料的质量稳定。
4、具有高CTI值、低阻燃剂析出性，无卤环保，综合性能均衡等优势，可以广泛应用于接触器、漏电保护器、断路器外壳等电子电器领域的产品。
具体实施方式
下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明，但不以任何形式限制本发明。应当指出的是，对本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进。这些都属于本发明的保护范围。
对比例1～3
PA6/PA1010合金组合物，包括表1所示的重量百分比含量的各组分；其制备方法如下：
（1）按表1所示的重量百分比含量称取原料，放入高混机中混合2～5分钟，出料；
（2）将上述混合好的原料加入双螺杆挤出机，挤出造粒，既得所述PA6/PA1010合金组合物；所述双螺杆挤出机的挤出温度、螺杆转数等参数如表2所示。
实施例1～8
阻燃玻纤增强PA6/PA1010合金组合物，包括表1所示的重量百分比含量的各组分；其制备方法如下：
（1）按表1所示的重量百分比含量称取原料，放入高混机中混合2～5分钟，出料；表1中的复配阻燃母粒包括以下质量百分比含量的各组分：除铁赤磷母粒：50%；防迁移剂：25%；高CTI助剂：25%；
（2）将上述混合好的原料加入双螺杆挤出机，挤出造粒，既得所述阻燃玻纤增强PA6/PA1010合金组合物；所述双螺杆挤出机的挤出温度、螺杆转数等参数如表2所示。
表1对比例1～3及实施例1～8的原材料配方
  原料名称   PA6   PA1010   复配阻燃母粒   玻璃纤维   抗氧剂   润滑分散剂
  对比例1   37.3   30   12   20   0.2   0.5
  对比例2   33.3   30   11   25   0.2   0.5
  对比例3   24.3   30   10   35   0.2   0.5
  实施例1   39   40   0   20   0.6   0.4
  实施例2   20   41   15   22.5   1   0.5
  实施例3   25.3   30   9   35   0.1   0.6
  实施例4   21.3   30   8   40   0.2   0.5
  实施例5   22.3   30   7   40   0.2   0.5
  实施例6   23.3   30   6   40   0.6   0.1
  实施例7   41   20   12.8   25   0.2   1
  实施例8   30   27   15   27   0.2   0.8
表2
实施例9、性能测试
采用ASTM标准，对实施例1～8及对比例1～3制得的PA6/PA1010合金组合物样品，进行性能测试对比。测试性能对比如表3所示：
表3
Figure BDA00001894915700051
由表3可知，实施例1与对比例1、2、3相比，说明采用本发明的复配阻燃母粒体系制得的高CTI、低析出性阻燃PA6/PA12合金组合物，具有以下几点优点：
（1）综合力学性能更高：在拉伸强度、弯曲强度、弯曲模量、冲击强度等力学性能指标上均取得较大的提高；
（2）CTI值更高：将CTI从320V提高到660V；
（3）腐蚀性试验得到的PH值由酸性变为中性，说明本发明采用的复配阻燃母粒体系克服了传统阻燃母粒体系中普通红磷在一定条件下迁移的制品表面，然后红磷在氧气和水的作用下最终形成对金属制件有腐蚀性的磷系酸性物质的缺陷。
综上所述，本发明的组合物具有高CTI值、低阻燃剂析出性，无卤环保，综合性能均衡等优点，可以广泛应用于接触器、漏电保护器、断路器外壳等电子电器领域的产品。

Claims (10)

1.一种阻燃玻纤增强PA6/PA1010合金组合物，其特征在于，该组合物包括以下重量百分比含量的各组分：
Figure FDA00001894915600011
2.根据权利要求1所述的阻燃玻纤增强PA6/PA1010合金组合物，其特征在于，所述的PA6的特性粘度为2.4dL/g。
3.根据权利要求1所述的阻燃玻纤增强PA6/PA1010合金组合物，其特征在于，所述的PA1010特性粘度为2.4dL/g，由癸二酸经缩聚制得。
4.根据权利要求1所述的阻燃玻纤增强PA6/PA1010合金组合物，其特征在于，所述的复配阻燃母粒包括以下重量百分比含量的各组分：除铁赤磷母粒：50%；防迁移剂：25%；高CTI助剂：25%。
5.根据权利要求1所述的阻燃玻纤增强PA6/PA1010合金组合物，其特征在于，所述的玻璃纤维为表面经硅烷偶联剂处理的无碱玻璃纤维。
6.根据权利要求1所述的阻燃玻纤增强PA6/PA1010合金组合物，其特征在于，所述的抗氧剂为受阻酚类抗氧剂。
7.根据权利要求1所述的阻燃玻纤增强PA6/PA1010合金组合物，其特征在于，所述的润滑分散剂为硅酮。
8.一种如权利要求1所述的阻燃玻纤增强PA6/PA1010合金组合物的制备方法，其特征在于，所述制备方法具体为：将所述各组分按重量配比放入高混机中混合，出料，双螺杆挤出机挤出造粒，即可。
9.根据权利要求8所述的阻燃玻纤增强PA6/PA1010合金组合物的制备方法，其特征在于，所述混合的时间为2～5分钟。
10.根据权利要求8所述的阻燃玻纤增强PA6/PA1010合金组合物的制备方法，其特征在于，所述双螺杆挤出机的挤出温度为200～225℃，螺杆转数为30～40Hz。
CN2012102474624A 2012-07-17 2012-07-17 阻燃玻纤增强pa6/pa1010合金组合物及其制备方法 Pending CN102732000A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012102474624A CN102732000A (zh) 2012-07-17 2012-07-17 阻燃玻纤增强pa6/pa1010合金组合物及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012102474624A CN102732000A (zh) 2012-07-17 2012-07-17 阻燃玻纤增强pa6/pa1010合金组合物及其制备方法

Publications (1)

Publication Number Publication Date
CN102732000A true CN102732000A (zh) 2012-10-17

Family

ID=46988339

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012102474624A Pending CN102732000A (zh) 2012-07-17 2012-07-17 阻燃玻纤增强pa6/pa1010合金组合物及其制备方法

Country Status (1)

Country Link
CN (1) CN102732000A (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113544213A (zh) * 2019-03-06 2021-10-22 巴斯夫欧洲公司 用于高光泽应用的聚酰胺模塑组合物
WO2022043115A1 (en) * 2020-08-28 2022-03-03 Basf Se Polyamide composition with inclined plane tracking resistance
EP3931260B1 (de) * 2019-02-25 2023-04-05 Basf Se Polyamid-formmassen mit erhöhter hydrolysebeständigkeit

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102382464A (zh) * 2011-09-07 2012-03-21 上海日之升新技术发展有限公司 高cti值、低腐蚀性红磷阻燃玻纤增强pa66材料及其制备方法
CN102558839A (zh) * 2011-12-21 2012-07-11 上海普利特复合材料股份有限公司 一种低气味抗静电红磷阻燃热塑性组合物及其制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102382464A (zh) * 2011-09-07 2012-03-21 上海日之升新技术发展有限公司 高cti值、低腐蚀性红磷阻燃玻纤增强pa66材料及其制备方法
CN102558839A (zh) * 2011-12-21 2012-07-11 上海普利特复合材料股份有限公司 一种低气味抗静电红磷阻燃热塑性组合物及其制备方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3931260B1 (de) * 2019-02-25 2023-04-05 Basf Se Polyamid-formmassen mit erhöhter hydrolysebeständigkeit
CN113544213A (zh) * 2019-03-06 2021-10-22 巴斯夫欧洲公司 用于高光泽应用的聚酰胺模塑组合物
WO2022043115A1 (en) * 2020-08-28 2022-03-03 Basf Se Polyamide composition with inclined plane tracking resistance

Similar Documents

Publication Publication Date Title
CN102775782B (zh) 阻燃玻纤增强pa66/pp合金组合物及其制备方法
CN102775771A (zh) 阻燃玻纤增强pa6/pp合金组合物及其制备方法
CN102382464A (zh) 高cti值、低腐蚀性红磷阻燃玻纤增强pa66材料及其制备方法
CN101805508B (zh) 一种具有改善低温韧性的无卤阻燃聚苯醚组合物及其制备方法
CN102732019B (zh) 阻燃玻纤增强pa610/ppo合金组合物及其制备方法
CN104592722B (zh) 高光泽低翘曲玻纤增强pbt/pp合金及其制备方法
CN102732021B (zh) 高cti值阻燃玻纤增强pa66/pe合金组合物及其制备方法
CN102942738B (zh) 一种高cti值、高gwit值环保阻燃玻纤增强pp/ppo合金材料及其制备方法
CN102731978A (zh) 阻燃玻纤增强pbt/pet合金组合物及其制备方法
CN102732000A (zh) 阻燃玻纤增强pa6/pa1010合金组合物及其制备方法
CN103013101B (zh) 一种高cti值、高gwit值阻燃玻纤增强pa6/pa66合金材料
CN102732020A (zh) 阻燃玻纤增强pa66/ppo合金组合物及其制备方法
CN102775781B (zh) 阻燃玻纤增强pa610/pa612合金组合物及其制备方法
CN102964688B (zh) 一种高cti值、高gwit值环保阻燃玻纤增强pp/pa11合金材料及其制备方法
CN103012921B (zh) 一种高cti值、高gwit值阻燃玻纤增强hdpe/pa66合金材料
CN102775776B (zh) 玻纤增强pa6/pa66合金组合物及其制备方法
CN102775773B (zh) 阻燃玻纤增强pa6/pa612合金组合物及其制备方法
CN104419182A (zh) 环保阻燃增强pc复合材料及其制备方法
CN102732026A (zh) 低析出性阻燃玻纤增强pa6/pa46合金组合物
CN102643526A (zh) 超高耐热性无卤阻燃聚苯醚组合物
CN102732001A (zh) 高cti阻燃玻纤增强pa6/pa610合金组合物
CN102732024A (zh) 阻燃玻纤增强pa46/pa610合金组合物及其制备方法
CN102775783A (zh) 阻燃玻纤增强pa66/pa46合金组合物及其制备方法
CN102731999A (zh) 阻燃玻纤增强pa6组合物及其制备方法
CN102731977A (zh) 高cti值阻燃玻纤增强pet组合物及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20121017