CN102704289A - Fixation method of natural plant indigo dye for wax printing - Google Patents
Fixation method of natural plant indigo dye for wax printing Download PDFInfo
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- CN102704289A CN102704289A CN2012100577039A CN201210057703A CN102704289A CN 102704289 A CN102704289 A CN 102704289A CN 2012100577039 A CN2012100577039 A CN 2012100577039A CN 201210057703 A CN201210057703 A CN 201210057703A CN 102704289 A CN102704289 A CN 102704289A
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Abstract
The invention discloses a fixation method of natural plant indigo dye for wax printing. The fixation method is realized by combining a method for removing surface dyeing through oxidation with a method for fixation through a composite dye-fixing agent. The fixation method comprises the following steps of: putting a fiber product which is dyed by the natural plant indigo dye and dried into an alkaline solution of hydrogen peroxide and a detergent (sodium dodecyl benzene sulfonate or lauryl sodium sulfate and the like), and digesting at the temperature of between 95 and 100 DEG C for 10 to 30 minutes, washing and drying, wherein the concentration (mass percent) of hydrogen peroxide is 0.05 to 0.1 percent, the concentration (mass percent) of sodium dodecyl benzene sulfonate is 0.1 to 0.3 percent, the pH value is 10 to 12, and the bath ratio is 1:20; and digesting the fiber product which is treated by oxidation surface dyeing removal in the solution of the composite dye-fixing agent which consists of animal glue and polyquaternium at the temperature of between 60 and 70 DEG C for 10 to 30 minutes, washing and drying, wherein the concentration (mass percent) of the animal glue in the solution is 1 to 2 percent, and the concentration (mass percent) of polyquaternium is 1 to 3 percent. The plant fiber product obtained by the dye-fixing process keeps the plant indigo fragrance, is bright in color, difficult to fade during friction, formaldehyde-free, green and environment-friendly.
Description
Technical field:
The present invention relates to a kind of color-fixing method of batik, belong to technical field of textile printing with the natural plants bipseudoindoxyl dye.
Background technology:
Vegetable indigo is the traditional handicraft of Chinese Minority Nationalities--a kind of natural plants extensive dyestuff that-batik is adopted; Be a kind of nontoxic, harmless, pollution-free; Dyestuff with peat-reek and health care; Its dyeing articles is bright in colour, tone is graceful and good hand feeling is abundant, have chemical synthetic dye incomparable advantage.In ancient times, vegetable indigo is to use the most extensive and most important dyestuff, can dye fibres such as throwing, hair, cotton, fiber crops.In minority areas such as Yao nationality on ground such as Yunnan Province of China, Guizhou, Guangxi and Hainan, Miao ethnic group, Zhuangs; Continue to use the traditional handicraft of vegetable indigo dyeing always; The batik and waxprinting article of these ethnic groups has characteristic; Except that einnehmen function, also be to receive the especially tourist souvenir of foreign tourist's welcome of visitor deeply now as them.
Traditional indigo wax-dyeing process generally comprises following steps: dye liquor prepare-on floral designs, wax--dyeing-dewaxing--cross glue-decatize five steps such as (or drying).Detailed process is: 1, in indigo dye liquor, add lime or batchings such as plant ash, vinasse or swill earlier, make dye liquor that the fermentation reduction take place.2, on the floral designs of fibre (cloth), wax, 3, when dyeing, cloth is put into dye liquor, soak half an hour and take out, dry, put into dye liquor then and dye again, dye so repeatedly every day three times, dye a couple of days continuously and can become blue cloth.The cloth that 4, will dye required color carried out the glue processing, and to increase fabric strength and to improve dyefastness, the glue that is adopted generally is animal glue such as gelatin, gelatine.5, the stained clot-h that will cross behind the glue is put into the pot decatize after about 20 minutes, takes out to shine (drying in the air) and do.
There is the problem of crock fastness poor (be prone to decolouring) by above traditional resulting batik and waxprinting article of vegetable indigo dyeing, had a strong impact on the quality of vegetable indigo batiks.
For improving the crock fastness (promptly improve colour fixation) of vegetable indigo on goods; The present invention has provided a plant indigo fixation new method; This method is on the traditional handicraft basis; When crossing glue, with the method for oxidation the loose colour on the stained clot-h is sloughed earlier, again with animal glue and cation quaternary ammonium salt compound as color-fixing agent to the indigo fixation treatment of carrying out.Compare with the dyeing articles that traditional handicraft obtains, better with the resulting dyeing articles colour fixation of color-fixing method provided by the invention, can keep simultaneously that dyeing articles is bright in colour, tone is graceful, good hand feeling is abundant, fragrance is pleasant and characteristics such as health care.
Summary of the invention:
The invention relates to the method for the crock fastness that improves natural plants bipseudoindoxyl dye batik and waxprinting article, is to slough loose colour through oxidation to realize with the method that adopts compound color-fixing agent fixation to combine.
The characteristic that the loose colour step is taken off in oxidation be with natural plants indigo dyeing and the fibre that dries in the alkaline solution of hydrogen peroxide solution and washing agent (neopelex or lauryl sodium sulfate etc.); After 10～30 minutes, washing is dried at 95～100 ℃ of following digestions.Hydrogen peroxide concentration (mass fraction) is 0.05～0.1%, and neopelex concentration (mass fraction) is 0.1～0.3%, pH10～12, bath raio 1: 20.
The characteristic of vegetable indigo fixation step be with the fibre after taking off loose colour with oxidation and handling in the solution of the composite color-fixing agent of forming by animal glue and polyquaternium, digestion after 10～30 minutes under 60-70 ℃ of temperature, clean drying.Animal glue concentration (mass fraction) is 1～2% in the body lotion, and polyquaternium concentration (mass fraction) is 1～3%.
Through following examples the present invention is described:
Embodiment 1 is with after 3 milliliter of 30% hydrogen peroxide solution, 1g neopelex, 1g dissolution of sodium hydroxide are in 1L water; Solution is heated near after the boiling (95～100 ℃); To put into the solution digestion with vegetable indigo dyeing and the plant fiber products that has dewaxed in 1: 20 ratio of bath raio took out after 30 minutes; Make loose colour break away from fiber surface with the clear water washing, dry.10g gelatin and 20g polyquaternium (dimethyl diallyl ammonium chloride-acrylamide copolymer) are dissolved in the 1L water, put into the plant fiber products after loose colour is taken off in oxidation, be heated to 60 ℃ of digestions after 30 minutes, the taking-up washing is also dried.The gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Embodiment 2 is with after 2 milliliter of 30% hydrogen peroxide solution, 2g lauryl sodium sulfate, 2g dissolution of sodium hydroxide are in 1L water; Solution is heated near after the boiling (95～100 ℃); To put into the solution digestion with vegetable indigo dyeing and the plant fiber products that has dewaxed in 1: 20 ratio of bath raio took out after 20 minutes; Make loose colour break away from fiber surface with the clear water washing, dry.10g gelatin and 20g polyquaternium (dimethyl diallyl ammonium chloride-acrylamide copolymer) are dissolved in the 1L water, put into the plant fiber products after loose colour is taken off in oxidation, be heated to 60 ℃ of digestions after 30 minutes, the taking-up washing is also dried.The gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Embodiment 3 is with after 2 milliliter of 30% hydrogen peroxide solution, 3g neopelex, 3g dissolution of sodium hydroxide are in 1L water; Solution is heated near after the boiling (95～100 ℃); To put into solution with vegetable indigo dyeing and the plant fiber products that has dewaxed in 1: 20 ratio of bath raio; Digestion took out after 10 minutes, made loose colour break away from fiber surface with the clear water washing, dried.10g gelatin and 20g polyquaternium (dimethyl diallyl ammonium chloride-acrylamide copolymer) are dissolved in the 1L water, put into the plant fiber products after loose colour is taken off in oxidation, be heated to 60 ℃ of digestions after 20 minutes, the taking-up washing is also dried.The gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.。
Embodiment 4 is with after 2 milliliter of 30% hydrogen peroxide solution, 3g lauryl sodium sulfate, 4g dissolution of sodium hydroxide are in 1L water; Solution is heated near after the boiling (95～100 ℃); Will be putting into the solution digestion with the vegetable indigo dyeing and the plant fiber products that dewax in 1: 20 ratio of bath raio took out after 10 minutes; Make loose colour break away from fiber surface with the clear water washing, dry.20g gelatin and 10g polyquaternium (diallyldimethylammonium chloride monomer homopolymers) are dissolved in the 1L water, put into the plant fiber products after loose colour is taken off in oxidation, be heated to 60 ℃ of digestions after 10 minutes, the taking-up washing is also dried.The gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Embodiment 5 is with after 3 milliliter of 30% hydrogen peroxide solution, 2g neopelex, 0.4g dissolution of sodium hydroxide are in 1L water; Solution is heated near after the boiling (95～100 ℃); Will be putting into the solution digestion with the vegetable indigo dyeing and the plant fiber products that dewax in 1: 20 ratio of bath raio took out after 30 minutes; Make loose colour break away from fiber surface with the clear water washing, dry.10g ox glue and 20g polyquaternium (diallyldimethylammonium chloride monomer homopolymers) are dissolved in the 1L water, put into the plant fiber products after loose colour is taken off in oxidation, be heated to 70 ℃ of digestions after 30 minutes, the taking-up washing is also dried.The gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Embodiment 6 is with after 3 milliliter of 30% hydrogen peroxide solution, 3g neopelex, 0.04g dissolution of sodium hydroxide are in 1L water; Solution is heated near after the boiling (95～100 ℃); Will be putting into the solution digestion with the vegetable indigo dyeing and the plant fiber products that dewax in 1: 20 ratio of bath raio took out after 30 minutes; Make loose colour break away from fiber surface with the clear water washing, dry.10g ox glue and 30g polyquaternium (diallyldimethylammonium chloride monomer homopolymers) are dissolved in the 1L water, put into the plant fiber products after loose colour is taken off in oxidation, be heated to 70 ℃ of digestions after 30 minutes, the taking-up washing is also dried.The gained plant fiber products keeps vegetable indigo fragrance, lovely luster, and friction is difficult for fading.
Claims (7)
1. a batik is characterized in that with the color-fixing method of natural plants bipseudoindoxyl dye: slough loose colour through the oxidation digestion earlier, adopt the method for compound color-fixing agent fixation to realize again.
2. batik as claimed in claim 1 is with the color-fixing method of natural plants bipseudoindoxyl dye; It is characterized in that: step and the technology that the oxidation digestion takes off loose colour be with natural plants indigo dyeing and the fibre that dries in the alkaline solution of hydrogen peroxide solution and washing agent (neopelex or lauryl sodium sulfate etc.); After 10～30 minutes, washing is dried at 95～100 ℃ of following digestions.
3. batik according to claim 1 is with the color-fixing method of natural plants bipseudoindoxyl dye; It is characterized in that: the characteristic of vegetable indigo fixation step be with the fibre after taking off loose colour with oxidation and handling in the solution of the composite color-fixing agent of forming by animal glue and polyquaternium; Digestion was cleaned and is dried after 10～30 minutes under 60-70 ℃ of temperature.
4. batik according to claim 2 is with the color-fixing method of natural plants bipseudoindoxyl dye; It is characterized in that: described hydrogen peroxide concentration (mass fraction) is 0.05～0.1%; Neopelex (or lauryl sodium sulfate) concentration (mass fraction) is 0.1～0.3%; PH10～12, bath raio 1: 20.
5. batik according to claim 3 is characterized in that with the color-fixing method of natural plants bipseudoindoxyl dye: animal glue concentration (mass fraction) is 1～2% in the body lotion, and polyquaternium concentration is (mass fraction) 1～3%, bath raio 1: 20.
According to claim 3 with require the color-fixing method of 5 described batiks with the natural plants bipseudoindoxyl dye, it is characterized in that: described animal glue is ox glue or gelatin.
According to claim 3 with require the color-fixing method of 5 described batiks with the natural plants bipseudoindoxyl dye; It is characterized in that: described polyquaternium is a polyquaternium cationic high-molecular polymer, like diallyldimethylammonium chloride monomer homopolymers or dimethyl diallyl ammonium chloride-acrylamide copolymer.
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104074017A (en) * | 2014-07-15 | 2014-10-01 | 太仓市虹鹰印花有限公司 | Multi-batik method |
| CN105113301A (en) * | 2015-09-08 | 2015-12-02 | 湖州宏鑫绸厂 | Novel natural animal and plant source color fixing agent as well as preparation method and color fixing process |
| CN105951482A (en) * | 2016-07-19 | 2016-09-21 | 广东德润纺织有限公司 | Fabric washing and color fixing consecutive processing technology |
| CN106283721A (en) * | 2016-07-31 | 2017-01-04 | 贵州省从江县盈茂农业科技开发有限公司 | A kind of manufacture method of the bright cloth of the Dong nationality |
| CN106366692A (en) * | 2016-08-30 | 2017-02-01 | 杭州吴越人家工艺服饰有限公司 | Manufacturing process for indigo dye and blue-dyed printed fabric |
| CN107245890A (en) * | 2017-08-07 | 2017-10-13 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | The batik method and batik burlap of burlap |
| CN107268297A (en) * | 2017-08-07 | 2017-10-20 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | The batik method and batik cotton of cotton |
| CN108486913A (en) * | 2018-04-24 | 2018-09-04 | 无锡职业技术学院 | A kind of gorgeous degree and color fixing process improving indigo batik |
| CN108505370A (en) * | 2018-04-24 | 2018-09-07 | 无锡职业技术学院 | A kind of color fixing process of indigo batik |
| CN108716137A (en) * | 2018-05-07 | 2018-10-30 | 贵州西江阿幼民族文化博物馆有限公司 | A kind of color forming method of batik bipseudoindoxyl dye |
| CN108841010A (en) * | 2018-06-06 | 2018-11-20 | 常州纺织服装职业技术学院 | A kind of preparation method and applications of gelatin iron chelate |
| CN109457517A (en) * | 2018-10-29 | 2019-03-12 | 嘉兴珠韵服装有限公司 | The preparation of modified gelatin/cation-modified anorthite compound color fixing agent and the application in acid dyeing |
| CN110306358A (en) * | 2019-08-08 | 2019-10-08 | 苏州虹锦生态纺织科技有限公司 | A kind of processing method of real silk fabric natural dye dying |
| CN112252056A (en) * | 2020-10-22 | 2021-01-22 | 安顺市西秀区星月苗族蜡染工艺品有限公司 | Wax printing color fixing method for vegetable natural dye |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104074017A (en) * | 2014-07-15 | 2014-10-01 | 太仓市虹鹰印花有限公司 | Multi-batik method |
| CN105113301A (en) * | 2015-09-08 | 2015-12-02 | 湖州宏鑫绸厂 | Novel natural animal and plant source color fixing agent as well as preparation method and color fixing process |
| CN105113301B (en) * | 2015-09-08 | 2017-09-29 | 广东名斯度服饰有限公司 | A kind of natural animal-plant source color fixing agent and preparation method thereof and color fixing process |
| CN105951482A (en) * | 2016-07-19 | 2016-09-21 | 广东德润纺织有限公司 | Fabric washing and color fixing consecutive processing technology |
| CN106283721A (en) * | 2016-07-31 | 2017-01-04 | 贵州省从江县盈茂农业科技开发有限公司 | A kind of manufacture method of the bright cloth of the Dong nationality |
| CN106366692A (en) * | 2016-08-30 | 2017-02-01 | 杭州吴越人家工艺服饰有限公司 | Manufacturing process for indigo dye and blue-dyed printed fabric |
| CN107268297B (en) * | 2017-08-07 | 2020-01-10 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | Wax printing method for cotton cloth and wax printed cotton cloth |
| CN107245890A (en) * | 2017-08-07 | 2017-10-13 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | The batik method and batik burlap of burlap |
| CN107268297A (en) * | 2017-08-07 | 2017-10-20 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | The batik method and batik cotton of cotton |
| CN108486913A (en) * | 2018-04-24 | 2018-09-04 | 无锡职业技术学院 | A kind of gorgeous degree and color fixing process improving indigo batik |
| CN108505370A (en) * | 2018-04-24 | 2018-09-07 | 无锡职业技术学院 | A kind of color fixing process of indigo batik |
| CN108716137A (en) * | 2018-05-07 | 2018-10-30 | 贵州西江阿幼民族文化博物馆有限公司 | A kind of color forming method of batik bipseudoindoxyl dye |
| CN108841010A (en) * | 2018-06-06 | 2018-11-20 | 常州纺织服装职业技术学院 | A kind of preparation method and applications of gelatin iron chelate |
| CN109457517A (en) * | 2018-10-29 | 2019-03-12 | 嘉兴珠韵服装有限公司 | The preparation of modified gelatin/cation-modified anorthite compound color fixing agent and the application in acid dyeing |
| CN110306358A (en) * | 2019-08-08 | 2019-10-08 | 苏州虹锦生态纺织科技有限公司 | A kind of processing method of real silk fabric natural dye dying |
| CN110306358B (en) * | 2019-08-08 | 2021-11-23 | 苏州虹锦生态纺织科技有限公司 | Processing method for dyeing real silk fabric by natural dye |
| CN112252056A (en) * | 2020-10-22 | 2021-01-22 | 安顺市西秀区星月苗族蜡染工艺品有限公司 | Wax printing color fixing method for vegetable natural dye |
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