CN102702780A - Method for preventing fading of monascus red pigment and application thereof - Google Patents

Method for preventing fading of monascus red pigment and application thereof Download PDF

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Publication number
CN102702780A
CN102702780A CN2012100158637A CN201210015863A CN102702780A CN 102702780 A CN102702780 A CN 102702780A CN 2012100158637 A CN2012100158637 A CN 2012100158637A CN 201210015863 A CN201210015863 A CN 201210015863A CN 102702780 A CN102702780 A CN 102702780A
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monascorubin
amino acid
fading
red pigment
solution
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郑慧英
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TIANKANGYUAN BIOLOGICAL TECHNOLOGY Co Ltd TIANJIN
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TIANKANGYUAN BIOLOGICAL TECHNOLOGY Co Ltd TIANJIN
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Abstract

The invention provides a practical method for preventing the fading of monascus red pigment, and a method for dyeing food, cosmetics and medicines by use of monascus red pigment with an excellent anti-fading effect. The method for preventing the fading of monascus red pigment is characterized in that: the monascus red pigment is dissolved in 0.1% solution of tryptophan, histidine, tyrosine or methionine to prevent the fading of monascus red pigment. The monascus red pigment is dissolved in 0.1% solution of tryptophan, histidine, tyrosine or methionine to form a monascus red pigment-amino acid preparation. The method provided by the invention can effectively prevent the fading of the monascus red pigment caused by illumination; and meanwhile, since the amino acid solution is used for preventing the fading of monascus red pigment, the monascus red pigment-amino acid preparation is very safe to a human body.

Description

Prevent method and application that monascorubin fades
Technical field
The present invention relates to food, makeup or medicine dyeing field, more particularly, relate to the method and the application that prevent that monascorubin from fading.
Background technology
People appeal the security of food, pharmaceuticals, makeup and feed, reduce the use of the synthetic coloring matter that contains carinogenicity, teratogenecity gradually, and hope can be made safe pigment with additive method.Wherein, monascorubin enjoys and gazes at and be widely used.
Because monascorubin can be produced by illumination effect and fades and metachromatism, the value of commodity is obviously descended, so prevent that monascorubin from fading and variable color becomes important problem.
As everyone knows, prevent the method that monascorubin fades: monascorubin is dissolved in butanols, the ethanol.But monascorubin is used in the aqueous goods more, so this method is impracticable.Other method has adds the method for monascorubin such as tea extract, coffee extract, mountain peach extract, sesamol, vitamin C to or stablizes the method for monascorubin with chitosan, but aforesaid method is all undesirable.
Summary of the invention
The purpose of this invention is to provide the practical method that monascorubin fades that prevents; The monascorubin superior with fade-proof effect carries out painted method to food, makeup, medicine; Simultaneously, monascorubin-amino acid preparation is provided.
The present invention prevents the method that monascorubin fades, and it is characterized in that, monascorubin is dissolved in the solution of 0.1% tryptophane, Histidine, tyrosine or methionine(Met), prevents that monascorubin from fading.Monascorubin is dissolved in the solution of 0.1% tryptophane, Histidine, tyrosine or methionine(Met), forms monascorubin-amino acid preparation.
A kind of application that prevents the method that monascorubin fades is dissolved in monascorubin in the solution of 0.1% tryptophane, Histidine, tyrosine or methionine(Met), with this mixed solution food, makeup or medicine is dyeed.
A kind of application that prevents the method that monascorubin fades on painted food, makeup or medicine with monascorubin, is smeared the solution of 0.1% tryptophane, Histidine, tyrosine or methionine(Met).
Method of the present invention can prevent effectively that monascorubin from fading because of what illumination caused, simultaneously, because use amino acid solution to prevent fading of monascorubin, so human body is had very high security.
Embodiment
Below in conjunction with being done, the present invention further describes.
In the present invention, through letting monascorubin be dissolved in 0.1% amino acid solution, can prevent that monascorubin from fading because of what illumination caused.The monascorubin look valency that uses in the present invention is E10%=10~200 normally, comparatively it is desirable to 10~100, and even more ideal is 40~60.
The amino acid that uses among the present invention is tryptophane, Histidine, tyrosine or methionine(Met).These amino acid can use separately, also can two or morely use together.
Its amino acid whose concentration of amino acid solution of dissolving monascorubin is greater than 0.1%.Monascorubin and mix greater than 0.1% amino acid solution forms monascorubin-amino acid preparation, and photostabilization is good.If amino acid whose concentration is lower than 0.1%, photostabilization is poor.So amino acid whose concentration is greater than 0.1% in the amino acid solution, ideal concentration is greater than 0.3%.Amino acid whose concentration is preferably less than 3% normally less than 5%.
Amino acid solution is amino acid solution normally, still according to the difference of monascorubin dyeing object, also can use water-soluble solvents such as alcohols such as methyl alcohol, ethanol, USP Kosher.Food is being used amino acid solution painted the time.
In the amino acid solution of dissolving monascorubin, monascorubin and amino acid whose weight ratio be monascorubin (E10%=60) normally: amino acid=1: 0.001~1: 1000, preferably 1: 0.01~1: 100.
The painted method of monascorubin of the present invention.Specifically: let monascorubin be dissolved in, food, makeup or medicine are dyeed with this solution greater than in 0.1% the amino acid solution.In order to let monascorubin be dissolved in the amino acid, general stirring and dissolving at room temperature.With above-mentioned solution food is dyeed.
Dyeing to as if solid or when semi-solid, dyeing process is to smear, spray, flood the method for smearing with hairbrush.The method of preferably using dipping to smear because the amino acid solution of monascorubin has superior photostabilization, can be modulated tank solution in advance, and this solution can life-time service, so very convenient on dyeing procedure.Smearing with monascorubin in the solution and amino acid whose weight ratio generally is monascorubin (E10%=60): amino acid=1: 0.05~1: 3, it is desirable to 1: 0.05~1: 2, and ideal is 1: 0.07~1: 1.
Above-mentioned dyeing process is applicable to solid or semisolid various food.For example: processing of aquatic products classes such as fish ham, fish sausage, breaded fish stick, breaded fish stick; Poultry such as ham, bacon, jerky meat product class; Cake classes such as rice cake, crisp biscuit, swelled candy rice, steamed stuffed bun, candy, jelly; Pickles class such as assorted eight-treasure pickles; Jam etc.In addition, present method also can be used for solid or semisolid various medicine, makeup.Good with the painted food photostabilization of present method.It is painted that this dyeing process preferably is applied to solid.
Describe with embodiment below, but the present invention does not receive the restriction of embodiment.
Embodiment 1 with monascorubin (E10%=60) with 200 times of 1% tryptophane solution dilutions.Get 7ml and put into the glass sample bottle.Sample bottle is placed on the indoor preservation 6 days of opening luminescent lamp.Make reference substance, try to achieve the survival rate of monascorubin by following formula.The result is as shown in table 1.
Formula: monascorubin survival rate (%)=(absorbancy that the absorbancy/of the 500nm of irradiation article is shone the 500nm of article) * 100%
Embodiment 2~5 comparative examples 1~3, except with the 1% tryptophane aqueous solution of the aminoacid replacement in the table 1, other use is tried to achieve survival rate with embodiment 1 identical method.The result is as shown in table 1.
[table 1]
Figure BDA0000131788120000031
The embodiment 6 usefulness 1% tryptophane aqueous solution is with 10 times of monascorubin dilutions; Get the glass sample bottle that 1ml puts into 10ml, the bottle sample is placed on the indoor preservation 7 days of luminescent lamp, relatively irradiation article; With the embodiment 1 the same monascorubin survival rate of trying to achieve, the result is as shown in table 2.
Embodiment 7, comparative example 4 use with embodiment 6 same methods and try to achieve survival rate except replacing with the amino acid solution in the table 2 the 1% tryptophane aqueous solution.The result is as shown in table 2.
[table 2]
Figure BDA0000131788120000032
Embodiment 8 modulation are diluted 10 times solution with 1% tryptophane with monascorubin (E10%=60), minced fish are carried out 10 minutes dip dyeing with above-mentioned solution.The flesh of fish after the dyeing is put into tray the indoor preservation of opening luminescent lamp 3 days, observe its fading extent.Find that it is not obvious to fade.
Comparative example 4 is used distilled water diluting, and other are the same with embodiment 8 operations.The result finds: fade obviously, the flesh of fish almost becomes white.
Monascorubin is the material of the microorganisms of monascus, and its substratum and cultural method also have a lot.No matter but the monascorubin which kind of method is produced all is applicable to the present invention.
Embodiment recited above describes the preferred embodiment for the present invention; Be not that design of the present invention and scope are limited; Under the prerequisite that does not break away from design philosophy of the present invention; Common engineering technical personnel make technical scheme of the present invention in this area various distortion and improvement all should belong to protection scope of the present invention.

Claims (7)

1. a method that prevents that monascorubin from fading is characterized in that, monascorubin is dissolved in the solution of tryptophane, Histidine, tyrosine or the methionine(Met) of 0.1-5%, prevents that monascorubin from fading.
2. the method that prevents that monascorubin from fading according to claim 1 is characterized in that, monascorubin and amino acid whose weight ratio are monascorubins: amino acid=1: 0.001~1: 1000.
3. the method that prevents that monascorubin from fading according to claim 2 is characterized in that, monascorubin and amino acid whose weight ratio are monascorubins: amino acid=preferably 1: 0.01~1: 100.
4. the method that prevents that monascorubin from fading according to claim 1 is characterized in that, monascorubin look valency is E10%=10~200 normally.
5. the method that prevents that monascorubin from fading according to claim 1 is characterized in that, monascorubin is dissolved in the solution of 0.1% tryptophane, Histidine, tyrosine or methionine(Met), forms monascorubin-amino acid preparation.
6. an application that prevents the method that monascorubin fades is characterized in that, monascorubin is dissolved in the solution of 0.1-5% tryptophane, Histidine, tyrosine or methionine(Met), with this mixed solution food, makeup or medicine is dyeed.
7. an application that prevents the method that monascorubin fades is characterized in that, on painted food, makeup or medicine with monascorubin, smears the solution of 0.1-5% tryptophane, Histidine, tyrosine or methionine(Met).
CN2012100158637A 2012-01-18 2012-01-18 Method for preventing fading of monascus red pigment and application thereof Pending CN102702780A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103849653A (en) * 2014-03-27 2014-06-11 广州大正新材料科技有限公司 Preparation method of citrinin-free high-color value red konjic rice powder
CN105199426A (en) * 2015-10-30 2015-12-30 湖南农业大学 Method for extracting purple sweet potato pigments with natural amino acid phosphate aqueous solution
CN105695512A (en) * 2016-04-07 2016-06-22 常州思宇环保材料科技有限公司 Preparation method of monascus red pigment
CN109699888A (en) * 2018-12-28 2019-05-03 武汉轻工大学 A kind of high stability albumen-monascorubin compound and preparation method thereof
WO2024022771A1 (en) 2022-07-29 2024-02-01 Givaudan Sa Composition comprising a polyketide pigment

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003000191A (en) * 2001-06-25 2003-01-07 Yaegaki Hakko Giken Kk Method for preventing photofading of monascus color
KR20060033176A (en) * 2004-10-14 2006-04-19 학교법인연세대학교 Monascus pigment possessing lipase inhibiting activity
CN101161731A (en) * 2006-10-10 2008-04-16 福建农林大学 Method for preparing highly-dissolvable water-soluble monascus pigment
CN102433019A (en) * 2011-11-17 2012-05-02 江门科隆生物技术股份有限公司 Monascus red pigment preparing method capable of improving light stability and heat stability of monascus red pigment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003000191A (en) * 2001-06-25 2003-01-07 Yaegaki Hakko Giken Kk Method for preventing photofading of monascus color
KR20060033176A (en) * 2004-10-14 2006-04-19 학교법인연세대학교 Monascus pigment possessing lipase inhibiting activity
CN101161731A (en) * 2006-10-10 2008-04-16 福建农林大学 Method for preparing highly-dissolvable water-soluble monascus pigment
CN102433019A (en) * 2011-11-17 2012-05-02 江门科隆生物技术股份有限公司 Monascus red pigment preparing method capable of improving light stability and heat stability of monascus red pigment

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103849653A (en) * 2014-03-27 2014-06-11 广州大正新材料科技有限公司 Preparation method of citrinin-free high-color value red konjic rice powder
CN105199426A (en) * 2015-10-30 2015-12-30 湖南农业大学 Method for extracting purple sweet potato pigments with natural amino acid phosphate aqueous solution
CN105199426B (en) * 2015-10-30 2017-08-25 湖南农业大学 A kind of method that utilization natural amino acid aqueous phosphatic extracts purple potato pigment
CN105695512A (en) * 2016-04-07 2016-06-22 常州思宇环保材料科技有限公司 Preparation method of monascus red pigment
CN109699888A (en) * 2018-12-28 2019-05-03 武汉轻工大学 A kind of high stability albumen-monascorubin compound and preparation method thereof
WO2024022771A1 (en) 2022-07-29 2024-02-01 Givaudan Sa Composition comprising a polyketide pigment

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Application publication date: 20121003