CN102702340A - Feather fibrin and preparation method thereof - Google Patents
Feather fibrin and preparation method thereof Download PDFInfo
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- CN102702340A CN102702340A CN2012101545425A CN201210154542A CN102702340A CN 102702340 A CN102702340 A CN 102702340A CN 2012101545425 A CN2012101545425 A CN 2012101545425A CN 201210154542 A CN201210154542 A CN 201210154542A CN 102702340 A CN102702340 A CN 102702340A
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Abstract
The invention discloses a feather fibrin and a preparation method thereof. The preparation method comprises the following steps: cleaning and sterilizing feather with hydrogen peroxide or zone, adding oxidant for oxidation, and heating for 1-3 hours to 80-120 DEG C; dissolving with alkali for 0.5-4 hours, adjusting the pH to 12-14; precipitating with acid for 0.5-4 hours and adjusting the pH to 1-3; filtering 1-3 times, washing the precipitate 1-3 times after filtering, and then drying to obtain the feather fibrin product. The feather fibrin cannot be dissolved in water or acid, but can be dissolved in alkali; and in the fibrin, the protein contain is 65-80 percent by weight, and the fat content is no more than 1 percent by weight.
Description
Technical field
The present invention relates to a kind of scleroproein and method of manufacture thereof, be specifically related to a kind of feather fiber albumen and method of manufacture thereof.
Background technology
Fiber is divided into man-made fiber and thiozell.Man-made fiber is to utilize the petroleum synthetic, and cost is very high.Thiozell is the fiber that utilizes the albumen synthetic of animal and plant raw material extraction.Thiozell has milk protein fibre, soybean fiber, pupa albumen fiber, feather protein fiber.But milk protein fibre, soybean fiber, pupa albumen fibrous material price height, it is low to extract the scleroproein amount, and general 100 kilograms can only be extracted 2 kilograms of scleroproeins; And 100 kilograms of feathers can extract 10 kilograms of scleroproeins.Other fibrinous raw material sources are limited, and receive seasonal effect; The feather raw material sources are extensive.The lipid content of other scleroproein raw material is high, influence the quality of thiozell; At the bottom of the feather lipid content, do not influence the quality of thiozell.
One of country that China is herding in the world, poultry farming is maximum; The feather resource is extremely abundant; Especially in modern times in the agricultural, large-scale poultry farming has produced a large amount of feather refuses, and this is a rich in protein resource; Development and use to these waste feathers can not only reduce environmental pollution, also can produce economic benefit and social benefit simultaneously.
Summary of the invention
The objective of the invention is to solve the defective of above-mentioned prior art, a kind of price is low, the protein content amount is high relatively scleroproein and method of manufacture thereof are provided.
For solving above-mentioned technical problem, the present invention adopts following technical scheme:
Feather fiber albumen; Water insoluble; Be insoluble to acid; Can be dissolved in alkali; Lipid content massfraction≤1% in the feather fiber albumen; The protein content massfraction is 65%-80% in the scleroproein, and various amino acid whose massfractions are in the albumen: aspartic acid 5%-6.5%, Threonine 2.5%-4%, Serine 7.5%-8.5%, L-glutamic acid 8.5%-10%, glycocoll 5%-6.5%, L-Ala 3%-4%, Gelucystine 0.2%-0.7%, Xie Ansuan 4.5%-5.5%, methionine(Met) 0.05%-0.15%, Isoleucine 2%-3.5%, leucine 3.5%-5.5%, phenylalanine(Phe) 2.2%-3%, Methionin 0.2%-0.7%, Histidine 0.02%-0.1%, l-arginine 3%-4%, proline(Pro) 5.5%-6.5%.
Feather fiber albumen, said feather comprises: one or more in drake feather, goose feather, chicken feather, pig hair, wool, the horsehair.
Feather fiber albumen, the protein content massfraction is 75% in the said scleroproein.
The proteic method of manufacture of feather fiber comprises: feather is cleaned virus killing, then heated oxide; Add alkali then and dissolve, add acid then and precipitate, filter again; Throw out is washed after drying; Obtain the feather fiber protein product, said cleaning virus killing is to use ydrogen peroxide 50 or ozone that feather was soaked 1 hour, and keeping temperature is the 10-30 degree; Oxygenant in the heated oxide is a kind of in nitric acid, sulfuric acid, Youxiaolin, potassium permanganate, ozone, Peracetic Acid, SRM 935a, the chlorine, and Heating temperature is the 80-120 degree, and be 1-3 hour heat-up time; Adding the alkali of alkali in dissolving is sodium hydroxide, Pottasium Hydroxide, and pH value scope is 12-14, dissolution time 0.5-4 hour; Add the acid of acid in precipitating and be a kind of in sulfuric acid, nitric acid, the hydrochloric acid, pH value scope is 1-3, time 0.5-4 hour.
The proteic method of manufacture of feather fiber, the temperature of said cleaning virus killing are 25 degree; The massfraction of the nitric acid in the said heated oxide, the vitriol oil, Youxiaolin, potassium permanganate, ozone, Peracetic Acid, SRM 935a is 10-50%; Saidly add the sodium hydroxide of alkali in dissolving, the massfraction of Pottasium Hydroxide is 10-60%; The said massfraction that adds the sulfuric acid of acid in precipitating, nitric acid, hydrochloric acid is 10-40%.
The proteic method of manufacture of feather fiber, the massfraction of the nitric acid in the said heated oxide, the vitriol oil, Youxiaolin, potassium permanganate, ozone, Peracetic Acid, SRM 935a are 30%; Saidly add the sodium hydroxide of alkali in dissolving, the massfraction of Pottasium Hydroxide is 40%; The said massfraction that adds the sulfuric acid of acid in precipitating, nitric acid, hydrochloric acid is 30%; Heating temperature in the said heated oxide is 100 degree.
The proteic method of manufacture of feather fiber saidly adds alkali to carry out the dissolved dissolution time is 3 hours; Saidly add acid to carry out the sedimentary time be 3 hours.
The proteic method of manufacture of feather fiber, said filtration number of times is 1-3 time, and washing times is 1-3 time, and washing composition is pure water or soft water.
The proteic method of manufacture of feather fiber, be 5-30 hour said time of drying, temperature 80-120 degree.
The proteic method of manufacture of feather fiber is characterized in that be 20 hours said time of drying, and temperature is 100 degree.
Advantage of the present invention:
1, product feather fiber albumen of the present invention utilizes feather etc. can not spin protein fibre to process, and raw material sources are extensive, and utilized some scrap feed material, help environment protection.
2, formulating of recipe is reasonable, has reduced concentration, consumption and the action time of chemical reagent, prevents chemical reagent to the excessive dissolution of feather and be unfavorable for the carrying out of spinning, thereby reaches energy-saving and environmental protection, purpose efficiently.
3, the textile touch of utilizing feather fiber albumen to process is abundant, and excellent property, price are lower than similar lining, have the bigger market competitiveness.
Embodiment
According to one embodiment of present invention, a certain amount of drake feather is put into cleaning equipment, add ydrogen peroxide 50, regulating water temperature is 10 degree, opens equipment washing 1 hour, then with the washing lotion filtering, uses flushing with clean water 3-5 minute again, and the filtering washing lotion is collected drake feather.Then drake feather is put into equipment, add massfraction and be 10% nitric acid, regulating water temperature is 80 degree, and be 1 hour heat-up time, treat the feather dissolving after, add massfraction again and be 10% sodium hydroxide solution, regulating the pH value is 12, dissolution time 0.5 hour.Add massfraction then and be 10% sulfuric acid, regulating the pH value is 1, dissolution time 0.5 hour; Filter 1 time then and obtain throw out, with pure water with throw out washing 1 time, with the drying precipitate of cleaning 5 hours; Drying temperature is 80 degree, obtains feather fiber albumen.Its main performance index is: feather fiber albumen is water insoluble; Be insoluble to acid; Can be dissolved in alkali; Lipid content massfraction 0.8% in the feather fiber albumen; The protein content massfraction is 65% in the scleroproein, and various amino acid whose massfractions are in the albumen: aspartic acid 5%, Threonine 2.5%, Serine 7.5%, L-glutamic acid 8.5%, glycocoll 5%, L-Ala 3%, Gelucystine 0.2%, Xie Ansuan 4.5%, methionine(Met) 0.05%, Isoleucine 2%, leucine 3.5%, phenylalanine(Phe) 2.2%, Methionin 0.2%, Histidine 0.02%, l-arginine 3%, proline(Pro) 5.5%.
According to one embodiment of present invention, a certain amount of wool is put into cleaning equipment, add ydrogen peroxide 50, regulating water temperature is 30 degree, opens equipment washing 1 hour, then with the washing lotion filtering, uses flushing with clean water 3-5 minute again, and the filtering washing lotion is collected wool.Then wool is put into equipment, add massfraction and be 40% sulfuric acid, regulating water temperature is 120 degree, and be 3 hours heat-up time, treat the feather dissolving after, add massfraction again and be 60% potassium hydroxide solution, regulating the pH value is 14, dissolution time 4 hours.Add massfraction then and be 40% nitric acid, regulating the pH value is 3, dissolution time 4 hours; Filter 2 times then and obtain throw out, with pure water with throw out washing 2 times, with the drying precipitate of cleaning 30 hours; Drying temperature is 120 degree, obtains feather fiber albumen.Its main performance index is: feather fiber albumen is water insoluble; Be insoluble to acid; Can be dissolved in alkali; Lipid content massfraction 0.9% in the feather fiber albumen; The protein content massfraction is 80% in the scleroproein, and various amino acid whose massfractions are in the albumen: aspartic acid 6.5%, Threonine 4%, Serine 8.5%, L-glutamic acid 10%, glycocoll 6.5%, L-Ala 4%, Gelucystine 0.7%, Xie Ansuan 5.5%, methionine(Met) 0.15%, Isoleucine 3.5%, leucine 5.5%, phenylalanine-3,4-quinone %, Methionin 0.7%, Histidine 0.1%, l-arginine 4%, proline(Pro) 6.5%.
According to one embodiment of present invention, a certain amount of goose feather is put into cleaning equipment, add ozone, regulating water temperature is 25 degree, opens equipment washing 1 hour, then with the washing lotion filtering, uses flushing with clean water 3-5 minute again, and the filtering washing lotion is collected goose feather.Then goose feather is put into equipment, add massfraction and be 40% nitric acid, regulating water temperature is 100 degree, and be 2 hours heat-up time, treat the feather dissolving after, add solid sodium hydroxide again, regulating the pH value is 13, dissolution time 2 hours.Add massfraction then and be 30% sulfuric acid, regulating the pH value is 2, dissolution time 2 hours; Carry out filter 23 then and time obtain throw out, with pure water with throw out washing 3 times, with the drying precipitate of cleaning 20 hours; Drying temperature is 100 degree, obtains feather fiber albumen.Its main performance index is: feather fiber albumen is water insoluble; Be insoluble to acid; Can be dissolved in alkali; Lipid content massfraction 0.75% in the feather fiber albumen; The protein content massfraction is 77% in the scleroproein, and various amino acid whose massfractions are in the albumen: aspartic acid 5.79%, Threonine 3.36%, Serine 7.15%, L-glutamic acid 8.68%, glycocoll 5.05%, L-Ala 3.83%, Gelucystine 0.59%, Xie Ansuan 5.18%, methionine(Met) 0.21%, Isoleucine 2.83%, leucine 4.8%, phenylalanine-3,4-quinone .01%, Methionin 0.55%, Histidine 0.09%, l-arginine 3.78%, proline(Pro) 6.12%.
According to one embodiment of present invention, a certain amount of chicken feather is put into cleaning equipment, add ozone, regulating water temperature is 25 degree, opens equipment washing 1 hour, then with the washing lotion filtering, uses flushing with clean water 3-5 minute again, and the filtering washing lotion is collected chicken feather.Then chicken feather is put into equipment, add massfraction and be 40% nitric acid, regulating water temperature is 100 degree, and be 2 hours heat-up time, treat the feather dissolving after, add massfraction again and be 40% sodium hydroxide solution, regulating the pH value is 13, dissolution time 2 hours.Add massfraction then and be 30% sulfuric acid, regulating the pH value is 2, dissolution time 2 hours; Carry out filter 23 then and time obtain throw out, with pure water with throw out washing 3 times, with the drying precipitate of cleaning 20 hours; Drying temperature is 100 degree, obtains feather fiber albumen.Its main performance index is: feather fiber albumen is water insoluble; Be insoluble to acid; Can be dissolved in alkali; Lipid content massfraction 0.85% in the feather fiber albumen; The protein content massfraction is 75% in the scleroproein, and various amino acid whose massfractions are in the albumen: aspartic acid 5.99%, Threonine 3.26%, Serine 8.15%, L-glutamic acid 9.68%, glycocoll 5.85%, L-Ala 3.43%, Gelucystine 0.49%, Xie Ansuan 5.08%, methionine(Met) 0.11%, Isoleucine 2.93%, leucine 4.9%, phenylalanine(Phe) 2.41%, Methionin 0.45%, Histidine 0.06%, l-arginine 3.68%, proline(Pro) 6.02%.
Claims (10)
1. feather fiber albumen; It is characterized in that; Said feather fiber albumen is water insoluble; Be insoluble to acid; Can be dissolved in alkali; Lipid content massfraction≤1% in the feather fiber albumen, the protein content massfraction is 65%-80% in the scleroproein, various amino acid whose massfractions are in the albumen: aspartic acid 5%-6.5%, Threonine 2.5%-4%, Serine 7.5%-8.5%, L-glutamic acid 8.5%-10%, glycocoll 5%-6.5%, L-Ala 3%-4%, Gelucystine 0.2%-0.7%, Xie Ansuan 4.5%-5.5%, methionine(Met) 0.05%-0.15%, Isoleucine 2%-3.5%, leucine 3.5%-5.5%, phenylalanine(Phe) 2.2%-3%, Methionin 0.2%-0.7%, Histidine 0.02%-0.1%, l-arginine 3%-4%, proline(Pro) 5.5%-6.5%.
2. feather fiber albumen according to claim 1 is characterized in that said feather comprises: one or more in drake feather, goose feather, chicken feather, pig hair, wool, the horsehair.
3. feather fiber albumen according to claim 1 is characterized in that the protein content massfraction is 75% in the said scleroproein.
4. the proteic method of manufacture of feather fiber, comprising: feather is cleaned virus killing, and heated oxide adds alkali then and dissolves then; Add acid then and precipitate, filter again, throw out is washed after drying; Obtain the feather fiber protein product, it is characterized in that
Said cleaning virus killing is to use ydrogen peroxide 50 or ozone that feather was soaked 1 hour, and keeping temperature is the 10-30 degree;
Oxygenant in the heated oxide is a kind of in nitric acid, sulfuric acid, Youxiaolin, potassium permanganate, ozone, Peracetic Acid, SRM 935a, the chlorine, and Heating temperature is the 80-120 degree, and be 1-3 hour heat-up time;
Add the alkali of alkali in dissolving and be in solid sodium hydroxide, solid potassium hydroxide, sodium hydroxide solution, the potassium hydroxide solution any one, pH value scope is 12-14, dissolution time 0.5-4 hour;
Add the acid of acid in precipitating and be a kind of in sulfuric acid, nitric acid, the hydrochloric acid, pH value scope is 1-3, time 0.5-4 hour.
5. according to the proteic method of manufacture of the said feather fiber of claim 4, it is characterized in that,
The temperature of said cleaning virus killing is 25 degree;
The massfraction of the nitric acid in the said heated oxide, the vitriol oil, Youxiaolin, potassium permanganate, ozone, Peracetic Acid, SRM 935a is 10-50%;
Saidly add the sodium hydroxide solution of alkali in dissolving, the massfraction of potassium hydroxide solution is 10-60%;
The said massfraction that adds the sulfuric acid of acid in precipitating, nitric acid, hydrochloric acid is 10-40%.
6. according to the proteic method of manufacture of the said feather fiber of claim 5, it is characterized in that,
The massfraction of the nitric acid in the said heated oxide, the vitriol oil, Youxiaolin, potassium permanganate, ozone, Peracetic Acid, SRM 935a is 30%;
Saidly add the sodium hydroxide solution of alkali in dissolving, the massfraction of potassium hydroxide solution is 40%;
The said massfraction that adds the sulfuric acid of acid in precipitating, nitric acid, hydrochloric acid is 30%;
Heating temperature in the said heated oxide is 100 degree.
7. according to the proteic method of manufacture of the said feather fiber of claim 4, it is characterized in that,
Saidly add alkali to carry out the dissolved dissolution time be 3 hours;
Saidly add acid to carry out the sedimentary time be 3 hours.
8. according to the proteic method of manufacture of the said feather fiber of claim 4, it is characterized in that said filtration number of times is 1-3 time, washing times is 1-3 time, and washing composition is pure water or soft water.
9. according to the proteic method of manufacture of the said feather fiber of claim 4, it is characterized in that be 5-30 hour said time of drying, temperature 80-120 degree.
10. according to the proteic method of manufacture of the said feather fiber of claim 9, it is characterized in that be 20 hours said time of drying, temperature is 100 degree.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101545425A CN102702340A (en) | 2012-05-18 | 2012-05-18 | Feather fibrin and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101545425A CN102702340A (en) | 2012-05-18 | 2012-05-18 | Feather fibrin and preparation method thereof |
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| CN102702340A true CN102702340A (en) | 2012-10-03 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105887213A (en) * | 2016-05-05 | 2016-08-24 | 安徽工程大学 | Preparation method and application of osier chicken feather fiber |
| CN108059488A (en) * | 2018-01-19 | 2018-05-22 | 周丽华 | A kind of organic fertilizer preparation method based on livestock and poultry hair discarded object |
| CN112127033A (en) * | 2020-09-24 | 2020-12-25 | 兰州三毛实业有限公司 | Production and processing method of wool containing grass thorn and coarse-cavity structure |
| CN112547754A (en) * | 2020-11-05 | 2021-03-26 | 江苏景泰石油化工装备有限公司 | Control method and system of waste treatment system, readable storage medium and programmable controller |
-
2012
- 2012-05-18 CN CN2012101545425A patent/CN102702340A/en active Pending
Non-Patent Citations (2)
| Title |
|---|
| 周彬，王慧玲: "再生羽毛蛋白纤维的研制", 《化纤与纺织技术》 * |
| 胡新华: "羽毛蛋白的提取研究", 《皮革科学与工程》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105887213A (en) * | 2016-05-05 | 2016-08-24 | 安徽工程大学 | Preparation method and application of osier chicken feather fiber |
| CN108059488A (en) * | 2018-01-19 | 2018-05-22 | 周丽华 | A kind of organic fertilizer preparation method based on livestock and poultry hair discarded object |
| CN112127033A (en) * | 2020-09-24 | 2020-12-25 | 兰州三毛实业有限公司 | Production and processing method of wool containing grass thorn and coarse-cavity structure |
| CN112547754A (en) * | 2020-11-05 | 2021-03-26 | 江苏景泰石油化工装备有限公司 | Control method and system of waste treatment system, readable storage medium and programmable controller |
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Application publication date: 20121003 |