CN102686562B - 用发酵过程得到的6-氨基己酸来制备己内酰胺 - Google Patents

用发酵过程得到的6-氨基己酸来制备己内酰胺 Download PDF

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Publication number
CN102686562B
CN102686562B CN201080059413.7A CN201080059413A CN102686562B CN 102686562 B CN102686562 B CN 102686562B CN 201080059413 A CN201080059413 A CN 201080059413A CN 102686562 B CN102686562 B CN 102686562B
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CN
China
Prior art keywords
caprolactam
aminocaproic acid
less
aca
cyclization
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CN201080059413.7A
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English (en)
Chinese (zh)
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CN102686562A (zh
Inventor
鲁道夫·菲利普斯·玛丽亚·古伊特
托马斯·万德杜斯
罗拉纳·麦德勒尼·拉姆斯多克
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Genomatica Inc
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DSM IP Assets BV
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Publication date
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Priority to CN201410284066.8A priority Critical patent/CN104177282B/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/16—Separation or purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C07D223/10—Oxygen atoms attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Polyamides (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
CN201080059413.7A 2009-12-22 2010-12-22 用发酵过程得到的6-氨基己酸来制备己内酰胺 Active CN102686562B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410284066.8A CN104177282B (zh) 2009-12-22 2010-12-22 用发酵过程得到的6‑氨基己酸来制备己内酰胺

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09180383 2009-12-22
EP09180383.3 2009-12-22
PCT/NL2010/050878 WO2011078668A1 (en) 2009-12-22 2010-12-22 The preparation of caprolactam from 6-amino caproic acid obtained in a fermentation process

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201410284066.8A Division CN104177282B (zh) 2009-12-22 2010-12-22 用发酵过程得到的6‑氨基己酸来制备己内酰胺

Publications (2)

Publication Number Publication Date
CN102686562A CN102686562A (zh) 2012-09-19
CN102686562B true CN102686562B (zh) 2014-07-16

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CN201080059413.7A Active CN102686562B (zh) 2009-12-22 2010-12-22 用发酵过程得到的6-氨基己酸来制备己内酰胺
CN201410284066.8A Active CN104177282B (zh) 2009-12-22 2010-12-22 用发酵过程得到的6‑氨基己酸来制备己内酰胺

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Country Status (9)

Country Link
US (3) US20130030146A1 (https=)
JP (6) JP5777067B2 (https=)
CN (2) CN102686562B (https=)
BR (2) BR112012015506A2 (https=)
EA (2) EA029354B1 (https=)
MY (3) MY196967A (https=)
TW (3) TWI537386B (https=)
UA (1) UA105409C2 (https=)
WO (1) WO2011078668A1 (https=)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI537386B (zh) * 2009-12-22 2016-06-11 Ｄｓｍ智慧財產有限公司 由發酵法獲得的６－胺己酸製備己內醯胺
US10087472B2 (en) 2013-05-06 2018-10-02 Korea Research Institute Of Bioscience And Biotechnology Biological synthesis of 6-aminocaproic acid and transgenic microorganism therefor
WO2014182016A1 (ko) * 2013-05-06 2014-11-13 한국생명공학연구원 6-아미노카프로산의 생물학적 합성 및 이를 위한 형질전환 미생물
WO2016048048A1 (ko) * 2014-09-23 2016-03-31 한국생명공학연구원 신규 카프로락탐 전환 효소를 이용한 ε-카프로락탐의 제조 방법
US20160297747A1 (en) * 2015-04-08 2016-10-13 Invista North America S.A.R.L. Materials and methods for the selective recovery of monovalent products from aqueous solutions using continuous ion exchange
RU2640657C1 (ru) * 2017-02-15 2018-01-11 Федеральное государственное бюджетное образовательное учреждение высшего образования "Ивановский государственный химико-технологический университет" (ИГХТУ) Способ выделения капролактама из содержащих капролактам и его олигомеры полимеров
CN113015578B (zh) 2018-09-18 2023-11-21 英威达纺织（英国）有限公司 用于从水性混合物中回收胺及其衍生物的系统和方法
JP7205275B2 (ja) * 2018-09-21 2023-01-17 日立金属株式会社 ガリウムの回収方法
CN109280023B (zh) * 2018-12-04 2020-06-12 河北美邦工程科技股份有限公司 一种己内酰胺连续结晶纯化方法
IT201800021409A1 (it) * 2018-12-28 2020-06-28 Aquafil S P A Processo per la produzione di epsilon caprolattame dall’acido 6-aminocaproico.
JP7196669B2 (ja) * 2019-02-14 2022-12-27 日立金属株式会社 ガリウムの回収方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999011616A1 (en) * 1997-09-03 1999-03-11 Alliedsignal Inc. A process for the purification of caprolactam obtained from the depolymerization of polyamide-containing carpet
US6194572B1 (en) * 1997-02-19 2001-02-27 Dsm N.V. Process to prepare ε-caprolactam
WO2005068643A2 (en) * 2004-01-19 2005-07-28 Dsm Ip Assets B.V. Biochemical synthesis of 6-amino caproic acid
US20070149777A1 (en) * 2004-06-10 2007-06-28 Board Of Trustees Of Michigan State University Synthesis of caprolactam from lysine

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1268869A (en) 1968-09-04 1972-03-29 Teijin Ltd PROCESS FOR THE PREPARATION OF epsilon-CAPROLACTAM
EP0860431A1 (en) * 1997-02-19 1998-08-26 Dsm N.V. Process to prepare e-caprolactam
EP0943608A1 (en) 1998-03-20 1999-09-22 Dsm N.V. Process for the continuous purification of crude epsilon--caprolactam
DE10255508A1 (de) * 2002-11-27 2004-06-17 Forschungszentrum Jülich GmbH Verfahren zur Kultivierung von Zellen zur Produktion von Substanzen
US7145713B2 (en) * 2004-07-13 2006-12-05 Montana State University Techniques for recovering optical spectral features using a chirped optical field
US7947483B2 (en) * 2007-08-10 2011-05-24 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
TW202306945A (zh) 2008-03-11 2023-02-16 美商吉諾瑪蒂卡股份有限公司 由α-酮庚二酸製備6-胺己酸之技術
TWI537386B (zh) * 2009-12-22 2016-06-11 Ｄｓｍ智慧財產有限公司 由發酵法獲得的６－胺己酸製備己內醯胺

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6194572B1 (en) * 1997-02-19 2001-02-27 Dsm N.V. Process to prepare ε-caprolactam
WO1999011616A1 (en) * 1997-09-03 1999-03-11 Alliedsignal Inc. A process for the purification of caprolactam obtained from the depolymerization of polyamide-containing carpet
WO2005068643A2 (en) * 2004-01-19 2005-07-28 Dsm Ip Assets B.V. Biochemical synthesis of 6-amino caproic acid
US20070149777A1 (en) * 2004-06-10 2007-06-28 Board Of Trustees Of Michigan State University Synthesis of caprolactam from lysine

Also Published As

Publication number Publication date
TW201129699A (en) 2011-09-01
CN102686562A (zh) 2012-09-19
JP2013515050A (ja) 2013-05-02
BR122017013721A2 (https=) 2011-06-30
MY196967A (en) 2023-05-15
UA105409C2 (uk) 2014-05-12
EA201200931A1 (ru) 2013-01-30
TWI624546B (zh) 2018-05-21
JP6499225B2 (ja) 2019-04-10
JP2017214358A (ja) 2017-12-07
BR122017013721A8 (pt) 2018-01-02
TW201726922A (zh) 2017-08-01
CN104177282A (zh) 2014-12-03
JP2021098720A (ja) 2021-07-01
MY177957A (en) 2020-09-28
TWI537386B (zh) 2016-06-11
MY161889A (en) 2017-05-15
JP2015180635A (ja) 2015-10-15
US20130030146A1 (en) 2013-01-31
CN104177282B (zh) 2017-06-27
JP5777067B2 (ja) 2015-09-09
EA201792404A1 (ru) 2018-03-30
TWI563090B (en) 2016-12-21
WO2011078668A1 (en) 2011-06-30
TW201615838A (zh) 2016-05-01
BR112012015506A2 (pt) 2015-09-22
EA029354B1 (ru) 2018-03-30
US20210171459A1 (en) 2021-06-10
JP2023099166A (ja) 2023-07-11
US20160200677A1 (en) 2016-07-14
JP2019115352A (ja) 2019-07-18

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Address after: California, USA

Patentee after: Genomatica, Inc.

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Patentee before: DSM IP ASSETS B.V.