The charged detection method of sulfur hexafluoride electrical equipment fault
Technical field
The invention belongs to electrical engineering technical field, be specifically related to a kind of charged detection method of sulfur hexafluoride electrical equipment fault.
Background technology
Insulating medium sulfur hexafluoride gas in High-Voltage Electrical Appliances, stable chemical nature, but the dissociation product producing in discharge process as with equipment in micro-moisture, gaseous impurities, electrode material and insulating material react, will produce the decomposition product of complicated component, cause equipment corrosion.And the performance degradation of insulating medium also can cause the decreasing insulating of equipment, so that the personal safety that jeopardizes security of operation and operator.The detection of sulfur hexafluoride gas humidity is the effective means that prevention insulation fault occurs, and utilizes the work of the decomposition product diagnosis electrical equipment situation of sulfur hexafluoride gas mainly to concentrate at present in the detection of gaseous decomposition product, as fluoridizes thionyl (SOF
2), sulphuric dioxide (SO
2), hydrogen fluoride (HF), sulfuretted hydrogen (H
2s) and carbon monoxide (CO) etc., these decomposition product complicated components, form changeable, and have toxicity in various degree, the error that the unevenness of gaseous state component distributing and analyzing detecting method exist is in addition given by detecting decomposition product diagnostic device situation and is brought larger uncertainty.Contact in sulfur hexafluoride air cell, insulator, electrical connection, pedestal etc. are mainly comprised of iron (Fe), aluminium (Al), copper (Cu), silver (Ag), tungsten (W), magnesium oxide (MgO) and a small amount of insulating polymer material.Sulfur hexafluoride gas decomposition product is mostly acrid gas, easily reacts with metal parts in sulfur hexafluoride air cell, and final sulfuration or the fluoride solid product of forming.When particularly when having, the situation such as office puts, corona discharge, arc discharge occurs, metal is directly activated into gaseous state, generation particulate solid after react with sulfur hexafluoride dissociation product or gas decomposition product.
Summary of the invention
The technical problem to be solved in the present invention is, large for sulfur hexafluoride gas decomposition product measuring error, by detecting decomposition product, diagnose the defect that sulfur hexafluoride electrical equipment fault difficulty is large, fault is difficult to location, a kind of method of utilizing air chamber internal solid particle diagnosis sulfur hexafluoride electrical equipment fault is proposed, particularly for the diagnosis of sulfur hexafluoride electrical equipment latency fault, the hidden danger that discovering device exists in time, avoids fault to worsen and causes security incident.
Technical solution of the present invention is that the charged detection method of the sulfur hexafluoride electrical equipment fault providing is to be following detecting step:
(1), get one of the teflon hose that caliber≤¢ 5mm, pipe range are 100~10000mm and mate with described teflon hose pipe diameter size and the filter membrane of filter opening diameter≤¢ 30 μ m standby.Described standby filter membrane is the one in quantitative filter paper, metal fibre film, quartz glass fibre film, polypropylene filter membrane, Teflon filter membrane, polyvinyl chloride fibre film, cellulose nitrate microporous barrier, cellulose acetate microporous barrier, polycarbonate nucleopore filter;
(2), by step (1) standby filter membrane fixed closed institute for one end of teflon hose;
(3) other end not being closed of the teflon hose, step (2) one end of obtaining being closed, be connected with the delivery outlet of peripheral hardware sulfur hexafluoride electrical equipment to be detected, control the flow velocity of sulfur hexafluoride gas of this peripheral hardware sulfur hexafluoride electrical equipment delivery outlet to be detected output at 1~1000mlmin
-1in scope, to can guarantee that the percent of pass that the sulfur hexafluoride gas of this peripheral hardware sulfur hexafluoride electrical equipment delivery outlet output to be detected flows through from described filter membrane reaches 100 ﹪;
(4), treat that the time that the sulfur hexafluoride gas of the sulfur hexafluoride electrical equipment delivery outlet to be detected of peripheral hardware described in step (3) output flows through from described filter membrane reaches 1~60min, remove filter membrane;
(5), to step (4) the filter membrane that removes implement that the analysis of atomic absorption spectrometry, atomic emission spectrometry analysis, atomic Fluorescence Spectrometry To The Analysis, ultravioletvisible spectroscopy analysis, ion chromatography analysis, ICP-AES analysis, inductively coupled plasma mass spectrometry analysis, x-ray fluorescence spectrometry method, X ray energy dispersion spectrometry are analyzed, x-ray photoelectron spectroscopy method is analyzed, the one of Auger electron spectroscopy in analyzing, obtain this institute and remove the ultimate analysis conclusion of filter membrane; Or to step (4) the filter membrane that removes implement X-ray diffraction method material phase analysis, obtain this institute and remove the material phase analysis conclusion of filter membrane.Meanwhile, to step (1) the filter membrane enforcement blank assay of standby and step (4) the identical material of filter membrane of removing, obtain the blank assay result of this identical material filter membrane;
(6), to step (5) the ultimate analysis conclusion of the step that obtains (4) filter membrane that removes or the material phase analysis conclusion of step (4) filter membrane that removes, compare with the blank assay result of step (5) the identical material filter membrane that obtains, obtain one or more elements in institute's iron content, aluminium, copper, silver, tungsten, magnesium, carbon in the solid particle that above-mentioned steps (4) filter membrane that removes leaches, be contained element in the solid particle leaching in the sulfur hexafluoride gas that the delivery outlet of the described peripheral hardware of above-mentioned steps (3) sulfur hexafluoride electrical equipment to be detected exports.Then utilizing contained element in the solid particle leaching in the sulfur hexafluoride gas of delivery outlet output of this peripheral hardware sulfur hexafluoride electrical equipment to be detected is the corresponding element relation of the iron that comprises in the parts from described peripheral hardware sulfur hexafluoride electrical equipment to be detected, aluminium, copper, silver, tungsten, magnesium, carbon, and the diagnosing malfunction that this peripheral hardware sulfur hexafluoride electrical equipment to be detected is existed also draws diagnosis.
The invention has the beneficial effects as follows: the sampling process of using this method to implement, can in sulfur hexafluoride gas humidity, purity, decomposition product test process, synchronously carry out, belong to band electro-detection, can under the condition of the sulfur hexafluoride electrical equipment that do not disintegrate, diagnose and locate fault and latency fault that this equipment exists, thereby the hidden danger that discovering device exists in time, avoids fault to worsen and causes security incident.
Embodiment
Embodiment 1,
(1), get one of the teflon hose that caliber≤¢ 5mm, pipe range are 100mm and mate with described teflon hose pipe diameter size and the filter membrane of filter opening diameter≤¢ 30 μ m standby.Described standby filter membrane is quantitative filter paper;
(2), by step (1) standby filter membrane fixed closed institute for one end of teflon hose;
(3) other end not being closed of the teflon hose, step (2) one end of obtaining being closed, be connected with the delivery outlet of peripheral hardware sulfur hexafluoride electrical equipment to be detected, control the flow velocity of sulfur hexafluoride gas of this peripheral hardware sulfur hexafluoride electrical equipment delivery outlet to be detected output at 1~1000mlmin
-1in scope;
(4), treat that the time that the sulfur hexafluoride gas of the sulfur hexafluoride electrical equipment delivery outlet to be detected of peripheral hardware described in step (3) output flows through from described filter membrane reaches 1~60min, remove filter membrane;
(5), to step (4) the filter membrane that removes implement atomic absorption spectrometry, obtain the ultimate analysis conclusion of step (4) filter membrane that removes.Meanwhile, to step (1) the filter membrane enforcement blank assay of standby and step (4) the identical material of filter membrane of removing, obtain the blank assay result of this identical material filter membrane;
(6), to step (5) the ultimate analysis conclusion of the step that obtains (4) filter membrane that removes, compare with the blank assay result of step (5) the identical material filter membrane that obtains, obtain one or more elements in institute's iron content, aluminium, copper, silver, tungsten, magnesium, carbon in the solid particle that above-mentioned steps (4) filter membrane that removes leaches, be contained element in the solid particle leaching in the sulfur hexafluoride gas that the delivery outlet of the described peripheral hardware of above-mentioned steps (3) sulfur hexafluoride electrical equipment to be detected exports.Then utilizing contained element in the solid particle leaching in the sulfur hexafluoride gas of delivery outlet output of this peripheral hardware sulfur hexafluoride electrical equipment to be detected is the corresponding element relation of the iron that comprises in the parts from described peripheral hardware sulfur hexafluoride electrical equipment to be detected, aluminium, copper, silver, tungsten, magnesium, carbon, and the diagnosing malfunction that this peripheral hardware sulfur hexafluoride electrical equipment to be detected is existed also draws diagnosis.
Embodiment 2.
(1), get one of the teflon hose that caliber≤¢ 5mm, pipe range are 10000mm and mate with described teflon hose pipe diameter size and the filter membrane of filter opening diameter≤¢ 30 μ m standby.Described standby filter membrane is polycarbonate nucleopore filter;
Step (2)~(4) are with embodiment 1;
(5), to step (4) the filter membrane that removes implement X-ray diffraction method material phase analysis, obtain the material phase analysis conclusion of step (4) filter membrane that removes.Meanwhile, to step (1) the filter membrane enforcement blank assay of standby and step (4) the identical material of filter membrane of removing, obtain the blank assay result of this identical material filter membrane;
(6), to step (5) the material phase analysis conclusion of the step that obtains (4) filter membrane that removes, compare with the blank assay result of step (5) the identical material filter membrane that obtains, obtain one or more elements in institute's iron content, aluminium, copper, silver, tungsten, magnesium, carbon in the solid particle that above-mentioned steps (4) filter membrane that removes leaches, be contained element in the solid particle leaching in the sulfur hexafluoride gas that the delivery outlet of the described peripheral hardware of above-mentioned steps (3) sulfur hexafluoride electrical equipment to be detected exports.Then utilizing contained element in the solid particle leaching in the sulfur hexafluoride gas of delivery outlet output of this peripheral hardware sulfur hexafluoride electrical equipment to be detected is the corresponding element relation of the iron that comprises in the parts from described peripheral hardware sulfur hexafluoride electrical equipment to be detected, aluminium, copper, silver, tungsten, magnesium, carbon, and the diagnosing malfunction that this peripheral hardware sulfur hexafluoride electrical equipment to be detected is existed also draws diagnosis.