CN102676099A - Multipurpose quick-drying adhesive and preparation method thereof - Google Patents
Multipurpose quick-drying adhesive and preparation method thereof Download PDFInfo
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- CN102676099A CN102676099A CN2012101646479A CN201210164647A CN102676099A CN 102676099 A CN102676099 A CN 102676099A CN 2012101646479 A CN2012101646479 A CN 2012101646479A CN 201210164647 A CN201210164647 A CN 201210164647A CN 102676099 A CN102676099 A CN 102676099A
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Abstract
The invention discloses a multipurpose quick-drying adhesive, which comprises the following components by weight: 30-40 parts of methyl methacrylate, 2-4 parts of chloroprene rubber, 6-10 parts of ethyl acetate, 0.5-1 part of ascorbic acid (ASA), 0.5-1 part of ferric sulfate, 5-7 parts of styrene, 0.02-0.03 part of azodiisobutyronitrile, 8-15 parts of 307# unsaturated polyester resins and 5-10 parts of industrial gasoline. The multipurpose quick-drying adhesive, provided by the invention, can be quickly cured at low temperature of minus 10 DEG C, and has the characteristics of cold resistance, water resistance, alcohol resistance, gasoline resistance and the like; the application range is wide, the multipurpose quick-drying adhesive is suitable for binding metal materials such as aluminum, iron, stainless steel, copper and the like, and nonmetallic substances such as organic glass, polystyrene, rigid polyvinyl chloride, polycarbonate, ABS (acrylonitrile butadiene styrene), and the binding intensity is high; a preparation process provided by the invention is simple and easy to implement.
Description
Technical field
The present invention relates to the chemical preparations field, relate in particular to a kind of multi-usage Quick-drying Adhesive and preparation method thereof.
Background technology
In the prior art, the glue paste that can under coldcondition, use is few, and the glue paste that can use with this understanding basically all is special-purpose, and use range is restricted.In addition, when existing glue paste uses under each condition, need pressurization to be cured mostly; Strengthened operation easier so undoubtedly; And unusual trouble, and solidify bad meeting and cause the later stage result of use bad, therefore a kind of use range is extensive; Be prone to solidify, the multi-usage glue paste of good physical performance becomes the demand in market.
Summary of the invention
In order to overcome above-mentioned deficiency, it is extensive that technical problem to be solved provides a kind of use range just in the present invention, is prone to solidified multi-usage Quick-drying Adhesive.
The technical problem that the present invention also will solve provides the preparation method of above-mentioned multi-usage Quick-drying Adhesive.
For solving the problems of the technologies described above, the technical scheme that the present invention adopted is following:
A kind of multi-usage Quick-drying Adhesive, it comprises the component of following parts by weight:
30～40 parts of TEB 3Ks
2～4 parts of X 050s
6～10 parts in ETHYLE ACETATE
0.5～1 part in xitix (ASA)
0.5～1 part in ferric sulfate
5～7 parts of vinylbenzene
0.02～0.03 part of Diisopropyl azodicarboxylate
307
#8～15 parts of unsaturated polyester resins
5～10 parts of non-leaded gasolines.
As screening formulation, described multi-usage Quick-drying Adhesive comprises the component of following parts by weight:
35 parts of TEB 3Ks
3 parts of X 050s
8 parts in ETHYLE ACETATE
0.8 part in xitix (ASA)
0.8 part in ferric sulfate
6 parts of vinylbenzene
0.025 part of Diisopropyl azodicarboxylate
307
#12 parts of unsaturated polyester resins
7 parts of non-leaded gasolines.
Prepare the method for above-mentioned multi-usage Quick-drying Adhesive, it comprises the steps:
(1) presses formula ratio, in reactor drum, drop into ETHYLE ACETATE and gasoline, add the X 050 that tears to shreds while stirring, heating in water bath to 65 ℃～70 ℃;
(2) treat the solution clear, add TEB 3K, styryl Diisopropyl azodicarboxylate again, be warming up to 85 ℃～90 ℃, be incubated 1.5～2 hours;
(3) be warming up to 95 ℃～100 ℃, kept 2～3 hours, solution transparent thick liquid;
(4) be cooled to room temperature, add 307
#Unsaturated polyester resin and xitix (ASA) and ferric sulfate stir and promptly get described multi-usage Quick-drying Adhesive.
Beneficial effect: multi-usage Quick-drying Adhesive of the present invention, can low temperature subzero 10 the degree under fast setting, have characteristics such as cold-resistant, waterproof, anti-alcohol, anti-gasoline; Use range is extensive, is applicable to the bonding of nonmetallic substances such as metallic substance such as aluminium, iron, stainless steel, copper and synthetic glass, PS, rigid polyvinyl chloride, polycarbonate, ABS resin, and cohesive strength is high; Preparation technology of the present invention is simple, is easy to realize.
Embodiment:
Embodiment 1
A kind of multi-usage Quick-drying Adhesive, it comprises the component of following parts by weight:
35 parts of TEB 3Ks
3 parts of X 050s
8 parts in ETHYLE ACETATE
0.8 part in xitix (ASA)
0.8 part in ferric sulfate
6 parts of vinylbenzene
0.025 part of Diisopropyl azodicarboxylate
307
#12 parts of unsaturated polyester resins
7 parts of non-leaded gasolines.
Prepare the method for above-mentioned multi-usage Quick-drying Adhesive, it comprises the steps:
(1) presses formula ratio, in reactor drum, drop into ETHYLE ACETATE and gasoline, add the X 050 that tears to shreds while stirring, heating in water bath to 65 ℃～70 ℃;
(2) treat the solution clear, add TEB 3K, styryl Diisopropyl azodicarboxylate again, be warming up to 85 ℃～90 ℃, be incubated 2 hours;
(3) be warming up to 95 ℃～100 ℃, kept 2.5 hours, solution transparent thick liquid;
(4) be cooled to room temperature, add 307
#Unsaturated polyester resin and xitix (ASA) and ferric sulfate stir and promptly get described multi-usage Quick-drying Adhesive.
The above-mentioned tackiness agent that makes is applied to the adherend surface, can be at the subzero 10 ℃ of following fast setting of low temperature, be 10 hours set time.
Embodiment 2
A kind of multi-usage Quick-drying Adhesive, it comprises the component of following parts by weight:
30 parts of TEB 3Ks
2 parts of X 050s
6 parts in ETHYLE ACETATE
0.5 part in xitix (ASA)
0.5 part in ferric sulfate
5 parts of vinylbenzene
0.02 part of Diisopropyl azodicarboxylate
307
#8 parts of unsaturated polyester resins
5 parts of non-leaded gasolines.
Prepare the method for above-mentioned multi-usage Quick-drying Adhesive, it comprises the steps:
(1) presses formula ratio, in reactor drum, drop into ETHYLE ACETATE and gasoline, add the X 050 that tears to shreds while stirring, heating in water bath to 65 ℃～70 ℃;
(2) treat the solution clear, add TEB 3K, styryl Diisopropyl azodicarboxylate again, be warming up to 85 ℃～90 ℃, be incubated 1.5 hours;
(3) be warming up to 95 ℃～100 ℃, kept 2 hours, solution transparent thick liquid;
(4) be cooled to room temperature, add 307
#Unsaturated polyester resin and xitix (ASA) and ferric sulfate stir and promptly get described multi-usage Quick-drying Adhesive.
The above-mentioned tackiness agent that makes is applied to the adherend surface, can be at the subzero 10 ℃ of following fast setting of low temperature, be 12 hours set time.
Embodiment 3
A kind of multi-usage Quick-drying Adhesive, it comprises the component of following parts by weight:
40 parts of TEB 3Ks
4 parts of X 050s
10 parts in ETHYLE ACETATE
1 part in xitix (ASA)
1 part in ferric sulfate
7 parts of vinylbenzene
0.03 part of Diisopropyl azodicarboxylate
307
#15 parts of unsaturated polyester resins
10 parts of non-leaded gasolines.
Prepare the method for above-mentioned multi-usage Quick-drying Adhesive, it comprises the steps:
(1) presses formula ratio, in reactor drum, drop into ETHYLE ACETATE and gasoline, add the X 050 that tears to shreds while stirring, heating in water bath to 65 ℃～70 ℃;
(2) treat the solution clear, add TEB 3K, styryl Diisopropyl azodicarboxylate again, be warming up to 85 ℃～90 ℃, be incubated 2 hours;
(3) be warming up to 95 ℃～100 ℃, kept 3 hours, solution transparent thick liquid;
(4) be cooled to room temperature, add 307
#Unsaturated polyester resin and xitix (ASA) and ferric sulfate stir and promptly get described multi-usage Quick-drying Adhesive.
The above-mentioned tackiness agent that makes is applied to the adherend surface, can be at the subzero 8 ℃ of following fast setting of low temperature, be 15 hours set time.
The foregoing description only is explanation technical conceive of the present invention and characteristics, its objective is to let to be familiar with these those skilled in the art and can to understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalents that spirit has been done according to the present invention or modification all should be encompassed within protection scope of the present invention.
Claims (3)
1. multi-usage Quick-drying Adhesive is characterized in that it comprises the component of following parts by weight:
30～40 parts of TEB 3Ks
2～4 parts of X 050s
6～10 parts in ETHYLE ACETATE
0.5～1 part in xitix (ASA)
0.5～1 part in ferric sulfate
5～7 parts of vinylbenzene
0.02～0.03 part of Diisopropyl azodicarboxylate
307
#8～15 parts of unsaturated polyester resins
5～10 parts of non-leaded gasolines.
2. multi-usage Quick-drying Adhesive according to claim 1 is characterized in that it comprises the component of following parts by weight:
35 parts of TEB 3Ks
3 parts of X 050s
8 parts in ETHYLE ACETATE
0.8 part in xitix
0.8 part in ferric sulfate
6 parts of vinylbenzene
0.025 part of Diisopropyl azodicarboxylate
307
#12 parts of unsaturated polyester resins
7 parts of non-leaded gasolines.
3. the method for preparing the described multi-usage Quick-drying Adhesive of claim 1 is characterized in that it comprises the steps:
(1) presses formula ratio, in reactor drum, drop into ETHYLE ACETATE and gasoline, add the X 050 that tears to shreds while stirring, heating in water bath to 65 ℃～70 ℃;
(2) treat the solution clear, add TEB 3K, styryl Diisopropyl azodicarboxylate again, be warming up to 85 ℃～90 ℃, be incubated 1.5～2 hours;
(3) be warming up to 95 ℃～100 ℃, kept 2～3 hours, solution transparent thick liquid;
(4) be cooled to room temperature, add 307
#Unsaturated polyester resin and xitix and ferric sulfate stir and promptly get described multi-usage Quick-drying Adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101646479A CN102676099A (en) | 2012-05-25 | 2012-05-25 | Multipurpose quick-drying adhesive and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101646479A CN102676099A (en) | 2012-05-25 | 2012-05-25 | Multipurpose quick-drying adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102676099A true CN102676099A (en) | 2012-09-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101646479A Pending CN102676099A (en) | 2012-05-25 | 2012-05-25 | Multipurpose quick-drying adhesive and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102994022A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Instant adhesive |
| CN106634684A (en) * | 2016-11-16 | 2017-05-10 | 吴定财 | Quick-drying adhesive and preparation method thereof |
| CN107043443A (en) * | 2017-05-11 | 2017-08-15 | 佛山市高明大都化工有限公司 | A kind of multi-purpose adhesive glue |
| CN108587518A (en) * | 2018-05-07 | 2018-09-28 | 安吉祥力胶粘剂有限公司 | A kind of solvent type adhesive and preparation method thereof |
| CN111072864A (en) * | 2019-12-23 | 2020-04-28 | 广州熵能创新材料股份有限公司 | Grafted chloroprene rubber powder and preparation method and application thereof |
| CN114525081A (en) * | 2022-03-15 | 2022-05-24 | 宁波骋拓金属制造有限公司 | Chloroprene rubber pasting process |
| CN115746366A (en) * | 2022-11-26 | 2023-03-07 | 夜视丽新材料(仙居)有限公司 | Improved high-strength polyester film and acrylic resin laminating adhesive |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065082A (en) * | 1991-03-15 | 1992-10-07 | 辛辉 | A kind of modified version neoprene graft binding agent and manufacture method thereof |
-
2012
- 2012-05-25 CN CN2012101646479A patent/CN102676099A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065082A (en) * | 1991-03-15 | 1992-10-07 | 辛辉 | A kind of modified version neoprene graft binding agent and manufacture method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 宋后昆: "一种万能胶粘剂制作技术", 《中小企业科技》 * |
| 张凯，等: "乙烯基单体乳液接枝改性氯丁胶乳的制备及其机理", 《华南理工大学学报（自然科学版）》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102994022A (en) * | 2012-10-31 | 2013-03-27 | 安徽东方金河精密机械制造有限公司 | Instant adhesive |
| CN106634684A (en) * | 2016-11-16 | 2017-05-10 | 吴定财 | Quick-drying adhesive and preparation method thereof |
| CN107043443A (en) * | 2017-05-11 | 2017-08-15 | 佛山市高明大都化工有限公司 | A kind of multi-purpose adhesive glue |
| CN108587518A (en) * | 2018-05-07 | 2018-09-28 | 安吉祥力胶粘剂有限公司 | A kind of solvent type adhesive and preparation method thereof |
| CN111072864A (en) * | 2019-12-23 | 2020-04-28 | 广州熵能创新材料股份有限公司 | Grafted chloroprene rubber powder and preparation method and application thereof |
| CN114525081A (en) * | 2022-03-15 | 2022-05-24 | 宁波骋拓金属制造有限公司 | Chloroprene rubber pasting process |
| CN115746366A (en) * | 2022-11-26 | 2023-03-07 | 夜视丽新材料(仙居)有限公司 | Improved high-strength polyester film and acrylic resin laminating adhesive |
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Application publication date: 20120919 |