CN108587518A - A kind of solvent type adhesive and preparation method thereof - Google Patents

A kind of solvent type adhesive and preparation method thereof Download PDF

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Publication number
CN108587518A
CN108587518A CN201810425032.4A CN201810425032A CN108587518A CN 108587518 A CN108587518 A CN 108587518A CN 201810425032 A CN201810425032 A CN 201810425032A CN 108587518 A CN108587518 A CN 108587518A
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CN
China
Prior art keywords
parts
solvent type
type adhesive
isobutanol
methacrylamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810425032.4A
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Chinese (zh)
Inventor
李伟农
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
An Auspicious Adhesive Co Ltd
Original Assignee
An Auspicious Adhesive Co Ltd
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Publication date
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Priority to CN201810425032.4A priority Critical patent/CN108587518A/en
Publication of CN108587518A publication Critical patent/CN108587518A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J111/00Adhesives based on homopolymers or copolymers of chloroprene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C09J167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The invention discloses a kind of solvent type adhesives and preparation method thereof.The solvent type adhesive includes the raw material of following parts by weight:It is 10 15 parts of neoprene, 6 10 parts of silica powder, 15 20 parts of Methacrylamide, 8 15 parts of methyl acetate, 6 15 parts of chlorohydrin rubber, 6 17 parts of unsaturated polyester resin, 8 14 parts of polyethylene glycol, 30 50 parts of isobutanol, 13 parts of antifoaming agent, 2513 parts double.The solvent type adhesive of the present invention is combined by neoprene, silica powder, Methacrylamide, methyl acetate, chlorohydrin rubber, unsaturated polyester resin, polyethylene glycol, isobutanol, antifoaming agent and double 25, with good resistance to ozone, water-fast, chemical-resistant reagent, durable and ageing-resistant etc. performances, the poor feature of the solvent type adhesive cold resistance of traditional mode of production is improved, the quality and performance of solvent type adhesive are enhanced.

Description

A kind of solvent type adhesive and preparation method thereof
Technical field
The present invention relates to a kind of adhesive, specifically a kind of solvent type adhesive and preparation method thereof.
Background technology
Solvent type adhesive is the prodigious a kind of adhesive of yield, it is the material based on rubber, plastics, and cooperation is added Agent is dissolved into solvent and manufactured, and its feature is to volatilize and cure by solvent, and initial adhesion force is high, and elasticity is big, peel strength height Deng especially suitable for the bonding of different expansion materials, having been widely used for shoemaking, paper, construction material, sail now Cloth, synthetic fibers, leather, metal, timber etc..Being widely used and promoting with solvent type adhesive, people are for it Performance and quality have higher requirement, therefore develop that new solvent type adhesive is extremely urgent, traditional mode of production it is molten Dosage form adhesive cold resistance is poor.
Invention content
The purpose of the present invention is to provide a kind of solvent type adhesives and preparation method thereof, to solve in above-mentioned background technology The problem of proposition.
To achieve the above object, the present invention provides the following technical solutions:
A kind of solvent type adhesive, the solvent type adhesive include the raw material of following parts by weight:10-15 parts of neoprene, 6-10 parts of silica powder, 15-20 parts of Methacrylamide, 8-15 parts of methyl acetate, 6-15 parts of chlorohydrin rubber, unsaturated polyester (UP) It is 6-17 parts of resin, 8-14 parts of polyethylene glycol, 30-50 parts of isobutanol, 1-3 parts of antifoaming agent, two or five 1-3 parts double.
As a further solution of the present invention:The solvent type adhesive includes the raw material of following parts by weight:Neoprene rubber 11-14 parts of glue, 7-9 parts of silica powder, 16-19 parts of Methacrylamide, 10-13 parts of methyl acetate, 7-13 parts of chlorohydrin rubber, It is 8-15 parts of unsaturated polyester resin, 9-11 parts of polyethylene glycol, 38-45 parts of isobutanol, 1-2 parts of antifoaming agent, two or five 2-3 parts double.
As a further solution of the present invention:The solvent type adhesive includes the raw material of following parts by weight:Neoprene rubber 12 parts of glue, 8 parts of silica powder, 18 parts of Methacrylamide, 11 parts of methyl acetate, 9 parts of chlorohydrin rubber, unsaturated polyester resin 13 parts, it is 10 parts of polyethylene glycol, 40 parts of isobutanol, 1.3 parts of antifoaming agent, 25 2.5 parts double.
A kind of preparation method of solvent type adhesive, includes the following steps:(1)According to above-mentioned formula weigh neoprene, Silica powder, Methacrylamide, methyl acetate, chlorohydrin rubber, unsaturated polyester resin, polyethylene glycol, isobutanol, defoaming Agent and double 25, it is spare;(2)Neoprene, Methacrylamide, methyl acetate, isobutanol and polyethylene glycol are added and reacted In kettle, 2-3h is stirred at 40-50 DEG C, is cooled to room temperature;(3)By silica powder, chlorohydrin rubber and unsaturated polyester resin It is added in reaction kettle, continues to stir 20-40min;(4)Antifoaming agent and double 25 are added in reaction kettle, continue to stir 20- 30min is stirred evenly to obtain the final product.
As a further solution of the present invention:Step(2)By neoprene, Methacrylamide, methyl acetate, isobutanol It is added in reaction kettle with polyethylene glycol, stirs 2.6h at 45 DEG C, be cooled to room temperature.
As a further solution of the present invention:Step(3)Silica powder, chlorohydrin rubber and unsaturated polyester resin are added Enter in reaction kettle, continues to stir 30min.
As a further solution of the present invention:Step(4)Antifoaming agent and double 25 are added in reaction kettle, continue to stir 25min is stirred evenly to obtain the final product.
Compared with prior art, the beneficial effects of the invention are as follows:
The solvent type adhesive of the present invention passes through neoprene, silica powder, Methacrylamide, methyl acetate, chloropharin rubber Glue, unsaturated polyester resin, polyethylene glycol, isobutanol, antifoaming agent and double 25 are combined, and have good resistance to ozone, resistance to Water, chemical-resistant reagent, durable and ageing-resistant etc. performances, improve the poor spy of the solvent type adhesive cold resistance of traditional mode of production Point enhances the quality and performance of solvent type adhesive.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of solvent type adhesive, the solvent type adhesive include the raw material of following parts by weight:10 parts of neoprene, oxidation 6 parts of silicon powder, 15 parts of Methacrylamide, 8 parts of methyl acetate, 6 parts of chlorohydrin rubber, 6 parts of unsaturated polyester resin, polyethylene glycol 8 parts, it is 30 parts of isobutanol, 1 part of antifoaming agent, 251 parts double.
A kind of preparation method of solvent type adhesive, includes the following steps:(1)According to above-mentioned formula weigh neoprene, Silica powder, Methacrylamide, methyl acetate, chlorohydrin rubber, unsaturated polyester resin, polyethylene glycol, isobutanol, defoaming Agent and double 25, it is spare;(2)Neoprene, Methacrylamide, methyl acetate, isobutanol and polyethylene glycol are added and reacted In kettle, 2h is stirred at 40 DEG C, is cooled to room temperature;(3)Silica powder, chlorohydrin rubber and unsaturated polyester resin are added anti- It answers in kettle, continues to stir 20min;(4)Antifoaming agent and double 25 are added in reaction kettle, continues to stir 20min, stir evenly i.e. .
Embodiment 2
A kind of solvent type adhesive, the solvent type adhesive include the raw material of following parts by weight:15 parts of neoprene, oxidation 10 parts of silicon powder, 20 parts of Methacrylamide, 15 parts of methyl acetate, 15 parts of chlorohydrin rubber, 17 parts of unsaturated polyester resin, poly- second It is 14 parts of glycol, 50 parts of isobutanol, 3 parts of antifoaming agent, 253 parts double.
A kind of preparation method of solvent type adhesive, includes the following steps:(1)According to above-mentioned formula weigh neoprene, Silica powder, Methacrylamide, methyl acetate, chlorohydrin rubber, unsaturated polyester resin, polyethylene glycol, isobutanol, defoaming Agent and double 25, it is spare;(2)Neoprene, Methacrylamide, methyl acetate, isobutanol and polyethylene glycol are added and reacted In kettle, 3h is stirred at 50 DEG C, is cooled to room temperature;(3)Silica powder, chlorohydrin rubber and unsaturated polyester resin are added anti- It answers in kettle, continues to stir 40min;(4)Antifoaming agent and double 25 are added in reaction kettle, continues to stir 30min, stir evenly i.e. .
Embodiment 3
A kind of solvent type adhesive, the solvent type adhesive include the raw material of following parts by weight:12 parts of neoprene, oxidation 8 parts of silicon powder, 18 parts of Methacrylamide, 11 parts of methyl acetate, 9 parts of chlorohydrin rubber, 13 parts of unsaturated polyester resin, poly- second two It is 10 parts of alcohol, 40 parts of isobutanol, 1.3 parts of antifoaming agent, 25 2.5 parts double.
A kind of preparation method of solvent type adhesive, includes the following steps:(1)According to above-mentioned formula weigh neoprene, Silica powder, Methacrylamide, methyl acetate, chlorohydrin rubber, unsaturated polyester resin, polyethylene glycol, isobutanol, defoaming Agent and double 25, it is spare;(2)Neoprene, Methacrylamide, methyl acetate, isobutanol and polyethylene glycol are added and reacted In kettle, 2.6h is stirred at 45 DEG C, is cooled to room temperature.(3)Silica powder, chlorohydrin rubber and unsaturated polyester resin are added In reaction kettle, continue to stir 30min.(4)Antifoaming agent and double 25 are added in reaction kettle, continues to stir 25min, stir evenly To obtain the final product.
Performance test:Remove adhesive strength(Canvas):11KN/m.Low temperature properties:Do not freeze within 6 days at -30 DEG C.Durability:Room It is interior to use 15-18;Outdoor 2-4.
Embodiment 4
A kind of solvent type adhesive, the solvent type adhesive include the raw material of following parts by weight:11 parts of neoprene, oxidation 7 parts of silicon powder, 16 parts of Methacrylamide, 10 parts of methyl acetate, 7 parts of chlorohydrin rubber, 8 parts of unsaturated polyester resin, poly- second two It is 9 parts of alcohol, 38 parts of isobutanol, 1 part of antifoaming agent, 252 parts double.
A kind of preparation method of solvent type adhesive, includes the following steps:(1)According to above-mentioned formula weigh neoprene, Silica powder, Methacrylamide, methyl acetate, chlorohydrin rubber, unsaturated polyester resin, polyethylene glycol, isobutanol, defoaming Agent and double 25, it is spare;(2)Neoprene, Methacrylamide, methyl acetate, isobutanol and polyethylene glycol are added and reacted In kettle, 2.3h is stirred at 42 DEG C, is cooled to room temperature;(3)Silica powder, chlorohydrin rubber and unsaturated polyester resin are added In reaction kettle, continue to stir 25min;(4)Antifoaming agent and double 25 are added in reaction kettle, continues to stir 23min, stir evenly To obtain the final product.
Embodiment 5
A kind of solvent type adhesive, the solvent type adhesive include the raw material of following parts by weight:14 parts of neoprene, oxidation 9 parts of silicon powder, 19 parts of Methacrylamide, 13 parts of methyl acetate, 13 parts of chlorohydrin rubber, 15 parts of unsaturated polyester resin, poly- second It is 11 parts of glycol, 45 parts of isobutanol, 2 parts of antifoaming agent, 253 parts double.
A kind of preparation method of solvent type adhesive, includes the following steps:(1)According to above-mentioned formula weigh neoprene, Silica powder, Methacrylamide, methyl acetate, chlorohydrin rubber, unsaturated polyester resin, polyethylene glycol, isobutanol, defoaming Agent and double 25, it is spare;(2)Neoprene, Methacrylamide, methyl acetate, isobutanol and polyethylene glycol are added and reacted In kettle, 2.7h is stirred at 48 DEG C, is cooled to room temperature;(3)Silica powder, chlorohydrin rubber and unsaturated polyester resin are added In reaction kettle, continue to stir 35min;(4)Antifoaming agent and double 25 are added in reaction kettle, continues to stir 27min, stir evenly To obtain the final product.
Embodiment 6
A kind of solvent type adhesive, the solvent type adhesive include the raw material of following parts by weight:12 parts of neoprene, oxidation 9 parts of silicon powder, 17 parts of Methacrylamide, 14 parts of methyl acetate, 7 parts of chlorohydrin rubber, 16 parts of unsaturated polyester resin, poly- second two It is 9 parts of alcohol, 38 parts of isobutanol, 1.2 parts of antifoaming agent, 25 1.3 parts double.
A kind of preparation method of solvent type adhesive, includes the following steps:(1)According to above-mentioned formula weigh neoprene, Silica powder, Methacrylamide, methyl acetate, chlorohydrin rubber, unsaturated polyester resin, polyethylene glycol, isobutanol, defoaming Agent and double 25, it is spare;(2)Neoprene, Methacrylamide, methyl acetate, isobutanol and polyethylene glycol are added and reacted In kettle, 2.4h is stirred at 44 DEG C, is cooled to room temperature;(3)Silica powder, chlorohydrin rubber and unsaturated polyester resin are added In reaction kettle, continue to stir 34min;(4)Antifoaming agent and double 25 are added in reaction kettle, continues to stir 23min, stir evenly To obtain the final product.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, one skilled in the relevant art within the scope of knowledge, can also be under the premise of not departing from this patent objective Various changes can be made.

Claims (7)

1. a kind of solvent type adhesive, which is characterized in that the solvent type adhesive includes the raw material of following parts by weight:Neoprene 10-15 parts of rubber, 6-10 parts of silica powder, 15-20 parts of Methacrylamide, 8-15 parts of methyl acetate, chlorohydrin rubber 6-15 It is part, 6-17 parts of unsaturated polyester resin, 8-14 parts of polyethylene glycol, 30-50 parts of isobutanol, 1-3 parts of antifoaming agent, two or five 1-3 parts double.
2. solvent type adhesive according to claim 1, which is characterized in that the solvent type adhesive includes following weight The raw material of number:11-14 parts of neoprene, 7-9 parts of silica powder, 16-19 parts of Methacrylamide, methyl acetate 10-13 Part, 7-13 parts of chlorohydrin rubber, 8-15 parts of unsaturated polyester resin, 9-11 parts of polyethylene glycol, 38-45 parts of isobutanol, antifoaming agent 1-2 Part, it is two or five 2-3 parts double.
3. solvent type adhesive according to claim 1, which is characterized in that the solvent type adhesive includes following weight The raw material of number:12 parts of neoprene, 8 parts of silica powder, 18 parts of Methacrylamide, 11 parts of methyl acetate, chlorohydrin rubber 9 It is part, 13 parts of unsaturated polyester resin, 10 parts of polyethylene glycol, 40 parts of isobutanol, 1.3 parts of antifoaming agent, 25 2.5 parts double.
4. a kind of preparation method according to any solvent type adhesives of claim 1-3, which is characterized in that including following Step:(1)Neoprene, silica powder, Methacrylamide, methyl acetate, chlorohydrin rubber, no are weighed according to above-mentioned formula Saturated polyester resin, polyethylene glycol, isobutanol, antifoaming agent and double 25, it is spare;(2)By neoprene, Methacrylamide, Methyl acetate, isobutanol and polyethylene glycol are added in reaction kettle, stir 2-3h at 40-50 DEG C, are cooled to room temperature;(3)By oxygen SiClx powder, chlorohydrin rubber and unsaturated polyester resin are added in reaction kettle, continue to stir 20-40min;(4)By antifoaming agent and Double 25 are added in reaction kettle, continue to stir 20-30min, stir evenly to obtain the final product.
5. the preparation method of solvent type adhesive according to claim 4, which is characterized in that step(2)By neoprene, Methacrylamide, methyl acetate, isobutanol and polyethylene glycol are added in reaction kettle, and 2.6h is stirred at 45 DEG C, are cooled to often Temperature.
6. the preparation method of solvent type adhesive according to claim 4, which is characterized in that step(3)By silica powder Body, chlorohydrin rubber and unsaturated polyester resin are added in reaction kettle, continue to stir 30min.
7. the preparation method of solvent type adhesive according to claim 4, which is characterized in that step(4)By antifoaming agent and Double 25 are added in reaction kettle, continue to stir 25min, stir evenly to obtain the final product.
CN201810425032.4A 2018-05-07 2018-05-07 A kind of solvent type adhesive and preparation method thereof Pending CN108587518A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810425032.4A CN108587518A (en) 2018-05-07 2018-05-07 A kind of solvent type adhesive and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201810425032.4A CN108587518A (en) 2018-05-07 2018-05-07 A kind of solvent type adhesive and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108587518A true CN108587518A (en) 2018-09-28

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102676099A (en) * 2012-05-25 2012-09-19 太仓市新星轻工助剂厂 Multipurpose quick-drying adhesive and preparation method thereof
CN103173134A (en) * 2013-02-26 2013-06-26 安徽明珠颜料科技有限公司 Solvent-based neoprene adhesive
CN103173132A (en) * 2013-02-26 2013-06-26 安徽明珠颜料科技有限公司 High-performance adhesive for shoemaking

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102676099A (en) * 2012-05-25 2012-09-19 太仓市新星轻工助剂厂 Multipurpose quick-drying adhesive and preparation method thereof
CN103173134A (en) * 2013-02-26 2013-06-26 安徽明珠颜料科技有限公司 Solvent-based neoprene adhesive
CN103173132A (en) * 2013-02-26 2013-06-26 安徽明珠颜料科技有限公司 High-performance adhesive for shoemaking

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
宋后昆: ""一种万能胶粘剂制作技术"", 《中小企业科技》 *

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Application publication date: 20180928