CN102673054A - Sound reducing polymer interlayers - Google Patents

Sound reducing polymer interlayers Download PDF

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Publication number
CN102673054A
CN102673054A CN2012101747836A CN201210174783A CN102673054A CN 102673054 A CN102673054 A CN 102673054A CN 2012101747836 A CN2012101747836 A CN 2012101747836A CN 201210174783 A CN201210174783 A CN 201210174783A CN 102673054 A CN102673054 A CN 102673054A
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polymer sheet
polymer
plasticising
vinyl butyral
plasticizer
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CN102673054B (en
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卢琼恩
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Solutia Inc
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Solutia Inc
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/02—2 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2274/00—Thermoplastic elastomer material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/10—Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31627—Next to aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31627—Next to aldehyde or ketone condensation product
    • Y10T428/3163—Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31942—Of aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31942—Of aldehyde or ketone condensation product
    • Y10T428/31946—Next to second aldehyde or ketone condensation product

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  • Laminated Bodies (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Sound reducing polymer interlayers are provided. The present invention is in the field of polymer interlayers and multiple layer glass panels comprising polymer interlayers, and, more specifically, the present invention is in the field of polymer interlayers comprising multiple thermoplastic sheets.

Description

Lower the Polymer interlayers of sound
The application is that international application no is that to get into national applications that the China national stage obtains number be 200680008118.2 to PCT/US2006/009665, international filing date to be on March 16th, 2006, denomination of invention be the dividing an application of the application for a patent for invention of " lowering the Polymer interlayers of sound ", original application.
Technical field
The present invention relates to Polymer interlayers and comprise the compound glass plate field of Polymer interlayers, and more specific, the present invention relates to comprise a plurality of thermal plasticity slices' Polymer interlayers field.
Background of invention
Gather (vinyl butyral) (PVB) be generally used for making can be in photic zone compound (for example safety glass or polymeric layer compound) as the polymer sheet layer compound in intermediate layer.Safety glass typically refers to transparent laminate, and it comprises to place and gathers (vinyl butyral) sheet between two sheet glass.Safety glass is through being commonly used to for building and automobile door and window transparent barrier to be provided.It mainly acts on is to absorb energy, and the energy that is for example produced by object strikes makes glass fragment can not penetrate door and window or distribution, thereby farthest reduces destruction or injury to object or person in the closed area.Safety glass also can be in order to provide other beneficial effect, for example weakens noise, reduces UV and/or the transmission of IR light and/or strengthen the outward appearance of window and attractive in appearance.
Existing thermoplastic polymer can for example gather (vinyl butyral) by monolayer thermoplastic property polymer in the safety glass) to form, its one or more improvement physical characteristic has seen through the transmission percentage of this glass with reduction sound through change.Routine trial to this type of sound attenuating comprises the thermoplastic polymer that use has lower glass transition temperatures.Other trial comprises uses two adjacent thermoplastic polymer layers, and wherein these layers have different characteristic (referring to No. the 5th, 340,654, United States Patent (USP) for example and the 5th, 190, No. 826 and U.S. Patent application 2003/0139520A1 number).
Need further through improved composition and method to strengthen the compound glass plate, especially to comprise the muffler acoustic attenuation property of the compound glass plate that gathers (vinyl butyral) layer, be easy to processing simultaneously and can not have a negative impact optical property.
Summary of the invention
The present invention provides and can be used for the application of compound glass plate class to reduce the multilayer intermediate layer of transmission through the sound quantity of this plate.This effect realizes through in two or more polymer sheets that have been combined as single multilayer intermediate layer, keeping the difference of plasticizer concentration.
Detailed Description Of The Invention
According to the present invention, be surprised to find at present, can give this plate good sound rejection characteristic through the multilayer intermediate layer being included in the compound glass plate, wherein said intermediate layer comprises two polymer sheets with different plasticizer concentrations.As this paper sets forth in full in detail, stably to comprise different plasticizers concentration, have now found that the sound that can make transmission see through the compound glass plate reduces for example more than 2 decibels in interested frequency or frequency field through the allotment polymer sheet.Further; Owing to the embodiment with three polymer sheet layer can make easy operating and can be used as the direct replacement in the conventional intermediate layer in the conventional method through allotment, need not use used manufacturing approach so intermediate layer of the present invention can be used for various application and not make any change these.For example, in the application facet of windshield, can comprise with intermediate layer of the present invention replacing the conventional polymer intermediate layer and need not to change the laminating method that is used to form final windshield.
" intermediate layer " used herein is any thermoplastic construction that can be used for the safety glass in compound glass application examples such as windshield and the construction window; " multilayer " intermediate layer is through the layer combination that two or more are independent; Usually through the laminating method combination, become single intermediate layer and any intermediate layer of forming.
In each embodiment of the present invention, the multilayer intermediate layer comprises two polymer sheets that are set to contact with each other, and wherein each polymer sheet all comprises thermoplastic polymer, as other local detailed description of this paper.Thermoplastic polymer in each sheet can be identical or different.In these embodiments, have each polymer sheets of different plasticizer loadings through manufacturing, then this two-layerly is laminated together to form single multilayer intermediate layer, and gives this intermediate layer sound attenuation.The composition of these polymer sheets can make plasticizer can ignore or be zero from the net migration amount of polymer sheet to another polymer sheet, keeps plasticizer differential by this.
" plasticizer loading " used herein can be weighed by the umber (phr) of per 100 parts of resins in the w/w benchmark.For example, if 30 gram plasticizer are made an addition in the 100 gram fluoropolymer resins, then the plasticizer loading of gained plasticized polymer should be 30phr.As this paper was in full employed, when providing the plasticizer loading of polymer sheet, the plasticizer loading of this concrete sheet was that the phr according to the melt plasticizer that is used for preparing this concrete sheet confirms.
For the sheet of plasticizer loading the unknown, can measure plasticizer loading via wet chemical method, wherein The suitable solvent or solvent mixture are used to from sheet, extract plasticizer.Weight through obtaining sample strip and through the weight of the sheet of extraction can be calculated plasticizer loading (representing with phr).Under the situation of two polymer sheet interlayer, earlier a polymer sheet is separated with physics mode with another sheet, measure the plasticizer loading of each polymer sheet then.
In each embodiment of the present invention, the plasticizer loading of two polymer sheets differs 8phr, 10phr, 12phr, 15phr, 18phr, 20phr or 25phr at least.Each sheet for example can contain 30 to 100phr, 40 to 90phr or 50 to 80phr.
In each embodiment of the present invention, the residual hydroxyl content of the thermoplastic polymer component of polymer sheet is different, and this makes can make the sheet with stabilizing plasticizer difference.Residual hydroxyl content used herein (like vinyl hydroxyl content or gather (vinyl alcohol) (PVOH) content) is meant and machines the hydroxyl quantity that keeps as side group on the polymer chain of back.For example, gathering (vinyl butyral) can be hydrolyzed to and gather (vinyl alcohol) through gathering (vinyl acetate), gathers (vinyl alcohol) then and forms with the butyraldehyde reaction and gather (vinyl butyral) preparation.In gathering (vinyl acetate) hydrolytic process, be not that all acetic acid esters side groups all change into hydroxyl usually.In addition, the reaction with butyraldehyde can not make all hydroxyls all change into acetal groups usually.Therefore, finally gather in (vinyl butyral), on polymer chain, have residual acetate group (vinyl acetate groups) and residual hydroxy groups (vinyl hydroxy) usually as side group any.Residual hydroxyl content used herein is to measure with the percetage by weight benchmark according to ASTM 1396.
In each embodiment of the present invention, the residual hydroxyl content of two adjacent polymer sheet can differ at least 1.8%, 2.0%, 2.2%, 2.5%, 3.0%, 4.0%, 5.0%, 7.5% or at least 10%.The residual hydroxyl content that deducts the sheet with low residual hydroxyl content through the residual hydroxyl content from sheet with higher residual hydroxyl content is calculated this difference.For example, if first polymer sheet has the residual hydroxyl content of 20 weight %, second polymer sheet has the residual hydroxyl content of 17 weight %, and then the residual hydroxyl content of two sheets differs 3 weight %.
For the plasticizer of given type, the compatibility of gathering this plasticizer in (vinyl butyral) is determined by hydroxy radical content to a great extent.Usually, have gathering (vinyl butyral) and will reducing plasticizer compatbility or capacity of big residual hydroxyl content.Equally, have gathering (vinyl butyral) and will increasing plasticizer compatbility or capacity of low residual hydroxyl content.These character can be used for selecting respectively to gather the hydroxy radical content of (vinyl butyral) polymer and allocate each polymer sheet to allow the difference of plasticizer loading between suitable plasticizer addition and these polymer sheets of stable maintenance.
As as known in the art, can control residual hydroxyl content through other variable in control reaction time, reactant concentration and the manufacturing approach.In each embodiment, the residual hydroxyl content of two sheets is as follows: first less than 25% and second less than 23%; First less than 23% and second less than 21%; First less than 21% and second less than 19%; First less than 20% and second less than 17%; First less than 18% and second less than 15%; First less than 15% and second less than 12%.In arbitrary these embodiments, can use in aforementioned paragraphs to the given any value of hydroxy radical content difference between two layers.
As used herein, tensile break stress of polymer sheet (tensile break stress) or tensile strength define and measure according to the method that is set forth among the JIS K6771.In each embodiment of the present invention; Two polymer sheets have following tensile break stress, wherein below first polymer sheet in the tabulation be the polymer sheet that has than low plasticizer content: first polymer sheet greater than 135 kilograms/square centimeter and second polymer sheet less than 120 kilograms/square centimeter; First polymer sheet greater than 150 kilograms/square centimeter and second polymer sheet less than 135 kilograms/square centimeter; First polymer sheet greater than 165 kilograms/square centimeter and second polymer sheet less than 150 kilograms/square centimeter; Or first polymer sheet greater than 180 kilograms/square centimeter and second polymer sheet less than 165 kilograms/square centimeter; Or the tensile break stress of common two polymer sheets differs at least 15 kilograms/square centimeters.
Conventional laminated glass used herein forms through the conventional intermediate layer that lamination is generally used for commercially available laminated glass at present, and wherein said conventional intermediate layer has 200 kilograms/square centimeter or higher tensile break stress.For purposes of the present invention, conventional laminated glass is called " reference layer compound plate " or " reference plate ".
The sound insulation that is used for characterizing the glassy layer compound that is made up of intermediate layer of the present invention improves the reference layer compound plate of setting forth with reference to above paragraph and confirms.In having the typical layers compound of two glass outer layer, " thickness of glass of combination " is the summation of layer glass thickness; Have three layers or more in the more complicated layer compound of compound glass, the thickness of glass of combination should be three layers or the summation of compound glass more.
For purposes of the present invention, " coincidence frequency (coincident frequency) " to be fingerboard show the frequency that plunges sound transmission loss (dip) locate because of " coincidence effect (coincident effect) ".The coincidence frequency of reference plate is usually between 2,000 to 6,000 hertz, and the monolithic glass sheet that can be empirically equals to merge in the reference plate thickness of glass by thickness is confirmed from following algorithm
f c = 15,000 d
Wherein " d " is total glass thickness and the " f that representes with millimeter c" unit is hertz.
For purposes of the present invention, can measure the improvement of acoustical behavior through the increase of locating sound transmission loss in the coincidence frequency (with reference to frequency) of reference plate.
For layer compound of the present invention with fixed dimension or conventional reference plate, " sound transmission loss " measured according to ASTM E90 (95) under 20 ℃ of fixed temperatures.
In each embodiment of the present invention; When being laminated between two sheet glass plates; Multilayer of the present invention intermediate layer is compared with suitable the compared reference plate in multilayer of the present invention intermediate layer with having single conventional intermediate layer and thickness, reduces at least 2 decibels of the transfer voice (dB) that see through this laminated glass pane.
In each embodiment of the present invention; When intermediate layer of the present invention is laminated between two sheet glass; Compare with comparable reference plate; Intermediate layer of the present invention with reference to improve under the frequency at least 2 decibels of sound transmission loss, more preferably 4 decibels and even more preferably 6 decibels or more, for example 8 decibels or more.
The trial that prior art production comprises in order to the adjacent polymer sheet intermediate layer that reduces the transfer voice that sees through the compound glass plate depends on the various compositions arrangements between these sheets.Instance comprises United States Patent (USP) the 5th, 190, and No. 826, the acetal of different carbon length is used in its instruction, and different polymerization degree is used in 2003/0139520A1 number instruction of Japanese patent application 3124441A and U.S. Patent application.Two other application cases, Japan Patent the 3rd, 377,848 and United States Patent (USP) the 5th, 340,654 be taught in use at least 5 moles of % among of two adjacent sheet residual acetate content as forming difference.
In each embodiment of the present invention; And obviously be different from used approach in these application; Two adjacent polymer sheet of the present invention have above-mentioned different plasticizers content, and each sheet further has less than 5 moles of %, less than 4 moles of %, less than 3 moles of %, less than 2 moles of % or less than the residual acetate content of 1 mole of %.These residual acetate concentration can with the above-mentioned residual hydroxyl content combination in any that provides forming two polymer sheets of the present invention, these sheets have described plasticizer loading and residual hydroxyl content difference and have less to there not being residual acetate content simultaneously.Other embodiment in multilayer of the present invention intermediate layer comprises the intermediate layer with two above polymer sheets, and wherein one or more said extra polymer sheets have less than 5 moles of %, less than 4 moles of %, less than 3 moles of %, less than 2 moles of % or less than the residual acetate content of 1 mole of %.
Further embodiment of the present invention comprises arbitrary above-mentioned embodiment, and these embodiments further comprise and are set up the polymer sheet that contacts with the polymer sheet with higher plasticizer loading.The increase of this polymer lamella produces the three-layer structure with following structure: have first polymer sheet of relative low plasticizer content // have, the second polymer sheet // polymer sheet of highly plasticized relatively agent content.This polymer sheet can have the composition identical with first polymer sheet, or they can be different.
In a plurality of embodiments; Polymer sheet has the composition identical with first polymer sheet; This provides a kind of like this three laminated intermediate layers; Its reluctant relatively polymer sheet is laminated between two easy-to-handle relatively, obtains to be easy to relatively handle and can directly include in the multilayer intermediate layer of existing method thus, the previous composition that uses two outer polymer sheets with intermediate layer of the present invention of this existing method; Or has a single polymers sheet of the composition that causes similar treatment characteristic (for example, adhesion tendency).
In single intermediate layer, utilize in the embodiment of three polymer sheets at other; Polymer sheet has the composition that is different from first polymer sheet, and the composition difference between the polymer sheet and second polymer sheet can be any above-mentioned given difference of difference that is directed against between first polymer sheet and second polymer sheet.For example, an exemplary can be: have second polymer sheet of first polymer sheet of 20% residual hydroxyl content // have, 16% residual hydroxyl content // the have polymer sheet of 18% residual hydroxyl content.It should be noted that in this example polymer sheet is different from second polymer sheet because of the residual hydroxyl content that it has than the hydroxy radical content big 2% of second polymer sheet at least.Certainly, mentioned any other difference of this paper full text can separately or be united to distinguish polymer layer and the second polymer layer.
Except that three layers of embodiment described herein; Other embodiment comprises the intermediate layer that has more than three layers; Wherein can use the sheet of other low residual hydroxy groups, for example have plasticizer loading and the hydroxy radical content of alternate and the repetition (iteration) of the polymer sheet of the lower or insignificant residual acetate content of choosing wantonly of alternate.The intermediate layer that forms in this way for example can have 4,5,6 or up to 10 independent layer.
Can include other conventional layer as known in the art in intermediate layer of the present invention.For example; Thin polymer film (in other local elaboration in detail of this paper) with metal layer, infrared external reflection lamination or other deposition performance layer on it for example gathers (ethylene glycol terephthalate) like polyester, can be included in and appoint between the two-layer polymer sheet of the present invention.For example, in two-layer embodiment, can make intermediate layer: have the polyester film of the polymer sheet of highly plasticized relatively agent content // have performance layer // the have polymer sheet of relative low plasticizer content with following layout.Usually, according to the result and concrete application of expectation, can add the thermoplasticity extra play to multilayer of the present invention intermediate layer as gathering (vinyl butyral), polyester film, bottom (primer layers) and hard conating.
In each embodiment of the present invention, through using the coextrusion method, the single polymers sheet can realize that the peculiar same sound of two polymer sheet interlayer with different plasticizer loadings reduces effect.As well known in the art, coextrusion can be used for being formed on the single polymers sheet that has the zone in the sheet, wherein each regional shape approximation shape that independent layer is had when using a plurality of.For each intermediate layer embodiment of the present invention; Wherein two or more separate polymer sheets are set to contact with each other and subsequent layer is pressed into single intermediate layer; Also have such embodiment, wherein the polymer sheet of coextrusion has two or more zoness of different corresponding to layer independent in the lamination of the present invention intermediate layer.In addition, with coarctate each the compound glass plate of separate polymer lamella, prepare the method and the method for preparing compound glass plate of the present invention in intermediate layer, also have the similar embodiment of using the coextrusion polymer sheet to replace the multilayer intermediate layer for wherein.
Except that the intermediate layer that this paper provided, the present invention also provides the method that lowers the sound level that sees through opening, and this method is included in the step that the compound glass plate that comprises arbitrary intermediate layer of the present invention is set in the opening.
The present invention also comprises the method for making the intermediate layer; The method includes the steps of: form first polymer sheet and second polymer sheet; Wherein as other local elaboration of this paper; Two polymer sheets have different compositions, and these two polymer sheets are laminated together to form the intermediate layer.
The present invention also comprises the method for making the intermediate layer; This method may further comprise the steps: the step that forms first polymer sheet, second polymer sheet and polymer sheet; Wherein these three polymer sheets have the composition corresponding to other local three layers of embodiments being set forth of this paper, and these three polymer sheets are laminated together to form the intermediate layer.
The present invention also comprises the method for making multilayer glazing (glazing), and it comprises arbitrary intermediate layer of the present invention is laminated to two rigid transparent plates known in the art, for example between glass or the acrylic.
The present invention also comprises the compound glass plate that contains multilayer of the present invention intermediate layer, for example windshield and construction window.
The present invention also comprises the compound glass plate that contains multilayer of the present invention intermediate layer, for example windshield and construction window.Also comprise and contain plastics such as acrylic resin or other multilayer glazing plate (glazing panel) for the suitable material of glass plate.
Thin polymer film
" thin polymer film " used herein has been meant the relative thin of performance enhancement layer effect and the polymeric layer of rigidity.Thin polymer film is different from polymer sheet used herein; Reason is that thin polymer film self can not provide essential penetration-resistant and glass retention properties for multilayer glazing structure (glazing structure), and the improvement in performance such as infrared absorption characteristic only is provided.Gather (ethylene glycol terephthalate) the most frequently used thin polymer film of doing.
In each embodiment, thin polymer film has 0.013 millimeter to 0.20 millimeter, the thickness of preferred 0.025 millimeter to 0.1 millimeter or 0.04 to 0.06 millimeter.Thin polymer film can be randomly through surface treatment or coating to improve one or more character, for example adhesiveness or infrared radiation reflection.These functional performance layers comprise that for example multilayer laminated, it is used for reflective infrared solar radiation and visible light transmissive when being exposed to sunshine.This is multilayer laminated to be well known in the art (referring to for example WO 88/01230 and United States Patent (USP) the 4th; 799, No. 745) and can comprise (optically cooperating) dielectric layer of the Collaboration optically of metal level that for example one or more dust is thick and one or more (for example two) sequential aggradation.As also well-known that kind (referring to United States Patent (USP) for example the 4th, 017, No. 661 and the 4th, 786, No. 783), can choose wantonly with of the defrosting or the demist of resistance mode heating of metal layer to be used for any relevant glassy layer.
The thin polymer film that can be used for another type of the present invention is set forth in United States Patent (USP) the 6th, 797, and in No. 396, it has comprised the infrared reflecting effect and a plurality of non-metallic layers of the interference that do not produce metal level and caused.
In some embodiments; Thin polymer film is optically transparent (promptly the object of contiguous this layer side can be seen through eyes through the particular observer of this layer observation from opposite side fully); And regardless of forming; Usually it is bigger to have more any adjacent polymer sheet, remarkable in certain embodiments bigger stretch modulus.In each embodiment, polymer film layer contains thermoplastic.What in thermoplastic, have suitable character is nylon, polyurethane, acrylic resin, Merlon, polyolefin (for example polypropylene), cellulose acetate and Triafol T, vinyl chloride-base polymer and copolymer, or the like.In each embodiment, thin polymer film comprises the material of the film of stretched thermoplastic again that for example has pointed character, and it comprises polyester, for example gathers (ethylene glycol terephthalate) and gathers (ethylene glycol terephthalate) glycol (PETG).In each embodiment; Use gathers (ethylene glycol terephthalate); And in many embodiments; PETG through biaxial stretch-formed improving intensity, and through thermally-stabilised with provide when the temperature that stands to raise low shrinkage character (for example, in 150 ℃ after following 30 minutes in the contraction of both direction all less than 2%).
The various coatings that gather (ethylene glycol terephthalate) film that can use with the present invention and process for treating surface are set forth in No. the 0157030th, the disclosed European application.Thin polymer film of the present invention also can comprise hard conating well known in the art and/or anti-fog layer.
Polymer sheet
" polymer sheet " used herein is meant any thermoplastic polymer composition that forms thin layer through any proper method, and it is suitable for individually or is used as layer with the lamination form more than one deck closing the intermediate layer that the glazing plate provides enough penetration-resistants and glass delay character.Plasticising gathers (vinyl butyral) and is most commonly used to form polymer sheet.
Polymer sheet can comprise any suitable polymer, and in preferred embodiments, polymer sheet comprises and gathers (vinyl butyral).Gather in (vinyl butyral) embodiment of the present invention in given the comprising of arbitrary this paper, comprise that wherein polymeric components forms or mainly by gathering another embodiment that (vinyl butyral) formed by gathering (vinyl butyral) as the polymeric components of polymer sheet.In these embodiments, any change of additive disclosed herein all can be used for containing by gathering (vinyl butyral) and forms or mainly by the polymer sheet that gathers the polymer that (vinyl butyral) form.
In one embodiment, polymer sheet comprises the polymer that gathers (vinyl alcohol) based on the part acetalation.In another embodiment, polymer sheet comprise be selected from gather (vinyl butyral), polyurethane, polyvinyl chloride, gather (ethylene vinyl acetate) and the combination or the like polymer.In other embodiments, polymer sheet comprises gather (vinyl butyral) of plasticising.In further embodiment, polymer sheet comprises and gathers (vinyl butyral) and one or more other polymer.Also can use other to have the polymer of suitable plasticising capacity (plasticizing capacity).Providing the specific any paragraph of this paper that is used for gathering preferable range, numerical value and/or the method (such as but not limited to plasticizer, component percentage, thickness and characteristic enhancement additive) of (vinyl butyral); In the time can using, those scopes also are applicable to other polymer and the blend polymer that can be used as the polymer sheet component that this paper discloses.
The embodiment of gathering (vinyl butyral) for comprising; Gathering (vinyl butyral) can be through known acetalation method preparation; This method be included in make under the existence of acid catalyst gather (vinyl alcohol) with the butyraldehyde reaction, subsequently neutralize this catalyst, separate, stable and dry this resin; It should be understood that and as other local elaboration of this paper, to control residual hydroxyl content in many embodiments.
In each embodiment, polymer sheet comprises that molecular weight is greater than 30,000,40,000,50; 000,55,000,60,000,65,000,70; 000, the gathering of 120,000,250,000 or 350,000 gram/moles (g/mol or dalton) (vinyl butyral).Also can add a small amount of dialdehyde or three aldehyde during the acetalation step so that molecular weight increases to greater than 350 dalton (referring to No. the 4th, 874,814, United States Patent (USP) for example; The 4th, 814, No. 529; And the 4th, 654, No. 179).Term used herein " molecular weight " is meant weight average molecular weight.
If except that the above-mentioned any embodiment with plasticizer loading difference of this paper, use extra conventional polymer sheet, these extra conventional polymer sheets can comprise 20 to 60,25 to 60,20 to 80 or 10 to 70 parts of plasticizer/100 part resins (phr).Certainly, also can use other quantity for concrete application if suit.In certain embodiments, plasticizer has and is less than 20, is less than 15, is less than 12 or be less than the hydrocarbon segment of 10 carbon atoms.
Any suitable plasticizer can be added into fluoropolymer resin of the present invention to form polymer sheet.Used plasticizer especially can comprise the ester of polyacid or polyalcohol in the polymer sheet of the present invention.The plasticizer that is fit to comprises for example mixture, diisononyl adipate, adipic acid enanthol nonyl alcohol ester, the dibutyl sebacate of triethylene glycol two-(2 Ethylbutanoic acid ester), triethylene glycol two-(2 ethyl hexanoic acid ester), triethylene glycol two heptanoates, tetraethylene glycol bis-enanthate, dihexyl adipate, dioctyl adipate, adipic acid hexanol hexamethylene alcohol ester, adipic acid heptyl ester and adipic acid ester in the ninth of the ten Heavenly Stems; The decanedioic acid alkyd resins of polymeric plasticizer such as oily modification; The mixture of phosphate and adipate ester (for example is disclosed in United States Patent (USP) the 3rd; 841; Person in No. 890) and adipate ester (for example be disclosed in United States Patent (USP) the 4th; Person in 144, No. 217), reach the mixture and the combination of above-mentioned substance.Spendable other plasticizer is by C 4To C 9Alkylol and ring C 4To C 10Mixed adipate ester that alcohol is processed (as be disclosed in United States Patent (USP) the 5th, 013, No. 779 in person) and C 6To C 8Adipate ester (the for example own ester of adipic acid).In preferred embodiments, plasticizer is triethylene glycol two-(a 2 ethyl hexanoic acid ester).
Also can comprise adhesiveness controlling agent (ACA) in the polymer sheet of the present invention to give the adhesiveness of expectation.For example, in three polymer sheet embodiments, can these reagent be included in the outer plate.Can use any in United States Patent (USP) the 5th, 728, disclosed ACA in No. 472.In addition, residual sodium acetate and/or potassium acetate can be regulated through the amount that changes used hydrogen related oxide in the acid neutralization.In each embodiment, polymer sheet of the present invention also comprises two (2 Ethylbutanoic acid) magnesium (chemical abstracts 79992-76-0) except that comprising sodium acetate.Can comprise the said magnesium salts of effective control polymer sheet to the amount of the adhesion of glass.
Can include additive in the polymer sheet, to strengthen its performance in final products.As well known in the art, these additives include but not limited to combination of plasticizer, dyestuff, pigment, stabilizing agent (for example, UV stabilizer), anti-oxidant, fire retardant, other IR absorbent, antiblocking agent, above-mentioned additive or the like.
The reagent that selectivity absorbs light in visible or the near infrared spectrum can add in any suitable polymer sheet.Spendable reagent comprises dye well pigment, for example tin indium oxide, antimony tin or lanthanum hexaboride (LaB 6).
Any proper method all can be used for preparing polymer sheet of the present invention and multilayer intermediate layer.Those skilled in the art have known the details that is used for preparation and gathers the appropriate methodology of (vinyl butyral) (referring to United States Patent (USP) for example the 2nd, 282, No. 057 and the 2nd, 282, No. 026).In one embodiment, can use the solvent method that is set forth among the Vinyl Acetal Polymers (in Encyclopedia of Polymer Science & Technology, the 3rd edition, the 8th rolls up 381-399 page or leaf, B.E.Wade (2003)).The aqueous process that in another embodiment, can use wherein to be set forth.Gathering (vinyl butyral) can be purchased with various forms, for example with Butvar TMResin is available from Solutia Inc., St.Louis, Missouri.
" resin " used herein is meant polymer (for example gathering (the vinyl butyral)) component of the mixture removal that from reach subsequently by acid catalysis, is produced with polymer precursor.Resin has other component, for example acetic acid esters, salt and alcohol usually except that polymer (for example gathering (vinyl butyral))." melt " used herein is meant that resin and plasticizer reach the mixture of other optional additive.
A kind of illustrative methods that formation gathers (vinyl butyral) layer comprises gather (vinyl butyral) of extruding the fusion that contains resin, plasticizer and additive; And make this melt (for example pass the sheet die head subsequently; Die head with opening, this opening the size of a direction significantly greater than with the size of its orthogonal direction).Another illustrative methods that formation gathers (vinyl butyral) layer comprises melt is cast on the roller from die head, solidifies this resin and removes the resin of this curing subsequently as sheet.In any of two embodiments, superficial makings (surface texture) laminated or the two sides all can be controlled through the surface of adjustment die openings or through on the roller surface texture being set.Other technology that is used for the key-course texture comprises the parameter that changes material (for example, the water content of resin and/or plasticizer, melt temperature, gather the molecular weight distribution of (vinyl butyral) or the combination of above-mentioned parameter).And, can said layer be configured to comprise the space protrusion that limits temporary transient surface irregularity that so that in lamination process, promote the degassing of said layer, subsequently, the high temperature of laminating method and high pressure make convexity be fused in the layer, obtain smooth result thus.
Can realize the manufacturing in multilayer intermediate layer through using techniques well known in the art, three layers of for example independent preparation polymer sheet, down that these three sheets are laminated together to obtain single multilayer intermediate layer at suitable condition (for example pressure and heating) then.
Can prepare the polymer sheet that comprises zone of the present invention through any method well known in the art with different plasticizer loadings.In typical method, can independently form two or more melt that comprises fluoropolymer resin, plasticizer and any desired additive and coextrusion, have single polymers sheet with formation corresponding to the zone of used each melt.For example; But coextrusion has first melt of regulation plasticizer loading and plasticizer loading has first area and second area with formation than second melt of the little 20phr of plasticizer loading of first melt polymer sheet; Each zone all is similar to the shape of independent sheet, and wherein the plasticizer loading of second area is stably than the little 20phr of plasticizer loading of first melt.
In each embodiment, intermediate layer of the present invention can have 0.1 to 2.5 millimeter, 0.2 to 2.0 millimeter, 0.25 to 1.75 millimeter, reach the gross thickness of 0.3 to 1.5 millimeter (mm).The separate polymer sheet in multilayer intermediate layer can have for example approximately equalised thickness, when adding together, obtains the given total thickness of preceding text.Certainly, in other embodiments, the thickness of these layers can be different, but still the gross thickness that can add and provide to preceding text.
The above-mentioned parameter that is used for polymer sheet also can be applicable to the arbitrary layer that gathers (vinyl butyral) type layer of multi-ply construction of the present invention.
Following paragraph is set forth the various technology that can be used for improving and/or measuring the polymer sheet characteristic.
Polymer sheet particularly gathers the transparency of (vinyl butyral) layer, can confirm through measuring haze value, and haze value is when incident beam quantification from the quantity of the light of incident beam direction scattering during through this layer.Can measure percent haze according to following technology.But operative installations D25 type Hazemeter, (Reston VA), uses light source C to measure haze value with 2 degree viewing angles according to ASTM D1003-61 (checking and approving again in 1977)-program A available from Hunter Associates.In each embodiment of the present invention, percent haze is less than 5%, less than 3% and less than 1%.
Can use UV-Vis-NIR spectrophotometer (the for example Lambda 900 of Perkin Elmer manufactured) to quantize transmission of visible light through the method for setting forth among the international standard ISO 9050:1990.In each embodiment, the transmissivity that sees through polymer sheet of the present invention is at least 60%, at least 70% or at least 80%.
Can impact adhesiveness (pummel adhesion) according to following commercial measurement, wherein " impact " and be used to quantize the adhesiveness of polymer sheet to glass in this article, following technology is used for confirming pummel.Double glazing layer laminate samples is under the pressure heat lamination condition of standard, to process.Being cooled to these layers compound approximately ,-18 ℃ (0 ℉) also beats to glass broken with the hammer manual work.Remove all then and do not adhere to the cullet that gather (vinyl butyral) layer, and the remaining quantity range estimation ground that adheres to the glass that gathers (vinyl butyral) layer is compared with series of standards.These standards keep adhering to the grade of gathering on (vinyl butyral) layer corresponding in various degree glass wherein.Particularly, pummel is that null representation does not have remaining glass to adhere to gather on (vinyl butyral) layer.Pummel is that the glass of 10 expressions 100% keeps adhering to gathering on (vinyl butyral) layer.Of the present invention gathering (vinyl butyral) layer can have for example 3 to 10 pummel value.
Can confirm the tensile break stress of polymer sheet according to the program among the JIS K6771 of being set forth in.
Embodiment
Gather (vinyl butyral) sheet with what 3GEH (triethylene glycol two-(2 ethyl hexanoic acid the ester)) allotment of different amounts had a pointed residual hydroxyl content, their sheet thickness is listed in the table below in 1.These sheets are used to construct intermediate layer of the present invention or are used to make reference plate as conventional intermediate layer.In all sheets, residual acetate content all can be ignored and all less than 1 mole of %.
Table 1. gathers (vinyl butyral) sheet
Figure BSA00000726369800131
The embodiment in conventional intermediate layer and intermediate layer of the present invention lists in table 2
Table 2
*The intermediate layer is stored under low temperature (common 10 ℃) or the room temperature (common 20 to 23 ℃).
Conventional laminated glass is reference plate and all is showed in the following table 3 by the embodiment of the laminated glass that constitutes with respect to the significantly improved intermediate layer of reference plate acoustical behavior.
Table 3
Figure BSA00000726369800151
*The glassy layer compound comprises the sheet glass plate of two symmetries, and promptly each sheet glass has identical thickness.
*The STL=sound transmission loss.
According to the present invention, can provide now and reduce transfer voice and be easy to handle and be easy to include in the multilayer intermediate layer of multi-ply construction like the laminated glass pane that is used for windshield and construction window.
Although explained the present invention with reference to exemplary, it will be understood by a person skilled in the art that, can make multiple change and available its equivalent terms to these embodiments and substitute its key element and do not deviate from scope of the present invention.In addition, also can implement a lot of modifications and not deviate from base region of the present invention for adapting to concrete condition or material instruction of the present invention.Therefore, this paper is intended to the present invention is limited to disclosed particular as the best contemplated mode of embodiment of the present invention, but is intended to make the present invention to contain the embodiment that all are in the appended claim scope.
Should further understand; Any scope, numerical value or the characteristic that provide to any single component of the present invention; As if compatible, can exchange use with any scope that provides to any other component of the present invention, numerical value or characteristic and each given component of this paper full text all had the embodiment that limits numerical value to form.For example, can also form the polymer sheet that comprises residual acetate content with any given range (if suitable), to form many belonging in the scope of the invention but the arrangement that need not give unnecessary details except any scope that provides to plasticizer is.
The summary or any claim in given any Reference numeral only should not be construed as for illustrative purposes invention required for protection is limited to arbitrary in the specific embodiments shown in any figure.
Except as otherwise noted, otherwise these figure draw in proportion.
Each list of references of this paper institute reference comprises that journal article, patent, patent application and books all are incorporated herein with the mode that its integral body is quoted.

Claims (26)

1. the Polymer interlayers of a coextrusion comprises: the ground floor that gathers (vinyl butyral) that comprises plasticising; The second layer that gathers (vinyl butyral) that comprises plasticising; At least 10 parts greatly/100 parts of the amounts of plasticizer in the more said ground floor of the amount of plasticizer in the wherein said second layer; The residual hydroxyl content as expressed in weight percent of the more said ground floor of residual hydroxyl content as expressed in weight percent that the wherein said second layer had is low by at least 2%, and the wherein said ground floor and the said second layer contact with each other and wherein said ground floor and the said second layer respectively have the residual acetate content less than 5 moles of %; With the polymer layer that is set to contact with said the second polymer layer; Wherein said polymer layer comprises gather (vinyl butyral) of plasticising; At least 10 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the said plasticising that gathers the more said polymer layer of amount of plasticizer in (vinyl butyral) of the said plasticising of wherein said the second polymer layer; Wherein plasticizer loading is weighed by the umber of per 100 parts of resins in the w/w benchmark, and residual hydroxyl content is to measure with the percetage by weight benchmark according to ASTM 1396.
2. the Polymer interlayers of the coextrusion of claim 1, at least 15 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the said plasticising that gathers more said first polymeric layer of amount of plasticizer in (vinyl butyral) of the said plasticising of wherein said the second polymer layer.
3. the Polymer interlayers of the coextrusion of claim 1; Less than 150 kilograms/square centimeter, measure according to the method that is set forth among the JIS K6771 by tensile break stress greater than the tensile break stress of 165 kilograms/square centimeter and said the second polymer layer for the tensile break stress of wherein said first polymeric layer.
4. the Polymer interlayers of the coextrusion of claim 1; Less than 165 kilograms/square centimeter, measure according to the method that is set forth among the J1S K6771 by tensile break stress greater than the tensile break stress of 180 kilograms/square centimeter and said the second polymer layer for the tensile break stress of wherein said first polymeric layer.
5. the Polymer interlayers of the coextrusion of claim 4, the residual hydroxyl content as expressed in weight percent of more said first polymeric layer of residual hydroxyl content as expressed in weight percent that wherein said the second polymer layer had low at least 4%.
6. the Polymer interlayers of the coextrusion of claim 1, the residual hydroxyl content as expressed in weight percent of more said first polymeric layer of residual hydroxyl content as expressed in weight percent that wherein said the second polymer layer had low at least 8%.
7. the Polymer interlayers of the coextrusion of claim 1, wherein said the second polymer layer have as expressed in weight percent have less than 17.0% residual hydroxyl content and said first polymeric layer as expressed in weight percent less than 20% residual hydroxyl content.
8. a Polymer interlayers comprises: first polymer sheet that gathers (vinyl butyral) that comprises plasticising; Second polymer sheet that gathers (vinyl butyral) that comprises plasticising, wherein said second polymer sheet contacts with said first polymer sheet; The polymer sheet of gathering (vinyl butyral) that comprises plasticising, wherein said polymer sheet contacts with said second polymer sheet; At least 12 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers (vinyl butyral) or said polymer sheet that gathers the plasticising of more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet; More said first polymer sheet of residual hydroxyl content as expressed in weight percent that wherein said second polymer sheet is had or the residual hydroxyl content as expressed in weight percent of said polymer sheet low at least 2%; And wherein said first polymer sheet and said second polymer sheet respectively have the residual acetate content less than 5 moles of %; Wherein plasticizer loading is weighed by the umber of per 100 parts of resins in the w/w benchmark, and residual hydroxyl content is to measure with the percetage by weight benchmark according to ASTM 1396.
9. the intermediate layer of claim 8, at least 15 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers (vinyl butyral) or said polymer sheet that gathers the plasticising of more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet.
10. the intermediate layer of claim 9, at least 18 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers (vinyl butyral) or said polymer sheet that gathers the plasticising of more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet.
11. the intermediate layer of claim 9, at least 20 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers (vinyl butyral) or said polymer sheet that gathers the plasticising of more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet.
12. the intermediate layer of claim 9, at least 25 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers (vinyl butyral) or said polymer sheet that gathers the plasticising of more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet.
13. the intermediate layer of claim 9, wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 25% separately, and said second polymer sheet has the residual hydroxyl content less than 23%.
14. the intermediate layer of claim 9, wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 23% separately, and said second polymer sheet has the residual hydroxyl content less than 21%.
15. the intermediate layer of claim 9, wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 21% separately, and said second polymer sheet has the residual hydroxyl content less than 19%.
16. the intermediate layer of claim 9, wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 20% separately, and said second polymer sheet has the residual hydroxyl content less than 17%.
17. a Polymer interlayers comprises: first polymer sheet that gathers (vinyl butyral) that comprises plasticising; Second polymer sheet that gathers (vinyl butyral) that comprises plasticising, wherein said second polymer sheet contacts with said first polymer sheet; The polymer sheet of gathering (vinyl butyral) that comprises plasticising, wherein said polymer sheet contacts with said second polymer sheet; At least 10 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers (vinyl butyral) or said polymer sheet that gathers the plasticising of more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet; More said first polymer sheet of residual hydroxyl content as expressed in weight percent that wherein said second polymer sheet is had or the residual hydroxyl content as expressed in weight percent of said polymer sheet low at least 2%; Wherein said first polymer sheet and said second polymer sheet respectively have the residual acetate content less than 5 moles of %; And wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 23% separately; And said second polymer sheet has the residual hydroxyl content less than 21%; Wherein plasticizer loading is weighed by the umber of per 100 parts of resins in the w/w benchmark, and residual hydroxyl content is to measure with the percetage by weight benchmark according to ASTM 1396.
18. the intermediate layer of claim 17, wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 21% separately, and said second polymer sheet has the residual hydroxyl content less than 19%.
19. the intermediate layer of claim 17, wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 20% separately, and said second polymer sheet has the residual hydroxyl content less than 17%.
20. the intermediate layer of claim 17, wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 18% separately, and said second polymer sheet has the residual hydroxyl content less than 15%.
21. the intermediate layer of claim 17, wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 15% separately, and said second polymer sheet has the residual hydroxyl content less than 12%.
22. a Polymer interlayers comprises: first polymer sheet that gathers (vinyl butyral) that comprises plasticising; Second polymer sheet that gathers (vinyl butyral) that comprises plasticising, at least 10 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet; The residual hydroxyl content as expressed in weight percent of more said first polymer sheet of residual hydroxyl content as expressed in weight percent that wherein said second polymer sheet is had low at least 2%; Wherein said first polymer sheet and said second polymer sheet contact with each other; Wherein said first polymer sheet and said second polymer sheet respectively have the residual acetate content less than 5 moles of %; Be set to the polymer sheet that contacts with said second polymer sheet; Wherein said polymer sheet comprises at least 10 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising of the more said polymer sheet of amount of plasticizer in the gathering of the plasticising that gathers (vinyl butyral) and wherein said second polymer sheet (vinyl butyral) of plasticising; Remain at least 10 parts greatly/100 parts of the amounts of plasticizer in more said first polymer sheet and the polymer sheet with the amount of plasticizer in wherein said second polymer sheet; Wherein plasticizer loading is weighed by the umber of per 100 parts of resins in the w/w benchmark, and residual hydroxyl content is to measure with the percetage by weight benchmark according to ASTM 1396.
23. the Polymer interlayers of claim 22; Wherein keeping contacting four stars after date at least with polymer sheet with said second polymer sheet, the amount of plasticizer remains at least 10 parts greatly/100 parts of the amounts of plasticizer in more said first polymer sheet and the polymer sheet in said second polymer sheet.
24. a compound glass plate comprises: Polymer interlayers, said Polymer interlayers comprises: first polymer sheet that gathers (vinyl butyral) that comprises plasticising; Second polymer sheet that gathers (vinyl butyral) that comprises plasticising, wherein said second polymer sheet contacts with said first polymer sheet; The polymer sheet of gathering (vinyl butyral) that comprises plasticising, wherein said polymer sheet contacts with said second polymer sheet; At least 12 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers (vinyl butyral) or said polymer sheet that gathers the plasticising of more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet; More said first polymer sheet of residual hydroxyl content as expressed in weight percent that wherein said second polymer sheet is had or the residual hydroxyl content as expressed in weight percent of said polymer sheet low at least 2%; And wherein said first polymer sheet and said second polymer sheet respectively have the residual acetate content less than 5 moles of %; Wherein plasticizer loading is weighed by the umber of per 100 parts of resins in the w/w benchmark, and residual hydroxyl content is to measure with the percetage by weight benchmark according to ASTM 1396.
25. the glass plate of claim 24, at least 15 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers (vinyl butyral) or said polymer sheet that gathers the plasticising of more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet.
26. a compound glass plate comprises: Polymer interlayers, said Polymer interlayers comprises: first polymer sheet that gathers (vinyl butyral) that comprises plasticising; Second polymer sheet that gathers (vinyl butyral) that comprises plasticising, wherein said second polymer sheet contacts with said first polymer sheet; The polymer sheet of gathering (vinyl butyral) that comprises plasticising, wherein said polymer sheet contacts with said second polymer sheet; At least 10 parts greatly/100 parts of the amounts of gathering plasticizer in (vinyl butyral) of the plasticising that gathers (vinyl butyral) or said polymer sheet that gathers the plasticising of more said first polymer sheet of amount of plasticizer in (vinyl butyral) of the plasticising of wherein said second polymer sheet; More said first polymer sheet of residual hydroxyl content as expressed in weight percent that wherein said second polymer sheet is had or the residual hydroxyl content as expressed in weight percent of said polymer sheet low at least 2%; Wherein said first polymer sheet and said second polymer sheet respectively have the residual acetate content less than 5 moles of %; And wherein said first polymer sheet and said polymer sheet have the residual hydroxyl content less than 23% separately; And said second polymer sheet has the residual hydroxyl content less than 21%; Wherein plasticizer loading is weighed by the umber of per 100 parts of resins in the w/w benchmark, and residual hydroxyl content is to measure with the percetage by weight benchmark according to ASTM 1396.
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