CN102671294A - Biological cell therapeutic apparatus - Google Patents
Biological cell therapeutic apparatus Download PDFInfo
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- CN102671294A CN102671294A CN2012100684967A CN201210068496A CN102671294A CN 102671294 A CN102671294 A CN 102671294A CN 2012100684967 A CN2012100684967 A CN 2012100684967A CN 201210068496 A CN201210068496 A CN 201210068496A CN 102671294 A CN102671294 A CN 102671294A
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Abstract
The invention provides a biological cell therapeutic apparatus which has excellent skin tactility and current effect of stimulation. The biological cell therapeutic apparatus possesses a supporting body and an electrification layer fixedly formed on a surface of the supporting body. The electrification layer is provided with a base material, cathodes of zinc oxide particles dispersedly included in the base material to take effects as an N type semiconductor; and anodes of precious metal particles dispersedly included in the base material, wherein at least part of the cathodes of zinc oxide particles and at least part of the anodes of precious metal particles are in contact to form a biological cell unit; besides, at least part of the biological cell unit is configured on a surface of the base material.
Description
Technical field
The present invention relates to a kind of biobattery therapeutic appliance, specifically, relate to following biobattery therapeutic appliance, its with the state of contact skin under use, carry out the disposal at object position thereby hypodermic energising is stimulated through faint direct current power.
Background technology
In recent years, worried patient in chronic shoulder ache or lumbago increases, and up to now, sells a lot of drug of topical application, hot moxibustion, clipped wire, magnetic therapeutic appliance, low-frequency therapy apparatus etc. on the market as the family therapy utensil.These therapeutic appliance have the blood circulation that promotes affected part according to various principles, remove the effect of the refuse that is detained partly.
As the therapeutic appliance of basis, a kind of biobattery therapeutic appliance (patent documentation 1 to 4) through energising stimulation therapy muscle and neural fatigue is proposed with above-mentioned general therapeutic appliance different principle.Experiment showed, this biobattery therapeutic apparatus with contact skin the time, to form biobattery and produce DC current, and, be a kind ofly to have identical even than the good therapeutic appliance of its better therapeutic effect with above-mentioned home-use therapeutic appliance.
Fig. 1 representes the general shape of this existing biobattery therapeutic appliance.This biobattery therapeutic appliance has pedestal 1, quasiconductor 2, supporter 3, sticks on the skin 4.Pedestal 1 is to implement gold-plated plastic pedestal, works as the positive pole of battery.On the other hand, quasiconductor 2 uprightly remains on the pedestal 1, works as the negative pole of battery, forms a battery by pedestal 1 and quasiconductor 2.
Can know from accompanying drawing, this biobattery therapeutic appliance, the skin scope that covers for the area with contact skin point is bigger, is difficult in approximating position and pastes a plurality of.In addition, existence such as size, skin feel, shape need the aspect of improvement.In addition, under the situation that this prior biological battery therapeutic appliance is sticked on the skin use, the accident of injured skin is a lot.
For example, in order to prevent skin injury, propose to be used to improve the technology (patent documentation 5 and 6) of its surface structure.But the biobattery therapeutic appliance of these propositions is pasting under the situation about using on the skin, and skin feel is insufficient, still has the probability to the damage of skin.In addition, can't fully obtain stable galvanism effect.
Patent documentation 1: japanese kokai publication hei 8-173554 communique
Patent documentation 2: japanese kokai publication hei 11-123245 communique
Patent documentation 3: TOHKEMY 2000-84093 communique
Patent documentation 4: TOHKEMY 2000-126308 communique
Patent documentation 5: TOHKEMY 2000-237322 communique
Patent documentation 6: TOHKEMY 2007-130145 communique
Summary of the invention
In view of the foregoing, the object of the present invention is to provide a kind of skin feel good, and can obtain the biobattery therapeutic appliance of good galvanism effect.
In order to solve above-mentioned problem, the present invention has following structure.
1, the present invention is a kind of biobattery therapeutic appliance, and the layer that electrifies that it has supporter and forms in above-mentioned supporting body surface set is characterized in that,
The above-mentioned layer that electrifies has: base material; The negative pole of zinc oxide fine particles, it is included in the above-mentioned base material dispersedly, works as N-type semiconductor; And the positive pole of fine particle of noble metal, it is included in the above-mentioned base material dispersedly,
The positive pole of the negative pole of the above-mentioned zinc oxide fine particles of at least a portion and at least a portion fine particle of noble metal contacts with each other, and constitute biological battery unit, and at least a portion biological battery unit is configured on the substrate surface.
2. biobattery therapeutic appliance, the layer that electrifies that it has supporter and forms in above-mentioned supporting body surface set is characterized in that,
The above-mentioned layer that electrifies has: negative electrode layer, and it has base material and is included in the negative pole as the acting zinc oxide fine particles of N-type semiconductor in the above-mentioned base material dispersedly; And
The positive pole of noble metal film, its set are present between above-mentioned supporter and the above-mentioned negative electrode layer, and the negative pole of the above-mentioned zinc oxide fine particles of at least a portion is configured in substrate surface, contact with the positive pole of noble metal film, constitute biological battery unit.
3. biobattery therapeutic appliance, it has the supporter that forms a plurality of base materials of the portion that electrifies at least on the surface and link above-mentioned a plurality of base materials, it is characterized in that,
The above-mentioned portion of electrifying has: the negative pole of zinc oxide fine particles, and it is included in above-mentioned substrate surface dispersedly, works as N-type semiconductor; And the positive pole of fine particle of noble metal, it is included in above-mentioned substrate surface dispersedly,
The positive pole of the negative pole of at least a portion zinc oxide fine particles and the above-mentioned fine particle of noble metal of at least a portion contacts with each other, and constitutes biological battery unit at substrate surface.
4. biobattery therapeutic appliance, the portion that electrifies that it has base material and forms in above-mentioned substrate surface set is characterized in that,
The above-mentioned portion of electrifying makes the biological battery unit that contacts with each other as the negative pole of the acting zinc oxide fine particles of N-type semiconductor, with the positive pole of fine particle of noble metal and constitute a plurality of side by side and/or arranged in series, constitutes electric loop.
5. the biobattery therapeutic appliance described in any as in 1 to 3 is characterized in that above-mentioned supporter is formed by the material that ionization tendency is between above-mentioned zinc oxide fine particles and the above-mentioned noble metal granule.
In addition, in this description, claims, the weight portion of base material is represented dry weight part (dry weight part of binding agent) of base material.
In the record of this description, claims, " zinc oxide fine particles " comprises at least that the surface is the microgranule of zinc oxide.In addition, " fine particle of noble metal " comprises the microgranule of the surf zone at least of microgranule by the noble metal coating.For example, silver-plated copper powder etc. is the fine particle of noble metal that the present invention relates to.
In the record of this description, claim, so-called " microgranule " is meant to have the particle that constitutes the required big small particle diameter of biobattery therapeutic appliance that the present invention relates to.
The mean diameter of zinc oxide fine particles is to utilize BET meter and the value calculated according to specific surface area.
The mean diameter of the fine particle of noble metal of argentum powder etc. is the value through the D50 of laser diffractometry mensuration.
The effect of invention
According to the present invention, can provide skin feel good, and can obtain the biobattery therapeutic appliance of good electric current effect of stimulation.
Description of drawings
Fig. 1 is the cutaway view of 1 example of the existing general biobattery therapeutic appliance of expression.
Fig. 2 is the cutaway view of the 1st embodiment of this biobattery therapeutic appliance of expression.
Fig. 3 is the key diagram of the 2nd embodiment of this biobattery therapeutic appliance of expression, (a) is vertical view, (b) is the cutaway view along the III-III line.
Fig. 4 is the cutaway view of the 4th embodiment of this biobattery therapeutic appliance of expression.
Fig. 5 is the vertical view of the 5th embodiment of this biobattery therapeutic appliance of expression.
Fig. 6 is the cutaway view of the 6th embodiment of this biobattery therapeutic appliance of expression, (a) representes one of them example, (b) representes other examples, (c) is the key diagram of the action effect of the catenate biobattery of ball.
Fig. 7 is the cutaway view of the 7th embodiment of this biobattery therapeutic appliance of expression.
Fig. 8 is the cutaway view of an example of the 8th embodiment of this biobattery therapeutic appliance of expression.
The specific embodiment
This biobattery therapeutic appliance is characterised in that use as negative pole, makes it contact with the positive pole of noble metal as the acting zinc oxide fine particles of N-type semiconductor, constitutes biobattery.
Below, at length describe for embodiment of the present invention.
(the 1st embodiment)
For the 1st embodiment of biobattery therapeutic appliance, use Fig. 2 to describe.
This biobattery therapeutic appliance 20 has supporter 21 and the layer 24 that electrifies that anchors at this supporting body surface.As the layer 24 that electrifies, the positive pole 22 (representing) that constitutes by fine particle of noble metal through decentralized configuration in base material 25 (for example binding agent) and form by the negative pole 23 (representing) that constitutes as the acting zinc oxide fine particles of N-type semiconductor with white circular with dark circles.The negative pole 23 of the above-mentioned zinc oxide fine particles of at least a portion and the positive pole 22 of at least a portion fine particle of noble metal contact with each other, and constitute biological battery unit, and at least a portion biological battery unit are configured in substrate surface.
If the zinc oxide fine particles and the fine particle of noble metal of nanoscale or approaching with it magnitude are mixed together and are engaged in the base material, then a large amount of zinc oxide fine particles contact with fine particle of noble metal, constitute countless biological battery unit.
And, when these microgranules and contact skin, constitute electric loop, on skin, pass through little electric current.Because positive pole 22 all is a microgranule with negative pole 23, thus not coarse with the surface of contact skin, compared with prior art have the advantages of good skin sense of touch.And, because constitute countless biological battery unit, so can stablize and generating fully at substrate surface.
Anodal 22 so long as fine particle of noble metal get final product.As the metal of fine particle of noble metal use, so long as be not easy to take place chemical change and compare the higher noble metal of electrode potential or its alloy to get final product with the semiconductor particle that becomes negative pole.For example, can be gold (Au) silver (Ag), platinum family and alloy thereof etc.
As fine particle of noble metal, its particle diameter is not special qualification, but from constituting the angle of a plurality of biological battery unit, preferred littler particle diameter, and angle from making, thicker particle diameter is handled easily.If realize the compromise of the two, for example then can using, mean diameter is the noble metal of 1nm to 50 mu m range, mean diameter 20nm to 15 μ m, mean diameter 10 μ m to 15 μ m, mean diameter 20nm to 40nm etc.But the present invention is defined as these microgranules.
Negative pole is so long as get final product as the acting zinc oxide fine particles of N-type semiconductor.The compared with metal that zinc oxide fine particles and above-mentioned fine particle of noble metal use has lower standard single electrode potential.Because zinc oxide fine particles works as N-type semiconductor, so can utilize known any means to handle zinc oxide fine particles, for example, mix as long as carry out the N type, promptly utilize aluminum (Al), calcium (Ga), antimony (Sb) etc. that zinc oxide fine particles is mixed.But the present invention carries out this processing, is not to be defined in as the acting zinc oxide fine particles of N-type semiconductor.
The particle diameter of zinc oxide fine particles is not particularly limited, but mean diameter is at 1nm to 200nm, preferred 1nm to 100nm, the scope of especially preferred 1nm to 50nm.In addition, mean diameter can be the size of 20nm to 15 μ m, 10 μ m to 15 μ m, 20nm to 40nm etc.
The fine particle of noble metal that contains in the base material 25 is 25 weight portion to 30 weight portions with respect to base material 100 weight portions for example, and in addition, the zinc oxide fine particles that contains in the base material is 25 weight portion to 50 weight portions with respect to base material 100 weight portions.
To the mixing of the fine particle of noble metal and the zinc oxide fine particles of base material 25, for example, can be through base material be dissolved in the solvent, the known any means that fine particle of noble metal and zinc oxide fine particles dispersing and mixing wait is therein carried out.
And; To contain fine particle of noble metal and as the base material 25 of the acting zinc oxide fine particles of N-type semiconductor through dispersing and mixing; With respect to supporter 21; Through for example apply, the method set of any known such as injection, screen, silk screen printing, injection mo(u)lding and/or mould molding, form the layer 24 that electrifies.
Above-mentioned supporter 21 is so long as can be fit to the base material of the flexible any material such as paper, cloth, non-woven fabrics or plastic foil of having of skin shape and get final product.Through making under the situation that this biobattery therapeutic appliance and contact skin use, preferably can be suitable for flexible paper, cloth, non-woven fabrics or the plastic foil etc. of having of skin shape, through using these materials, can further improve skin feel.
(the 2nd embodiment)
For the 2nd embodiment of biobattery therapeutic appliance, use Fig. 3 (a) to reach and (b) describe.
Fig. 3 (a) is the vertical view of this biobattery therapeutic appliance 30 in the 2nd embodiment, and Fig. 3 (b) is the III-III line cutaway view along Fig. 3 (a).
This biobattery therapeutic appliance 30 comprises supporter 21 and the lip-deep a plurality of layers 24 that electrify that are fixed on above-mentioned supporter 21.The layer 24 that electrifies comprises the positive pole 22 that is made up of fine particle of noble metal and by the negative pole 23 that constitutes as the acting zinc oxide fine particles of N-type semiconductor in base material 25, anchor at above-mentioned supporting body surface and form.
In Fig. 3 (b), represent positive pole 22 with dark circles, represent negative pole 23 with white circular.
This biobattery therapeutic appliance 30 in the 2nd embodiment is except comprising a plurality of electrifying the layer 24, and is identical with the structure of this biobattery therapeutic appliance of putting down in writing in the 1st embodiment, constitutes the loop with contact skin.Also this biobattery therapeutic appliance with the record of the 1st embodiment is identical in essence for its action effect.
(the 3rd embodiment)
The supporter 21 that can make that this biobattery therapeutic appliance replaces in above-mentioned the 1st embodiment and the 2nd embodiment is suitable for the flexible base material that has of skin shape, uses metal arbitrarily.Other structures can be the identical structures of this biobattery therapeutic appliance with the 1st embodiment and the 2nd embodiment.As long as comprise the positive pole 22 that constitutes by fine particle of noble metal and, get final product thereby form the layer 24 that electrifies by the base material of the negative pole 23 that constitutes as the acting zinc oxide fine particles of N-type semiconductor through surperficial set at the supporter 21 of metal.
Through using the supporter of metal, can be used as uses such as necklace, pendicle and bracelet.
Under the situation of the supporter that uses metal, especially, can constitute supporter by the material that ionization tendency is between above-mentioned zinc oxide fine particles and the fine particle of noble metal.For example, be under the situation of Au at fine particle of noble metal, can be in the material between above-mentioned zinc oxide fine particles and the Au by ionization tendency, i.e. formations such as Ag, Cu, Sn for example.Through such formation, between the positive pole 22 of the negative pole 23 of supporter 21, above-mentioned zinc oxide fine particles and fine particle of noble metal, produce electromotive force, realize that the ability of biobattery therapeutic appliance improves.In addition, in this case, whole supporter all is made up of the material that ionization tendency is between above-mentioned zinc oxide fine particles and the fine particle of noble metal.As long as through plating the surface is made up of above-mentioned material, can reaches its intended purposes.
(the 4th embodiment)
Other examples of the shape of the supporter 21 among Fig. 4 in expression above-mentioned the 1st embodiment of change and the 2nd embodiment.This biobattery therapeutic appliance of the 4th embodiment changes the shape of the supporter in above-mentioned the 3rd embodiment.Other structure can be identical with the 3rd embodiment.
The supporter 42 that this biobattery therapeutic appliance 40 comprises handle 41, be wholely set with this handle 41, the layer 43 that electrifies that comprises positive pole and negative pole that forms in above-mentioned supporting body surface.The layer 43 that electrifies can be and the 1st embodiment or the identical structure of the 2nd embodiment.
(the 5th embodiment)
Use Fig. 5 to describe for the 5th embodiment of this biobattery therapeutic appliance.
This biobattery therapeutic appliance 50 has supporter 51 and the layer 54 that electrifies that is formed on above-mentioned supporting body surface, and this layer 54 that electrifies has positive electrode layer 52 and negative electrode layer.Positive electrode layer 52 is noble metal films that at least a portion on the surface of supporter 51 forms.It is on the zone on the noble metal film that negative electrode layer is formed on positive electrode layer 52, and the part of positive electrode layer 52 is exposed.Negative electrode layer in base material 5 (binding agent) dispersing and mixing for example mean diameter be the negative pole 53 of 1nm to 50 μ m as the acting zinc oxide fine particles of N-type semiconductor.The combined amount of zinc oxide fine particles is for for example constituting with respect to base material (binding agent) 100 weight portion dispersing and mixing zinc oxide fine particles 25 weight portion to 50 weight portions, and the negative electrode layer that constitutes in this manner anchors on the metal level thin film.And at least a portion of negative pole 53 is configured in the surface of base material 55, contacts with positive electrode layer 52.
Except the structure of positive electrode layer 52, this biobattery therapeutic appliance 50 is that the structure of supporter 51, base material 55 and negative pole 53 can be identical with any one structure of the 1st embodiment to the 4 embodiments.
In addition, the negative pole 53 on this biobattery therapeutic appliance 50 is not necessarily the microgranule of zinc oxide, also can be the oxidized zinc microgranule (that is, the surface is the zinc microgranule of zinc oxide) in surface.This biobattery therapeutic appliance 50 for example forms positive pole 52 through gold-plated the grade, then, needs only the arbitrary region in anodal 52 (positive electrode layer), and set gets final product with respect to the negative electrode layer that binding agent 100 weight portions contain the zinc microgranule of 25 weight portion to 50 weight portions.The oxidation of zinc microparticle surfaces can be carried out in any manufacture process.Through this structure, can omit operations such as the doping of zinc oxide, the pulverizing of the zinc oxide after the doping, even granulation.This is because the surface oxidation of zinc microgranule forms the zinc oxide overlay film as N-type semiconductor.The stable conduction that zinc that can contain through this microgranule thus, and zinc oxide carry out ZnOZn.
(the 6th embodiment)
Fig. 6 (a) representes the 6th embodiment.This biobattery therapeutic appliance 60 is the structures that link a plurality of spherical base materials 65 through supporter 61.In addition, base material is not limited to spherical, can become arbitrary shapes such as ellipticity, tabular, drops.
The synthetic resin of in explanation, mentioning etc. as base material use front embodiment; Under the situation about cooperating with its mixing; As acting zinc oxide fine particles of N-type semiconductor and fine particle of noble metal, be dispersed in above-mentioned substrate surface and the negative pole of the above-mentioned zinc oxide fine particles that contains and anodal at least a portion of above-mentioned fine particle of noble metal contact with each other in this substrate surface decentralized configuration.
As other examples of the 6th embodiment, shown in Fig. 6 (b), coat substrate surface by noble metal film (positive pole), decentralized configuration is also effective as the acting zinc oxide fine particles of N-type semiconductor on this thin film.
The material that links the supporter of base material is not particularly limited, but the preferred ion tendency is in the material (at noble metal film is under the situation of Au, for example is Ag, Cu, Sn etc.) between zinc oxide fine particles and the noble metal film.
In the above-described embodiment; Be not limited to dispersing and mixing in base material (binding agent) " zinc oxide fine particles and fine particle of noble metal " perhaps " zinc oxide fine particles " base material is solidified and makes; Also can make base material earlier, then at its surperficial dispersing and mixing " zinc oxide fine particles and fine particle of noble metal " or " zinc oxide fine particles ".We can say this structure also with aforementioned embodiments in " zinc oxide fine particles and fine particle of noble metal " or " zinc oxide fine particles " identical.
Fig. 6 (c) is the key diagram of the action effect of expression ball catenate biobattery, anodal (fine particle of noble metal) 62 of expression and negative pole (zinc oxide fine particles) 63 and biology skins such as () human bodies B state of contact.Figure just to the left is that zinc oxide fine particles 63 contacts with fine particle of noble metal 62 and the example that disposes.In this case, because positive pole contacts with negative pole, so electric current shown in arrow, passes through in the part that skin surface is more shallow.Figure just to the right is the example of zinc oxide fine particles 63 and fine particle of noble metal 62 configured separate.Label 80 is the conductors that connect zinc oxide fine particles 63 and fine particle of noble metal 62.In this example because anodal 62 with negative pole 63 away from, so electric current such as the darker part of skin that arrow is shown in are passed through.Its result passes a plurality of cells and pair cell stimulates.Therefore, through spacing, distribution, the combined amount of suitable adjustment setting anodal 62, can become biobattery corresponding to the expectation of purpose with negative pole 63.
(the 7th embodiment)
Fig. 7 representes the 7th embodiment.This biobattery therapeutic appliance 70, the layer that electrifies are to make the biological battery unit that contacts with each other as the negative pole 73 of the acting zinc oxide fine particles of N-type semiconductor and the positive pole 72 of fine particle of noble metal parallelly connected and/or be connected in series, and on base material 71, constitute electric loop.This structure is through application of printed distribution technology, and those skilled in the art can easily make, but can constitute the very large biobattery therapeutic appliance of generating capacity of degree of electrical generation.Therefore, also can connect LED etc. as required makes it luminous.
(the 8th embodiment)
Below, describe for the 8th embodiment of the biobattery of fiber shape.
Specific fibre constitutes following conducting fibre (following abbreviate this conducting fibre as the N fiber); It is in the acting resin as binding agent; (surface is the microgranule of zinc oxide at least to sneak into the zinc oxide of micro particles; For example, wrap the microgranule that the oxidized zinc in zinciferous surface coats), perhaps carry out lamination etc. it is worked as N-type semiconductor.Here, the N fiber constitutes supporter that the present invention relates to and the layer that electrifies with base material and negative pole.
Formation is to become the conducting fibre that anodal noble metal is a main component (below, abbreviate this conducting fibre as the A fiber).Here, the A fiber constitutes supporter and has base material and the anodal layer that electrifies.
The conductive fiber that preparation can be switched on (below, abbreviate this conducting fibre as the C conductive fiber).This conductive fiber preferred ion tendency is between the both positive and negative polarity.Here, the C conductive fiber constitutes supporter or supporter and the base material that the present invention relates to.
N-type semiconductor is processed into the appropriate structuring of expectation, prepares the particle of easy fixation on fiber (following abbreviate this particle as the N particle).Here, the N particle constitutes the negative pole that the present invention relates to.
Noble metal is processed into the appropriate structuring of expectation, prepares to withstand on admittedly easily particle on the fiber (following abbreviate this particle as the A particle).Here, the A particle constitutes the positive pole that the present invention relates to.
The biobattery of fiber shape passes through from above-mentioned N fiber, A fiber, C fiber, N particle, reaches the A particle and suitably select; With material and non-woven fabrics or the fabric combination selected, constitute the biobattery therapeutic appliance that has the supporter that the present invention relates to and be provided with base material, negative pole, the anodal layer that electrifies.Particularly can the illustration combinations.
1) with the structure of N fiber and A fiber combinations.Through this structure, can obtain to have supporter and the biobattery therapeutic appliance that the present invention relates to that is provided with base material, negative pole, the anodal layer that electrifies.
2) structure that N fiber, A fiber and C conductive fiber is made up.Through this structure, can obtain to have supporter and the biobattery therapeutic appliance that the present invention relates to that is provided with base material, negative pole, the anodal layer that electrifies.
Non-woven fabrics or the fabric and the particulate structure of A that 3) will constitute by the N fiber.Through this structure, can obtain to have supporter and the biobattery therapeutic appliance that the present invention relates to that is provided with base material, negative pole, the anodal layer that electrifies.
4) above-mentioned 3) in add the C conductive fiber structure.Through this structure, can obtain to have supporter and the biobattery therapeutic appliance that the present invention relates to that is provided with base material, negative pole, the anodal layer that electrifies.
Non-woven fabrics or the fabric and the particulate structure of N that 5) will constitute by the A fiber.Through this structure, can obtain to have supporter and the biobattery therapeutic appliance that the present invention relates to that is provided with base material, negative pole, the anodal layer that electrifies.
6) above-mentioned 5) in add the C conductive fiber structure.Through this structure, can obtain to have supporter and the biobattery therapeutic appliance that the present invention relates to that is provided with base material, negative pole, the anodal layer that electrifies.
7) non-woven fabrics that constitutes by the C conductive fiber or fabric and N particle, the particulate structure of A.Through this structure, can obtain to have supporter and the biobattery therapeutic appliance that the present invention relates to that is provided with base material, negative pole, the anodal layer that electrifies.
8) with above-mentioned whole N fibers, A fiber, C fiber, N particle and the particulate structure of A.Through this structure, can obtain to have supporter and the biobattery therapeutic appliance that the present invention relates to that is provided with base material, negative pole, the anodal layer that electrifies.
In addition, said structure only is an illustration.The biobattery of the fiber shape that the present invention relates to not is to be defined in above-mentioned 1) to 8).In addition, the biobattery of the fiber shape that the present invention relates to except formation can certainly add other materials, parts, key element etc.
In addition; In the 8th embodiment, be illustrated for the basic structure of the biobattery of fiber shape, but in the 8th embodiment; Can certainly suitably select and implement, so that the concrete structure of in above-mentioned the 1st to the 7th embodiment item, explaining is corresponding with the 8th embodiment.
The biobattery of above-mentioned fiber shape has to become and can stick on the health, perhaps through being processed on the medicated clothing and with the excellent results of the matched biobattery of health.
(negative pole and anodal processing method)
As negative pole and anodal processing method, can enumerate dry plating (sputter, ion plating, vapor deposition).This processing method is particularly suitable for negative pole processing, through resin film or resin plate, synthetic resin, glass etc. are carried out film printing, thereby can process flexible electrode or complicated shape part fully.In addition, its electrical characteristic can obtain roughly approaching with metal degree.For example,, can the plate after the sputter be processed into the shape that needs, carry out mask processing, or after processing, utilize and for example be used for the electric shape that needs are processed in insulating mask printing etc. according to demand as electrode.
The biobattery of making negative pole will in binding agent, sneaking into the N-type semiconductor of attritive powder sticks under the situation on the skin; Generating capacity is relatively poor; Have only at the most about 0.7 to 0.8 volt; But through sputter zinc oxide is joined in the resin film under the situation as electrode, have about 1.3 volts and roughly identical generating capacity with the situation of metal.In addition, the color of negative pole roughly is transparent, as biobattery and anodal combination, also can not damage anodal metal appearance.
For example; Make under the banded continuously situation of biobattery in mode with chain; From chain one end to other end overgild, after the chain that only becomes negative pole is gold-plated, through the anticathode sputter; Whole or surperficial part to a surface of this chain is processed, and also has the design effect that outward appearance appears to gold chain.
In addition, can utilize the supporter 90 of conductor to link anodal chain shown in Figure 8 82 and negative pole chain 83.And the positive pole and the negative pole that constitute in this manner are through gelationus medicament 91 and contact skin.Utilize this structure, supporter 90 preferred ion tendencies are in the material between the positive and negative pole material, link through the material of utilizing the intermediate-ion tendency, and positive pole and negative pole integral body are with rectangular generating.
[embodiment]
Make and the suitable biobattery of above-mentioned the 1st embodiment, observe power generation stabilization property etc.
Embodiment 1
Making embodiment 1 as follows and 2 at the laminar surface coating normal saline that electrifies separately, estimates the stability of generating as electrical characteristic.In addition, estimate for the state and the outward appearance of separately the laminar surface that electrifies.
Use allyl resin as base material, it is the zinc oxide fine particles of 10 to 15 μ m that negative pole uses by the mean diameter after the aluminum doping, and anodal use mean diameter is the silver-colored microgranule of 10 to 15 μ m.
Make this zinc oxide fine particles and silver-colored microgranule ratio, mix with base material in being dissolved in solvent to equate with the dry weight of base material.The biobattery suitable with the 1st embodiment made in its curing.With oxide powder and zinc and argentum powder respectively with the blended biobattery of 25 weight portions as embodiment 1, will be with respect to base material 100 weight portions and respectively with the blended biobattery of 30 weight portions as embodiment 2.
In embodiment 1 and 2, all can obtain stable generating.Can observe not generating fluctuation, and the fully generating of generated energy.
In addition, embodiment 1 and 2, anodal silver becomes the silver yellow color from metallochrome, judges that the color of electric layer also is preferred for commodity.
Embodiment 3
Making embodiment 3 as follows.Apply normal saline at each battery surface, estimate power generation stabilization property as electrical characteristic.In addition, estimate for the apparent condition and the outward appearance of each battery.
Use allyl resin as base material, the mean diameter after the negative pole use is mixed by aluminum is 20 to 40nm zinc oxide fine particles, and anodal use mean diameter is 20 to 40nm silver-colored microgranule.As embodiment 3, use the zinc oxide fine particles of 50 weight portions and the silver-colored microgranule of 30 weight portions, with the above-mentioned manufacturing likewise biobattery suitable with the 1st embodiment.
In embodiment 3, confirm stable and generating fully.In addition, the outward appearance of the layer that electrifies, the metallochrome of silver-colored microgranule becomes the silver yellow color, and the transparency of zinc oxide fine particles is very high.The layer that electrifies making embodiment 3 forms under the situation of gold-plated metal, can penetrate the metallochrome of observing substrate.It can think very good characteristic as commodity.
In addition, under layer situation of manufacturing biobattery therapeutic appliance that electrify of using this composition, can carry out the silk screen printing of small mesh, thus, make the layer that electrifies of 5 to 10 microns left and right thicknesses.Thereby can realize the miniaturization of biobattery therapeutic appliance.
Embodiment 4
Use allyl resin as base material, the mean diameter after the negative pole use is mixed by aluminum is 150 to 250nm zinc oxide fine particles, and anodal use mean diameter is the silver-colored microgranule of 10 to 15 μ m.With respect to dry weight 100 weight portions of base material, the silver-colored microgranule of the zinc oxide fine particles of 50 weight portions and 25 weight portions is mixed with base material in being dissolved in solvent.It is solidified, make the biobattery suitable, as embodiment 4 with the 1st embodiment.
Embodiment 4 is both generating fluctuations also, the fluctuation of the laminar surface that also do not electrify, well-behaved as biobattery.But the transparency of negative pole particle is not enough, is worse than embodiment 3 as the characteristic of commodity.Can know that in order to obtain the transparency of negative pole particle the mean diameter that must make zinc oxide fine particles is 20 to 40nm.
Embodiment 5
Use allyl resin as base material, it is 20 to 40nm zinc oxide fine particles that negative pole uses by the adulterated mean diameter of aluminum, and anodal to use mean diameter be the silver-colored microgranule of 10 to 15 μ m.With respect to dry weight 100 weight portions of base material, the silver-colored microgranule of the zinc oxide fine particles of 50 weight portions and 25 weight portions is mixed with base material in being dissolved in solvent.It is solidified, make the biobattery suitable, as embodiment 5 with the 1st embodiment.
Embodiment 5 can obtain stable and generating fully.In addition, the transparency of zinc oxide fine particles is high, and alternate with the color of the xanchromatic silver-colored microgranule of silver, the good external appearance characteristic when performance provides as commodity.The layer that electrifies making embodiment 5 forms under the situation of filled gold, can penetrate the gold of seeing substrate.It is considered to very good characteristic as commodity.
Comparative Examples 1
Making Comparative Examples as follows applies normal saline at each battery surface, and the stability of estimating generating is as electrical characteristic.In addition, estimate for the state and the outward appearance of the laminar surface that electrifies.Here the weight portion that occurs is the numerical value with respect to base material 100 weight portions.
Use allyl resin (binding agent) as base material, it is the Zinc oxide powder of 250 to 350 μ m that negative pole uses by the mean diameter after the aluminum doping, the anodal silver powder of using 250 to 350 μ m.
With respect to the dry weight of base material, with identical ratio, that is, respectively with 10 weight portions with argentum powder and doping zinc-oxide powder with mixed by the base material after the dissolution with solvents.With its curing, make biobattery and obtain Comparative Examples 1.
In Comparative Examples 1, between the different zone of the laminar surface that electrifies, generating has fluctuation, can't obtain stable generating.
As the reason that can't obtain stable electric generation, the inventor infers it is because the particle diameter of Zinc oxide powder is bigger, and how the quantity that can't make biological battery unit is to degree of the present invention, in addition, and decentralized configuration equably.
[industrial applicibility]
According to the present invention, can provide a kind of skin feel good, and can obtain the biobattery therapeutic appliance of good galvanism effect.This biobattery therapeutic appliance purifies the local refuse that is detained through promoting blood circulation, thereby aches and the treatment and the prevention of pain in the lumbar region etc. at shoulder, and beauty treatment fields such as skin maintenance, the improvement of skin matter all can effectively use.
In addition, this biobattery can be used as through the generating of above-mentioned biobattery the material after the ionizing is used through the utensil that skin imports.
In addition, biobattery therapeutic appliance of the present invention can be used for various device effectively.
For example, be applied under the situation of ultrasonic beautifying device, with ultrasonic beautifying device as supporter; What formation the present invention relates to above that (for example electrifies layer; Main body side as side of the positive electrode, will be contacted a side as negative side, thereby makes it have the function as biobattery therapeutic appliance of the present invention with face); Thus, can bring into play as the ultrasound wave of ultrasonic beautifying device and Overlay as the galvanism effect of biobattery therapeutic appliance.
In addition, form the nasal cavity expanding part of nasal cavity spreading belt, form the layer that electrifies that the present invention relates to by conductive material.As the layer that electrifies, for example, making an end is side of the positive electrode, and making multiterminal is negative side, and integral body also can form positive pole, negative pole.The nasal cavity spreading belt that forms thus, it is inferior to have the situation that has nose to stop up at user, can improve the effect of blood circulation obstacle etc.In addition, if the nasal cavity spreading belt that will constitute thus can use along the crooked mask combination in nose shape ground with the conductive material that passes metal wire etc. in upper side, can further increase the galvanism effect through the conductive material of metal wire.
Claims (5)
1. biobattery therapeutic appliance, the layer that electrifies that it has supporter and forms in above-mentioned supporting body surface set is characterized in that,
The above-mentioned layer that electrifies has: base material; The negative pole of zinc oxide fine particles, it is included in the above-mentioned base material dispersedly, works as N-type semiconductor; And the positive pole of fine particle of noble metal, it is included in the above-mentioned base material dispersedly,
The positive pole of the negative pole of the above-mentioned zinc oxide fine particles of at least a portion and at least a portion fine particle of noble metal contacts with each other, and constitute biological battery unit, and at least a portion biological battery unit is configured on the substrate surface.
2. biobattery therapeutic appliance, the layer that electrifies that it has supporter and forms in above-mentioned supporting body surface set is characterized in that,
The above-mentioned layer that electrifies has: negative electrode layer, and it has base material and is included in the negative pole as the acting zinc oxide fine particles of N-type semiconductor in the above-mentioned base material dispersedly; And
The positive pole of noble metal film, its set are present between above-mentioned supporter and the above-mentioned negative electrode layer,
The negative pole of the above-mentioned zinc oxide fine particles of at least a portion is configured in substrate surface, contacts with the positive pole of noble metal film, constitutes biological battery unit.
3. biobattery therapeutic appliance, it has the supporter that forms a plurality of base materials of the portion that electrifies at least on the surface and link above-mentioned a plurality of base materials, it is characterized in that,
The above-mentioned portion of electrifying has: the negative pole of zinc oxide fine particles, and it is included in above-mentioned substrate surface dispersedly, works as N-type semiconductor; And the positive pole of fine particle of noble metal, it is included in above-mentioned substrate surface dispersedly,
The positive pole of the negative pole of at least a portion zinc oxide fine particles and the above-mentioned fine particle of noble metal of at least a portion contacts with each other, and constitutes biological battery unit at substrate surface.
4. biobattery therapeutic appliance, the portion that electrifies that it has base material and forms in above-mentioned substrate surface set is characterized in that,
The above-mentioned portion of electrifying makes the biological battery unit that contacts with each other as the negative pole of the acting zinc oxide fine particles of N-type semiconductor, with the positive pole of fine particle of noble metal and constitute a plurality of side by side and/or arranged in series, constitutes electric loop.
5. like any described biobattery therapeutic appliance in the claim 1 to 3, it is characterized in that,
Above-mentioned supporter is formed by the material that ionization tendency is between above-mentioned zinc oxide fine particles and the above-mentioned noble metal granule.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
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| JP2011056706 | 2011-03-15 | ||
| JP2011-056706 | 2011-03-15 | ||
| JP2012045494A JP5881158B2 (en) | 2011-03-15 | 2012-03-01 | Biological battery treatment tool |
| JP2012-045494 | 2012-03-01 |
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| CN102671294A true CN102671294A (en) | 2012-09-19 |
| CN102671294B CN102671294B (en) | 2015-04-01 |
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Cited By (2)
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| TWI663957B (en) * | 2016-05-09 | 2019-07-01 | 信越化學工業股份有限公司 | Bio-electrode and method for manufacturing the same |
| TWI702033B (en) * | 2016-03-03 | 2020-08-21 | 日商信越化學工業股份有限公司 | Biological electrode and manufacturing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP6372888B2 (en) * | 2015-06-22 | 2018-08-15 | 賢司 小蒲 | Biological battery treatment tool |
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| JP2000237323A (en) * | 1999-02-24 | 2000-09-05 | Satellite Intelligence:Kk | Skin contact treatment tool |
| JP2007130145A (en) * | 2005-11-09 | 2007-05-31 | Yusuke Kokama | Organism electric battery treating implement |
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| JP2000237323A (en) * | 1999-02-24 | 2000-09-05 | Satellite Intelligence:Kk | Skin contact treatment tool |
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