CN102671294B - Biological cell therapeutic apparatus - Google Patents
Biological cell therapeutic apparatus Download PDFInfo
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- CN102671294B CN102671294B CN201210068496.7A CN201210068496A CN102671294B CN 102671294 B CN102671294 B CN 102671294B CN 201210068496 A CN201210068496 A CN 201210068496A CN 102671294 B CN102671294 B CN 102671294B
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Abstract
The invention provides a biogalvanic battery treating device for providing excellent touch feeling and obtaining an excellent current stimulation effect. The biogalvanic battery treating device includes: a support body; and an electrogenic layer fixedly formed on the surface of the support body. The electrogenic layer includes: a base material; negative electrodes of zinc oxide fine particles which are contained by distribution in the base material and function as an N-type semiconductor; and positive electrodes of noble metal particles which are contained by distribution in the base material. The base material is any synthetic resin of thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polyvinyl chloride, polyester, polyether, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly propylene carbonate, and phenoxy resin. At least a part of the negative electrodes of the zinc oxide particles and at least a part of the positive electrodes of the noble metal particles are brought into contact with each other to constitute an biogalvanic battery unit, and at least a part of the biogalvanic battery unit is arranged on the surface of the base material concerning the biogalvanic battery treating device.
Description
Technical field
The present invention relates to a kind of biobattery therapeutic appliance, specifically, relate to following biobattery therapeutic appliance, its with the state of contact skin under use, by faint direct current power hypodermic energising stimulated thus carry out the disposal at object position.
Background technology
In recent years, the worried patient in chronic shoulder ache or lumbago increases, and up to now, market is sold a lot of drug of topical application, hot moxibustion, clipped wire, magnetic therapeutic utensil, low-frequency therapy apparatus etc. as family therapy utensil.These therapeutic appliance have the blood circulation promoting affected part according to various principle, remove the effect of the refuse of delay partly.
As according to the therapeutic appliance with above-mentioned general therapeutic appliance different principle, a kind of biobattery therapeutic appliance (patent documentation 1 to 4) by be energized stimulation therapy muscle and neural fatigue is proposed.Experiment proves, this biobattery therapeutic apparatus producing DC current with forming biobattery during contact skin, and, be a kind of excellent therapeutic appliance with even than it better therapeutic effect identical with above-mentioned Household therapeutic utensil.
Fig. 1 represents the general shape of this existing biobattery therapeutic appliance.This biobattery therapeutic appliance has pedestal 1, quasiconductor 2, supporter 3, is pasted onto on skin 4.Pedestal 1 implements gold-plated plastic pedestal, and the positive pole as battery works.On the other hand, quasiconductor 2 uprightly remains on pedestal 1, and the negative pole as battery works, and forms a battery by pedestal 1 and quasiconductor 2.
From accompanying drawing, this biobattery therapeutic appliance, the skin ranges for the area covering with contact skin point is larger, is difficult to paste multiple at approximating position.In addition, there is the aspect needing to improve in size, skin feel, shape etc.In addition, when this existing biobattery therapeutic appliance being pasted onto skin and using, the accident of injured skin is a lot.
Such as, in order to prevent skin injury, the technology (patent documentation 5 and 6) for improving its surface structure is proposed.But, these propose biobattery therapeutic appliance, when paste skin uses, skin feel is insufficient, still there is the probability of the damage to skin.In addition, stable galvanism effect cannot fully be obtained.
Patent documentation 1: Japanese Unexamined Patent Publication 8-173554 publication
Patent documentation 2: Japanese Unexamined Patent Publication 11-123245 publication
Patent documentation 3: Japanese Unexamined Patent Publication 2000-84093 publication
Patent documentation 4: Japanese Unexamined Patent Publication 2000-126308 publication
Patent documentation 5: Japanese Unexamined Patent Publication 2000-237322 publication
Patent documentation 6: Japanese Unexamined Patent Publication 2007-130145 publication
Summary of the invention
In view of the foregoing, the object of the present invention is to provide a kind of skin feel good, and the biobattery therapeutic appliance of excellent galvanism effect can be obtained.
In order to solve above-mentioned problem, the present invention has following structure.
1, the present invention is a kind of biobattery therapeutic appliance, its electric layer having supporter and fix formation in above-mentioned supporting body surface, it is characterized in that,
Above-mentioned electric layer has: base material; The negative pole of zinc oxide fine particles, it is included in above-mentioned base material dispersedly, works as N-type semiconductor; And the positive pole of fine particle of noble metal, it is included in above-mentioned base material dispersedly,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
The negative pole of above-mentioned zinc oxide fine particles contacts with each other with the positive pole of fine particle of noble metal at least partially at least partially, forms biological battery unit, and biological battery unit configuration on substrate surface at least partially.
2. a biobattery therapeutic appliance, its electric layer having supporter and fix formation in above-mentioned supporting body surface, is characterized in that,
Above-mentioned electric layer has: negative electrode layer, and it has base material and is included in the negative pole of the zinc oxide fine particles worked as N-type semiconductor in above-mentioned base material dispersedly; And
The positive pole of noble metal film, it is fixedly present between above-mentioned supporter and above-mentioned negative electrode layer,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
The negative pole of above-mentioned zinc oxide fine particles is configured in substrate surface at least partially, with the positive contact of noble metal film, forms biological battery unit.
3. a biobattery therapeutic appliance, it has the multiple base materials forming power generation section on surface, and links the supporter of above-mentioned multiple base material, it is characterized in that,
Above-mentioned power generation section has: the negative pole of zinc oxide fine particles, and it is included in above-mentioned substrate surface dispersedly, works as N-type semiconductor; And the positive pole of fine particle of noble metal, it is included in above-mentioned substrate surface dispersedly,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
The negative pole of zinc oxide fine particles contacts with each other with the positive pole of above-mentioned fine particle of noble metal at least partially at least partially, forms biological battery unit at substrate surface.
4. a biobattery therapeutic appliance, its power generation section having base material and fix formation at above-mentioned substrate surface, is characterized in that,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
Above-mentioned power generation section makes the negative pole of the zinc oxide fine particles worked as N-type semiconductor, contact with each other with the positive pole of fine particle of noble metal and the multiple arranged in parallel of biological battery unit that forms, forms electric loop.
5. a biobattery therapeutic appliance, its power generation section having base material and fix formation at above-mentioned substrate surface, is characterized in that,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
Above-mentioned power generation section makes the negative pole of the zinc oxide fine particles worked as N-type semiconductor, contact with each other with the positive pole of fine particle of noble metal and the multiple arranged in series of biological battery unit that forms, forms electric loop.
6., as the biobattery therapeutic appliance described in any one in 1 to 3, it is characterized in that, the material that above-mentioned supporter is between above-mentioned zinc oxide fine particles and above-mentioned noble metal granule by ionization tendency is formed.
In addition, in this description, claims, the weight portion of base material represents dry weight part of base material (dry weight part of binding agent).
In the record of this description, claims, " zinc oxide fine particles " comprises at least surface is the microgranule of zinc oxide.In addition, " fine particle of noble metal " at least surf zone of comprising microgranule is by the coated microgranule of noble metal.Such as, silver-plated copper powder etc. are the fine particle of noble metal that the present invention relates to.
In the record of this description, claim, so-called " microgranule " refers to the particle having and form the required large small particle diameter of the biobattery therapeutic appliance that the present invention relates to.
The mean diameter of zinc oxide fine particles is the value utilizing BET to count and calculate according to specific surface area.
The mean diameter of the fine particle of noble metal of argentum powder etc. is the value of the D50 measured by laser diffractometry.
The effect of invention
According to the present invention, skin feel can be provided good, and the biobattery therapeutic appliance of excellent electric current effect of stimulation can be obtained.
Accompanying drawing explanation
Fig. 1 is the sectional view of 1 example representing existing general biobattery therapeutic appliance.
Fig. 2 is the sectional view of the 1st embodiment representing this biobattery therapeutic appliance.
Fig. 3 is the key diagram of the 2nd embodiment representing this biobattery therapeutic appliance, and (a) is top view, and (b) is the sectional view along III-III line.
Fig. 4 is the sectional view of the 4th embodiment representing this biobattery therapeutic appliance.
Fig. 5 is the top view of the 5th embodiment representing this biobattery therapeutic appliance.
Fig. 6 is the sectional view of the 6th embodiment representing this biobattery therapeutic appliance, and (a) represents one of them example, and (b) represents other examples, and (c) is the key diagram of the action effect of the biobattery of ball chain.
Fig. 7 is the sectional view of the 7th embodiment representing this biobattery therapeutic appliance.
Fig. 8 is the sectional view of an example of the 8th embodiment representing this biobattery therapeutic appliance.
Detailed description of the invention
The feature of this biobattery therapeutic appliance is, the zinc oxide fine particles being used as N-type semiconductor to work, as negative pole, makes the positive contact of itself and noble metal, forms biobattery.
Below, embodiments of the present invention are described in detail.
(the 1st embodiment)
For the 1st embodiment of biobattery therapeutic appliance, Fig. 2 is used to be described.
This biobattery therapeutic appliance 20 has supporter 21 and is fixed on an electric layer 24 of this supporting body surface.As playing an electric layer 24, by being distributed the positive pole 22 (representing by dark circles) be made up of fine particle of noble metal and the negative pole 23 (representing by white circular) be made up of the zinc oxide fine particles worked as N-type semiconductor forms in base material 25 (such as binding agent).The negative pole 23 of above-mentioned zinc oxide fine particles and the positive pole 22 of fine particle of noble metal at least partially contact with each other at least partially, form biological battery unit, and biological battery unit are configured in substrate surface at least partially.
If be mixed together with fine particle of noble metal by the zinc oxide fine particles of nanoscale or magnitude close with it and coordinate in the substrate, then a large amount of zinc oxide fine particles contacts with fine particle of noble metal, forms countless biological battery unit.
Further, when these microgranules and contact skin, electric loop is formed, by micro-electric current on skin.Because positive pole 22 and negative pole 23 are all microgranules, so not coarse with the surface of contact skin, compared with prior art there is good skin feel.And, because form countless biological battery unit at substrate surface, so can carry out stable and generate electricity fully.
As long as positive pole 22 fine particle of noble metal.As the metal that fine particle of noble metal uses, as long as chemical change is less likely to occur and the noble metal that electrode potential is higher compared with the semiconductor particle becoming negative pole or its alloy.Such as, can be gold (Au) silver (Ag), platinum family and alloy thereof etc.
As fine particle of noble metal, its particle diameter is not be particularly limited to, but from forming the angle of multiple biological battery unit, preferably less particle diameter, and from the angle manufactured, thicker particle diameter easily processes.If the compromise both realizing, then can use that such as mean diameter is 1nm to 50 μm of scope, the noble metal of mean diameter 20nm to 15 μm, mean diameter 10 μm to 15 μm, mean diameter 20nm to 40nm etc.But the present invention is defined as these microgranules.
As long as the zinc oxide fine particles that negative pole works as N-type semiconductor.The metallographic phase ratio that zinc oxide fine particles and above-mentioned fine particle of noble metal use, has lower standard single electrode potential.Because zinc oxide fine particles works as N-type semiconductor, so known any means process zinc oxide fine particles can be utilized, such as, adulterate as long as carry out N-type, namely utilize aluminum (Al), calcium (Ga), antimony (Sb) etc. to adulterate to zinc oxide fine particles.But the present invention carries out this process, be not be defined in the zinc oxide fine particles worked as N-type semiconductor.
The particle diameter of zinc oxide fine particles is not particularly limited, but mean diameter is at 1nm to 200nm, preferred 1nm to 100nm, especially preferably the scope of 1nm to 50nm.In addition, mean diameter can be 20nm to 15 μm, 10 μm to 15 μm, the size etc. of 20nm to 40nm.
As long as base material 25 is during fabrication as the material that binding agent works, such as, be the synthetic resin of thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin etc.
The fine particle of noble metal contained in base material 25, be such as 25 weight portion to 30 weight portions relative to base material 100 weight portion, in addition, the zinc oxide fine particles contained in base material is 25 weight portion to 50 weight portions relative to base material 100 weight portion.
To the fine particle of noble metal of base material 25 and the mixing of zinc oxide fine particles, such as, by by base material dissolves in a solvent, fine particle of noble metal and zinc oxide fine particles dispersion can be blended in its medium known any means and carry out.
And, using by dispersion mixing containing fine particle of noble metal and the base material 25 of zinc oxide fine particles that works as N-type semiconductor, relative to supporter 21, by such as applying, spraying, screen, silk screen printing, any known method such as injection mo(u)lding and/or mould molding fix, and formed electric layer 24.
The thickness (maximum gauge) playing electric layer 24 can correspond to the using method of this biobattery therapeutic appliance 20, desirably selects.Such as, be less than or equal to 150 μm, be less than or equal to 100 μm, be less than or equal to 50 μm, be less than or equal to 10 μm, preferably 5 to 10 μm.
As long as above-mentioned supporter 21 can be applicable to the base material with any materials such as flexible paper, cloth, non-woven fabrics or plastic foils of skin shape.When using by making this biobattery therapeutic appliance and contact skin, what preferably can be suitable for skin shape has flexible paper, cloth, non-woven fabrics or plastic foil etc., by applying these materials, can improve skin feel further.
Play electric layer 24 to the forming region of supporter 21, can be supporter 21 expectation surface on the surface area of expectation.Such as, can be at least one surface of supporter at least partially, in this case, can be coated with on same above-mentioned surface and be applied to the fixing bonding agent of skin.In addition, electric layer can be played in the formation on the whole at least one surface of supporter 21.In this case, this biobattery therapeutic appliance can also be fixed on for skin adhesive, attachment or fixing fixed part, such as, in adhesive tape.
(the 2nd embodiment)
For the 2nd embodiment of biobattery therapeutic appliance, Fig. 3 (a) and (b) is used to be described.
Fig. 3 (a) is the top view of this biobattery therapeutic appliance 30 in the 2nd embodiment, and Fig. 3 (b) is the III-III line sectional view along Fig. 3 (a).
Multiple the electric layer 24 that this biobattery therapeutic appliance 30 comprises supporter 21 and is fixed on the surface of above-mentioned supporter 21.Play electric layer 24 in base material 25, comprise the positive pole 22 be made up of fine particle of noble metal and the negative pole 23 be made up of the zinc oxide fine particles worked as N-type semiconductor, be fixed on above-mentioned supporting body surface and formed.
In Fig. 3 (b), represent positive pole 22 by dark circles, represent negative pole 23 by white circular.
This biobattery therapeutic appliance 30 in 2nd embodiment is except comprising multiple electric layer 24, identical with the structure of this biobattery therapeutic appliance recorded in the 1st embodiment, forms loop with contact skin.This biobattery therapeutic appliance that its action effect is also recorded with the 1st embodiment is in essence identical.
(the 3rd embodiment)
The supporter 21 that can make that this biobattery therapeutic appliance replaces in above-mentioned 1st embodiment and the 2nd embodiment is suitable for the base material with flexibility of skin shape, uses arbitrary metal.Other structures can be the structures identical with this biobattery therapeutic appliance of the 1st embodiment and the 2nd embodiment.As long as contained the base material of the positive pole 22 be made up of fine particle of noble metal and the negative pole 23 be made up of the zinc oxide fine particles worked as N-type semiconductor by the surperficial fixed packet of the supporter 21 at metal, thus formed electric layer 24.
By using the supporter of metal, can as uses such as necklace, pendicle and bracelets.
When using the supporter of metal, especially, the material that can be between above-mentioned zinc oxide fine particles and fine particle of noble metal by ionization tendency forms supporter.Such as, when fine particle of noble metal is Au, material between above-mentioned zinc oxide fine particles and Au, the i.e. formation such as such as Ag, Cu, Sn can be in by ionization tendency.By such formation, between the negative pole 23 and the positive pole 22 of fine particle of noble metal of supporter 21, above-mentioned zinc oxide fine particles, produce electromotive force, the ability realizing biobattery therapeutic appliance improves.In addition, in this case, the material that whole supporter is all between above-mentioned zinc oxide fine particles and fine particle of noble metal by ionization tendency is not needed to form.As long as only made surface be made up of above-mentioned material by plating, the object of expection can be reached.
(the 4th embodiment)
Other examples of the shape of the supporter 21 changed in above-mentioned 1st embodiment and the 2nd embodiment are represented in Fig. 4.This biobattery therapeutic appliance of 4th embodiment changes the shape of the supporter in above-mentioned 3rd embodiment.Other structure can be identical with the 3rd embodiment.
The supporter 42 that this biobattery therapeutic appliance 40 comprises handle 41, be wholely set with this handle 41, above-mentioned supporting body surface formed comprise positive pole and negative pole play electric layer 43.Playing electric layer 43 can be the structure identical with the 1st embodiment or the 2nd embodiment.
Supporter 42 can be following structure, it is under the state be integrated with handle 41 one-tenth, axle centered by the axle running through the length direction of this biobattery therapeutic appliance, makes a part for this biobattery therapeutic appliance comprising supporter 42 or play electric layer 43 rotate, thus works as cylinder.In this case, user can hold handle 41, has made electric layer 43 and the part contact that will dispose, while make it roll, thus uses biobattery therapeutic appliance.
(the 5th embodiment)
Fig. 5 is used to be described for the 5th embodiment of this biobattery therapeutic appliance.
This biobattery therapeutic appliance 50 has supporter 51 and is formed in an electric layer 54 of above-mentioned supporting body surface, and this plays electric layer 54 and has anode layer 52 and negative electrode layer.Anode layer 52 is the noble metal films formed at least partially on the surface of supporter 51.Negative electrode layer is formed on the region on anode layer 52 i.e. noble metal film, and a part for anode layer 52 is exposed.Negative electrode layer dispersion in the base material 5 (binding agent) mixes the negative pole 53 that such as mean diameter is the zinc oxide fine particles worked as N-type semiconductor of 1nm to 50 μm.The combined amount of zinc oxide fine particles is for such as forming relative to base material (binding agent) 100 weight portion dispersion mixed oxidization zinc microgranule 25 weight portion to 50 weight portion, and the negative electrode layer formed in this manner is fixed on metal layer thin film.Further, the surface being configured in base material 55 at least partially of negative pole 53, contacts with anode layer 52.
Except the structure of anode layer 52, the structure of this biobattery therapeutic appliance 50 i.e. supporter 51, base material 55 and negative pole 53 can be identical to the 4th any one structure of embodiment with the 1st embodiment.
In addition, the microgranule of the not necessarily zinc oxide of the negative pole 53 in this biobattery therapeutic appliance 50 also can be the oxidized zinc microgranule (that is, surface is the zinc microgranule of zinc oxide) in surface.This biobattery therapeutic appliance 50 such as forms positive pole 52 by gold-plated grade, and then, as long as at the arbitrary region of positive pole 52 (anode layer), immobile phase contains the negative electrode layer of the zinc microgranule of 25 weight portion to 50 weight portions for binding agent 100 weight portion.The oxidation of zinc microparticle surfaces can be carried out in any one manufacture process.By this structure, the operation such as pulverizing, uniform granulation of the zinc oxide after the doping of zinc oxide, doping can be omitted.This is because the surface oxidation of zinc microgranule, form the zinc oxide overlay film as N-type semiconductor.Thus, the zinc that can be contained by this microgranule and zinc oxide carry out the stable conduction of ZnOZn.
(the 6th embodiment)
Fig. 6 (a) represents the 6th embodiment.This biobattery therapeutic appliance 60 is the structures being linked multiple spheroidal substrate 65 by supporter 61.In addition, base material is not limited to spherical, can become the arbitrary shapes such as ellipticity, tabular, drops.
The synthetic resin etc. mentioned in the explanation of earlier embodiments is being used as base material, with its mixing and when coordinating, be distributed the zinc oxide fine particles and fine particle of noble metal that work as N-type semiconductor at this substrate surface, be dispersed in above-mentioned substrate surface and the contacting with each other at least partially of the negative pole of above-mentioned zinc oxide fine particles contained and the positive pole of above-mentioned fine particle of noble metal.
As other examples of the 6th embodiment, as shown in Fig. 6 (b), by noble metal film (positive pole) coated substrate surface, be distributed the zinc oxide fine particles worked as N-type semiconductor on the thin film also effective.
The material linking the supporter of base material is not particularly limited, but preferred ionization is inclined to the material (when noble metal film is Au, such as, being Ag, Cu, Sn etc.) be between zinc oxide fine particles and noble metal film.
In the above-described embodiment, be not limited in base material (binding agent), after dispersion mixing " zinc oxide fine particles and fine particle of noble metal " or " zinc oxide fine particles ", base material is solidified and manufacture, also first base material can be made, then at its Dispersion on surface mixing " zinc oxide fine particles and fine particle of noble metal " or " zinc oxide fine particles ".This structure is also identical with " zinc oxide fine particles and fine particle of noble metal " or " zinc oxide fine particles " in aforementioned embodiments.
Fig. 6 (c) is the key diagram of the action effect of the biobattery representing ball chain, represents the state that positive pole (fine particle of noble metal) 62 and negative pole (zinc oxide fine particles) 63 and the biology B such as (human body skin) contacts.Figure just is to the left that zinc oxide fine particles 63 contacts with fine particle of noble metal 62 and the example configured.In this case, because positive pole and cathode contact, so electric current as shown by arrows, the part more shallow at skin surface is passed through.Figure just is to the right the example of zinc oxide fine particles 63 and fine particle of noble metal 62 configured separate.Label 80 is the conductors connecting zinc oxide fine particles 63 and fine particle of noble metal 62.In this example embodiment because positive pole 62 and negative pole 63 away from, so electric current passes through in the part that skin is darker as shown by arrows.Its result, stimulates cell through multiple cell.Therefore, by suitably adjusting the spacing of setting positive pole 62 and negative pole 63, distribution, combined amount, the biobattery of the expectation corresponding to object can be become.
(the 7th embodiment)
Fig. 7 represents the 7th embodiment.This biobattery therapeutic appliance 70, playing an electric layer is make the negative pole 73 of the zinc oxide fine particles worked as N-type semiconductor in parallel with the biological battery unit that the positive pole 72 of fine particle of noble metal contacts with each other and/or be connected in series, and base material 71 forms electric loop.This structure is by application of printed layout techniques, and those skilled in the art can easily manufacture, and can form can the very large biobattery therapeutic appliance of generating capacity of degree of electrical generation.Therefore, also can connect LED etc. as required makes it luminous.
(the 8th embodiment)
Below, the 8th embodiment for the biobattery of fiber shape is described.
The fiber of regulation forms following conducting fibre (below by this conducting fibre referred to as N fiber), it is in the resin worked as binding agent, (at least surface is the microgranule of zinc oxide to be mixed into the zinc oxide of micro particles, such as, comprise the microgranule that the oxidized zinc in surface of zinc is coated), or carry out lamination etc. and make it work as N-type semiconductor.Here, N fiber forms the supporter that the present invention relates to and an electric layer with base material and negative pole.
Form to become the conducting fibre (following, by this conducting fibre referred to as A fiber) that the noble metal of positive pole is main component.Here, A fiber forms supporter and has an electric layer of base material and positive pole.
The conductive fiber (following, by this conducting fibre referred to as C conductive fiber) that preparation can be energized.This conductive fiber preferred ionization tendency is between both positive and negative polarity.Here, C conductive fiber forms the supporter or supporter and base material that the present invention relates to.
N-type semiconductor is processed into the appropriate structuring of expectation, prepares easily to be fixed on particle on fiber (below by this particle referred to as N particle).Here, N particle forms the negative pole that the present invention relates to.
Noble metal is processed into the appropriate structuring of expectation, prepares easily admittedly to withstand on particle on fiber (below by this particle referred to as A particle).Here, A particle forms the positive pole that the present invention relates to.
The biobattery of fiber shape by suitably selecting from above-mentioned N fiber, A fiber, fiber C, N particle and A particle, by material and the non-woven fabrics selected or fabric combination, form the supporter that has and the present invention relates to and be provided with the biobattery therapeutic appliance of an electric layer of base material, negative pole, positive pole.Following combination can be illustrated particularly.
1) by the structure of N fiber and A fiber combinations.By this structure, can obtain there is supporter and be provided with base material, negative pole, positive pole play the biobattery therapeutic appliance that the present invention of electric layer relates to.
2) by the structure of N fiber, A fiber and C conductive fiber combination.By this structure, can obtain there is supporter and be provided with base material, negative pole, positive pole play the biobattery therapeutic appliance that the present invention of electric layer relates to.
3) by the non-woven fabrics that is made up of N fiber or fabric and the particulate structure of A.By this structure, can obtain there is supporter and be provided with base material, negative pole, positive pole play the biobattery therapeutic appliance that the present invention of electric layer relates to.
4) above-mentioned 3) middle structure of adding C conductive fiber.By this structure, can obtain there is supporter and be provided with base material, negative pole, positive pole play the biobattery therapeutic appliance that the present invention of electric layer relates to.
5) by the non-woven fabrics that is made up of A fiber or fabric and the particulate structure of N.By this structure, can obtain there is supporter and be provided with base material, negative pole, positive pole play the biobattery therapeutic appliance that the present invention of electric layer relates to.
6) above-mentioned 5) middle structure of adding C conductive fiber.By this structure, can obtain there is supporter and be provided with base material, negative pole, positive pole play the biobattery therapeutic appliance that the present invention of electric layer relates to.
7) non-woven fabrics be made up of C conductive fiber or fabric and N particle, the particulate structure of A.By this structure, can obtain there is supporter and be provided with base material, negative pole, positive pole play the biobattery therapeutic appliance that the present invention of electric layer relates to.
8) by above-mentioned whole N fiber, A fiber, fiber C, N particle and the particulate structure of A.By this structure, can obtain there is supporter and be provided with base material, negative pole, positive pole play the biobattery therapeutic appliance that the present invention of electric layer relates to.
In addition, said structure is only illustrate.The biobattery of the fiber shape that the present invention relates to not is be defined in above-mentioned 1) to 8).In addition, except forming the biobattery of the fiber shape that the present invention relates to, other materials, parts, key element etc. can certainly be added.
In addition, in the 8th embodiment, the basic structure for the biobattery of fiber shape is illustrated, but in the 8th embodiment, can certainly suitably select and implement, to make the concrete structure that illustrates in above-mentioned 1st to the 7th embodiment item corresponding with the 8th embodiment.
The biobattery of above-mentioned fiber shape, has and becomes and can be pasted onto on health, or by processing the excellent results of the matched biobattery with health on medicated clothing.
(processing method of negative pole and positive pole)
As the processing method of negative pole and positive pole, dry plating (sputtering, ion plating, evaporation) can be enumerated.This processing method is particularly suitable for negative pole processing, by carrying out film printing to resin film or resin plate, synthetic resin, glass etc., thus can process pliable and tough electrode or complicated shape part completely.In addition, its electrical characteristic can obtain roughly with the degree of metal approach.Such as, as electrode, the plate after sputtering can be processed into the shape of needs, carry out mask processing according to demand, or utilize the mask printing etc. such as insulating to be processed into the electric shape of needs after processing.
The biobattery making negative pole when being mixed into the N-type semiconductor of attritive powder in binding agent is pasted onto on skin, generating capacity is poor, about only having 0.7 to 0.8 volt at the most, but when to be joined by zinc oxide in resin film as electrode by sputtering, there is about 1.3 volts and roughly identical with the situation of metal generating capacity.In addition, the color of negative pole is roughly transparent, combines, also can not damage the metal appearance of positive pole as biobattery and positive pole.
Such as, when making biobattery link continuously in the mode of chain, from chain one end to other end overgild, after the chain only becoming negative pole is gold-plated, sputtered by anticathode, one of this chain surperficial whole or surperficial part is processed, also there is the design effect that outward appearance appears to gold chain.
In addition, the supporter 90 of conductor can be utilized to link the positive pole chain 82 shown in Fig. 8 and negative pole chain 83.Further, the positive pole formed in this manner and negative pole, by the medicament 91 of glue and contact skin.Utilize this structure, supporter 90 preferred ionization is inclined to the material be between positive and negative pole material, and the material be inclined to by utilizing intermediate-ionization links, and positive pole and negative pole entirety are with rectangular generating.
[embodiment]
Make the biobattery suitable with above-mentioned 1st embodiment, observe power generation stability etc.
Embodiment 1
Making embodiment 1 and 2 as follows, plays electric layer surface application normal saline respective, evaluates the stability of generating as electrical characteristic.In addition, the respective state playing electric layer surface and outward appearance are evaluated.
Use allyl resin as base material, negative pole uses the mean diameter after being adulterated by aluminum to be the zinc oxide fine particles of 10 to 15 μm, and positive pole use mean diameter is the silver-colored microgranule of 10 to 15 μm.
Make this zinc oxide fine particles and silver-colored microgranule with the ratio equal with the dry weight of base material, mix with the base material dissolved in a solvent.Solidified and manufactured the biobattery suitable with the 1st embodiment.By oxide powder and zinc and argentum powder respectively using the biobattery of 25 weight portions mixing as embodiment 1, by relative to base material 100 weight portion respectively using the biobattery of 30 weight portions mixing as embodiment 2.
All stable generating can be obtained in embodiment 1 and 2.The fluctuation that do not generate electricity can be observed, and the generating of abundant generated energy.
In addition, embodiment 1 and 2, the silver of positive pole becomes silver yellow color from metallochrome, judges that the color of electric layer is also preferred for commodity.
Embodiment 3
Making embodiment 3 as follows.At each battery surface coating normal saline, evaluate power generation stability as electrical characteristic.In addition, the apparent condition of each battery and outward appearance are evaluated.
Use allyl resin as base material, negative pole uses the mean diameter after being adulterated by aluminum to be the zinc oxide fine particles of 20 to 40nm, and positive pole use mean diameter is the silver-colored microgranule of 20 to 40nm.As embodiment 3, use the silver-colored microgranule of the zinc oxide fine particles of 50 weight portions and 30 weight portions, manufacture the biobattery suitable with the 1st embodiment as described above.
In embodiment 3, confirm stable and generate electricity fully.In addition, play the outward appearance of electric layer, the metallochrome of silver-colored microgranule becomes silver yellow color, and the transparency of zinc oxide fine particles is very high.When making an electric layer for embodiment 3 be formed as gold-plated metal, the metallochrome observing substrate can be penetrated.It can think very good feature as commodity.
In addition, when using an electric layer of this composition to manufacture biobattery therapeutic appliance, can carry out the silk screen printing of small mesh, thus, what manufacture 5 to 10 microns thickness plays electric layer.Thus the miniaturization of biobattery therapeutic appliance can be realized.
Embodiment 4
Use allyl resin as base material, negative pole uses the mean diameter after being adulterated by aluminum to be the zinc oxide fine particles of 150 to 250nm, and positive pole use mean diameter is the silver-colored microgranule of 10 to 15 μm.Relative to dry weight 100 weight portion of base material, the silver-colored microgranule of the zinc oxide fine particles of 50 weight portions and 25 weight portions is mixed with the base material dissolved in a solvent.Solidified, manufactured the biobattery suitable with the 1st embodiment, as embodiment 4.
Embodiment 4 had not both generated electricity fluctuation yet, did not play the fluctuation on electric layer surface yet, well-behaved as biobattery.But the transparency of negative pole particle is inadequate, and the feature as commodity is worse than embodiment 3.The known transparency in order to obtain negative pole particle, must make the mean diameter of zinc oxide fine particles be 20 to 40nm.
Embodiment 5
Use allyl resin as base material, negative pole uses the mean diameter of being adulterated by aluminum to be the zinc oxide fine particles of 20 to 40nm, and positive pole use mean diameter is the silver-colored microgranule of 10 to 15 μm.Relative to dry weight 100 weight portion of base material, the silver-colored microgranule of the zinc oxide fine particles of 50 weight portions and 25 weight portions is mixed with the base material dissolved in a solvent.Solidified, manufactured the biobattery suitable with the 1st embodiment, as embodiment 5.
Embodiment 5 can obtain stable and generate electricity fully.In addition, the transparency of zinc oxide fine particles is high, and alternate with the color of the silver-colored microgranule of silver yellow color, shows excellent external appearance characteristic when providing as commodity.When making an electric layer for embodiment 5 be formed as filled gold, the gold seeing substrate can be penetrated.It is considered to very good feature as commodity.
Comparative example 1
Making comparative example as follows, at each battery surface coating normal saline, evaluates the stability of generating as electrical characteristic.In addition, the state and outward appearance that play electric layer surface are evaluated.Here the weight portion occurred is the numerical value relative to base material 100 weight portion.
Use allyl resin (binding agent) as base material, negative pole uses the mean diameter after being adulterated by aluminum to be the Zinc oxide powder of 250 to 350 μm, and positive pole uses the silver powder of 250 to 350 μm.
Relative to the dry weight of base material, with identical ratio, that is, with 10 weight portions, argentum powder and doping zinc-oxide powder are mixed with by the base material after dissolution with solvents respectively.Solidified, manufacture biobattery and obtain comparative example 1.
In comparative example 1, rising between different region, electric layer surface, generating has fluctuation, cannot obtain stable generating.
As the reason that cannot obtain stable electric generation, inventor infers it is because the particle diameter of Zinc oxide powder is comparatively large, the quantity of biological battery unit cannot be made many to degree of the present invention, in addition, cannot be distributed equably.
[industrial applicibility]
According to the present invention, a kind of skin feel can be provided good, and the biobattery therapeutic appliance of excellent galvanism effect can be obtained.This biobattery therapeutic appliance by promoting blood circulation, the refuse of purification local retention, thus ache and the treatment of pain in the lumbar region etc. and prevention at shoulder, and the beauty treatment fields such as skin maintenance, skin quality improvement all can effectively use.
In addition, the utensil that the material after ionizing imports through skin can use as the generating by above-mentioned biobattery by this biobattery.
In addition, biobattery therapeutic appliance of the present invention can effectively for various equipment.
Such as, when being applied to ultrasonic beautifying device, using ultrasonic beautifying device as supporter, what formation thereon the present invention relates to plays electric layer (such as, using main body side as side of the positive electrode, side will be contacted as negative side with face, thus make it have the function as biobattery therapeutic appliance of the present invention), thus, the Overlay of the ultrasound wave as ultrasonic beautifying device and the galvanism effect as biobattery therapeutic appliance can be played.
In addition, formed the nasal cavity expansion parts of nasal cavity expansion band by conductive material, form the electric layer that the present invention relates to.As playing electric layer, such as, make one end be side of the positive electrode, make multiterminal be negative side, entirety also can form positive pole, negative pole.The nasal cavity expansion band formed thus, has and has the situation of nasal blockage inferior at user, can improve the effect of blood circulation obstacle etc.In addition, if by the nasal cavity expansion band formed thus with upper side through the conductive material of metal wire etc. can along nose shape the mask combination that bends uses, can by the conductive material of metal wire, increase galvanism effect further.
Claims (6)
1. a biobattery therapeutic appliance, its electric layer having supporter and fix formation in above-mentioned supporting body surface, is characterized in that,
Above-mentioned electric layer has: base material; The negative pole of zinc oxide fine particles, it is included in above-mentioned base material dispersedly, works as N-type semiconductor; And the positive pole of fine particle of noble metal, it is included in above-mentioned base material dispersedly,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
The negative pole of above-mentioned zinc oxide fine particles contacts with each other with the positive pole of fine particle of noble metal at least partially at least partially, forms biological battery unit, and biological battery unit configuration on substrate surface at least partially.
2. a biobattery therapeutic appliance, its electric layer having supporter and fix formation in above-mentioned supporting body surface, is characterized in that,
Above-mentioned electric layer has: negative electrode layer, and it has base material and is included in the negative pole of the zinc oxide fine particles worked as N-type semiconductor in above-mentioned base material dispersedly; And
The positive pole of noble metal film, it is fixedly present between above-mentioned supporter and above-mentioned negative electrode layer,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
The negative pole of above-mentioned zinc oxide fine particles is configured in substrate surface at least partially, with the positive contact of noble metal film, forms biological battery unit.
3. a biobattery therapeutic appliance, it has the multiple base materials forming power generation section on surface, and links the supporter of above-mentioned multiple base material, it is characterized in that,
Above-mentioned power generation section has: the negative pole of zinc oxide fine particles, and it is included in above-mentioned substrate surface dispersedly, works as N-type semiconductor; And the positive pole of fine particle of noble metal, it is included in above-mentioned substrate surface dispersedly,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
The negative pole of zinc oxide fine particles contacts with each other with the positive pole of above-mentioned fine particle of noble metal at least partially at least partially, forms biological battery unit at substrate surface.
4. a biobattery therapeutic appliance, its power generation section having base material and fix formation at above-mentioned substrate surface, is characterized in that,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
Above-mentioned power generation section makes the negative pole of the zinc oxide fine particles worked as N-type semiconductor, contact with each other with the positive pole of fine particle of noble metal and the multiple arranged in parallel of biological battery unit that forms, forms electric loop.
5. a biobattery therapeutic appliance, its power generation section having base material and fix formation at above-mentioned substrate surface, is characterized in that,
Above-mentioned base material is any one synthetic resin in thermoplastic resin, acrylic resin, polyurethane resin, polyvinyl acetate, polrvinyl chloride, polyester, polyethers, polyacrylonitrile, polystyrene, polyethylene, polypropylene, polyamide, poly-carbonic acid and phenoxy resin
Above-mentioned power generation section makes the negative pole of the zinc oxide fine particles worked as N-type semiconductor, contact with each other with the positive pole of fine particle of noble metal and the multiple arranged in series of biological battery unit that forms, forms electric loop.
6., as the biobattery therapeutic appliance in claims 1 to 3 as described in any one, it is characterized in that,
The material that above-mentioned supporter is between above-mentioned zinc oxide fine particles and above-mentioned noble metal granule by ionization tendency is formed.
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| JP2011056706 | 2011-03-15 | ||
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| JP2012045494A JP5881158B2 (en) | 2011-03-15 | 2012-03-01 | Biological battery treatment tool |
| JP2012-045494 | 2012-03-01 |
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| CN106256388A (en) * | 2015-06-22 | 2016-12-28 | 小蒲贤司 | Organism battery therapeutic appliance |
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| JP6652513B2 (en) * | 2016-03-03 | 2020-02-26 | 信越化学工業株式会社 | Bioelectrode manufacturing method |
| JP6549517B2 (en) * | 2016-05-09 | 2019-07-24 | 信越化学工業株式会社 | Bioelectrode and method of manufacturing the same |
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| JP2000237322A (en) * | 1999-02-24 | 2000-09-05 | Satellite Intelligence:Kk | Skin contact treatment tool using fine battery |
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