CN102660411B - Environment-friendly paraffin removing agent and preparation method thereof - Google Patents

Environment-friendly paraffin removing agent and preparation method thereof Download PDF

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Publication number
CN102660411B
CN102660411B CN 201210131526 CN201210131526A CN102660411B CN 102660411 B CN102660411 B CN 102660411B CN 201210131526 CN201210131526 CN 201210131526 CN 201210131526 A CN201210131526 A CN 201210131526A CN 102660411 B CN102660411 B CN 102660411B
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China
Prior art keywords
agent
removing agent
environment
environmental protection
inorganic salt
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CN102660411A (en
Inventor
朱孔浩
蒋振华
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Jingrui Electronic Materials Co.,Ltd.
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SUZHOU JINGRUI CHEMICAL CO Ltd
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Abstract

The invention discloses an environment-friendly paraffin removing agent and a preparation method thereof. The environment-friendly paraffin removing agent consists of the following components in part by weight: 0.1-10 parts of inorganic salt, 0.01-3 parts of wetting agent, 0.01-3 parts of emulsifying agent, 0.01-3 parts of solubilizing agent and 80-99 parts of deionized water; the inorganic salt is one or a mixture of ethylenediaminetetraacetic acid tetrasodium and sodium citrate; the wetting agent is iso-tridecanol polyoxyethylene ether (9EO); the emulsifying agent is an anionic surfactant; and the solubilizing agent is tween 80. The preparation method comprises the following steps of: adding the inorganic salt in the deionized water, adequately agitating, and then, adding the wetting agent, the emulsifying agent and solubilizing agent, and agitating uniformly to prepare the environment-friendly paraffin removing agent. The environment-friendly paraffin removing agent provided by the invention is good in paraffin removal effect, does not include a volatile solvent, and is nontoxic, nonirritating and environment-friendly, and the cost for waste water treatment is greatly reduced.

Description

A kind of environmental protection wax removing agent and preparation method thereof
Technical field
The present invention relates to a kind of wax removing agent and preparation method thereof, relate in particular to a kind of environmental protection wax removing agent and preparation method thereof.
Background technology
Wax removing agent is of many uses in the industrial processes production process, is mainly used to remove the wax layer of workpiece surface.
The wax removing agent of selling in the market exists long, energy consumption of paraffin removal time greatly, easily workpiece to be caused corrosion and to shortcomings such as environment are unfriendly.
Chinese invention patent application prospectus CN102250698A discloses a kind of wax removing agent, contain the polyoxyethylene nonylphenol ether series of surfactants in described composition, the tensio-active agent of this nonyl phenol series exists all that biological degradability is poor, lipotropy is strong, easily at mud and biological cylinder accumulation, and may jeopardize by food chain the shortcoming of the existence of all species with chronic effect.
Chinese invention patent application prospectus CN102212836A discloses Wax removal water and the compound method thereof that is used for cleaning polishing workpiece surface wax dirt, contain a large amount of tripoly phosphate sodium STPPs in wherein said Wax removal water, contain the discharging of phosphorus waste liquid, easily cause body eutrophication, to environment, threaten ecotope.
Summary of the invention
For the deficiencies in the prior art, one of technical problem to be solved by this invention is to provide a kind of environmental protection wax removing agent, does not use any organic solvent, and nontoxic, nonirritant, environmentally friendly, greatly reduces the cost of wastewater treatment.
Two of technical problem to be solved by this invention is to provide the preparation method of above-mentioned environmental protection wax removing agent.
The present invention seeks to be achieved through the following technical solutions:
A kind of environmental protection wax removing agent is made of by weight following component:
Inorganic salt 0.1-10 part;
Wetting agent 0.01-3 part;
Emulsifying agent 0.01-3 part;
Solubilizing agent 0.01-3 part;
Deionized water 80-99 part;
Described inorganic salt are a kind of or its mixture in tetrasodium ethylenediamine tetraacetate and Trisodium Citrate;
Described wetting agent is isomery-tridecanol polyoxyethylene ether (9EO);
Described emulsifying agent is anion surfactant;
Described solubilizing agent is tween 80.
Preferably, described anion surfactant is the polyether thiourea hydrochlorate.Optimum, described polyether thiourea hydrochlorate can be triton qs-15.Described triton qs-15, English another name: No. 15, CAS, Triton QS: the tensio-active agent TRITON QS-15 that 11105-10-5, the present invention adopt Dow Chemical to produce.
The present invention also provides a kind of preparation method of environmental protection wax removing agent, adopt following steps: first inorganic salt are added in deionized water and fully stir, and then add wetting agent, emulsifying agent and solubilizing agent, and stir, can make a kind of environmental protection wax removing agent of the present invention.
The concrete application of environmental protection wax removing agent of the present invention can be: at first, regulate the temperature of environmental protection wax removing agent at 20-80 ℃, content of wax workpiece is immersed in this environmental protection wax removing agent fully, can complete dewaxing in standing 3-10 minute.After the wax on content of wax workpiece removes fully, take out workpiece and clean up, namely complete the paraffin removal whole process of content of wax workpiece.
Environmental protection wax removing agent of the present invention, paraffin removal is effective, does not contain volatile solvent, and nontoxic, nonirritant is environmentally friendly, greatly reduces the cost of wastewater treatment.
Embodiment
The invention will be further described below by specific embodiment, but the present invention is not limited by following examples.
Embodiment 1:
Take each raw material according to corresponding embodiment 1 data of table 1.
Inorganic salt are added in deionized water fully stir, then add respectively wetting agent, emulsifying agent and solubilizing agent to stir, can make a kind of environmental protection wax removing agent of the present invention.
Get a certain amount of environmental protection wax removing agent in container, content of wax workpiece is immersed in the environmental protection wax removing agent fully.Control and remove wax liquid temperature at 20 ℃, standing 10 minutes.After wax removes fully, take out workpiece and water and clean up, namely complete the whole process that this process materials uses.
Table 1: environmental protection wax removing agent formula table unit: kilogram
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Tetrasodium ethylenediamine tetraacetate 0.1 / 4.5 / 5
Trisodium Citrate / 2 / 7 5
Isomery-tridecanol polyoxyethylene ether (9EO) 0.01 0.2 2 1 3
Tensio-active agent TRITON QS-15 3 1 2 0.01 0.05
Tween 80 3 2 1 0.05 0.01
Deionized water 80 85 90 95 99
Embodiment 2:
Take each raw material according to corresponding embodiment 2 data of table 1.Method according to embodiment 1 prepares environmental protection wax removing agent of the present invention.
Get a certain amount of environmental protection wax removing agent in container, content of wax workpiece is immersed in the environmental protection wax removing agent fully.Control and remove wax liquid temperature at 35 ℃, standing 8 minutes.After wax removes fully, take out workpiece and clean up, namely complete the whole process that this process materials uses.
Embodiment 3:
Take each raw material according to corresponding embodiment 3 data of table 1.Method according to embodiment 1 prepares environmental protection wax removing agent of the present invention.
Get a certain amount of environmental protection wax removing agent in container, content of wax workpiece is immersed in the environmental protection wax removing agent fully.Control and remove wax liquid temperature at 50 ℃, standing 6 minutes.After wax removes fully, take out workpiece and clean up, namely complete the whole process that this process materials uses.
Embodiment 4:
Take each raw material according to corresponding embodiment 4 data of table 1.Method according to embodiment 1 prepares environmental protection wax removing agent of the present invention.
Get a certain amount of environmental protection wax removing agent in container, content of wax workpiece is immersed in the environmental protection wax removing agent fully.Control and remove wax liquid temperature at 65 ℃, standing 4.5 minutes.After wax removes fully, take out workpiece and clean up, namely complete the whole process that this process materials uses.
Embodiment 5:
Take each raw material according to corresponding embodiment 5 data of table 1.Method according to embodiment 1 prepares environmental protection wax removing agent of the present invention.
Get a certain amount of environmental protection wax removing agent in container, content of wax workpiece is immersed in the environmental protection wax removing agent fully.Control and remove wax liquid temperature at 80 ℃, standing 3 minutes.After wax removes fully, take out workpiece and clean up, namely complete the whole process that this process materials uses.
Environmental protection wax removing agent of the present invention, paraffin removal is effective, does not contain volatile solvent, and nontoxic, nonirritant is environmentally friendly, greatly reduces the cost of wastewater treatment.
The above; it is only the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; variation or the replacement that can expect without creative work are within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.

Claims (3)

1. an environmental protection wax removing agent, is characterized in that, is comprised of by weight following component:
Inorganic salt 0.1-10 part;
Wetting agent 0.01-3 part;
Emulsifying agent 0.01-3 part;
Solubilizing agent 0.01-3 part;
Deionized water 80-99 part;
Described inorganic salt are a kind of or its mixture in tetrasodium ethylenediamine tetraacetate and Trisodium Citrate;
Described wetting agent is isomery-tridecanol polyoxyethylene ether 9EO;
Described emulsifying agent is anion surfactant, and described anion surfactant is the polyether thiourea hydrochlorate;
Described solubilizing agent is tween 80.
2. environmental protection wax removing agent as claimed in claim 1, it is characterized in that: described polyether thiourea hydrochlorate is triton qs-15.
3. the preparation method of environmental protection wax removing agent as claimed in claim 1 or 2, is characterized in that, adopts following steps: first inorganic salt are added in deionized water and fully stir, and then add wetting agent, emulsifying agent and solubilizing agent, stir.
CN 201210131526 2012-05-02 2012-05-02 Environment-friendly paraffin removing agent and preparation method thereof Active CN102660411B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN 201210131526 CN102660411B (en) 2012-05-02 2012-05-02 Environment-friendly paraffin removing agent and preparation method thereof

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CN102660411B true CN102660411B (en) 2013-06-19

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103831879B (en) * 2014-03-26 2016-05-25 湖北省林业科学研究院 A kind of bamboo material surface dewax method
CN105238377A (en) * 2015-09-23 2016-01-13 山东聚鑫化工有限公司 Water-based wax cleaning agent
US10767077B2 (en) * 2017-01-30 2020-09-08 Otis Elevator Company Load-bearing member surface treatment
CN107587149A (en) * 2017-11-03 2018-01-16 安徽新合富力科技有限公司 One kind seven is aluminium minute surface wax removing agent
CN109837077B (en) * 2019-03-13 2021-02-19 西安石油大学 Wax inhibitor-supported rubber paraffin removal ball and preparation method, preparation device and application thereof
CN110628521A (en) * 2019-10-10 2019-12-31 深圳市荣强科技有限公司 Surfactant for mobile phone wax removal and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1468950A (en) * 2002-07-15 2004-01-21 董丽萍 Multifunctional detergent
CN101033556A (en) * 2007-04-11 2007-09-12 姜堰市德美化工有限公司 Wax removal water for cleaning automobile aluminum wheel hub and preparing method thereof
CN101092558A (en) * 2007-07-20 2007-12-26 于毅 Viscosity reducting, de-waxing, deoiling auxiliary agent in use for extracting petroleum, and preparation method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1468950A (en) * 2002-07-15 2004-01-21 董丽萍 Multifunctional detergent
CN101033556A (en) * 2007-04-11 2007-09-12 姜堰市德美化工有限公司 Wax removal water for cleaning automobile aluminum wheel hub and preparing method thereof
CN101092558A (en) * 2007-07-20 2007-12-26 于毅 Viscosity reducting, de-waxing, deoiling auxiliary agent in use for extracting petroleum, and preparation method

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Address after: Cheng lake road, Wuzhong District Wuzhong Economic Development Zone of Suzhou City, Jiangsu Province, No. 3 215168

Patentee after: SUZHOU JINGRUI CHEMICAL CO., LTD.

Address before: Cheng lake road, Wuzhong District Wuzhong Economic Development Zone of Suzhou City, Jiangsu Province, No. 3 215168

Patentee before: Suzhou Jingrui Chemical Co.,Ltd.

CP03 Change of name, title or address

Address after: 215000 No. 168, Shanfeng Road, Hedong Industrial Park, Wuzhong Economic Development Zone, Suzhou, Jiangsu

Patentee after: Jingrui Electronic Materials Co.,Ltd.

Address before: 215168 No.3, Chenghu East Road, Wuzhong Economic Development Zone, Wuzhong District, Suzhou City, Jiangsu Province

Patentee before: SUZHOU CRYSTAL CLEAR CHEMICAL Co.,Ltd.

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