CN102660335B - Biological methanol oil prepared from illegal cooking oil products - Google Patents
Biological methanol oil prepared from illegal cooking oil products Download PDFInfo
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- CN102660335B CN102660335B CN201210184369.3A CN201210184369A CN102660335B CN 102660335 B CN102660335 B CN 102660335B CN 201210184369 A CN201210184369 A CN 201210184369A CN 102660335 B CN102660335 B CN 102660335B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B13/00—Recovery of fats, fatty oils or fatty acids from waste materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
- C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1826—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2200/00—Components of fuel compositions
- C10L2200/04—Organic compounds
- C10L2200/0461—Fractions defined by their origin
- C10L2200/0469—Renewables or materials of biological origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/74—Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes
Abstract
The invention discloses biological methanol oil prepared from illegal cooking oil products. The biological alcohol oil is characterized by being prepared by the following steps of: fully stirring the illegal cooking oil products which comprise 3-35 parts by weight of emulsifier and 2-25 parts by weight of water, so as to form emulsion; standing for 10-20 hours and then stirring and mixing the emulsion with 40-95 parts by weight of methanol; and standing for 4-8 hours to form the biological methanol oil. The illegal cooking oil product is an emulsifier which is obtained by removing water and impurities in the illegal cooking oil and saponifying obtained stearin and tripalmitin. The biological methanol oil disclosed by the invention has the advantages that the performance is stable, the oil is not liable to volatilize and does not self-ignite and in case ignition, the fire can be put out only by water. The product which has no toxin in combustion and no harm, no foreign smell and no smoke in use is novel renewable biomass energy source and conforms to national regulations according to monitoring by relevant departments. The biological methanol oil takes the illegal cooking oil product as a raw material so that the combustion performance is good, the cost is low and the biological methanol oil is of important significance in the aspects of reducing food safety threat, preventing the waste oil from polluting environment, reducing mineral fuel consumption and the like.
Description
Technical field
The present invention relates to a kind of bio-fuel-oil, particularly a kind ofly utilize discarded sewer oil to prepare kitchen range biological alcohol oil for raw material.
Background technology
Sewer oil is the refiltered oil that foreign material mix, and claims again hogwash fat, the number of chemical elements such as interior carbon containing, hydrogen, oxygen, sodium, calcium, potassium, manganese, iron, phosphorus, and main component is stearin and tripalmitin and multiple eating remaining mixture.Sewer oil comprises three classes: the one, by the greasy floating matter in water drain or by the leftovers of hotel, restaurant, the oil of leftovers (common name swill) through simply processing, extracting; The 2nd, the oil of output after pork inferior, haslet, pigskin processing and refinement; The 3rd, exceed after regulation the abendoned oil that the objectionable impuritiess such as peroxide value, acid value exceed standard for the oily access times of fried food product.Due to sewer oil complicated component, harmful, therefore, legal, effectively utilize sewer oil, threaten, avoid environmental pollution all significant reducing food safety.
Existing kitchen range fuel is mainly diesel oil, liquefied gas, piped gas and Sweet natural gas, and minority rural area is used biogas.Wherein, the fire temperature of coal gas and liquefied gas is at 400～900 DEG C, can meet popular family and medium and small food and drink uses, but can not meet 900-1200 DEG C of requirement of big-and-middle food and drink high temperature, and there is easily poisoning potential safety hazard of carbon monoxide in liquefied gas, piped gas, liquefied gas also has the danger of blast, and often there is generation its accident all parts of the country; And coal gas is again because the problem of pipe-line equipment, facility can not be benefited the common people of urban and urual areas of whole country comprehensively.Sweet natural gas more can not be popularized and be promoted in the whole nation by resource limit.Diesel oil has higher combustion heat value, but produces volume of smoke after burning, has a strong impact on environment.Biological alcohol oil is taking methyl alcohol as main raw material and a kind of environment friendly biological fuel newly developed; Can store at normal temperatures and pressures, transport, use, plain metal or plastic containers can be stored; Detect through national quality testing department, and through pilot conversion application, its technical feature and safety index meet the requirement of country to domestic fuel, are a kind of desirable environmental protection fuel.If utilize sewer oil to prepare biological alcohol oil, not only make sewer oil can be legal, recycling effectively, and sewer oil is still prepared the high quality raw material of biological alcohol oil.
Summary of the invention
For make sewer oil legal, effectively recycling, the present invention proposes a kind of sewer oil resultant that utilizes and prepares the preferably technology of biological alcohol oil of combustionproperty.
A kind of biological alcohol oil of being prepared by sewer oil resultant, it is characterized in that this biological alcohol oil is by weight by sewer oil resultant, be that 2 ~ 25 parts, 3 ~ 35 parts of emulsifying agents and water fully stirs formation emulsion, leave standstill and be uniformly mixed with 40 ~ 95 parts of methyl alcohol again after 10 ~ 24 hours, leave standstill 4 ~ 8 hours and form; Wherein, sewer oil resultant is a kind of sewer oil to be removed to the emulsifying agent that the stearin that obtains after moisture and impurity and tripalmitin obtain through saponification.
Described stearin and tripalmitin are to obtain by following method:
Get sewer oil appropriate, boil rear filtration, the liquid after filtration distributes fluid with shunting after cooling, then fluid is added in the container of adding a cover, carbonizing treatment at 400 ~ 700 DEG C, cooled and filtered, gained filtrate is stearin and palmitate glyceride mixture.
Described sewer oil can first filter out larger solid impurity in the process of heating, remain less impurity and filtered liquid, in this filtered liquid, also contain less impurity and moisture, therefore need to extract fluid after shunting, moisture is abandoned to it, and in fluid now, also containing less impurity cannot separate, and therefore needs further to carry out carbonizing treatment, form throw out and removed after filtration, can ensure that like this in this filtrate, the content of stearin and palmitate glyceride mixture reaches 95%.
The saponification process of described stearin and tripalmitin is:
Get by weight 4～14 parts, 70～90 parts of stearin and palmitate glyceride mixtures, sodium hydroxide or 6 ~ 16 parts, sodium carbonate and water and boil 30 ~ 60 minutes, in boiling part, slowly stir.
Through saponification reaction, stearin and palmitate glyceryl ester generate sodium stearate, sodium palmitate and glycerine under the highly basic effect of sodium hydroxide or sodium carbonate, and its saponification formation is yellow powder.
Described sewer oil resultant emulsifying agent and water can dissolve formation emulsified soln, and this emulsified soln and methyl alcohol all belong to polar material, are the mixing liquids that can dissolve each other.
Biological alcohol oil of the present invention, is made up of sewer oil resultant, first alcohol and water, and wherein sewer oil resultant is not only outstanding emulsifying agent, and itself or high performance fuel.The patent that China's application number is CN201110274634.2 discloses a kind of environment-friendly energy-saving biological alcohol oil patent, the minimum combustion heat value that needs methyl alcohol more than 75% just can reach 8600 kilocalories/kg in this patent; And the biological alcohol oil of this patent, in minimum situation, only need methyl alcohol 40%, greatly save the consumption of methyl alcohol, in addition because the fuel value of the 35% sewer oil resultant being used in conjunction with can be up to 9000 kilocalories/kg, be greater than the fuel value of methyl alcohol, therefore methanol fuel of the present invention is higher than the disclosed methanol fuel efficiency of this patent.
Biological alcohol oil stable performance of the present invention, not volatile, condensation point for-90 DEG C, not spontaneous combustion, ignition temperature be greater than 200 DEG C, without pressure, do not explode, accidental ignition water water and go out.The burning of this product is nontoxic, it is harmless to use, free from extraneous odour, smoke dust, is reproducible biomass new forms of energy, and through relevant departments, monitoring meets national regulation.
Because this biological alcohol oil fuel value can reach 5100 ~ 9000 kilocalories/kg, therefore of many uses, directly diesel oil substitute, liquefied gas, piped gas, Sweet natural gas be widely used in city and country family, shop, chafing dish restaurant, hotel, hotel, unit dining room, steam boiler and medium and small industrial combustion, Baoshang, cooking, cook.
It is raw material that this biological alcohol oil adopts sewer oil resultant, not only has good burning performance and cheap, and food safety threatens, avoids sewer oil environmental pollution, to reduce the aspects such as consumption of fossil fuels all significant reducing.
Embodiment
Embodiment 1: a kind of biological alcohol oil of being prepared by sewer oil resultant, this alcohol oil obtains by following step preparation:
1. get sewer oil 200kg, add in container and boil, filter with leaking wooden dipper or strainer, to remove waste residue, foreign material, the about 180kg of remaining liquid; After remaining liquid cooling but, fluid is separated with water with shunting, remove and anhydrate, remain about 160kg fluid; This fluid is added in lid container, carbonizing treatment at 600 DEG C, cooled and filtered remove because of carbonization be deposited to fluid bottom by the fine impurities of coking, obtain purity and be 95% stearin and the about 155kg of palmitate glyceride mixture, cooling for subsequent use.
2. get the stearin and palmitate glyceride mixture 14kg, sodium hydroxide 3.2kg, the water 2.8kg that in said process, obtain and put into container, boil 60 minutes, in boiling part, slowly stir, generate sodium stearate, sodium palmitate, the about 19kg of glycerine by saponification reaction, this object proterties is that yellow powder is biological alcohol oil emulsifying agent, cooling for subsequent use.
3. get emulsifying agent 1.2kg, water 0.8kg and add fully stirring in container, leave standstill 20 hours, allow emulsifying agent and water fully dissolve, to precipitate, remove tiny foreign material, obtain emulsion 2 kg, emulsion is mixed with concentration 99.9% methyl alcohol 18kg, fully stir, leave standstill 6 hours, make it abundant
mix, biological alcohol oil 20kg.This biological alcohol oil is applicable to the gasification oven of 400-800 degree fire temperature and the alcohol oil fan stove of 900-1200 degree fire temperature.
Embodiment 2: a kind of biological alcohol oil of being prepared by sewer oil resultant, this alcohol oil obtains by following step preparation:
1. get sewer oil 120kg, add in container and boil, filter with leaking wooden dipper or strainer, to remove waste residue, foreign material, the about 110kg of remaining liquid; After remaining liquid cooling but, fluid is separated with water with shunting, except anhydrating, remain the about 95kg of fluid; This fluid is added in lid container, carbonizing treatment at 500 DEG C, cooled and filtered remove carbonization postprecipitation to fluid bottom by the fine impurities of coking, obtain purity and be 95% stearin and palmitate glyceride mixture 93kg, cooling for subsequent use.
2. get the stearin and palmitate glyceride mixture 16kg, sodium carbonate 2.4kg, the water 1.6kg that in said process, obtain and put into container, boil 60 minutes, in boiling part, slowly stir, generate sodium stearate, sodium palmitate and glycerine 20kg by saponification reaction, this object proterties is that yellow powder is biological alcohol oil emulsifying agent, cooling for subsequent use.
3. get emulsifying agent 7kg, water 5kg and add fully stirring in container, leave standstill 20 hours, allow emulsifying agent and water fully dissolve, to precipitate, remove tiny foreign material, obtain emulsion 12 kg, it is in 99.9% methyl alcohol that emulsion is added to 8kg concentration, fully stir, leave standstill 4 hours, make it abundant
mix, biological alcohol oil 20kg.The alcohol oil fan stove that this biological alcohol oil is applicable to 1000-1300 degree fire temperature uses.
Claims (1)
1. a biological alcohol oil of being prepared by sewer oil resultant, it is characterized in that this biological alcohol oil is by weight by sewer oil resultant, be that 2 ~ 25 parts, 3 ~ 35 parts of emulsifying agents and water fully stirs formation emulsion, leave standstill and be uniformly mixed with 40 ~ 95 parts of methyl alcohol again after 10 ~ 24 hours, leave standstill 4 ~ 8 hours and form; Wherein, sewer oil resultant is a kind of sewer oil to be removed to the emulsifying agent that the stearin that obtains after moisture and impurity and tripalmitin obtain through saponification;
Described stearin and tripalmitin are to obtain by following method:
Get sewer oil appropriate, boil rear filtration, the liquid after filtration distributes fluid with shunting after cooling, then fluid is added in the container of adding a cover, carbonizing treatment at 400 ~ 700 DEG C, cooled and filtered, gained filtrate is stearin and palmitate glyceride mixture;
Described sewer oil can first filter out larger solid impurity in the process of boiling, remain less impurity and filtered liquid, in this filtered liquid, also contain less impurity and moisture, therefore need to extract fluid after shunting, moisture is abandoned to it, and in fluid now, also containing less impurity cannot separate, and therefore needs further to carry out carbonization, form throw out and removed after filtration, can ensure that like this in this filtrate, the content of stearin and palmitate glyceride mixture reaches 95%;
The saponification process of described stearin and tripalmitin is:
Get by weight 4～14 parts, 70～90 parts of stearin and palmitate glyceride mixtures, sodium hydroxide or 6 ~ 16 parts, sodium carbonate and water and boil 30 ~ 60 minutes, in boiling part, slowly stir;
By saponification reaction, stearin and palmitate glyceryl ester generate sodium stearate, sodium palmitate and glycerine under the effect of sodium hydroxide or sodium carbonate, and its saponification formation is yellow powder;
Described sewer oil resultant emulsifying agent and water can dissolve formation emulsified soln, and this emulsified soln and methyl alcohol all belong to polar material, are the mixing liquids that can dissolve each other.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210184369.3A CN102660335B (en) | 2012-06-06 | 2012-06-06 | Biological methanol oil prepared from illegal cooking oil products |
| PCT/CN2012/078421 WO2013181874A1 (en) | 2012-06-06 | 2012-07-10 | Biological methanol oil prepared from illegal cooking oil products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210184369.3A CN102660335B (en) | 2012-06-06 | 2012-06-06 | Biological methanol oil prepared from illegal cooking oil products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102660335A CN102660335A (en) | 2012-09-12 |
| CN102660335B true CN102660335B (en) | 2014-06-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210184369.3A Active CN102660335B (en) | 2012-06-06 | 2012-06-06 | Biological methanol oil prepared from illegal cooking oil products |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN102660335B (en) |
| WO (1) | WO2013181874A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102965160A (en) * | 2012-11-26 | 2013-03-13 | 滕春合 | Nano biofuel taking gutter oil as raw material and preparation method thereof |
| CN104593113A (en) * | 2013-10-31 | 2015-05-06 | 孙立 | Method for producing solid fuel from swill-cooked dirty oil |
| CN103627445B (en) * | 2013-11-20 | 2016-05-04 | 济南开发区星火科学技术研究院 | A kind of preparation method of waste oil biological alcohol oil |
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| US4908044A (en) * | 1989-04-25 | 1990-03-13 | T.A.V., Inc. | Semi solid ethanol based fuel |
| CN1102669A (en) * | 1993-11-12 | 1995-05-17 | 中国科学院化学研究所 | Emulsified heavy oil, its prepn. and application |
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| CN101875867A (en) * | 2009-04-28 | 2010-11-03 | 秦光校 | Novel environmentally-friendly biological alcohol oil formula |
| CN101892100A (en) * | 2009-05-19 | 2010-11-24 | 盛仁均 | Alcohol base fuel accelerating agent |
| CN102358853A (en) * | 2011-09-16 | 2012-02-22 | 邓群英 | Novel environmental protection and energy saving biological alcohol oil |
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| DE3525124A1 (en) * | 1985-07-13 | 1987-01-15 | Huels Chemische Werke Ag | FUELS AND HEATING OILS AND USE OF AN EMULGATOR SYSTEM FOR THE PRODUCTION OF THESE FUELS AND HEATING OILS |
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| CN100393843C (en) * | 2006-06-16 | 2008-06-11 | 刘火成 | Process for preparing biological diesel oil by using waste oil of plant and animal |
| CN101230285A (en) * | 2008-01-18 | 2008-07-30 | 黄霖孝 | Fuel extraction method |
| CN101805642B (en) * | 2010-04-22 | 2012-09-12 | 闫世江 | Biological liquid fuel and preparation method thereof |
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2012
- 2012-06-06 CN CN201210184369.3A patent/CN102660335B/en active Active
- 2012-07-10 WO PCT/CN2012/078421 patent/WO2013181874A1/en active Application Filing
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4908044A (en) * | 1989-04-25 | 1990-03-13 | T.A.V., Inc. | Semi solid ethanol based fuel |
| CN1102669A (en) * | 1993-11-12 | 1995-05-17 | 中国科学院化学研究所 | Emulsified heavy oil, its prepn. and application |
| CN1153203A (en) * | 1995-12-08 | 1997-07-02 | 刘志强 | Fuel oil emulsifying agent |
| CN101838559A (en) * | 2009-03-18 | 2010-09-22 | 北京绿品阳光国际技术开发有限公司 | Biological alcohol oil |
| CN101875867A (en) * | 2009-04-28 | 2010-11-03 | 秦光校 | Novel environmentally-friendly biological alcohol oil formula |
| CN101892100A (en) * | 2009-05-19 | 2010-11-24 | 盛仁均 | Alcohol base fuel accelerating agent |
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| CN102358853A (en) * | 2011-09-16 | 2012-02-22 | 邓群英 | Novel environmental protection and energy saving biological alcohol oil |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013181874A1 (en) | 2013-12-12 |
| CN102660335A (en) | 2012-09-12 |
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