CN102636536B - Pt-Cu合金中空纳米颗粒无酶葡萄糖传感器电极的制备和应用 - Google Patents
Pt-Cu合金中空纳米颗粒无酶葡萄糖传感器电极的制备和应用 Download PDFInfo
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- CN102636536B CN102636536B CN201210114991.7A CN201210114991A CN102636536B CN 102636536 B CN102636536 B CN 102636536B CN 201210114991 A CN201210114991 A CN 201210114991A CN 102636536 B CN102636536 B CN 102636536B
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- 239000008103 glucose Substances 0.000 title claims abstract description 50
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 45
- 239000000956 alloy Substances 0.000 title claims abstract description 45
- 229910018883 Pt—Cu Inorganic materials 0.000 title claims abstract description 39
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- 239000010452 phosphate Substances 0.000 claims description 7
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 5
- 241001465754 Metazoa Species 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 239000008280 blood Substances 0.000 claims description 5
- 210000004369 blood Anatomy 0.000 claims description 5
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 5
- 239000000376 reactant Substances 0.000 claims description 5
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 5
- 239000012279 sodium borohydride Substances 0.000 claims description 5
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 5
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- 229910017885 Cu—Pt Inorganic materials 0.000 description 23
- 239000010949 copper Substances 0.000 description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
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- 238000001514 detection method Methods 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
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- 238000000840 electrochemical analysis Methods 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 4
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- 229910052697 platinum Inorganic materials 0.000 description 4
- 108010015776 Glucose oxidase Proteins 0.000 description 3
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- 235000010323 ascorbic acid Nutrition 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
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- 229910052802 copper Inorganic materials 0.000 description 3
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- 229910000510 noble metal Inorganic materials 0.000 description 2
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- 229910001316 Ag alloy Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
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CN201210114991.7A CN102636536B (zh) | 2012-04-18 | 2012-04-18 | Pt-Cu合金中空纳米颗粒无酶葡萄糖传感器电极的制备和应用 |
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CN102636536B true CN102636536B (zh) | 2014-02-26 |
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Families Citing this family (7)
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CN104259476A (zh) * | 2014-09-26 | 2015-01-07 | 中国科学院深圳先进技术研究院 | 钯纳米粒子及其制备方法 |
CN104698165B (zh) * | 2015-03-20 | 2015-12-02 | 济南大学 | 一种铂基合金标记的三通道夹心型免疫传感器的制备方法及应用 |
CN104777203A (zh) * | 2015-04-02 | 2015-07-15 | 天津大学 | Pt-Ni合金纳米管阵列电极的制备方法及在无酶葡萄糖传感器的应用 |
CN108796463A (zh) * | 2018-06-29 | 2018-11-13 | 吉林大学 | 一种用于葡萄糖浓度检测的复合膜电极、制备方法及其应用 |
CN110125436A (zh) * | 2019-05-26 | 2019-08-16 | 北京化工大学 | 一种表面原子比可调的AuCu合金的制备方法及其应用 |
CN114002305A (zh) * | 2021-11-02 | 2022-02-01 | 怀化学院 | 基于纳米基质负载双金属催化剂的电化学传感器及其制作方法和用途 |
CN115739110B (zh) * | 2022-11-04 | 2024-01-30 | 湖州美奇医疗器械有限公司 | 基于铂的催化剂制备方法及其应用 |
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CN101975807B (zh) * | 2010-09-09 | 2013-02-27 | 天津大学 | 三维Pt-Pb纳米花针式无酶葡萄糖传感器电极的制备方法 |
CN102305819A (zh) * | 2011-05-27 | 2012-01-04 | 天津大学 | 一种葡萄糖传感器电极及制备方法 |
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