CN102634716B - 一种镁锌磷酸三钙复合材料的粉末热压烧结制备方法 - Google Patents
一种镁锌磷酸三钙复合材料的粉末热压烧结制备方法 Download PDFInfo
- Publication number
- CN102634716B CN102634716B CN 201210131179 CN201210131179A CN102634716B CN 102634716 B CN102634716 B CN 102634716B CN 201210131179 CN201210131179 CN 201210131179 CN 201210131179 A CN201210131179 A CN 201210131179A CN 102634716 B CN102634716 B CN 102634716B
- Authority
- CN
- China
- Prior art keywords
- powder
- magnesium
- tricalcium phosphate
- composite material
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 55
- 239000000843 powder Substances 0.000 title claims abstract description 35
- 238000005245 sintering Methods 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- JTBXMZRNMCUUPB-UHFFFAOYSA-K tricalcium magnesium zinc phosphate Chemical compound [Mg+2].[Ca+2].[Ca+2].[Ca+2].[Zn+2].[O-]P([O-])([O-])=O JTBXMZRNMCUUPB-UHFFFAOYSA-K 0.000 title claims abstract description 25
- 239000001506 calcium phosphate Substances 0.000 claims abstract description 37
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims abstract description 37
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims abstract description 36
- 235000019731 tricalcium phosphate Nutrition 0.000 claims abstract description 36
- 229940078499 tricalcium phosphate Drugs 0.000 claims abstract description 36
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 28
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 8
- 239000011812 mixed powder Substances 0.000 claims abstract description 7
- 239000011159 matrix material Substances 0.000 claims description 29
- 239000011777 magnesium Substances 0.000 claims description 20
- 229910052749 magnesium Inorganic materials 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 14
- 238000000748 compression moulding Methods 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 12
- 238000007731 hot pressing Methods 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 8
- 239000011701 zinc Substances 0.000 claims description 8
- 238000003825 pressing Methods 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 238000007669 thermal treatment Methods 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 abstract description 14
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000005242 forging Methods 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 13
- 238000005516 engineering process Methods 0.000 description 12
- 210000000988 bone and bone Anatomy 0.000 description 11
- 239000000470 constituent Substances 0.000 description 10
- 239000007769 metal material Substances 0.000 description 7
- 239000012620 biological material Substances 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- 229910000861 Mg alloy Inorganic materials 0.000 description 5
- 229910001069 Ti alloy Inorganic materials 0.000 description 5
- 239000003519 biomedical and dental material Substances 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 210000001124 body fluid Anatomy 0.000 description 4
- 239000010839 body fluid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 210000001519 tissue Anatomy 0.000 description 4
- 239000013060 biological fluid Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 230000004060 metabolic process Effects 0.000 description 3
- 238000004663 powder metallurgy Methods 0.000 description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 230000035876 healing Effects 0.000 description 2
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 239000007943 implant Substances 0.000 description 2
- 238000001727 in vivo Methods 0.000 description 2
- 238000000626 liquid-phase infiltration Methods 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000008467 tissue growth Effects 0.000 description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- 229910000882 Ca alloy Inorganic materials 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 208000030961 allergic reaction Diseases 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011173 biocomposite Substances 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000003169 central nervous system Anatomy 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 230000037345 metabolism of vitamins Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 230000002232 neuromuscular Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000008816 organ damage Effects 0.000 description 1
- 230000011164 ossification Effects 0.000 description 1
- 210000004409 osteocyte Anatomy 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 210000000496 pancreas Anatomy 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000001243 protein synthesis Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 230000014616 translation Effects 0.000 description 1
Images
Landscapes
- Materials For Medical Uses (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201210131179 CN102634716B (zh) | 2012-04-28 | 2012-04-28 | 一种镁锌磷酸三钙复合材料的粉末热压烧结制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201210131179 CN102634716B (zh) | 2012-04-28 | 2012-04-28 | 一种镁锌磷酸三钙复合材料的粉末热压烧结制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102634716A CN102634716A (zh) | 2012-08-15 |
CN102634716B true CN102634716B (zh) | 2013-08-07 |
Family
ID=46619292
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 201210131179 Active CN102634716B (zh) | 2012-04-28 | 2012-04-28 | 一种镁锌磷酸三钙复合材料的粉末热压烧结制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102634716B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110656269A (zh) * | 2019-10-25 | 2020-01-07 | 冯波 | 一种镁合金锻件及其制备工艺 |
CN111218598B (zh) * | 2020-02-08 | 2021-04-20 | 苏州轻金三维科技有限公司 | 一种三维打印用高强耐热轻合金及其制备方法 |
CN116919557B (zh) * | 2023-09-14 | 2023-12-15 | 泓欣科创(北京)科技有限公司 | 可降解接骨板及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101347639A (zh) * | 2007-07-20 | 2009-01-21 | 中国科学院金属研究所 | 医用镁合金/磷酸钙复合材料 |
CN101411891A (zh) * | 2008-12-01 | 2009-04-22 | 天津理工大学 | 一种可降解纳米钙磷化合物增强镁锌合金骨折内固定材料 |
CN101698116A (zh) * | 2009-10-30 | 2010-04-28 | 重庆大学 | 可生物降解的镁或镁合金与磷酸三钙复合材料的制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102108450B (zh) * | 2009-12-25 | 2012-08-29 | 清华大学 | 镁基复合材料的制备方法 |
-
2012
- 2012-04-28 CN CN 201210131179 patent/CN102634716B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101347639A (zh) * | 2007-07-20 | 2009-01-21 | 中国科学院金属研究所 | 医用镁合金/磷酸钙复合材料 |
CN101411891A (zh) * | 2008-12-01 | 2009-04-22 | 天津理工大学 | 一种可降解纳米钙磷化合物增强镁锌合金骨折内固定材料 |
CN101698116A (zh) * | 2009-10-30 | 2010-04-28 | 重庆大学 | 可生物降解的镁或镁合金与磷酸三钙复合材料的制备方法 |
Non-Patent Citations (2)
Title |
---|
Mg-6%Zn-10%(β-Ca3(PO4)2)复合材料的制备及腐蚀降解行为;陈福文等;《中国有色金属学报》;20120131;第22卷(第1期);39-44 * |
陈福文等.Mg-6%Zn-10%(β-Ca3(PO4)2)复合材料的制备及腐蚀降解行为.《中国有色金属学报》.2012,第22卷(第1期),39-44. |
Also Published As
Publication number | Publication date |
---|---|
CN102634716A (zh) | 2012-08-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103599561B (zh) | 一种镁合金/羟基磷灰石复合材料的制备方法 | |
CN106552940B (zh) | 一种梯度有序多孔TiAg合金的制备方法 | |
CN100451144C (zh) | 一种具有梯度孔隙率镍钛形状记忆合金的制备方法 | |
CN105522152B (zh) | 一种3d打印稀土钛合金材料的方法 | |
CN103028149B (zh) | 医用可降解Fe-Mg二元合金材料及其制备方法 | |
CN108504922B (zh) | 一种生物可降解铁锌合金及其制备方法 | |
CN103540784B (zh) | 一种生物医用多孔钛合金的制备方法 | |
CN103357063A (zh) | 一种可引导骨生长的金属复合材料及其应用 | |
CN102552973A (zh) | 医用可降解吸收Mg-Sr-Ca系镁合金植入体及其制备方法 | |
CN107190191B (zh) | 一种生物医用镁合金及其制备方法 | |
CN102258806A (zh) | 一种可降解镁基骨科植入生物医用材料及制备方法 | |
CN102634716B (zh) | 一种镁锌磷酸三钙复合材料的粉末热压烧结制备方法 | |
CN104120320A (zh) | 一种可降解稀土镁合金医用生物材料及制备方法 | |
CN104942283B (zh) | 钛合金粉末及其配制方法和应用 | |
CN108159488B (zh) | 一种能促进骨骼生长的多孔钛镁合金人工骨及其制备方法 | |
CN103184380A (zh) | 生物可降解Mg-Gd-Zn-Sr-Zr系镁合金及其制备方法 | |
Zhang et al. | Effect of different dopants on porous calcium silicate composite bone scaffolds by 3D gel-printing | |
CN104744038A (zh) | 一种用于制造牙根的氧化锆生物陶瓷及其制备方法 | |
CN104069542A (zh) | 髌骨组织工程支架及其制造材料和制备方法 | |
CN105400990A (zh) | 一种低模量高强度生物医用钛合金及其制备方法 | |
Balla et al. | Quasi-static torsional deformation behavior of porous Ti6Al4V alloy | |
CN103834894A (zh) | 一种在钛合金基体表面制备钛-聚乙烯多孔钛涂层的方法 | |
CN101524559A (zh) | 生物可降解纳米羟基磷灰石-镁金属基复合材料 | |
CN104803673A (zh) | 一种羟基磷灰石/钛酸钠复合生物陶瓷及其制备方法 | |
JP2012192016A (ja) | 高強度・低弾性に優れるチタン−マグネシウム材料 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240603 Address after: Room 140, Building 1, R&D Headquarters, Central South University Science and Technology Park, Yingzuo Road, Yuelu Street, Yuelu District, Changsha City, Hunan Province, 410006 Patentee after: Changsha magnesium New Material Technology Co.,Ltd. Country or region after: China Address before: Yuelu District City, Hunan province 410083 Changsha Lushan Road No. 932 Patentee before: CENTRAL SOUTH University Country or region before: China |