CN102634161A - Toughening and reinforcing paintable reclaimed ABS (Acrylonitrile-Butadiene-Styrene) and preparation method thereof - Google Patents
Toughening and reinforcing paintable reclaimed ABS (Acrylonitrile-Butadiene-Styrene) and preparation method thereof Download PDFInfo
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- CN102634161A CN102634161A CN2012101287955A CN201210128795A CN102634161A CN 102634161 A CN102634161 A CN 102634161A CN 2012101287955 A CN2012101287955 A CN 2012101287955A CN 201210128795 A CN201210128795 A CN 201210128795A CN 102634161 A CN102634161 A CN 102634161A
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Abstract
The invention discloses a toughening and reinforcing paintable reclaimed ABS (Acrylonitrile-Butadiene-Styrene) which consists of the following raw materials in part by weight: 60-90 parts of recycled ABS, 5-20 parts of toughening agent, 1-6 parts of compatilizer, 1-15 parts of filler and 0.1-1 part of antioxidant. The reclaimed ABS aggregates provided by the invention have excellent mechanical property and painting property.
Description
Technical field
The present invention relates to a kind of toughness reinforcing enhancing paintable regeneration ABS and preparation method thereof.
Background technology
ABS resin is vinyl cyanide, divinyl and styrol copolymer (abbreviation or the abbreviation of Acrylonitrile-Butadiene-Styrene).ABS resin is a kind of intensity height, good toughness, is easy to the thermoplastic macromolecule material of machine-shaping, is widely used in automotive industry, mechanical industry and electrical instrumentation industry, like gear, blade, panel board, casing, splash pan, handrail, safety helmet etc.Because ultraviolet degradation takes place the divinyl in the ABS resin easily, therefore many ABS resin product surfaces all can apply paint (generally being that acrylic acid series or polyurethane series coat with lacquer), and it is ornamental but also can alleviate the goods photoaging not only to have satisfied goods.Along with the increasingly stringent of the shortage and the environment protection of petroleum resources, the application of regeneration ABS resin progressively increases.Because market competition is fierce unusually, a lot of ABS production of articles commercial cities begin to adopt regeneration ABS to expect to reduce cost.Yet reclaim ABS resin because of solarization; Its mechanical property especially erosion-resisting characteristics can not show a candle to the ABS virgin material, reclaims the plastics that more or less all contain other in the ABS resin such as PC, PP, PE etc. simultaneously, the incompatible and layering of non-polar resin wherein such as PP, PE and ABS; Migration surface and enrichment easily; Thereby reduce the polarity that reclaims the ABS resin surface, cause reclaiming ABS resin and be difficult to japanning, the polarity paint that promptly applies comes off easily.Above drawbacks limit the application of regeneration ABS material.Chinese patent CN1646280, CN101016401 have proposed to improve the method that reclaims the ABS mechanical property, but do not mention the method that reclaims the difficult japanning in ABS surface that how to solve.The present invention proposes a kind of toughness reinforcing enhancing paintable regeneration ABS and preparation method thereof, not only promotes the mechanical property that reclaims ABS, and solves the problem that reclaims the difficult japanning of ABS.
Summary of the invention
The purpose of this invention is to provide a kind of toughness reinforcing enhancing paintable regeneration ABS and preparation method thereof.
The technical scheme that the present invention taked is:
A kind of toughness reinforcing enhancing paintable regeneration ABS, it is made up of following raw material: the compatilizer of the recovery ABS of 60-90 mass parts, the toughner of 5-20 mass parts, 1-6 mass parts, the filler of 1-15 mass parts, the oxidation inhibitor of 0.1-1 mass parts.
Preferably, the consumption that reclaims ABS is the 80-90 mass parts, and the consumption of toughner is the 8-15 mass parts, and the consumption of compatilizer is the 2-4 mass parts, and the consumption of filler is the 5-10 mass parts, and the consumption of oxidation inhibitor is the 0.2-0.5 mass parts; Reclaiming ABS is ABS goods reclaimed materials or tankage or mouth of a river material.
Said toughner is at least a among ABS high glue powder, EVA, SEBS, SBS, the EPDM.
Described compatilizer is the maleic anhydride graft polyolefine.
Described maleic anhydride graft polyolefine is a kind of among PP-g-MAH, the PE-g-MAH.
In the described maleic anhydride graft polyolefine, the percentage of grafting of maleic anhydride >=5%.
Described filler comprises lime carbonate, talcum powder, wollastonite, permanent white, kaolin.
Described oxidation inhibitor is at least a in Hinered phenols antioxidant, the phosphite ester kind antioxidant.
The preparation method of a kind of toughness reinforcing enhancing paintable regeneration ABS may further comprise the steps: various mixing of materials are even, and under 190-220 ℃, melt extrude again and get final product.
The invention has the beneficial effects as follows: regeneration ABS pellet provided by the invention has excellent mechanical property and varnishability.
Embodiment
A kind of toughness reinforcing enhancing paintable regeneration ABS, it is made up of following raw material: the compatilizer of the recovery ABS of 60-90 mass parts, the toughner of 5-20 mass parts, 1-6 mass parts, the filler of 1-15 mass parts, the oxidation inhibitor of 0.1-1 mass parts.
Preferably, the consumption that reclaims ABS is the 80-90 mass parts, and the consumption of toughner is the 8-15 mass parts, and the consumption of compatilizer is the 2-4 mass parts, and the consumption of filler is the 5-10 mass parts, and the consumption of oxidation inhibitor is the 0.2-0.5 mass parts.
The preparation method of a kind of toughness reinforcing enhancing paintable regeneration ABS may further comprise the steps: above-mentioned various mixing of materials are even, and under 190-220 ℃, melt extrude again and get final product.
Said toughner is at least a among ABS high glue powder, EVA, SEBS, SBS, the EPDM.Described compatilizer is the maleic anhydride graft polyolefine.Described maleic anhydride graft polyolefine is a kind of among PP-g-MAH, the PE-g-MAH.In the described maleic anhydride graft polyolefine, the percentage of grafting of maleic anhydride >=5%.Described filler comprises lime carbonate, talcum powder, wollastonite, permanent white, kaolin.Described oxidation inhibitor is at least a in Hinered phenols antioxidant, the phosphite ester kind antioxidant.
Below in conjunction with specific embodiment the present invention is done further prescription of the present invention is done further explanation:
Embodiment 1:
A kind of toughness reinforcing enhancing paintable regeneration ABS, its prescription is formed like following table 1:
Embodiment 2:
A kind of toughness reinforcing enhancing paintable regeneration ABS, its prescription is formed like following table 2:
Embodiment 3:
A kind of toughness reinforcing enhancing paintable regeneration ABS, its prescription is formed like following table 3:
Comparative Examples 1:
A kind of toughness reinforcing enhancing paintable regeneration ABS, its prescription is formed like following table 4:
Comparative Examples 2:
A kind of toughness reinforcing enhancing paintable regeneration ABS, its prescription is formed like following table 5:
Following table 6 is respectively the method standard of carrying out Mechanics Performance Testing and varnishability test with table 7:
Following table 8 is to be shaped to corresponding test block according to testing standard after the prescription of embodiment and Comparative Examples melt extrudes, and test block is carried out the result of performance test gained:
Can find out that from table 8 the toughness reinforcing paintable regeneration of the enhancing of the present invention's preparation ABS has excellent mechanical property and varnishability.
Raw material in the prescription of the present invention is all commercially available.
Claims (8)
1. toughness reinforcing enhancing paintable regeneration ABS, it is characterized in that: it is made up of following raw material: the compatilizer of the recovery ABS of 60-90 mass parts, the toughner of 5-20 mass parts, 1-6 mass parts, the filler of 1-15 mass parts, the oxidation inhibitor of 0.1-1 mass parts.
2. a kind of toughness reinforcing enhancing paintable regeneration ABS according to claim 1 is characterized in that: said toughner is at least a among ABS high glue powder, EVA, SEBS, SBS, the EPDM.
3. a kind of toughness reinforcing enhancing paintable regeneration ABS according to claim 1, it is characterized in that: described compatilizer is the maleic anhydride graft polyolefine.
4. a kind of toughness reinforcing enhancing paintable regeneration ABS according to claim 3 is characterized in that: described maleic anhydride graft polyolefine is a kind of among PP-g-MAH, the PE-g-MAH.
5. a kind of toughness reinforcing enhancing paintable regeneration ABS according to claim 3 is characterized in that: in the described maleic anhydride graft polyolefine, and the percentage of grafting of maleic anhydride >=5%.
6. a kind of toughness reinforcing enhancing paintable regeneration ABS according to claim 1, it is characterized in that: described filler comprises lime carbonate, talcum powder, wollastonite, permanent white, kaolin.
7. a kind of toughness reinforcing enhancing paintable regeneration ABS according to claim 1 is characterized in that: described oxidation inhibitor is at least a in Hinered phenols antioxidant, the phosphite ester kind antioxidant.
8. the preparation method of a kind of toughness reinforcing enhancing paintable regeneration ABS as claimed in claim 1 is characterized in that: may further comprise the steps: various mixing of materials are even, and under 190-220 ℃, melt extrude again and get final product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210128795.5A CN102634161B (en) | 2012-04-28 | 2012-04-28 | Toughening and reinforcing paintable reclaimed ABS (Acrylonitrile-Butadiene-Styrene) and preparation method thereof |
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| CN201210128795.5A CN102634161B (en) | 2012-04-28 | 2012-04-28 | Toughening and reinforcing paintable reclaimed ABS (Acrylonitrile-Butadiene-Styrene) and preparation method thereof |
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| CN102634161A true CN102634161A (en) | 2012-08-15 |
| CN102634161B CN102634161B (en) | 2014-01-15 |
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863732A (en) * | 2012-09-12 | 2013-01-09 | 江苏安格特科技发展有限公司 | Low-temperature impact-resistant extrusion-grade acrylonitrile butadiene styrene (ABS) alloy material |
| CN102875952A (en) * | 2012-09-07 | 2013-01-16 | 惠州市昌亿科技股份有限公司 | High-performance acrylonitrile butadiene styrene (ABS) alloy prepared from waste and worn electrical appliance ABS materials, and preparation method and application of ABS alloy |
| CN102952364A (en) * | 2012-09-19 | 2013-03-06 | 天津科创医药中间体技术生产力促进有限公司 | Toughening method for waste ABS (acrylonitrile butadiene styrene) |
| CN103275457A (en) * | 2013-06-14 | 2013-09-04 | 四川塑金科技有限公司 | Special material for waste ABS (acrylonitrile butadiene styrene) plastic regenerated and modified automobile and preparation method of special material |
| CN103665614A (en) * | 2013-11-21 | 2014-03-26 | 四川塑金科技有限公司 | Method for preparing and producing dedicated motorcycle material through recycling and modifying waste motorcycle plastic casings |
| CN104004315A (en) * | 2014-06-12 | 2014-08-27 | 吴永刚 | Regenerated acrylonitrile-butadiene-styrene (ABS) copolymer toughening modification material |
| CN104140635A (en) * | 2014-07-04 | 2014-11-12 | 广东宾豪旅行用品有限公司 | Recycled ABS plastic reinforced and toughened by adopting micro-crosslinking method and preparation method thereof |
| CN104140634A (en) * | 2014-07-04 | 2014-11-12 | 广东宾豪旅行用品有限公司 | Recycled ABS plastic for manufacturing traveling case shell and preparation method thereof |
| CN104530634A (en) * | 2014-12-26 | 2015-04-22 | 上海金发科技发展有限公司 | Environment-friendly high-proportion r-ABS (Recycled ABS) flame-retardant modified composition and preparation method and application thereof |
| CN105348720A (en) * | 2015-11-13 | 2016-02-24 | 安徽广源科技发展有限公司 | Recoverable composite plastic used for electric appliance elements |
| CN105907023A (en) * | 2016-06-03 | 2016-08-31 | 太仓市飞鸿塑钢制品有限公司 | Antistatic material with high toughness for safety helmets |
| CN106479108A (en) * | 2015-09-02 | 2017-03-08 | 深圳市联创科技集团有限公司 | Utilize what recycled plastic made to be still used for regenerated plastics of electrical equipment and preparation method thereof |
| CN107312351A (en) * | 2017-08-02 | 2017-11-03 | 合肥东恒锐电子科技有限公司 | The technique that a kind of electronic product plastic shell is recycled |
| CN107501850A (en) * | 2017-09-11 | 2017-12-22 | 广西鑫深科技有限公司 | Automobile rear spoiler proprietary material and preparation method thereof is prepared using discarded ABS resin |
| CN108410117A (en) * | 2018-04-23 | 2018-08-17 | 林淑录 | A kind of babinet ABS composite material and preparation method thereof |
| CN108912588A (en) * | 2018-08-16 | 2018-11-30 | 安徽省汉甲机电设备科技有限公司 | A kind of processing method that waste and old ABS plastic enhancing recycles |
| CN109135162A (en) * | 2018-08-28 | 2019-01-04 | 安徽江淮汽车集团股份有限公司 | Good ABS composite material of a kind of oil-resistant weather-resistant energy and preparation method thereof |
| CN111016205A (en) * | 2019-12-26 | 2020-04-17 | 江苏卡拉扬商务休闲用品有限公司 | Process method for recycling leftover materials of ABS (acrylonitrile butadiene styrene) draw-bar box |
| CN111234447A (en) * | 2020-03-18 | 2020-06-05 | 中北大学 | Epoxidized elastomer modified waste ABS plastic and preparation method thereof |
| CN115052927A (en) * | 2019-12-04 | 2022-09-13 | 英力士苯领集团股份公司 | Thermoplastic compound containing high-quality recycled material |
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| CN101016401A (en) * | 2007-03-02 | 2007-08-15 | 浙江大学 | Injection moulding composition based on reclaiming ABS |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101016401A (en) * | 2007-03-02 | 2007-08-15 | 浙江大学 | Injection moulding composition based on reclaiming ABS |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875952A (en) * | 2012-09-07 | 2013-01-16 | 惠州市昌亿科技股份有限公司 | High-performance acrylonitrile butadiene styrene (ABS) alloy prepared from waste and worn electrical appliance ABS materials, and preparation method and application of ABS alloy |
| CN102875952B (en) * | 2012-09-07 | 2014-07-16 | 惠州市昌亿科技股份有限公司 | High-performance acrylonitrile butadiene styrene (ABS) alloy prepared from waste and worn electrical appliance ABS materials, and preparation method and application of ABS alloy |
| CN102863732A (en) * | 2012-09-12 | 2013-01-09 | 江苏安格特科技发展有限公司 | Low-temperature impact-resistant extrusion-grade acrylonitrile butadiene styrene (ABS) alloy material |
| CN102952364A (en) * | 2012-09-19 | 2013-03-06 | 天津科创医药中间体技术生产力促进有限公司 | Toughening method for waste ABS (acrylonitrile butadiene styrene) |
| CN103275457A (en) * | 2013-06-14 | 2013-09-04 | 四川塑金科技有限公司 | Special material for waste ABS (acrylonitrile butadiene styrene) plastic regenerated and modified automobile and preparation method of special material |
| CN103665614B (en) * | 2013-11-21 | 2016-05-25 | 四川塑金科技有限公司 | Waste and old motorcycle plastic shell reclaims the preparation method of modification production motorcycle PP Pipe Compound |
| CN103665614A (en) * | 2013-11-21 | 2014-03-26 | 四川塑金科技有限公司 | Method for preparing and producing dedicated motorcycle material through recycling and modifying waste motorcycle plastic casings |
| CN104004315A (en) * | 2014-06-12 | 2014-08-27 | 吴永刚 | Regenerated acrylonitrile-butadiene-styrene (ABS) copolymer toughening modification material |
| CN104004315B (en) * | 2014-06-12 | 2016-10-19 | 吴永刚 | A kind of regeneration acrylonitrile-butadiene-styrene copolymer toughness-increasing modified material |
| CN104140634A (en) * | 2014-07-04 | 2014-11-12 | 广东宾豪旅行用品有限公司 | Recycled ABS plastic for manufacturing traveling case shell and preparation method thereof |
| CN104140635A (en) * | 2014-07-04 | 2014-11-12 | 广东宾豪旅行用品有限公司 | Recycled ABS plastic reinforced and toughened by adopting micro-crosslinking method and preparation method thereof |
| CN104530634A (en) * | 2014-12-26 | 2015-04-22 | 上海金发科技发展有限公司 | Environment-friendly high-proportion r-ABS (Recycled ABS) flame-retardant modified composition and preparation method and application thereof |
| CN104530634B (en) * | 2014-12-26 | 2017-11-03 | 上海金发科技发展有限公司 | Environment-friendly type regenerates ABS flame-proof modified compositions and preparation method and application at high proportion |
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| CN105348720A (en) * | 2015-11-13 | 2016-02-24 | 安徽广源科技发展有限公司 | Recoverable composite plastic used for electric appliance elements |
| CN105907023A (en) * | 2016-06-03 | 2016-08-31 | 太仓市飞鸿塑钢制品有限公司 | Antistatic material with high toughness for safety helmets |
| CN107312351A (en) * | 2017-08-02 | 2017-11-03 | 合肥东恒锐电子科技有限公司 | The technique that a kind of electronic product plastic shell is recycled |
| CN107501850A (en) * | 2017-09-11 | 2017-12-22 | 广西鑫深科技有限公司 | Automobile rear spoiler proprietary material and preparation method thereof is prepared using discarded ABS resin |
| CN108410117A (en) * | 2018-04-23 | 2018-08-17 | 林淑录 | A kind of babinet ABS composite material and preparation method thereof |
| CN108912588A (en) * | 2018-08-16 | 2018-11-30 | 安徽省汉甲机电设备科技有限公司 | A kind of processing method that waste and old ABS plastic enhancing recycles |
| CN109135162A (en) * | 2018-08-28 | 2019-01-04 | 安徽江淮汽车集团股份有限公司 | Good ABS composite material of a kind of oil-resistant weather-resistant energy and preparation method thereof |
| CN115052927A (en) * | 2019-12-04 | 2022-09-13 | 英力士苯领集团股份公司 | Thermoplastic compound containing high-quality recycled material |
| CN111016205A (en) * | 2019-12-26 | 2020-04-17 | 江苏卡拉扬商务休闲用品有限公司 | Process method for recycling leftover materials of ABS (acrylonitrile butadiene styrene) draw-bar box |
| CN111234447A (en) * | 2020-03-18 | 2020-06-05 | 中北大学 | Epoxidized elastomer modified waste ABS plastic and preparation method thereof |
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Address after: 510665 Guangzhou, Guangdong, Tianhe District Province Road West, No. 318 Patentee after: GUANGDONG RESEARCH INSTITITUTE OF PETROCHEMICAL AND FINE CHEMICAL ENGINEERING Address before: 510665 Guangzhou, Guangdong, Tianhe District, Tangxia, 318 West Po Road Patentee before: PETROLEUM AND CHEMICAL Research Institute OF GUANGDONG PROVINCE |
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Effective date of registration: 20200922 Address after: No.55, Shitan Avenue South, Shitan Town, Zengcheng District, Guangzhou City, Guangdong Province Patentee after: Guangdong Jinbai New Material Technology Co.,Ltd. Address before: 510665 Guangzhou, Guangdong, Tianhe District Province Road West, No. 318 Patentee before: GUANGDONG RESEARCH INSTITITUTE OF PETROCHEMICAL AND FINE CHEMICAL ENGINEERING |