CN102619477B - Wear and corrosion resistant iron-based alloy laser-cladding petroleum drill stem joint - Google Patents
Wear and corrosion resistant iron-based alloy laser-cladding petroleum drill stem joint Download PDFInfo
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- CN102619477B CN102619477B CN201110035745.8A CN201110035745A CN102619477B CN 102619477 B CN102619477 B CN 102619477B CN 201110035745 A CN201110035745 A CN 201110035745A CN 102619477 B CN102619477 B CN 102619477B
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 238000005260 corrosion Methods 0.000 title claims abstract description 32
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 32
- 238000004372 laser cladding Methods 0.000 title claims abstract description 31
- 230000007797 corrosion Effects 0.000 title claims abstract description 28
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 21
- 239000000956 alloy Substances 0.000 title claims abstract description 21
- 239000003208 petroleum Substances 0.000 title claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 26
- 238000000576 coating method Methods 0.000 claims abstract description 26
- 238000005253 cladding Methods 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 16
- 238000012545 processing Methods 0.000 claims abstract description 8
- 239000011159 matrix material Substances 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 244000137852 Petrea volubilis Species 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 229910001651 emery Inorganic materials 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 13
- 229910052804 chromium Inorganic materials 0.000 abstract description 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 2
- 229910052759 nickel Inorganic materials 0.000 abstract description 2
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000003466 welding Methods 0.000 description 10
- 238000005553 drilling Methods 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- PFRUBEOIWWEFOL-UHFFFAOYSA-N [N].[S] Chemical compound [N].[S] PFRUBEOIWWEFOL-UHFFFAOYSA-N 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000005121 nitriding Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 208000034189 Sclerosis Diseases 0.000 description 2
- LNSPFAOULBTYBI-UHFFFAOYSA-N [O].C#C Chemical group [O].C#C LNSPFAOULBTYBI-UHFFFAOYSA-N 0.000 description 2
- QFXZANXYUCUTQH-UHFFFAOYSA-N ethynol Chemical group OC#C QFXZANXYUCUTQH-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229940098458 powder spray Drugs 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- MEOSMFUUJVIIKB-UHFFFAOYSA-N [W].[C] Chemical compound [W].[C] MEOSMFUUJVIIKB-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention relates to a wear and corrosion resistant iron-based alloy laser-cladding petroleum drill stem joint. A layer of laser-cladding wear and corrosion resistant iron-based alloy coating is arranged on the surface of the drill stem joint and has the advantages of favorability in forming, compact tissue, uniformity in components and no crack; and the thickness of the laser-cladding wear and corrosion resistant iron-based alloy coating can be accurately controlled within 0.3 to 1.5mm. Cladding layers are not needed to completely cover the surface of the whole drill stem joint and are only required to respectively clad easily-abrasive belts at two ends of a joint cylinder for 30-50mm. The iron-based alloy powder comprises the following components in percentage by weight: 0.1-1.5 percent of C, 10-30 percent of Cr, 1-10 percent of Ni, 0.2-3.0 percent of Mn, 0.1-3.0 percent of Mo, 1.0-2.5 percent of Si, 0.1-3.5 percent of B and the balance of Fe, wherein the total weight percentage is 100 percent. According to the wear and corrosion resistant iron-based alloy laser-cladding petroleum drill stem joint, the problem that the drill stem joint is high in failing speed in an oil field is solved; the automation of a manufacturing and processing process of the drill stem joint is easily realized; and the drill stem joint has the advantages of high work efficiency, great advantages in economy and broad popularization prospect.
Description
Technical field
The invention belongs to petroleum drilling and mining equipment field, be specifically related to a kind of wear-and corrosion-resistant Laser Cladding of Iron-based Alloy joint of petroleum drill rod.
Background technology
Tool joint is the vitals of oil drill string, and its condition of work is very severe, and stressing conditions is very complicated.It will bear stretching, and the multiple load such as vibration are reversed in bending.In addition, joint also will be subject to the corrosion of drilling fluid and stratum media in creeping into, and its outside also can be subject to serious wearing and tearing, so the raising of the sclerosis of tool joint and abrasion resistant corrosion resistant performance thereof seems particularly important.The joint of ordinary metallic material, owing to being difficult to adapt to current abrasion and corrosion environment, is eliminated gradually.
In order to improve the application life of tool joint, generally its hardness is improved, the conventional method for curing of joint of petroleum drill rod has: manual repair welding, oxygen-acetylene repairing, plasma arc powder spray welding, sulphur nitrogen Combined Processing etc.
Manual repair welding: it is directly to have wearing layer certain thickness, that 50 millimeter are wide in electric welding mode to joint repair welding, use be the welding rod that pipe fills casting carbon tungsten carbide particle.The method is the most initial the most direct sclerosis restorative procedure, but the method inefficiency, and coating quality can not guarantee.
Oxygen-acetylene repairing: with oxy-acetylene reducing flame fusing pipe dress granular carbonization tungsten electrode, form wearing layer at joint surface.This method temperature is lower, and tungsten carbide particle does not melt, and can keep abrasion resistance, oxyacetylene torch heap is welded in wearing face built-up welding and is widely used, and compares with other overlaying methods, and welding equipment is simple, flexible operation, cost of investment are low, but work efficiency is low, require the workman of specialized operations.
Plasma arc powder spray welding: the heat that utilizes argon plasma arc to produce, on tool joint surface, form molten bath, alloy powder is preheated fusing in arc column, is ejected in molten bath, by regulating parameter, can on joint, obtain the wear-resistant strip needing.The arc column of powder plasma-arc welding is stable, and heat is concentrated, and heat utilization rate is high, and controllability is good, can control heat excessive, and dilution ratio is low, but because temperature after matrix local heating in reflow process reaches 900 ℃, can produce larger thermal deformation.
Sulphur nitrogen Combined Processing: the nitride carrying out in the rear workpiece of nitriding processing has very high hardness, heat stability and the very high spread, thereby can make the steel part after nitriding obtain high case hardness, abrasion resistance, fatigue strength, seizure resistance, Chinese People's Anti-Japanese Military and Political College's gas and superheated steam corrosive power, anti-temper softening ability, and reduce notch sensitivity.Thereby ion sulfurization technology can be prepared in metal surface FeS solid lubricant layer and improve material to wear-resistant performance, therefore conventionally at the joint after nitrogen treatment, carrying out ion sulfurization processing, thereby prepare nitrogen sulphur, meet processing layer, improved the ability of surface abrasion.But nitriding or sulfurizing can not Local treatment, during upper and lower drilling rod operation, pipe wrench retaining part easily skids, and needs special power tool.In addition, combination process more complicated, cost is higher.
Laser melting coating, as a kind of advanced person's process for modifying surface, along with improving constantly of laser power and stability, is widely applied and promotes rapidly.Laser melting and coating technique refers to that with different adding material modes, on coated matrix surface, place the coating material of selecting makes it to melt with matrix surface skim through laser irradiation simultaneously, and it is extremely low after rapid solidification, to form dilution factor, become the face coat of metallurgical binding with matrix material, thereby significantly improve the process of wear-resisting, anti-corrosion, heat-resisting, the non-oxidizability etc. of substrate material surface.Now, it has become having development prospect and having much one of new technology of characteristic in Modern Surface Technology system, and is having broad application prospects in the future.And the performance of cladding layer wear-and corrosion-resistant just in time can solve the problem running in tool joint work, this,, to extending application life of tool joint, improves the operating efficiency of creeping in oil field significant.
Summary of the invention
The object of this invention is to provide the tool joint of a kind of wear-and corrosion-resistant Laser Cladding of Iron-based Alloy, by iron(-)base powder is surperficial in tool joint with the mode cladding of laser melting coating, form wear-and corrosion-resistant iron alloy coating, thereby the wear and corrosion behavior of tool joint is significantly improved, extend the application life of tool joint, improve the operating efficiency of oil drilling.
For achieving the above object, the present invention takes following design scheme:
A kind of wear-and corrosion-resistant Laser Cladding of Iron-based Alloy joint of petroleum drill rod, it is characterized in that, this tool joint surface has the wear-and corrosion-resistant iron alloy coating of one deck laser melting coating, moulding is good, dense structure, and composition is even, and flawless, its thickness is 0.3-1.5mm, and cladding layer need not cover the surface of whole tool joint completely, only need be in the easy grinding belt cladding in the cylindrical two ends of joint.Wherein the concrete composition of iron(-)base powder is respectively according to quality percentage composition: C, 0.1-1.5; Cr, 10-30; Ni, 1-10; Mn, 0.2-3.0; Mo, 0.1-3.0; Si, 1.0-2.5; B, 0.1-3.5; Surplus is iron, and its weight sum is 100%.
Described laser cladding layer hardness can reach 53-58HRC.
Described high rigidity laser melting coating iron-based cladding layer and matrix are metallurgical binding, and its bond strength is not less than 90% of base material.
The tool joint of wear-and corrosion-resistant Laser Cladding of Iron-based Alloy, is characterized in that, the concrete steps of cladding are as follows:
(1) matrix surface pretreatment;
(2) adopt automatic powder feeding device, adjust powder sending quantity;
(3) adjust the running parameter of laser instrument, carry out laser melting coating;
(4) cooling under nature, carry out removing surface, check.
Surface preparation in described step (1) is with sand paper or the rust cleaning of hand-held emery wheel, with alcohol or acetone, cleans until surperficial without greasy dirt.
Powder sending quantity in described step (2) is 10~120g/min, according to the required thickness of laser cladding layer, regulates.
Laser melting coating concrete technology parameter in described step (3) is: high power CO
2laser-processing system, laser power 0.5~5kW, sweep speed 100~400mm/min, overlapping rate 20~30%.
The tool joint of wear-and corrosion-resistant Laser Cladding of Iron-based Alloy, is characterized in that, cladding layer need not cover the surface of whole tool joint completely, only need be wide at the cylindrical two ends of joint each cladding of easy grinding belt 30~50mm.
Advantage of the present invention is:
1. wear-and corrosion-resistant iron based laser cladding tool joint of the present invention, laser energy density is high, little to the heat affecting of matrix, can also can Local treatment form hardenability band to tool joint disposed of in its entirety.
2. wear-and corrosion-resistant iron based laser cladding tool joint of the present invention, wherein the formation of iron alloy coating is a kind of Fast Heating cooling process fast, therefore uniform crystal particles is tiny, and contain the intensified elements such as Cr, Ni, Mo, so the hardness of whole cladding layer is very high, can reach 53-58HRC, there is excellent abrasion resistance and corrosion resistance.
3. wear-and corrosion-resistant iron based laser cladding tool joint of the present invention, the composition of Laser Cladding of Iron-based Alloy coating wherein be take iron as main, has certain advantage in price, and preparation process is simple, and automaticity is high, steady quality.
4. wear-and corrosion-resistant iron based laser cladding tool joint of the present invention, Laser Cladding of Iron-based Alloy coating wherein can its thickness of meticulous control (adjustable continuously within the scope of 0.3mm~1.5mm), thereby can eliminate the problem that the drilling rod band of column sky bringing because overlay cladding is too thick reduces to affect drilling liquid pressure and drilling process.
5. wear-and corrosion-resistant iron based laser cladding tool joint of the present invention, Laser Cladding of Iron-based Alloy coating wherein and the dilution rate of matrix are low, and metallurgical binding intensity is high, can select flexibly as required cladding alloy powder, forms low-friction coefficient hardened layer.
Accompanying drawing explanation
Accompanying drawing is a kind of wear-and corrosion-resistant Laser Cladding of Iron-based Alloy of the present invention tool joint structural representation.
Embodiment:
Tool joint is carried out to Laser Cladding Treatment, and it carries out as follows:
(1) by the pending surface acetone wiped clean of tool joint, thoroughly remove greasy dirt.
(2) tool joint is put on rotary table, uses gravity powder feeder, adjust and make it reach suitable powder sending quantity 15~30g/min.
(3) in powder feeding, with laser, its surface is scanned, laser melting coating technological parameter be: laser power 3~4kW, sweep speed 200~300mm/min, overlapping rate 20~30%.Wherein the concrete composition of iron(-)base powder is respectively according to quality percentage composition: C, 0.1-1.5; Cr, 10-30; Ni, 1-10; Mn, 0.2-3.0; Mo, 0.1-3.0; Si, 1.0-2.5; B, 0.1-3.5; Surplus is iron, and its weight sum is 100%.
(4) treat that tool joint naturally cools to room temperature, carry out removing surface, inspection.
This tool joint surface has the wear-and corrosion-resistant iron alloy coating of one deck laser melting coating, and moulding is good, dense structure, and composition is even, and flawless, and its thickness is 1mm, only wide at the cylindrical two ends of joint each cladding of easy grinding belt 40mm.After cladding, the hardness of tool joint can reach 55HRC.
Although with reference to embodiment to disclosed a kind of wear-and corrosion-resistant Laser Cladding of Iron-based Alloy tool joint carried out special description, it is illustrative more than describing embodiment, not restrictive, without departing from the spirit and scope of the present invention, all variations and modification are all within the scope of the present invention.
Claims (1)
1. a wear-and corrosion-resistant Laser Cladding of Iron-based Alloy joint of petroleum drill rod, it is characterized in that, this tool joint surface has the anti-corrosion iron alloy coating of one deck laser cladding wear, described iron alloy coating moulding is good, dense structure, composition is even, and flawless, and its thickness can accurately be controlled within the scope of 0.3-1.5mm;
The concrete composition of this iron alloy coating is respectively according to quality percentage composition: C, 0.1-1.5; Cr, 10-30; Ni, 1-10; Mn, 0.2-3.0; Mo, 0.1-3.0; Si, 1.0-2.5; B, 0.1-3.5, surplus is iron, its weight sum is 100%;
Iron alloy coating hardness that described laser cladding wear is anti-corrosion is 53~58HRC; Described Laser Cladding Iron-based Alloy and matrix are metallurgical binding, and its bond strength is not less than 90% of matrix;
The concrete steps of cladding are as follows:
(1), matrix surface pretreatment; Surface preparation is with sand paper or the rust cleaning of hand-held emery wheel, with alcohol or acetone, cleans until surperficial without greasy dirt;
(2), adopt automatic powder feeding device, adjust powder sending quantity; Powder sending quantity is 10~120g/min, according to the required thickness of laser cladding layer, regulates;
(3), adjust the running parameter of laser instrument, carry out laser melting coating;
(4), cooling under nature, carry out removing surface, check;
Laser cladding technological parameter is: high power CO
2laser-processing system, laser power 0.5~5kW, sweep speed 100~400mm/min, overlapping rate 20~30%;
Described laser cladding wear is anti-corrosion, and iron alloy coating not exclusively covers the surface of whole tool joint, only wide at the cylindrical two ends of joint each cladding of easy grinding belt 30~50mm.
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CN201110035745.8A CN102619477B (en) | 2011-01-28 | 2011-01-28 | Wear and corrosion resistant iron-based alloy laser-cladding petroleum drill stem joint |
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