CN102612401A - Apparatus for removing trace amounts of ammonia from the gas discharged during a carbon-dioxide-collecting process using aqueous ammonia - Google Patents
Apparatus for removing trace amounts of ammonia from the gas discharged during a carbon-dioxide-collecting process using aqueous ammonia Download PDFInfo
- Publication number
- CN102612401A CN102612401A CN2010800515775A CN201080051577A CN102612401A CN 102612401 A CN102612401 A CN 102612401A CN 2010800515775 A CN2010800515775 A CN 2010800515775A CN 201080051577 A CN201080051577 A CN 201080051577A CN 102612401 A CN102612401 A CN 102612401A
- Authority
- CN
- China
- Prior art keywords
- ammonia
- sulfuric acid
- reactor
- tower
- carbon dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/346—Controlling the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/79—Injecting reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/50—Inorganic acids
- B01D2251/506—Sulfuric acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
The present invention relates to an apparatus which efficiently removes trace amounts of ammonia from the gas from which carbon dioxide has been removed and which is discharged during a carbon-dioxide-collecting process using aqueous ammonia, wherein the carbon-dioxide-collecting process separates carbon dioxide from the gas discharged during the burning of fossil fuels.
Description
Technical field
The present invention relates to a kind ofly remove the device that the micro-ammonia that emission gases led out behind the carbon dioxide is removed from the mist that contains carbon dioxide for the carbon dioxide absorption separation circuit that utilizes ammoniacal liquor; In more detail, relate to a kind of in utilizing the collecting carbonic anhydride device of ammoniacal liquor, use a spot of water and prevent the ammonia loss, in capturing device, utilize the non reversibility chemical reaction to remove to be included in the flue gas and the ammonia that leaks and reduce as far as possible ammonia content in the emission gases, remove the device that is utilizing the micro-ammonia in the gas that discharges in the collecting carbonic anhydride operation of ammoniacal liquor.
Background technology
In recent years, people begin to recognize the seriousness of global warming phenomenon, and countries in the world are sought the countermeasure to greenhouse gases painstakingly, and one of the biggest factor of such global warming is a carbon dioxide.
Such carbon dioxide produces when combustion of fossil fuel, as being used to capture or the method for separating carbon dioxide, uses absorption process usually, as such absorption process, Physical Absorption method and chemical absorption method is arranged.
As chemical absorption method; Following absorption process is arranged: select the excellent amine aqueous solution of the absorbability of carbon dioxide as absorbent, in the absorption tower, behind the chemical absorbing carbon dioxide; In removing tower, changing temperature separates; But using like this under the situation of amine as absorbent, the shortcoming of deterioration that exists the performance of the absorbent that uses significant amount of energy, causes by the sour gas in the flue gas to descend to cause by oxygen and so on, and as the price is rather stiff of the amine of absorbent.
In recent years, as the method for absorbent a lot of researchs are arranged to utilizing ammoniacal liquor, and proved conclusively on a large scale.
Compare with MEA (MEA) aqueous solution, the carbon dioxide absorption amount of ammoniacal liquor is about 3 times, and regenerated heat is about 1/3, therefore, is using under the situation of ammoniacal liquor as carbon-dioxide absorbent, and the scale of device diminishes, and can reduce energy usage.In addition, under the situation of ammoniacal liquor, have following advantage: price is merely 1/10 of ammonia, does not exist the performance of the absorbent that is caused by the sour gas in the flue gas to descend, and does not also have the deterioration that causes because of oxygen.
But because the vapour pressure of ammonia is high, thereby if there is not other wash mill, the amount of the ammonia that then leaks from the upper end, absorption tower is quite big, and ammonia belongs to global regulation gas, therefore is difficult to realize clean collecting carbonic anhydride equipment.
Thus, developed utilize water with the ammonia stripping that leaks, to water used in this process heat and reclaim ammonia, method and apparatus that the water that will remove ammonia is reused for ammonia stripping.
By such technology of the applicant exploitation Korean Patent 10-70399 number and 10-0836709 number etc. are arranged.
They are by ammonia stripping tower (perhaps absorption tower), and it is to be used for removing from flue gas carbon dioxide that separates and the unit of having removed the ammonia that is contained the flue gas of carbon dioxide; With the formations such as ammonia recovery tower that are used to reclaim the ammonia that is washed; The ammonia stripping tower that constitutes like this is in order to satisfy the emission intensity standard value; The clearance that needs to supply with a large amount of water and improve ammonia; Consume significant amount of energy at the ammonia recovery tower that is used for reclaiming ammonia thus, and the problem that exists the energy efficiency of collecting carbonic anhydride operation to descend.
In addition, such method is limited to the micro-ammonia of removing in the treated flue gas.
Summary of the invention
Technical task
The present invention carries out for the technical problem in the past that solves as above-mentioned, and its purpose is to provide a kind of and effectively removes the micro-ammonia that contained in the treated flue gas, can reduce the device water yield that in the collecting carbonic anhydride device, circulates, that be used for removing the micro-ammonia in the gas that the flue gas collecting carbonic anhydride operation of utilizing ammoniacal liquor discharges through the non reversibility chemical reaction.
Solve the problem means
The formation that is used for removing the device of the micro-ammonia in the gas that the collecting carbonic anhydride operation of utilizing ammoniacal liquor is discharged according to the present invention like this comprises: the absorption tower, and it utilizes ammoniacal liquor absorbing carbon dioxide optionally from flue gas; The ammonia stripping tower, its washing is from the ammonia of absorption tower discharging; Remove tower, it removes carbon dioxide from the ammoniacal liquor that is absorbed with carbon dioxide; The ammonia recovery tower, it will separate into the ammonia G&W and reclaim ammonia at above-mentioned scrubbing tower and the ammoniacal liquor that removes the generation of tower upper end; With the ammonia removal device, it makes the ammonia that from above-mentioned ammonia stripping tower, discharges and sulfuric acid reaction and handles, and the formation of above-mentioned ammonia removal device comprises: pipe, and it supplies with the flue gas of having removed carbon dioxide; Reactive tank, it makes the ammonia and the sulfuric acid solution reaction that comprise in the flue gas of supplying with through above-mentioned supply pipe separate out ammonium sulfate; The sulfuric acid feed unit, it supplies with sulfuric acid to above-mentioned reactive tank; With the water feed unit, it is kept constant mode according to the concentration that makes the sulfuric acid of supplying with through above-mentioned sulfuric acid feed unit and supplies with water.
Description of drawings
Fig. 1 is the structure chart according to ammonia removal device of the present invention.
Fig. 2 is the structure chart according to collecting carbonic anhydride operation of the present invention.
Symbol description to the accompanying drawing major part
1: supply pipe
2: reactor
3: sulfuric acid feed unit 3a: sulfuric acid supply pipe
31: sulfuric acid vessel 32: sulfuric acid pump 33:pH meter
4: water feed unit 4a: water supplying pipe
41: valve 42: level sensor
5: filler
6: water-circulating pipe
61: circulating pump
7: ammonium sulfate is removed container
10: the ammonia removal device
20: the absorption tower
30: remove tower
40: the ammonia recovery tower
50: scrubbing tower
60: heat exchanger
The specific embodiment
Below, with reference to accompanying drawing, specify the device of the micro-ammonia in the gas that removal of the present invention discharges in utilizing the flue gas collecting carbonic anhydride operation of ammoniacal liquor.
Fig. 1 is the structure chart according to ammonia removal device of the present invention, and Fig. 2 possesses the structure chart of the carbon dioxide capture system of ammonia removal device of the present invention for basis.
At first, ammonia removal device according to the present invention is to be used to make ammonia and sulfuric acid reaction to separate out the device of ammonium sulfate, and as shown in Figure 1, its structure comprises: ammonia supply pipe 1, and it supplies with ammonia; Ammonia reactor 2, it sprays sulfuric acid solution to the ammonia of supplying with through above-mentioned supply pipe 1, makes ammonia and sulfuric acid reaction and separates out ammonium sulfate; Sulfuric acid feed unit 3, it supplies with sulfuric acid to above-mentioned ammonia reactor 2; With water feed unit 4, its concentration according to the sulfuric acid of supplying with through above-mentioned sulfuric acid feed unit 3 is kept constant mode and is supplied with water.
The ammonia removal device that constitutes like this is arranged in the flue gas carbon dioxide capture system of utilizing ammoniacal liquor that as Fig. 2, constitutes and uses; The formation of the flue gas carbon dioxide capture system of utilizing ammoniacal liquor like this comprises: absorption tower 20, and it utilizes ammoniacal liquor absorbing carbon dioxide optionally from flue gas; Remove tower 30, it removes carbon dioxide from the ammoniacal liquor that contains carbon dioxide that is absorbed with carbon dioxide; Ammonia recovery tower 40, it will separate into the ammonia G&W and reclaim ammonia at ammonia stripping tower and the ammoniacal liquor that the upper end that removes tower produces; Scrubbing tower 50, it captures from the vapor phase ammonia of above-mentioned absorption tower 20 evaporations and is transported to above-mentioned concentration tower 40 or discharging; With ammonia removal device 10, it makes from the ammonia and the sulfuric acid reaction of above-mentioned scrubbing tower 50 dischargings and handles.
As shown in Figure 1; With regard to the ammonia removal device that as above that kind constitutes; Above-mentioned ammonia supply pipe 1 is provided with according to will vertically growing the mode that connects to the bottom of the ammonia react groove 2 that is provided with; Ammonia is fed into the interior bottom of ammonia react groove 2, and the sulfuric acid solution that has been diluted sulfuric acid by sulfuric acid feed unit 3 with 4 supplies of water feed unit is fed into the top of reactive tank 2 and is sprayed on the flue gas that contains ammonia from underfeed, and ammonia and sulfuric acid reaction generate ammonium sulfate.
So; In order sulfuric acid solution to be supplied to the top of reactor 2; Side at the reactor 2 of above-mentioned ammonia removal device is provided with circulation pipe 6, and is provided with circulating pump 61 at above-mentioned circulation pipe 6, and it is used for the sulfuric acid solution of the bottom that accumulates in above-mentioned reactor 2 is supplied to the top of reactor 2.
In addition, constitute in the reactor 2 of as above such ammonia removal device that constitutes and be provided with filler 5, it is used to prevent that the emission intensity that is fed into the bottom from capturing ammonia to top.
As stated, above-mentioned sulfuric acid feed unit 3 for be used for reactor 2 in and the sulfuric acid of ammonia react supply to the unit in the reactor 2, its formation comprises: sulfuric acid vessel 31, its storage have sulfuric acid; Sulfuric acid pump 32, its be arranged on sulfuric acid supply to from above-mentioned sulfuric acid vessel reactive tank 2 sulfuric acid supply pipe 3a the middle part and sulfuric acid is transported in the reactor; With pH meter 33, its detection is housed in the acidity of the sulfuric acid solution in the above-mentioned reactor 2 and controls the driving of sulfuric acid pump.
For the sulfuric acid feed unit 3 of such formation, above-mentioned pH meter 33 is measured the acidity of the sulfuric acid solution of the bottom surface that is housed in reactor 2, if determine the acidity below the certain acidity, then drives sulfuric acid pump 32, sulfuric acid is supplied to the inside of reactor.
That is, the acidity of sulfuric acid solution of bottom surface that is housed in reactor 2 is low to be meant that the sulfuric acid that is included in the sulfuric acid solution is few, do not have can with the sulfuric acid of ammonia react, thus, further supply with sulfuric acid, increase can with the amount of the sulfuric acid of ammonia react.
The amount that above-mentioned water feed unit 4 is used to detect sulfuric acid solution is housed in the state in the reactor 2 with the sulfuric acid solution of keeping abundant amount; Sulfuric acid solution through above-mentioned circulation pipe 6 be circulated to reactor 2 top and and ammonia react; Under the inadequate situation of sulfuric acid solution; The reaction of ammonia and sulfuric acid reduces, and the ammonia clearance descends, and therefore need keep the sulfuric acid solution of abundant amount.
Therefore; Above-mentioned water feed unit 4 is provided with the valve 41 that flows of control water in the centre of the water supplying pipe 4a that is connected with tank; And be provided with and detect the water level be housed in the sulfuric acid solution in the said reactor 2 and the level sensor 42 of the folding of by-pass valve control; According to water level, the amount of the feasible water of supplying with is regulated automatically thus.
Certainly, even when the acidity of sulfuric acid solution is too high, also can further supply with water, this can be according to the pH meter 33 detected acidity that constitute above-mentioned sulfuric acid feed unit 3, the quantity delivered that water is regulated in above-mentioned valve 41 foldings.
In addition; Be provided with ammonium sulfate in the bottom surface of above-mentioned reactor 2 and remove container 7; It is used to remove the ammonium sulfate of separating out through ammonia and sulfuric acid reaction, and can further be provided for ammonium sulfate is discharged into outside vent valves (not shown) in the bottom of above-mentioned ammonium sulfate removal container 7.
The formation that the Korean Patent that the carbon dioxide capture system that possesses as above the ammonium removal device that constitutes and the applicant have authorized is 10-0836709 number is identical or similar, but in order to help understanding, carries out following further specifying.
Above-mentioned absorption tower 20 is used to make carbon dioxide absorption in ammonia spirit, supplies with ammonia spirit from top, injects from the bottom to contain the mist of carbon dioxide and carbon dioxide is absorbed in the ammonia spirit of being supplied with.
That is, the ammonia spirit of supplying with from top flows to the bottom, makes carbon dioxide be absorbed in ammonia spirit.
Like this, the ammonia spirit that is absorbed with carbon dioxide is transported to the above-mentioned tower 30 that removes, and in removing tower 30, only removes carbon dioxide, and produces high-pureness carbon dioxide.
Remove in the tower 30 above-mentioned, the ammonia spirit that is absorbed with carbon dioxide is heated, make carbon dioxide eliminating.
Above-mentioned scrubbing tower 50 is the devices that are used to capture ammonia; It is captured in volatilization in the above-mentioned absorption tower 20 and the ammonia of discharging; The low concentration ammoniacal liquor that in scrubbing tower, has captured ammonia is fed into above-mentioned ammonia recovery tower 40 and separates into the ammonia G&W; Ammonia is transported to the bottom that removes tower, and the water of having removed ammonia is fed into scrubbing tower 50.
The ammoniacal liquor of in removing tower 30, having removed carbon dioxide is supplied to absorption tower 20 again, and absorbing carbon dioxide.
Promptly; In utilizing the collecting carbonic anhydride process of carbon dioxide capture system of the present invention, as shown in Figure 2, carbon dioxide is captured along the dotted line circulation; Ammonia is regenerated according to chain-dotted line direction circulation and absorbing carbon dioxide; Finish through such process after the capture of carbon dioxide, ammonia is fed into the ammonia removal device according to the direction transmission of solid line, and ammonia is removed thus.
That is, as stated, be fed into according to ammonia removal device according to the present invention 10 backs and separate out ammonium sulfate with sulfuric acid reaction, the ammonium sulfate of separating out like this is fed into fertilizer factory etc. and as the raw material of fertilizer.
Industrial applicibility
The present invention can make the ammonia of the trace that is contained in the flue gas of from the collecting carbonic anhydride device that utilizes ammoniacal liquor, discharging separate out ammonium sulfate at normal temperatures with sulfuric acid reaction, therefore can practice thrift the needed water of processing and the energy of the ammonia that volatilizees away.
In addition, through making removed like this ammonium sulfate can reduce the required expense of ammonia treatment as the raw material of fertilizer etc.
Claims (6)
1. the device of the micro-ammonia in the gas that in flue gas collecting carbonic anhydride operation, discharges of a removal; It is a device of removing the micro-ammonia in the gas that in utilizing the flue gas collecting carbonic anhydride operation of ammoniacal liquor, discharges; Its formation comprises: absorption tower (20), and it is used for utilizing ammoniacal liquor from flue gas absorbing carbon dioxide optionally; Remove tower (30), it is used for removing carbon dioxide from the ammoniacal liquor that contains carbon dioxide that is absorbed with carbon dioxide; Scrubbing tower (50), it captures from the vapor phase ammonia of said absorption tower (20) evaporation; Ammonia recovery tower (40), it is from said scrubbing tower (50) with remove separation of ammonia G&W the ammoniacal liquor that tower (30) upper end produces and reclaim ammonia; With ammonia removal device (10), it removes collection at large in said scrubbing tower (50) and the ammonia that discharges, it is characterized in that the formation of said ammonia removal device (10) comprising: ammonia supply pipe (1), and it supplies with ammonia; Ammonia reactor (2), it sprays sulfuric acid solution to the ammonia of supplying with through said supply pipe (1), makes ammonia and sulfuric acid reaction and separates out ammonium sulfate; Sulfuric acid feed unit (3), it supplies with sulfuric acid to said ammonia reactor (2); With water feed unit (4), it is kept constant mode according to the concentration that makes the sulfuric acid of supplying with through said sulfuric acid feed unit (3) and supplies with water.
2. the device of the micro-ammonia in the gas that removal according to claim 1 is discharged in flue gas collecting carbonic anhydride operation; It is characterized in that; Set inside at said reactor (2) has filler (5), to prevent that being fed into inner ammonia is discharged into top.
3. the device of the micro-ammonia in the gas that removal according to claim 1 is discharged in flue gas collecting carbonic anhydride operation; It is characterized in that; Side at said reactor (2) is provided with circulation pipe (6), and is provided with the circulating pump (61) that is used for the sulfuric acid solution of the bottom that accumulates in said reactor (2) is supplied to the top of reactor (2) at said circulation pipe (6).
4. ammonia removal device according to claim 1 is characterized in that, the formation of said sulfuric acid feed unit (3) comprising: sulfuric acid vessel (31), and its storage has sulfuric acid; Sulfuric acid pump (32), its be set at sulfuric acid supply to from said sulfuric acid vessel reactive tank (2) sulfuric acid supply pipe (3a) the middle part and sulfuric acid is transported in the reactor; And pH meter (33), its detection is housed in the acidity of the sulfuric acid solution in the said reactor (2) and controls the driving of sulfuric acid pump.
5. the device of the micro-ammonia in the gas that removal according to claim 1 is discharged in flue gas collecting carbonic anhydride operation; It is characterized in that; The formation of said water feed unit (4) comprising: valve (41), and it is arranged on the centre of the water supplying pipe (4a) that is connected with tank and controls flowing of water; And level sensor (42), its detection is housed in water level and the folding of by-pass valve control of the sulfuric acid solution in the said reactor (2).
6. the device of the micro-ammonia in the gas that removal according to claim 1 is discharged in flue gas collecting carbonic anhydride operation; It is characterized in that; Be provided with ammonium sulfate in the bottom surface of said reactor (2) and remove container (7), it is used to remove the ammonium sulfate of being separated out by ammonia and sulfuric acid reaction.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2009-0110863 | 2009-11-17 | ||
| KR1020090110863A KR101039624B1 (en) | 2009-11-17 | 2009-11-17 | Apparatus for removing trace of ammonia in off-gas of aqueous ammonia process to capture carbon dioxide |
| PCT/KR2010/003403 WO2011062338A1 (en) | 2009-11-17 | 2010-05-28 | Apparatus for removing trace amounts of ammonia from the gas discharged during a carbon-dioxide-collecting process using aqueous ammonia |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102612401A true CN102612401A (en) | 2012-07-25 |
| CN102612401B CN102612401B (en) | 2015-04-22 |
Family
ID=44059791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080051577.5A Active CN102612401B (en) | 2009-11-17 | 2010-05-28 | Apparatus for removing trace amounts of ammonia from the gas discharged during a carbon-dioxide-collecting process using aqueous ammonia |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101039624B1 (en) |
| CN (1) | CN102612401B (en) |
| WO (1) | WO2011062338A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107126826A (en) * | 2017-04-10 | 2017-09-05 | 天津凯赛特科技有限公司 | Ammonia-contained tail gas treating device and method in prepared by a kind of soda ash |
| CN108067181A (en) * | 2016-11-09 | 2018-05-25 | 韩国能量技术研究院 | The highly selective absorbent of carbon monoxide and its manufacturing method |
| CN115475502A (en) * | 2022-10-14 | 2022-12-16 | 苏州依斯倍环保装备科技有限公司 | Method and system for capturing carbon dioxide containing carbon dioxide emission tail gas |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101140775B1 (en) | 2012-03-02 | 2012-07-12 | (주)대우건설 | Apparatus for capture of carbon dioxide continuously circulating aqueous solution in duct reactor and the method thereof |
| CN105983322B (en) * | 2015-01-31 | 2018-04-06 | 中国石油化工股份有限公司 | The sprinkling equipment of neutralization reaction |
| CN105457472A (en) * | 2015-11-18 | 2016-04-06 | 华文蔚 | Cleaning device for ammonia-containing waste gas |
| KR20220118808A (en) | 2021-02-19 | 2022-08-26 | 삼성중공업 주식회사 | Ammonia gas emergency vent apparatus |
| KR102623562B1 (en) | 2023-06-23 | 2024-01-10 | 주식회사 이엔워터솔루션 | Hybrid type high-concentration ammonia gas removal device and method consisting of 2-channel one-loop circulation cycle ammonia gas collection and sulfuric acid solution gravity drop spraying |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004011127A1 (en) * | 2002-07-30 | 2004-02-05 | Scan-Airclean Aps | Method of purifying air, process for manufacture of fertilizer, apparatus for purifying air and building provided with this apparatus |
| JP2004174369A (en) * | 2002-11-27 | 2004-06-24 | Meidensha Corp | Gas treatment method and system therefor |
| KR20050017649A (en) * | 2003-08-08 | 2005-02-22 | 한국전력공사 | Method for removing carbon dioxide from exhaust gas |
| JP2005262051A (en) * | 2004-03-17 | 2005-09-29 | Takuma Co Ltd | Method and system for recovering carbon dioxide |
| KR100836709B1 (en) * | 2007-02-02 | 2008-06-10 | 한국에너지기술연구원 | Method of recovering carbon dioxide from mixed gas using aqueous ammonia with preventing ammonia loss and the apparatus thereof |
| WO2009056830A1 (en) * | 2007-11-01 | 2009-05-07 | Alstom Technology Ltd | Carbon capture system and process |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7867322B2 (en) | 2007-01-31 | 2011-01-11 | Alstom Technology Ltd | Use of SO2 from flue gas for acid wash of ammonia |
-
2009
- 2009-11-17 KR KR1020090110863A patent/KR101039624B1/en active IP Right Grant
-
2010
- 2010-05-28 CN CN201080051577.5A patent/CN102612401B/en active Active
- 2010-05-28 WO PCT/KR2010/003403 patent/WO2011062338A1/en active Application Filing
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004011127A1 (en) * | 2002-07-30 | 2004-02-05 | Scan-Airclean Aps | Method of purifying air, process for manufacture of fertilizer, apparatus for purifying air and building provided with this apparatus |
| JP2004174369A (en) * | 2002-11-27 | 2004-06-24 | Meidensha Corp | Gas treatment method and system therefor |
| KR20050017649A (en) * | 2003-08-08 | 2005-02-22 | 한국전력공사 | Method for removing carbon dioxide from exhaust gas |
| JP2005262051A (en) * | 2004-03-17 | 2005-09-29 | Takuma Co Ltd | Method and system for recovering carbon dioxide |
| KR100836709B1 (en) * | 2007-02-02 | 2008-06-10 | 한국에너지기술연구원 | Method of recovering carbon dioxide from mixed gas using aqueous ammonia with preventing ammonia loss and the apparatus thereof |
| WO2009056830A1 (en) * | 2007-11-01 | 2009-05-07 | Alstom Technology Ltd | Carbon capture system and process |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108067181A (en) * | 2016-11-09 | 2018-05-25 | 韩国能量技术研究院 | The highly selective absorbent of carbon monoxide and its manufacturing method |
| CN107126826A (en) * | 2017-04-10 | 2017-09-05 | 天津凯赛特科技有限公司 | Ammonia-contained tail gas treating device and method in prepared by a kind of soda ash |
| CN115475502A (en) * | 2022-10-14 | 2022-12-16 | 苏州依斯倍环保装备科技有限公司 | Method and system for capturing carbon dioxide containing carbon dioxide emission tail gas |
| CN115475502B (en) * | 2022-10-14 | 2024-04-26 | 苏州依斯倍环保装备科技有限公司 | Carbon dioxide capturing method and system for tail gas containing carbon dioxide emission |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102612401B (en) | 2015-04-22 |
| WO2011062338A1 (en) | 2011-05-26 |
| KR20110054273A (en) | 2011-05-25 |
| KR101039624B1 (en) | 2011-06-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102612401A (en) | Apparatus for removing trace amounts of ammonia from the gas discharged during a carbon-dioxide-collecting process using aqueous ammonia | |
| KR101545604B1 (en) | method for capturing carbon dioxide in power station flue gas and device therefor | |
| US8623307B2 (en) | Process gas treatment system | |
| EP2616160B1 (en) | Method and system for reducing energy requirements of a co2 capture system | |
| CN101716458A (en) | System for trapping carbon dioxide in flue gas of coal-fired power plant and corresponding treatment method | |
| NO332812B1 (en) | Amine emission control | |
| US10449481B2 (en) | CO2 recovery unit and CO2 recovery method | |
| CN111729483A (en) | Carbon dioxide capture system and method | |
| CN102992351B (en) | Method and device for purifying ammonia recovered from coal chemical industry wastewater | |
| EP2230000B1 (en) | Flue gas treatment system and method using ammonia solution | |
| CN104338418A (en) | Ammonia stripper for a carbon capture system for reduction of energy consumption | |
| CN103025407A (en) | Method and device for treating a contaminated alkaline amino acid saline solution | |
| KR101726162B1 (en) | Method of resource reuse of stripping system for acid gas capture | |
| KR101899600B1 (en) | Apparatus for treating carbon dioxide | |
| CN108278908B (en) | Flue gas waste heat and moisture recovery device | |
| CN201603511U (en) | Carbon dioxide trapping system in coal-fired power plant smoke | |
| JP2023068025A (en) | Carbon dioxide recovery system | |
| CN211226439U (en) | Energy comprehensive utilization system for flue gas white elimination coupling seawater desalination | |
| CN215982493U (en) | Energy recovery device system of amine method carbon dioxide capture coupling coal-fired boiler | |
| AU2015200530B2 (en) | Removal of non-volatiles from ammonia-based CO2-absorbent solution | |
| CN116328503A (en) | Skid-mounted coal bed methane MDEA deep decarburization desorption device and method | |
| KR20100073614A (en) | Recovery method of carbon dioxide from off gas by non used waste heat utilization |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |