CN102604417A - New technology for separating haematochrome and pectin from capsanthin centrifugate - Google Patents
New technology for separating haematochrome and pectin from capsanthin centrifugate Download PDFInfo
- Publication number
- CN102604417A CN102604417A CN2011104185111A CN201110418511A CN102604417A CN 102604417 A CN102604417 A CN 102604417A CN 2011104185111 A CN2011104185111 A CN 2011104185111A CN 201110418511 A CN201110418511 A CN 201110418511A CN 102604417 A CN102604417 A CN 102604417A
- Authority
- CN
- China
- Prior art keywords
- solvent
- centrifugal thing
- haematochrome
- capsanthin
- pectin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000001814 pectin Substances 0.000 title claims abstract description 17
- 235000010987 pectin Nutrition 0.000 title claims abstract description 17
- 229920001277 pectin Polymers 0.000 title claims abstract description 17
- VYIRVAXUEZSDNC-TXDLOWMYSA-N (3R,3'S,5'R)-3,3'-dihydroxy-beta-kappa-caroten-6'-one Chemical compound C([C@H](O)CC=1C)C(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC(=O)[C@]1(C)C[C@@H](O)CC1(C)C VYIRVAXUEZSDNC-TXDLOWMYSA-N 0.000 title claims abstract description 10
- VYIRVAXUEZSDNC-LOFNIBRQSA-N Capsanthyn Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC(=O)C2(C)CC(O)CC2(C)C VYIRVAXUEZSDNC-LOFNIBRQSA-N 0.000 title claims abstract description 10
- WRANYHFEXGNSND-LOFNIBRQSA-N capsanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC(=O)C2(C)CCC(O)C2(C)C WRANYHFEXGNSND-LOFNIBRQSA-N 0.000 title claims abstract description 10
- 235000018889 capsanthin Nutrition 0.000 title claims abstract description 10
- 235000012658 paprika extract Nutrition 0.000 title claims abstract description 10
- 239000001688 paprika extract Substances 0.000 title claims abstract description 10
- 238000005516 engineering process Methods 0.000 title abstract description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 11
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012046 mixed solvent Substances 0.000 claims abstract description 7
- 238000007670 refining Methods 0.000 claims abstract description 5
- 238000000605 extraction Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 claims description 40
- 229960002504 capsaicin Drugs 0.000 claims description 20
- 235000017663 capsaicin Nutrition 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 14
- 238000007127 saponification reaction Methods 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 9
- 239000001054 red pigment Substances 0.000 claims description 7
- 238000002386 leaching Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002274 desiccant Substances 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 2
- 239000000284 extract Substances 0.000 abstract description 3
- 240000008574 Capsicum frutescens Species 0.000 abstract description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 235000002568 Capsicum frutescens Nutrition 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000002566 Capsicum Nutrition 0.000 description 1
- 238000003811 acetone extraction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- -1 hydrogen potassium oxide Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
The invention discloses a new technology for separating haematochrome and pectin from capsanthin centrifugate and belongs to the technical field of hot pepper deep processing. The new technology comprises the following steps of: heating a certain amount of centrifugate at 40 DEG C for 60 minutes; adding potassium hydroxide and stirring uniformly; keeping certain temperature and shading to saponify for 5-7 hours; adding a mixed solvent of normal hexane and acetone, and stirring to extract for 50 minutes; performing repeated extraction for 3 times; and refining the extract and recycling the solvent to obtain the haematochrome. In the saponified haematochrome centrifugate, the haematochrome is extracted by the normal hexane and acetone, the pectin is decomposed by acetone and sinks, and the haematochrome and pectin do not interfere with each other so as to achieve the aim of thoroughly processing the centrifugate. The new technology disclosed by the invention is suitable for popularization and application in waste disposal after the haematochrome is processed.
Description
Technical field
The invention belongs to capsicum deep processing field, particularly extract the technology of CAPSAICIN and pectin.
Background technology
CAPSAICIN is through nearly 20 years development, and when output improved, quality product also required stricter immediately.Along with the raising of product standard index, CAPSAICIN also is accompanied by various impurity by a large amount of separating, when mainly concentrating on control throw out and acetone insoluble matter on the centrifugal centrifugal thing that comes out.If can not the CAPSAICIN in the centrifugal thing be extracted, still the product yield is not low for that kind, and production cost is also high, has influenced the competitiveness of product in market.Before this, not having a kind of special suitable method to handle the centrifugal thing of CAPSAICIN, can only be solvent with the normal hexane, dashes repeatedly and drenches, and incorporates production system into and carries out circulation again and again, separates dissolved again, separated again; Make centrifugal thing constantly accumulate, quantity is more and more, can only be confined to can not fundamentally be resolved in the production system.
Summary of the invention
For overcoming the defective of above-mentioned prior art; The invention discloses a kind of from the centrifugal thing of capsanthin the novel process of separate red pigment and pectin; CAPSAICIN is effectively separated with the pectin bullion simultaneously; Saved great amount of cost, the CAPSAICIN yield obviously improves, and the comprehensive benefit of CAPSAICIN is promoted significantly.
The technical scheme that the present invention adopted be a kind of from the centrifugal thing of capsanthin the novel process of separate red pigment and pectin, be raw material with the centrifugal thing of CAPSAICIN, through after the preliminary saponification; Use mixed solvent to extract CAPSAICIN, at first centrifugal thing is dropped in the mixing tank, heated 60 minutes down at 40 degrees centigrade; Be auxiliary material with 99.9% Pottasium Hydroxide then, behind 12kg water dilution 3kg Pottasium Hydroxide, join in the centrifugal thing of 100kg; Drop into the saponification jar after stirring, continue to keep 40 degrees centigrade, shading saponification 6 hours; Then with normal hexane: acetone is that the mixed solvent of 1:1 (volume ratio) serves as to extract solvent, in centrifugal thing, adds the extraction solvent of 4 times of volumes of centrifugal thing, stirs and extracts 50 minutes; Repeat leaching process 3 times; Obtain CAPSAICIN after refining extracting solution reclaims solvent, the light yellow or filemot thick substances that is separated to lower floor obtains pectin product through the vacuum-drying agent behind the recovery solvent.
The invention has the beneficial effects as follows in the leaching process; Through the centrifugal thing of CAPSAICIN after the saponification, wherein CAPSAICIN is by normal hexane and acetone extraction, and pectin because the reason of acetone thoroughly decomposed to sink; Do not disturb mutually after both separate, thereby reach the purpose of the centrifugal thing of thorough processing.
Embodiment
Embodiment 1, a kind of from the centrifugal thing of capsanthin the novel process of separate red pigment and pectin, be raw material with the centrifugal thing of CAPSAICIN; Through after the preliminary saponification, use mixed solvent to extract CAPSAICIN, at first the centrifugal thing of 550kg is dropped in the mixing tank; 40 degrees centigrade of down heating 60 minutes, be auxiliary material with 99.9% Pottasium Hydroxide then, this ratio of mixed solution that adds 12kg water dilution 3kg Pottasium Hydroxide in the centrifugal thing of 100kg drops into Pottasium Hydroxide; Mixed solution behind the input 66kg water dilute hydrogen potassium oxide 16.5kg, the saponification jar is dropped in the back that stirs, and continues to keep 40 degrees centigrade; Shading saponification 6 hours, then with normal hexane: acetone=1:1 (volume ratio) mixed solvent serves as to extract solvent, drops in the extractor; Use the extraction stirring solvent of 2200L to extract 50 minutes; Repeat leaching process 3 times, refining extracting solution reclaims and obtains look valency content behind the solvent is 175 CAPSAICIN 140kg, and the light yellow or filemot thick substances that is separated to lower floor is through the vacuum-drying agent; Obtain pectin product 390kg, slag charge 20kg after reclaiming solvent.
Embodiment 2, and the temperature that is to drop into behind the saponification jar with embodiment 1 difference keeps 30 degrees centigrade, and shading saponification 7 hours obtains look valency content and be 175 CAPSAICIN 138kg, pectin product 390kg, slag charge 22kg.
Embodiment 3, and the temperature that is to drop into behind the saponification jar with embodiment 1 difference keeps 50 degrees centigrade, and shading saponification 5 hours obtains look valency content and be 175 CAPSAICIN 139kg, pectin product 390kg, slag charge 21kg.
Claims (4)
1. the novel process of separate red pigment from the centrifugal thing of capsanthin is characterized in that centrifugal thing 40 degrees centigrade of heating 60 minutes down, adds the auxiliary material of 99.9% Pottasium Hydroxide then; After stirring, keep 30-50 degrees centigrade temperature, shading saponification 5-7 hours; Then with normal hexane: acetone is that 1:1 (volume ratio) mixed solvent serves as to extract solvent; Stir and extracted 50 minutes, repeat leaching process 3 times, obtain CAPSAICIN after refining extracting solution reclaims solvent.
According to claim 1 said from the centrifugal thing of capsanthin the novel process of separate red pigment, the ratio that it is characterized in that said Pottasium Hydroxide input joins in the centrifugal thing and stirs for add the mixed solution behind the 12kg water dilution 3kg Pottasium Hydroxide by the centrifugal thing of 100kg.
According to claim 1 said from the centrifugal thing of capsanthin the novel process of separate red pigment, the ratio that it is characterized in that said extraction solvent is 4 times of volumes of centrifugal thing.
4. the novel process of from the centrifugal thing of capsanthin, separating pectin is characterized in that centrifugal thing 40 degrees centigrade of heating 60 minutes down, adds the auxiliary material of 99.9% Pottasium Hydroxide then; After stirring, keep 30-50 degrees centigrade temperature, shading saponification 5-7 hours; Then with normal hexane: acetone is that 1:1 (volume ratio) mixed solvent serves as to extract solvent; Stir and extracted 50 minutes, repeat leaching process 3 times, obtain CAPSAICIN after refining extracting solution reclaims solvent; Light yellow or the filemot thick substances that is separated to lower floor obtains pectin product through the vacuum-drying agent behind the recovery solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104185111A CN102604417B (en) | 2011-12-15 | 2011-12-15 | New technology for separating haematochrome and pectin from capsanthin centrifugate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104185111A CN102604417B (en) | 2011-12-15 | 2011-12-15 | New technology for separating haematochrome and pectin from capsanthin centrifugate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102604417A true CN102604417A (en) | 2012-07-25 |
| CN102604417B CN102604417B (en) | 2013-12-11 |
Family
ID=46522213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104185111A Expired - Fee Related CN102604417B (en) | 2011-12-15 | 2011-12-15 | New technology for separating haematochrome and pectin from capsanthin centrifugate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102604417B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013179A (en) * | 2013-01-11 | 2013-04-03 | 邯郸市中进天然色素有限公司 | Method for enhancing extinction ratio of capsanthin pigment |
| CN104017105A (en) * | 2014-06-19 | 2014-09-03 | 中国农业大学 | Method for extracting pectin from pepper skin slag |
| CN104920912A (en) * | 2015-07-11 | 2015-09-23 | 青岛赛特香料有限公司 | Method for preparing feed additives containing capsanthin sedimentation slags |
| CN109370252A (en) * | 2018-11-23 | 2019-02-22 | 晨光生物科技集团股份有限公司 | A kind of refining methd of capsicum red pigment slag |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50115232A (en) * | 1974-02-26 | 1975-09-09 | ||
| JPS57190051A (en) * | 1981-05-18 | 1982-11-22 | San Ei Chem Ind Ltd | Production of paprika pigment |
| JPS58173164A (en) * | 1982-04-05 | 1983-10-12 | San Ei Chem Ind Ltd | Production of paprika coloring matter |
| JPS5933259A (en) * | 1982-08-19 | 1984-02-23 | San Ei Chem Ind Ltd | Preparation of carotenoid dyestuff |
| CN1053803A (en) * | 1991-03-18 | 1991-08-14 | 贵阳市云岩区农副业生产基地 | The production method of natural chilli pigment |
| CN1082570A (en) * | 1992-08-05 | 1994-02-23 | 郭湘泗 | From capsicum, extract the method for haematochrome |
| CN1740236A (en) * | 2004-08-23 | 2006-03-01 | 黄启强 | Production process of capsorubin and capsaicine |
| CN1911902A (en) * | 2006-08-04 | 2007-02-14 | 苏州洪升油脂化工机械有限公司 | Extraction technology of capsanthin and capsicine |
| CN102079883A (en) * | 2010-11-22 | 2011-06-01 | 武城县英潮经贸有限公司 | Novel process for extracting capsanthin and chilli extract by composite solvent |
| CN102181172A (en) * | 2011-03-09 | 2011-09-14 | 浙江大学 | Technique for preparing capsanthin pigment from chilies |
-
2011
- 2011-12-15 CN CN2011104185111A patent/CN102604417B/en not_active Expired - Fee Related
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50115232A (en) * | 1974-02-26 | 1975-09-09 | ||
| JPS57190051A (en) * | 1981-05-18 | 1982-11-22 | San Ei Chem Ind Ltd | Production of paprika pigment |
| JPS58173164A (en) * | 1982-04-05 | 1983-10-12 | San Ei Chem Ind Ltd | Production of paprika coloring matter |
| JPS5933259A (en) * | 1982-08-19 | 1984-02-23 | San Ei Chem Ind Ltd | Preparation of carotenoid dyestuff |
| CN1053803A (en) * | 1991-03-18 | 1991-08-14 | 贵阳市云岩区农副业生产基地 | The production method of natural chilli pigment |
| CN1082570A (en) * | 1992-08-05 | 1994-02-23 | 郭湘泗 | From capsicum, extract the method for haematochrome |
| CN1740236A (en) * | 2004-08-23 | 2006-03-01 | 黄启强 | Production process of capsorubin and capsaicine |
| CN1911902A (en) * | 2006-08-04 | 2007-02-14 | 苏州洪升油脂化工机械有限公司 | Extraction technology of capsanthin and capsicine |
| CN102079883A (en) * | 2010-11-22 | 2011-06-01 | 武城县英潮经贸有限公司 | Novel process for extracting capsanthin and chilli extract by composite solvent |
| CN102181172A (en) * | 2011-03-09 | 2011-09-14 | 浙江大学 | Technique for preparing capsanthin pigment from chilies |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013179A (en) * | 2013-01-11 | 2013-04-03 | 邯郸市中进天然色素有限公司 | Method for enhancing extinction ratio of capsanthin pigment |
| CN104017105A (en) * | 2014-06-19 | 2014-09-03 | 中国农业大学 | Method for extracting pectin from pepper skin slag |
| CN104920912A (en) * | 2015-07-11 | 2015-09-23 | 青岛赛特香料有限公司 | Method for preparing feed additives containing capsanthin sedimentation slags |
| CN109370252A (en) * | 2018-11-23 | 2019-02-22 | 晨光生物科技集团股份有限公司 | A kind of refining methd of capsicum red pigment slag |
| CN109370252B (en) * | 2018-11-23 | 2020-02-21 | 晨光生物科技集团股份有限公司 | Refining method of capsanthin pigment residue |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102604417B (en) | 2013-12-11 |
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Legal Events
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| C06 | Publication | ||
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Shang Zhuang 253300 Shandong city of Dezhou province Wucheng County town of pepper English Group Patentee after: ZHONGJIAO YINGCHAO SPICY INDUSTRY DEVELOPMENT Co.,Ltd. Address before: Shang Zhuang 253300 Shandong city of Dezhou province Wucheng County town of pepper English Group Patentee before: Wucheng Yingchao Economy and Trade Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: New technology for separating haematochrome and pectin from capsanthin centrifugate Effective date of registration: 20160708 Granted publication date: 20131211 Pledgee: Shandong agricultural financing Company limited by guarantee Pledgor: ZHONGJIAO YINGCHAO SPICY INDUSTRY DEVELOPMENT Co.,Ltd. Registration number: 2016370000044 |
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| PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131211 |