CN102587130A - Processing method of durable nano water-and-stain-proofing woolen fabric - Google Patents

Processing method of durable nano water-and-stain-proofing woolen fabric Download PDF

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CN102587130A
CN102587130A CN2012100569263A CN201210056926A CN102587130A CN 102587130 A CN102587130 A CN 102587130A CN 2012100569263 A CN2012100569263 A CN 2012100569263A CN 201210056926 A CN201210056926 A CN 201210056926A CN 102587130 A CN102587130 A CN 102587130A
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water
lining
agent
stain
proofing
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CN102587130B (en
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牟水法
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Shandong Huaao Textile Technology Co.,Ltd.
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SHENZHEN WOOLEN TEXTILE CO Ltd ZHEJIANG
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Abstract

The invention discloses a processing method of a durable nano water-and-stain-proofing woolen fabric, aiming to provide the processing method of the durable nano water-and-stain-proofing woolen fabric, which has a simple processing process, less resource and energy consumption, short construction period and a durable water-and stain-proofing effect. The processing method comprises the following steps of: preprocessing to a fabric and water-and-stain-proofing finishing of co-bath padding of a nano water-and-stain-proofing finishing agent and a cross-linking agent. According to the invention, by the preprocessing process and using the corresponding additives, the permeability of the water-and-stain-proofing agent in the fabric in the following water-and-stain-proofing processing is greatly improved; and simultaneously, in water-and-stain-proofing processing, various corresponding water-and-stain-proofing processing agents and a twice-immersing twice-rolling process are adopted, so that the water-and-stain-proofing processing agent can be fully combined with the fabric, and can permeate into the insides of fibers, and further, the water-and-stain proofing effect is more durable.

Description

The processing method of the antifouling slubbing lining of permanent seal cooling nano water-proof
Technical field
The present invention relates to textile product, relate in particular to the processing method of the antifouling slubbing lining of permanent seal cooling nano water-proof of cashmere, the rabbit hair, wool blended series products.
Background technology
Current society, people are constantly improving the requirement of dressing lining, except that warming, comfortable, fashion are the target pursued of people, and specific function, textiles with high content of technology are arranged, and more and more receive consumer's favor.Owing to the technological progress of dying of weaving material, the research and development of specific function textiles have also been promoted to have.At present high-end market is bigger to the demand of the antifouling lining of waterproof, is tool affinity like cashmere fiber to skin, so cashmere product receives the welcome of high-end piece market most.Opposite these high-grade fabrics also preferably can be washed less, and therefore many linings have just required the waterproof anti-fouling functions.
The auxiliary agent that can be used for the antifouling lining of waterproof at present is more, but can reach the antifouling auxiliary agent of waterproof seldom through disposable processed.Though nano assistant is arranged, its molecular particle size is very thin, usually less than 100nm, has good dispersiveness, permeability, can manyly be adsorbed onto more equably on the lining, therefore can obtain waterproof anti-fouling effect preferably with the nano water-proof anti-soil agent.If but through after repeatedly dry-cleaning, its effect can obviously descend, as uses following 5 kinds of finishing agents to handle through routine, and is also unsatisfactory through the detection effect:
Figure BSA00000679931900011
Can find out that from last table the waterproof anti-fouling effect before the dry-cleaning is relatively good after treatment, but classification of waterproof and all obviously reductions of antifouling grade after dry-cleaning descends generally more than 2 grades or 2 grades through 3-5 dry-cleaning.Though can suitably improve the waterproof antifouling property as handling through the antifouling auxiliary agent of repetitious waterproof, can bring damage to the quality of lining, in processing procedure, can bring the waste of more pollution and the water resource and the energy, the consumption worker is consuming time big, less economical.If after carrying out an antifouling processing of waterproof, can also keep waterproof antifouling property preferably through dry-cleaning repeatedly, will be great raising to the quality of the antifouling lining of waterproof, also practiced thrift multiple resource.
Summary of the invention
The object of the present invention is to provide that a kind of treatment process is simple, resource and energy resource consumption be few, the process-cycle is short, the processing method of the antifouling slubbing lining of permanent seal cooling nano water-proof that the waterproof anti-fouling effect is lasting.
In order to reach above-mentioned requirements, the processing method of the antifouling slubbing lining of permanent seal cooling nano water-proof: it includes successively to the pre-treatment of lining with nano water-proof anti-soil agent and crosslinking agent and bathes the waterproof soil resistant finish that pads together, and the characteristic of its treatment process is:
(1) pre-treatment:
Use following auxiliary agent:
ECO-9 finishing agent 15-25%owf (weight ratio of fabric and ECO-9 finishing agent)
NaHCO 3(every premium on currency contains 15-25g NaHCO to 15-25g/l 3)
Na 2SO 4(every premium on currency contains 10-20g Na to 10-20g/l 2SO 4)
Bath raio (weight ratio of fabric and water): 1: 10-1: 15
Through the rope dyeing machine pre-treatment, concrete treatment process is lining successively in above-mentioned auxiliary agent:
When 25 ℃ ± 3 ℃ of temperature; 12-18 minute → rope dyeing machine of rope dyeing machine running running 20-30 minute; Be warmed up to 70 ℃ ± 3 ℃, → insulation under 70 ℃ ± 3 ℃ environment, rope dyeing machine running 35-45 minute → wash 8-15 minute → draining with 40 ℃ ± 3 ℃ water temperatures;
Neutralisation treatment technology: the acetum of adding 1% neutralization in rope dyeing machine; bath raio (weight ratio of fabric and water): 1: 10-1: 15; heat 50 ℃ ± 3 ℃; lining turns round in rope dyeing machine, and 12-18 minute → draining → with 25 ℃ ± 3 ℃ flushing with clean water, 8-15 minute → draining → detection pH value is between 6-6.5;
Oven dry: the lining after will handling is dried under 90 ℃ of-110 ℃ of temperature;
(2) waterproof soil resistant finish:
Waterproof antifouling treatment agent and consumption:
UEG-3 nano water-proof anti-soil agent: consumption is that every premium on currency contains 50-70g;
The J2 crosslinking agent: consumption is that every premium on currency contains 2.5-4.5g;
Propylene glycol: consumption is that every premium on currency contains 15-25g;
Nonionic penetrant is used in weaving: consumption is that every premium on currency contains 0-3.5g;
Pick-up; 70%--75%;
Waterproof soil resistant finish technology: lining is immersed in the above-mentioned mixed uniformly waterproof antifouling treatment agent of 25 ℃ of temperature; Through twice roll extrusion of twice immersion of water calender roll; Wherein the pressure of roll remains on 0.45-0.55MPa; The speed that lining advances roll be 6-8 rice/minute, lining gets into roll and will keep smooth during roll extrusion;
(3) bake by routine: preliminary drying: 80 ℃--90 ℃; Training baking: 175 ℃--180 ℃, the time: 1 minute;
(4) by becoming finished product after the arrangement after the routine with the antifouling slubbing lining of waterproof.
The not good reason of the antifouling treatment effect of analytic routines waterproof is that the nano water-proof anti-soil agent does not combine with fiber; Just cover fiber surface formation one deck and refuse the water film through self-crosslinking; Perhaps too low and cause adhesion little with the crosslinked degree of fiber, so the antifouling durability of waterproof is poor.The permeability of waterproof anti-fouling agent in fabric when the present invention is the antifouling processing of follow-up waterproof through pre-treatment process with the use corresponding adjuvants is greatly enhanced; Simultaneously when the antifouling processing of waterproof; Adopting corresponding multiple waterproof antifouling treatment agent and two to soak two roll process makes the waterproof antifouling treatment agent fully combine with lining; And be penetrated into fibrous inside, make waterproof antifouling more lasting.
Description of drawings
Fig. 1 is the pre-treatment process curve map.
The specific embodiment
Below in conjunction with the present invention being done further description through embodiment and accompanying drawing.
The processing method of the antifouling slubbing lining of permanent seal cooling nano water-proof: it includes successively to the pre-treatment of lining with nano water-proof anti-soil agent and crosslinking agent and bathes the waterproof soil resistant finish that pads together, and the characteristic of its treatment process is:
(1) pre-treatment:
Use following auxiliary agent:
ECO-9 finishing agent 15-25%owf (weight ratio of fabric and ECO-9 finishing agent)
NaHCO 3(every premium on currency contains 15-25g NaHCO to 15-25g/l 3)
Na 2SO 4(every premium on currency contains 10-20g Na to 10-20g/l 2SO 4)
Bath raio (weight ratio of fabric and water): 1: 10-1: 15
Through the rope dyeing machine pre-treatment, concrete treatment process is lining successively in above-mentioned auxiliary agent:
When 25 ℃ ± 3 ℃ of temperature; 12-18 minute → rope dyeing machine of rope dyeing machine running running 20-30 minute; Be warmed up to 70 ℃ ± 3 ℃, → insulation under 70 ℃ ± 3 ℃ environment, rope dyeing machine running 35-45 minute → wash 8-15 minute → draining with 40 ℃ ± 3 ℃ water temperatures;
Neutralisation treatment technology: the acetum of adding 1% neutralization in rope dyeing machine; bath raio (weight ratio of fabric and water): 1: 10-1: 15; heat 50 ℃ ± 3 ℃; lining turns round in rope dyeing machine, and 12-18 minute → draining → with 25 ℃ ± 3 ℃ flushing with clean water, 8-15 minute → draining → detection pH value is between 6-6.5;
Oven dry: the lining after will handling is dried under 90 ℃ of-110 ℃ of temperature;
Above-mentioned pre-treatment process curve map is as shown in Figure 1;
(2) waterproof soil resistant finish:
Waterproof antifouling treatment agent and consumption:
UEG-3 nano water-proof anti-soil agent: consumption is that every premium on currency contains 50-70g;
The J2 crosslinking agent: consumption is that every premium on currency contains 2.5-4.5g;
Propylene glycol: consumption is that every premium on currency contains 15-25g;
Nonionic penetrant is used in weaving: use the SP-2 bleeding agent, consumption is that every premium on currency contains 0-3.5g;
Pick-up; 70%--75%;
Waterproof soil resistant finish technology: lining is immersed in the above-mentioned mixed uniformly waterproof antifouling treatment agent of 25 ℃ of temperature; Through twice roll extrusion of twice immersion of water calender roll (two soak two rolls); Wherein the pressure of roll remains on 0.45-0.55MPa; The speed that lining advances roll be 6-8 rice/minute, lining gets into roll and will keep smooth during roll extrusion.Above-mentioned pick-up also is liquid carrying rate, be on the fabric with liquid weight and the percentage of the weight of fabric own.Be fabric through behind the solution on the stock tank band, through rolling rod roll on the cloth cover later with solution weight with pad before the percentage of original fabric weight.Two soak two rolls and refers to fabric and contaminate dye liquor after roll rolled, and repeats twice.Fabric was heavy before A padded; It is heavy that B pads the back fabric, pick-up=(B-A)/A*100%.As: fabric original weight 100 restrains, and after padding through twice, weighs 170 grams, and pick-up is 70%;
(3) bake by routine: preliminary drying: 80 ℃--90 ℃; Training baking: 175 ℃--180 ℃, the time: 1 minute;
(4) by becoming finished product after the arrangement after the routine with the antifouling slubbing lining of waterproof.
General finishing agent consumption is different and different according to the kind of handling lining, shown in according to the form below:
Figure BSA00000679931900041
Wherein the main component of ECO-9 finishing agent is many hydroxys amino-compound, and effect is the durability that increases the waterproof anti-fouling effect; The main component of UEG-3 nano water-proof anti-soil agent is a dihalo triazine cyclisation thing, and effect is to give the fabric waterproof anti-pollution function; J2 crosslinking agent main component is a fluoroalkyl acrylates resin, makes and obtains stable cross-linked structure between the molecular structure of each finishing agent and finishing agent.The effect of propylene glycol is the solubility that improves other waterproof antifouling treatment agents; Weaving improves the osmosis of waterproof anti-soil agent to fabric with nonionic penetrant; Simultaneously fabric is played wetting, emulsification; Above-mentioned ECO-9 finishing agent, UEG-3 nano water-proof anti-soil agent and J2 crosslinking agent are all on sale in market, are that Shanghai Mei Xue International Trading Company Ltd produces in the present embodiment; Propylene glycol, market is on sale at home with nonionic penetrant in weaving, like bleeding agent SP-2 etc.
According to the antifouling slubbing lining of the waterproof finished product that said method is handled, detect through Japanese woolen inspection association (Tianjin): the finished product waterproof reaches 5 grades, still can reach 4 grades after dry-cleaning 5 times; Finished product is antifouling to be 5 grades, after dry-cleaning 5 times, still can reach 4 grades, and each item index all is superior to Nippon Standard.In addition, finished product detects through national wool spinning product quality supervision and test centers (Shanghai): 5 grades of finished product waterproof reach 4 grades after dry-cleaning 5 times; Antifouling 5 grades of finished product reaches 3.5 grades after dry-cleaning 3 times.See from detecting data, be significantly increased than conventional method with its waterproof antifouling property of the product after the antifouling processing of said method waterproof.

Claims (1)

1. the processing method of the antifouling slubbing lining of permanent seal cooling nano water-proof, it include successively to the pre-treatment of lining and with nano water-proof anti-soil agent and crosslinking agent with bathing the waterproof soil resistant finish that pads, the characteristic of its treatment process is:
(1) pre-treatment:
Use following auxiliary agent:
ECO-9 finishing agent 15-25%owf
NaHCO 3 15-25g/l
Na 2SO 4 10-20g/l
Bath raio: 1: 10-1: 15
Through the rope dyeing machine pre-treatment, concrete treatment process is lining successively in above-mentioned auxiliary agent:
When 25 ℃ ± 3 ℃ of temperature; 12-18 minute → rope dyeing machine of rope dyeing machine running running 20-30 minute; Be warmed up to 70 ℃ ± 3 ℃, → insulation under 70 ℃ ± 3 ℃ environment, rope dyeing machine running 35-45 minute → wash 8-15 minute → draining with 40 ℃ ± 3 ℃ water temperatures;
Neutralisation treatment technology: the acetum of adding 1% neutralization in rope dyeing machine; bath raio: 1: 10-1: 15; heat 50 ℃ ± 3 ℃; lining turns round in rope dyeing machine, and 12-18 minute → draining → with 25 ℃ ± 3 ℃ flushing with clean water, 8-15 minute → draining → detection pH value is between 6-6.5;
Oven dry: the lining after will handling is dried under 90 ℃ of-110 ℃ of temperature;
(2) waterproof soil resistant finish:
Waterproof antifouling treatment agent and consumption:
UEG-3 nano water-proof anti-soil agent: consumption is that every premium on currency contains 50-70g;
The J2 crosslinking agent: consumption is that every premium on currency contains 2.5-4.5g;
Propylene glycol: consumption is that every premium on currency contains 15-25g;
Nonionic penetrant is used in weaving: consumption is that every premium on currency contains 0-3.5g;
Pick-up; 70%--75%;
Waterproof soil resistant finish technology: lining is immersed in the above-mentioned mixed uniformly waterproof antifouling treatment agent of 25 ℃ of temperature; Through twice roll extrusion of twice immersion of water calender roll; Wherein the pressure of roll remains on 0.45-0.55MPa; The speed that lining advances roll be 6-8 rice/minute, lining gets into roll and will keep smooth during roll extrusion;
(3) bake by routine: preliminary drying: 80 ℃--90 ℃; Training baking: 175 ℃--180 ℃, the time: 1 minute;
(4) by becoming finished product after the arrangement after the routine with the antifouling slubbing lining of waterproof.
CN 201210056926 2012-03-05 2012-03-05 Processing method of durable nano water-and-stain-proofing woolen fabric Active CN102587130B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102965817A (en) * 2012-11-26 2013-03-13 江苏申利实业股份有限公司 Waterproof monomer-resisting fabric and production method thereof
CN110409183A (en) * 2019-08-31 2019-11-05 三赢家居用品(河源)有限公司 A kind of free-floride water-proof aagent and its methods for making and using same
CN110565379A (en) * 2019-09-04 2019-12-13 世联汽车内饰(苏州)有限公司 Healthy antifouling automobile fabric and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101122082A (en) * 2007-09-18 2008-02-13 南通港联纺织有限公司 Antifouling, water-proof and non-ironing post finishing method for woven plus material
CN101709545A (en) * 2009-12-15 2010-05-19 宁波艾利特服饰有限公司 Finishing method for textile fabrics
CN102051824A (en) * 2009-10-28 2011-05-11 山东魏桥创业集团有限公司 Method for preparing water, oil and stain repellent and easy-to-clean household fabric

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101122082A (en) * 2007-09-18 2008-02-13 南通港联纺织有限公司 Antifouling, water-proof and non-ironing post finishing method for woven plus material
CN102051824A (en) * 2009-10-28 2011-05-11 山东魏桥创业集团有限公司 Method for preparing water, oil and stain repellent and easy-to-clean household fabric
CN101709545A (en) * 2009-12-15 2010-05-19 宁波艾利特服饰有限公司 Finishing method for textile fabrics

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102965817A (en) * 2012-11-26 2013-03-13 江苏申利实业股份有限公司 Waterproof monomer-resisting fabric and production method thereof
CN110409183A (en) * 2019-08-31 2019-11-05 三赢家居用品(河源)有限公司 A kind of free-floride water-proof aagent and its methods for making and using same
CN110565379A (en) * 2019-09-04 2019-12-13 世联汽车内饰(苏州)有限公司 Healthy antifouling automobile fabric and preparation method thereof

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Effective date of registration: 20211227

Address after: 276200 No. 16, Wenhe Third Road, Mengyin County, Linyi City, Shandong Province

Patentee after: Shandong Shenzhou Wool Textile Co.,Ltd.

Address before: 314100 No. 66, Chengxi Avenue, Luoxing street, Jiashan County, Zhejiang Province

Patentee before: Zhejiang Shenzhou Woollen Textile Co.,Ltd.

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Effective date of registration: 20240520

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Patentee after: Shandong Huaao Textile Technology Co.,Ltd.

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Address before: 276200 No. 16, Wenhe Third Road, Mengyin County, Linyi City, Shandong Province

Patentee before: Shandong Shenzhou Wool Textile Co.,Ltd.

Country or region before: China