CN102550559A - Dibromocyanoacetamide (C2H2ON2Br2) disinfection tablet and preparation method thereof - Google Patents
Dibromocyanoacetamide (C2H2ON2Br2) disinfection tablet and preparation method thereof Download PDFInfo
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- CN102550559A CN102550559A CN2011104318895A CN201110431889A CN102550559A CN 102550559 A CN102550559 A CN 102550559A CN 2011104318895 A CN2011104318895 A CN 2011104318895A CN 201110431889 A CN201110431889 A CN 201110431889A CN 102550559 A CN102550559 A CN 102550559A
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- dibromocyanoacetamide
- dibromo
- tablet
- disinfection tablet
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 29
- UUIVKBHZENILKB-UHFFFAOYSA-N 2,2-dibromo-2-cyanoacetamide Chemical compound NC(=O)C(Br)(Br)C#N UUIVKBHZENILKB-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 28
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 10
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 8
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 8
- 238000012360 testing method Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract 2
- 230000001954 sterilising effect Effects 0.000 claims description 22
- 239000011734 sodium Substances 0.000 claims description 9
- MBEDDIHHCDUVJV-UHFFFAOYSA-N 2,2-dibromo-2-chloroacetamide Chemical compound NC(=O)C(Cl)(Br)Br MBEDDIHHCDUVJV-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- CFAJUDFVLRFQLK-UHFFFAOYSA-N n,n-dibromo-2-cyanoacetamide Chemical class BrN(Br)C(=O)CC#N CFAJUDFVLRFQLK-UHFFFAOYSA-N 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000005070 sampling Methods 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 13
- 239000000460 chlorine Substances 0.000 abstract description 13
- 229910052801 chlorine Inorganic materials 0.000 abstract description 13
- 235000017550 sodium carbonate Nutrition 0.000 abstract description 11
- 239000004744 fabric Substances 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 239000004299 sodium benzoate Substances 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract 3
- 239000002994 raw material Substances 0.000 abstract 3
- 238000004061 bleaching Methods 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- KEAYESYHFKHZAL-BJUDXGSMSA-N sodium-22 Chemical group [22Na] KEAYESYHFKHZAL-BJUDXGSMSA-N 0.000 abstract 1
- 239000012856 weighed raw material Substances 0.000 abstract 1
- 239000000645 desinfectant Substances 0.000 description 6
- 230000000249 desinfective effect Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- DGJMPUGMZIKDRO-UHFFFAOYSA-N cyanoacetamide Chemical compound NC(=O)CC#N DGJMPUGMZIKDRO-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000000149 penetrating effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- -1 benzoic sodium salt Chemical class 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000019249 food preservative Nutrition 0.000 description 2
- 239000005452 food preservative Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- 239000007785 strong electrolyte Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 210000004666 bacterial spore Anatomy 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 229910001504 inorganic chloride Inorganic materials 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 150000004045 organic chlorine compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229950009390 symclosene Drugs 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a dibromocyanoacetamide (C2H2ON2Br2) disinfection tablet and a preparation method thereof. The dibromocyanoacetamide disinfection tablet is prepared from the following raw materials in parts by weight: 50 parts of C2H2ON2Br2, 20 parts of sodium carbonate (Na2CO3), 8 parts of sodium benzoate and 22 parts of CMC (Carboxy Methylated Cellulose). The preparation method comprises the following steps of: adding weighed raw materials into a blending machine, blending for 1 hour at normal temperature, taking a sample so as to measure the content of effective bromine, stopping blending after the content of the effective bromine reaches 50+/-5wt%, pressure-testing some finished products, placing in cold water and observing effervescence time, sending the blended raw materials to a tablet making room for making the tablet after the blended raw materials reach the standard, and packaging to obtain the finished product of the dibromocyanoacetamide disinfection tablet. The preparation method is simple in process; and the prepared dibromocyanoacetamide disinfection tablet is a novel efficient disinfection tablet following a chlorine disinfection tablet; and by utilizing the dibromocyanoacetamide disinfection tablet, the problems of pungent smell and corrosion to metal of the chlorine disinfection tablet are solved, and bleaching properties to fabrics are reduced.
Description
Technical field
The present invention relates to a kind of dibromo cyanoacetamide sterilization sheet and preparation method thereof.
Background technology
Chlorine-containing disinfectant is meant that water-soluble generation has the hypochlorous disinfectant of microbiocidal activity, and its microbicidel active ingredient is often represented with available chlorine.The hypochlorous acid molecular weight is little, is prone to be diffused into bacterium surface and permeates cell membranes and gets in the thalline, makes the mycoprotein oxidation cause bacterial death.Chlorine-containing disinfectant can be killed various microorganisms, comprises bacterial propagule, virus, fungi, tubercle bacillus and the strongest bacterial spore of drag.This type disinfectant comprises inorganic chloride (like clorox, calcium hypochlorite, Efficacious Disinfeitant), organochlorine compound (like sodium dichloro cyanurate, sym-closene, oronain T etc.).Inorganic chlorine character is unstable, is subject to light, heat and moist influence, loses its active ingredient, and organochlorine is then relatively stable, but all unstable after water-soluble.
Chlorine-containing disinfectant is the high effect disinfectants that medical industry is used, and it is high with sterilizing rate, sterilizing time is short, fungicidal spectrum extensively is celebrated.But its shortcoming is penetrating odor, corroding metal to be arranged, fabric is had discoloration, and these shortcomings make its application receive environmental limitations.
Summary of the invention
The technical issues that need to address of the present invention just are to overcome the defective of prior art; A kind of dibromo cyanoacetamide sterilization sheet and preparation method thereof is provided; Technology of the present invention is simple; The dibromo cyanoacetamide sterilization sheet of producing is the new and effective sterilization sheet after the chlorine-containing disinfecting sheet, and it has solved the penetrating odor of chlorine-containing disinfecting sheet and to corrosion of metal, has reduced the bleachability to fabric.
For addressing the above problem, the present invention adopts following technical scheme:
The invention provides a kind of dibromo cyanoacetamide sterilization sheet, said sterilization sheet is the sterilization sheet that is formed by the feedstock production that following weight portion is equipped with:
Dibromo chloroacetamide C
2H
2ON
2Br
250 parts; Sodium carbonate Na
2CO
320 parts; 8 parts of Sodium Benzoates and CMC22 part.
The present invention provides a kind of described dibromo cyanoacetamide sterilization piece preparation method simultaneously:
With dibromo chloroacetamide C
2H
2ON
2Br
250 parts; Sodium carbonate Na
2CO
320 parts; 8 parts of Sodium Benzoates and CMC22 part have been measured the back and have been added in the compounder, after normal temperature was mixed 1 hour; The content of effective bromine is surveyed in sampling, after effectively bromine content reaches weight concentration and is 50% ± 5%, stops to be mixed; Several finished products of pressure testing are put into cold water and are observed the effervesce time, under 25 ℃ of conditions of room temperature; Two dibromo cyanoacetamides sterilization sheets are put into 1000ml running water 10min effervesce and are finished, will mix confected materials after up to standard and deliver to and carry out film-making between film-making, packing both finished product.
Among the present invention, dibromo cyanoacetamide (DBNPA) is a kind of novel potent Biocidal algae-killing agent and water treatment agent.The best approach of synthesizing it is at H
2O
2Effect under, make Br
2With cyanoacetamide (CAA) solution reflux, can prepare the dibromo cyanoacetamide of high yield.
Sodium carbonate, popular name soda, soda ash, washing soda, chemical formula: Na
2CO
3, under the general case white powder, be strong electrolyte.Density is 2.532g/cm
3, fusing point is 851 ℃, and is soluble in water, has the general character of salt.
Sodium Benzoate (chemical formula: C
6H
5CO
2Na), be benzoic sodium salt.Sodium Benzoate is the food preservative that is in daily use, and has to prevent the rotten effect of turning sour, extending the shelf life, and all is widely used in countries in the world.
CMC is the abbreviation of sodium carboxymethylcellulose, be native cellulose through the product that modification forms, be widely used.
Technology of the present invention is simple, and the dibromo cyanoacetamide sterilization sheet of production is the new and effective sterilization sheet after the chlorine-containing disinfecting sheet, and it has solved the penetrating odor of chlorine-containing disinfecting sheet and to corrosion of metal, has reduced the bleachability to fabric.
Embodiment
With dibromo chloroacetamide C
2H
2ON
2Br
250 parts; Sodium carbonate Na
2CO
320 parts; 8 parts of Sodium Benzoates and CMC22 part have been measured the back and have been added in the compounder, after normal temperature was mixed 1 hour; The content of effective bromine is surveyed in sampling, after effectively bromine content reaches weight concentration and is 50% ± 5%, stops to be mixed; Several finished products of pressure testing are put into cold water and are observed the effervesce time, under 25 ℃ of conditions of room temperature; Two dibromo cyanoacetamides sterilization sheets are put into 1000ml running water 10min effervesce and are finished, will mix confected materials after up to standard and deliver to and carry out film-making between film-making, packing both finished product.
Among the present invention, dibromo cyanoacetamide (DBNPA) is a kind of novel potent Biocidal algae-killing agent and water treatment agent.The best approach of synthesizing it is at H
2O
2Effect under, make Br
2With cyanoacetamide (CAA) solution reflux, can prepare the dibromo cyanoacetamide of high yield.
Sodium carbonate, popular name soda, soda ash, washing soda, chemical formula: Na
2CO
3, under the general case white powder, be strong electrolyte.Density is 2.532g/cm
3, fusing point is 851 ℃, and is soluble in water, has the general character of salt.
Sodium Benzoate (chemical formula: C
6H
5CO
2Na), be benzoic sodium salt.Sodium Benzoate is the food preservative that is in daily use, and has to prevent the rotten effect of turning sour, extending the shelf life, and all is widely used in countries in the world.
CMC is the abbreviation of sodium carboxymethylcellulose, be native cellulose through the product that modification forms, be widely used.
Technology of the present invention is simple, and the dibromo cyanoacetamide sterilization sheet of production is the new and effective sterilization sheet after the chlorine-containing disinfecting sheet, and it has solved the penetrating odor of chlorine-containing disinfecting sheet and to corrosion of metal, has reduced the bleachability to fabric.
What should explain at last is: obviously, the foregoing description only be for clearly the present invention is described and is done for example, and be not qualification to embodiment.For the those of ordinary skill in affiliated field, can also make other multi-form variation or change on the basis of the above description.Here need not also can't give exhaustive to all embodiments.And conspicuous variation of being amplified out thus or change still are among protection scope of the present invention.
Claims (2)
1. dibromo cyanoacetamide sterilization sheet, it is characterized in that: said sterilization sheet is the sterilization sheet that is formed by the feedstock production that following weight portion is equipped with:
Dibromo chloroacetamide C
2H
2ON
2Br
250 parts; Sodium carbonate Na
2CO
320 parts; 8 parts of Sodium Benzoates and CMC22 part.
2. dibromo cyanoacetamide as claimed in claim 1 sterilization piece preparation method is characterized in that said method is:
With dibromo cyanoacetamide C
2H
2ON
2Br
250 parts; Sodium carbonate Na
2CO
320 parts; 8 parts of Sodium Benzoates and CMC22 part have been measured the back and have been added in the compounder, after normal temperature was mixed 1 hour; The content of effective bromine is surveyed in sampling, after effectively bromine content reaches weight concentration and is 50% ± 5%, stops to be mixed; Several finished products of pressure testing are put into cold water and are observed the effervesce time, under 25 ℃ of conditions of room temperature; Two dibromo cyanoacetamides sterilization sheets are put into 1000ml running water 10min effervesce and are finished, will mix confected materials after up to standard and deliver to and carry out film-making between film-making, packing both finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104318895A CN102550559A (en) | 2011-12-21 | 2011-12-21 | Dibromocyanoacetamide (C2H2ON2Br2) disinfection tablet and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104318895A CN102550559A (en) | 2011-12-21 | 2011-12-21 | Dibromocyanoacetamide (C2H2ON2Br2) disinfection tablet and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102550559A true CN102550559A (en) | 2012-07-11 |
Family
ID=46398213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104318895A Pending CN102550559A (en) | 2011-12-21 | 2011-12-21 | Dibromocyanoacetamide (C2H2ON2Br2) disinfection tablet and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102550559A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4800082A (en) * | 1987-03-23 | 1989-01-24 | The Dow Chemical Company | Sustained release microbiological control composition |
| EP0953284A1 (en) * | 1998-04-24 | 1999-11-03 | Clearwater, Inc. | Biocide with accelerated dissolution |
| CN1650708A (en) * | 2004-02-04 | 2005-08-10 | 昆山鼎惠精细化工有限公司 | Disinfectant composition containing 2,2-dibromo-tricyano propanamide |
-
2011
- 2011-12-21 CN CN2011104318895A patent/CN102550559A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4800082A (en) * | 1987-03-23 | 1989-01-24 | The Dow Chemical Company | Sustained release microbiological control composition |
| EP0953284A1 (en) * | 1998-04-24 | 1999-11-03 | Clearwater, Inc. | Biocide with accelerated dissolution |
| CN1650708A (en) * | 2004-02-04 | 2005-08-10 | 昆山鼎惠精细化工有限公司 | Disinfectant composition containing 2,2-dibromo-tricyano propanamide |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SUN HANYUE Free format text: FORMER OWNER: XINJIANG LANLI JIEKANG BIOTECHNOLOGY CO., LTD. Effective date: 20120924 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20120924 Address after: The dawn of the 830000 the Xinjiang Uygur Autonomous Region Urumqi ironworks in Midong District Town Village Applicant after: Sun Hanyue Address before: The dawn of the 830000 the Xinjiang Uygur Autonomous Region Urumqi ironworks in Midong District Town Village Applicant before: Xinjiang Lanli Jiekang Biotechnology Co.,Ltd. |
|
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120711 |