CN102531340A - Preparation method of light pink crystal bead embryo - Google Patents
Preparation method of light pink crystal bead embryo Download PDFInfo
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- CN102531340A CN102531340A CN2011104019501A CN201110401950A CN102531340A CN 102531340 A CN102531340 A CN 102531340A CN 2011104019501 A CN2011104019501 A CN 2011104019501A CN 201110401950 A CN201110401950 A CN 201110401950A CN 102531340 A CN102531340 A CN 102531340A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
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Abstract
The invention relates to a preparation method of light pink crystal bead embryo. Aiming at the defects that the existing process for preparing light pink crystal bead embryo is poor in coloring repeatability, instable in product quality, low in production efficiency, and is not suitable for continuous tank kiln production operation, the invention provides a preparation method of the light pink crystal bead embryo, which is good in coloring repeatability, stable in product quality, high in production efficiency, and is suitable for continuous tank kiln production operation. In the preparation method of the light pink crystal bead embryo, the light pink crystal bead embryo is prepared from the following raw materials according to a weight ratio: 50-70 parts of quartz sand, 5-15 parts of sodium carbonate, 4-16 parts of potassium carbonate, 2-9 parts of potassium nitrate, 2-5 parts of boric acid, not more than 50-70 parts of lead silicate, not more than 3 parts of antimony trioxide, not more than 7 parts of barium carbonate, not more than 5 parts of titanium pigment, not more than 3 parts of zinc oxide and not more than 8-20 parts of erbium oxide.
Description
Technical field
The present invention relates to the artificial crystal production field, particularly a kind of preparation method of lightpink crystal pearl embryo.
Background technology
Lightpink crystal pearl embryo is the work in-process that are used for preparing the quartzy product of lightpink; Be to adopt erbium ion painted in the existing preparation lightpink crystal pearl embryo technology; Erbium ion is provided by erbium oxide, adopt product ubiquity that existing preparation lightpink crystal pearl embryo explained hereafter goes out color reproduction poor, unstable product quality; Production efficiency is low, is not suitable for the weak point of the production operation of continuous tank furnace.In addition, in existing preparation lightpink crystal pearl embryo technology, the red lead component is arranged in the composition of raw materials of lightpink crystal pearl embryo, red lead is volatile, can cause environmental pollution.
Summary of the invention
It is poor to the objective of the invention is to existing above-mentioned the color reproduction of existing preparation lightpink crystal pearl embryo technology; Unstable product quality, production efficiency is low, is not suitable for the weak point of the production operation of continuous tank furnace; Provide a kind of color reproduction good; Constant product quality, production efficiency is high, can be fit to the preparation method of lightpink crystal pearl embryo of the production operation of continuous tank furnace.
The technical scheme that the present invention adopted is accomplished through following mode: a kind of preparation method of lightpink crystal pearl embryo, the weight proportion of this lightpink crystal pearl embryo raw material is: 50～70 parts of silica sands, 5～15 parts of soda ash, 4～16 parts in salt of wormwood, 2～9 parts in saltpetre, 2～5 parts of boric acid, lead silicate≤50-70 part, Antimony Trioxide: 99.5Min≤3 part, barium carbonate≤7 part, white titanium pigment≤5 part, zinc oxide≤3 part, Erbium trioxide≤8-20 part.
In the preparation method of above-mentioned lightpink crystal pearl embryo, the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, keep oxidizing atmosphere and glass quartz liquation liquid level stabilizing when founding;
(4) the glass quartz liquation is molded into light pink water after the homogenizing cooling and bores the pearl embryo.
In the preparation method of above-mentioned lightpink crystal pearl embryo, in the preparation process (3) of lightpink crystal pearl embryo, temperature is controlled at 1300 ℃～1500 ℃ when founding.
In the preparation method of above-mentioned lightpink crystal pearl embryo, in the preparation process (4) of lightpink crystal pearl embryo, cooling temperature is controlled at 550 ℃～1030 ℃, and is preferred: 750 ℃～900 ℃.
The preparation method of lightpink crystal pearl embryo of the present invention compares with existing preparation lightpink crystal pearl embryo technology, has following characteristics:
1, adopts lightpink crystal pearl embryo composition of raw materials of the present invention, make the redox equilibrium of cupric ion in the process of founding keep stable, thereby obtain to have the lightpink of well reproduced property.
2, the preparation method of lightpink crystal pearl embryo of the present invention has reduced plumbous content in the crystal pearl embryo, adopts the Na-K-B-Si-Pb system to reach the optical property requirement of high refractive index.
3, in lightpink crystal pearl embryo composition of raw materials of the present invention, replace red lead with lead silicate, lead silicate is more stable, and is not volatile, has environment protection significance.
4, the present invention can carry out the continuous working kiln production operation, has improved efficient and production capacity.
Embodiment
Through embodiment the present invention is made further below and specifying.
Embodiment 1
A kind of preparation method of lightpink crystal pearl embryo, the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes; Wherein, the composition of raw materials of lightpink crystal pearl embryo (weight ratio) is: 50 parts of silica sands, 5 parts of soda ash, 5 parts in salt of wormwood, 2 parts in saltpetre, 2 parts of boric acid, 50 parts in lead silicate, 3 parts of Antimony Trioxide: 99.5Mins, 4 parts of barium carbonates, 2 parts of white titanium pigments, 1 part in zinc oxide, 15 parts of Erbium trioxides;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 550 ℃～1030 ℃, be molded into light pink water and bore the pearl embryo.
Embodiment 2
A kind of preparation method of lightpink crystal pearl embryo, the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes; Wherein, the composition of raw materials of lightpink crystal pearl embryo (weight ratio) is: 70 parts of silica sands, 15 parts of soda ash, 14 parts in salt of wormwood, 8 parts in saltpetre, 5 parts of boric acid, 65 parts in lead silicate, 3 parts of Antimony Trioxide: 99.5Mins, 5 parts of barium carbonates, 5 parts of white titanium pigments, 3 parts in zinc oxide, 20 parts of Erbium trioxides;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 550 ℃～1030 ℃, be molded into light pink water and bore the pearl embryo.
Embodiment 3
A kind of preparation method of lightpink crystal pearl embryo, the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes; Wherein, the composition of raw materials of lightpink crystal pearl embryo (weight ratio) is: 60 parts of silica sands, 80 parts of soda ash, 9 parts in salt of wormwood, 6 parts in saltpetre, 3 parts of boric acid, 55 parts in lead silicate, 2 parts of Antimony Trioxide: 99.5Mins, 2 parts of barium carbonates, 3 parts of white titanium pigments, 1 part in zinc oxide, 15 parts of Erbium trioxides;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into light pink water and bore the pearl embryo.
Embodiment 4
A kind of preparation method of lightpink crystal pearl embryo, the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes; Wherein, the composition of raw materials of lightpink crystal pearl embryo (weight ratio) is: 55 parts of silica sands, 7 parts of soda ash, 8 parts in salt of wormwood, 9 parts in saltpetre, 4 parts of boric acid, 3 parts of Antimony Trioxide: 99.5Mins, 14 parts in lead silicate, 5 parts of barium carbonates, 5 parts of white titanium pigments, 3 parts in zinc oxide, 8 parts of Erbium trioxides;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into light pink water and bore the pearl embryo.
Embodiment 5
A kind of preparation method of lightpink crystal pearl embryo, the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes; Wherein, the composition of raw materials of lightpink crystal pearl embryo (weight ratio) is: 65 parts of silica sands, 13 parts of soda ash, 4 parts in salt of wormwood, 7 parts in saltpetre, 3 parts of boric acid, lead silicate≤58 part, Antimony Trioxide: 99.5Min≤3 part, white titanium pigment≤5 part, zinc oxide≤3 part, Erbium trioxide≤17 part;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into light pink water and bore the pearl embryo.
Embodiment 6
A kind of preparation method of lightpink crystal pearl embryo, the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes; Wherein, the composition of raw materials of lightpink crystal pearl embryo (weight ratio) is: 57 parts of silica sands, 8 parts of soda ash, 16 parts in salt of wormwood, 3 parts in saltpetre, 4 parts of boric acid, 63 parts in lead silicate, 3 parts of Antimony Trioxide: 99.5Mins, 0.2 part in zinc oxide, 0.5 part of barium carbonate, 3 parts of white titanium pigments, 0.2 part of Erbium trioxide;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into light pink water and bore the pearl embryo.
Embodiment 7
A kind of preparation method of lightpink crystal pearl embryo, the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes; Wherein, the composition of raw materials of lightpink crystal pearl embryo (weight ratio) is: 68 parts of silica sands, 12 parts of soda ash, 9 parts in salt of wormwood, 4 parts in saltpetre, 5 parts of boric acid, 52 parts in lead silicate, 1 part of Antimony Trioxide: 99.5Min, 5 parts of barium carbonates, 3 parts in zinc oxide, Erbium trioxide≤13 part;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into light pink water and bore the pearl embryo.
Embodiment 8
A kind of preparation method of lightpink crystal pearl embryo, the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes; Wherein, the composition of raw materials of lightpink crystal pearl embryo (weight ratio) is: 62 parts of silica sands, 9 parts of soda ash, 10 parts in salt of wormwood, 5 parts in saltpetre, 2 parts of boric acid, 58 parts in lead silicate, 2 parts of Antimony Trioxide: 99.5Mins, 4 parts of barium carbonates, 3 parts of white titanium pigments, 2 parts in zinc oxide, 17 parts of Erbium trioxides;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into lightpink crystal pearl embryo.
Claims (5)
1. the preparation method of a lightpink crystal pearl embryo is characterized in that the weight proportion of this lightpink crystal pearl embryo raw material is: 50～70 parts of silica sands, 5～15 parts of soda ash, 4～16 parts in salt of wormwood, 2～9 parts in saltpetre, 2～5 parts of boric acid, lead silicate≤50-70 part, Antimony Trioxide: 99.5Min≤3 part, barium carbonate≤7 part, white titanium pigment≤5 part, zinc oxide≤3 part, Erbium trioxide≤8-20 part.
2. the preparation method of lightpink crystal pearl embryo according to claim 1 is characterized in that the preparation method of lightpink crystal pearl embryo may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of lightpink crystal pearl embryo mixes;
(2) the lightpink crystal pearl embryo raw material that mixes is carried out granulation through tablets press;
(3) will process granular lightpink crystal pearl embryo raw material and put into the glass quartz tank furnace and found, keep oxidizing atmosphere and glass quartz liquation liquid level stabilizing when founding;
(4) the glass quartz liquation is molded into light pink water after the homogenizing cooling and bores the pearl embryo.
3. the preparation method of lightpink crystal pearl embryo according to claim 2 is characterized in that in the preparation process (3) of lightpink crystal pearl embryo, temperature is controlled at 1300 ℃～1500 ℃ when founding.
4. the preparation method of lightpink crystal pearl embryo according to claim 2 is characterized in that in the preparation process (4) of lightpink crystal pearl embryo, cooling temperature is controlled at 550 ℃～1030 ℃.
5. the preparation method of lightpink crystal pearl embryo according to claim 4 is characterized in that in the preparation process (4) of lightpink crystal pearl embryo, cooling temperature is controlled at 750 ℃～900 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011104019501A CN102531340A (en) | 2011-12-07 | 2011-12-07 | Preparation method of light pink crystal bead embryo |
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| CN2011104019501A CN102531340A (en) | 2011-12-07 | 2011-12-07 | Preparation method of light pink crystal bead embryo |
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| CN102531340A true CN102531340A (en) | 2012-07-04 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104556696A (en) * | 2015-01-06 | 2015-04-29 | 浙江伟兴水晶有限公司 | Pink crystal bead embryo and preparation method thereof |
| CN109761502A (en) * | 2019-03-27 | 2019-05-17 | 广东蓝碟羽水晶饰品有限公司 | A kind of manufacturing method of rare earth tinted clear grey crystal pearl base |
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2011
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| US5656559A (en) * | 1994-06-23 | 1997-08-12 | Saint-Gobain Vitrage | Clear glass composition intended for the production of panes |
| CN101186437A (en) * | 2006-11-17 | 2008-05-28 | 山东省药用玻璃股份有限公司 | Neutral boron silicate glass used for medicinal mold-formed bottle and manufacturing method thereof |
| JP2010083721A (en) * | 2008-09-30 | 2010-04-15 | Reiseki:Kk | Method for storing granulate or powdery object to be stored |
| CN101857355A (en) * | 2010-06-02 | 2010-10-13 | 天台精工西力玻璃珠有限公司 | Method for producing glass beads used for curing high-level nuclear wastes |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104556696A (en) * | 2015-01-06 | 2015-04-29 | 浙江伟兴水晶有限公司 | Pink crystal bead embryo and preparation method thereof |
| CN104556696B (en) * | 2015-01-06 | 2016-03-23 | 浙江伟兴水晶有限公司 | A kind of rosy quartz pearl embryo and preparation method thereof |
| CN109761502A (en) * | 2019-03-27 | 2019-05-17 | 广东蓝碟羽水晶饰品有限公司 | A kind of manufacturing method of rare earth tinted clear grey crystal pearl base |
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Application publication date: 20120704 |