CN102515939B - Method for converting heavy metal-enriched plant into miscellaneous fertilizer containing biological carbon special for mine vegetation recovery - Google Patents
Method for converting heavy metal-enriched plant into miscellaneous fertilizer containing biological carbon special for mine vegetation recovery Download PDFInfo
- Publication number
- CN102515939B CN102515939B CN2011103812021A CN201110381202A CN102515939B CN 102515939 B CN102515939 B CN 102515939B CN 2011103812021 A CN2011103812021 A CN 2011103812021A CN 201110381202 A CN201110381202 A CN 201110381202A CN 102515939 B CN102515939 B CN 102515939B
- Authority
- CN
- China
- Prior art keywords
- heavy metal
- soil
- bamboo
- plant
- mine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
Landscapes
- Processing Of Solid Wastes (AREA)
Abstract
The invention relates to a method for converting a heavy metal-enriched plant into a miscellaneous fertilizer containing biological carbon special for mine vegetation recovery, which comprises the following steps of: (1) collecting and drying a straw; (2) collecting a bamboo branch and a bamboo pole, cutting the bamboo pole into a bamboo tube and drying the bamboo branch and the bamboo tube; (3) collecting and drying the heavy metal-enriched plant growing in a mine pollution area; (4) selecting soil on which weeds are grown, shoveling and digging the weeds together with the soil, preparing a blocky turf with soil, and drying; and (5) selecting a patch, bedding the straw and the bamboo branch, covering the bamboo tube on the straw and the bamboo branch, covering the heavy metal-enriched plant on the bamboo tube to pile into a woodpile, covering the turf with the soil on the woodpile, exposing the lower part of the woodpile, igniting the woodpile from the lower part, slowly burning, collecting burned soil and biological carbon after the extinguishment of fire and sieving to prepare the miscellaneous fertilizer containing the biological carbon. The method has the beneficial effects that the heavy metal-enriched plant growing in the mine area is utilized for burning the miscellaneous fertilizer, and the miscellaneous fertilizer is then utilized for improving a mine pollution matrix and promoting the growth of the plant, so that the safe recycling of a phytoremediation harvested product is realized.
Description
Technical field
The present invention relates to the environmental pollution control field, particularly relating to a kind of is the method that contains the charcoal farmyard manure of recovering plant cover of mine special use with the enriching heavy metal Plant Transformation.
Background technology
The conventional repair techniques of administering heavy metal contamination mainly comprises engineering, physical technique, chemical technology and physical chemistry technology etc.There is the expense height in conventional repair techniques, can causes Soil structure to destroy and the limitations such as fertility is impaired, secondary pollution.The phytoremediation of heavy metal contamination is to utilize the plant reduction, purify the heavy metal in the soil or reduce heavy metal toxicity and minimizing heavy metal transport property.It is few, effective, easy to operate and be applicable to the advantages such as large area repair that phytoremediation technology possesses expense, can produce good ecology and social benefit.Adopt phytoremediation technology to administer in the heavy metal pollution of soil process, plant can the enriched heavy metal.The safe handling of enriching heavy metal plant and utilization are the important steps that achieve effective control is polluted.
The heavy metal pollution of mine phytoremediation relates generally to plant extract and plant is fixed two aspects.Plant extract is repaired: plant absorbs pollutent from environment, and the transhipment pollutent divides to plant shoot, and the harvesting plant shoot divides environment purification.Plant fixed and repaired: utilize Revegetation and base material improvement, come passivation and fixed-contamination thing by absorption and sorption, accumulation and precipitation, reduce the pollutent biological effectiveness and move moving property, resistance control Pollutants Diffusion.The mine degenerate region is seriously polluted, and the total amount of pollutant is large, and it is dark to distribute, and it is long to adopt the plant extract recovery technique to purify the required cycle of heavy metal-polluted soil, is difficult in practice carry out.Adopt in a short time restore vegetation of plant fixed and repaired technology, stablize the Mine ecology system, reduce soil erosion, effectively resistance control heavy metal diffusion, therefore, adopting plant fixed and repaired technology prevention and control mine pollution is optimal selection.
Mine degenerate region matrix heavy metal content is high, and nutrition is poor, and a little less than the retention ability, most plants are difficult to settle down growth.In mine degenerate region restore vegetation, need improvement matrix, increase fertility and retention ability, reduce the biological effectiveness of heavy metal, Promoting plant growth.
Charcoal is a class height aromatize insoluble solids.Charcoal belongs to a type of black carbon.Charcoal, bamboo charcoal, straw carbon and rice hull carbon etc. are common charcoals.The height aromatize structure of charcoal makes it have higher biological chemistry and thermostability than other any type of organic carbon, but prolonged preservation is in environment and ancient settling and be difficult for by mineralising.Charcoal has that hole prosperity, specific surface area are large, there are the characteristics such as a large amount of negative charges and electric density height on the surface, and these characteristics make charcoal have very strong adsorptive power.Charcoal can increase soil pH value, soil nutrient is had certain constraint and holds give over to usefulness, reduces soil nutrient leaching and loss, increase the silty loam retention ability and reduce the soil erosion, absorption is heavy metal fixedly, reduces the toxicity of contaminated soil, promotes plant and microorganism growth.
For the safe handling of enriching heavy metal plant in the phytoremediation process with utilize problem, be the farmyard manure that contains charcoal with the Plant Transformation of enriching heavy metal, add farmyard manure to the mill tailings district, improvement matrix, Promoting plant growth and Revegetation reduce the diffusion of soil erosion and heavy metal.
Summary of the invention
The purpose of this invention is to provide a kind of is the method that contains the charcoal farmyard manure that is exclusively used in recovering plant cover of mine with the enriching heavy metal Plant Transformation.Utilize the enriching heavy metal plant production that produces in the phytoremediation process to contain the charcoal farmyard manure, with farmyard manure improvement mine pollution matrix, promote Revegetation again, realize the safe utilization of Pollution Plant.
Technical scheme of the present invention: a kind of is the method that contains the charcoal farmyard manure of recovering plant cover of mine special use with the enriching heavy metal Plant Transformation, may further comprise the steps:
(1) collects straw, dry;
(2) collect bamboo branch and bamboo bar, the bamboo bar is cut into thick bamboo tube, dry bamboo branch and thick bamboo tube;
(3) collect the enriching heavy metal plant that grows in the mine pollution district, dry;
(4) soil of the long weeds of selection is with soil to shovel together weeds and is dug, and makes lump zone soil turf, dries;
(5) select a small area of ground, place mat straw and bamboo branch cover thick bamboo tube on straw and the bamboo branch, cover the enriching heavy metal plant on the thick bamboo tube, build up rick with this, cover tape soil turf on the rick, the rick bottom is exposed, lights rick from the bottom, smoulder, fire extinguishes rear collection, and these burn soil and charcoal, sieve, and make to contain the charcoal farmyard manure.
Described enriching heavy metal plant be dyers' grapes (
Phytolacca americana), black nightshade (
Solanum nigrum) and Pinnate Beggarticks (
Bidens maximowicziana) in one or more.
Principle is: the plants such as dyers' grapes, black nightshade and Pinnate Beggarticks of mine pollution district growth, and can enriching heavy metal.When these enriching heavy metal plants were fired into charcoal, heavy metal was fixed in the charcoal with regard to chelating.
Mine tailing territorial matrix heavy metal content is high, and nutrition is poor, a little less than the retention ability.Charcoal can hinder the control heavy metal and be accumulated by plant absorbing, can fetter and hold and stay soil nutrient, reduces nutrient loss, increases mine tailing matrix retention ability; The farmyard manure mineral nutrition is abundant, and pathogeny is biological few.Therefore, add the farmyard manure that is rich in charcoal in the mine tailing district, can improve mine tailing matrix, Promoting plant growth and Revegetation reduce the diffusion of soil erosion and heavy metal.Charcoal stability is strong, is difficult for by mineralising, and the fixing heavy metal of chelating can be kept at the mine tailing district with the long-term fixing of charcoal.In addition, charcoal is the water-soluble heavy metal in the adsorbable fixedly mine tailing also, prevents that heavy metal from transferring in the water and soil of surrounding area.
Beneficial effect of the present invention:
(1) the enriching heavy metal Plant Transformation becomes charcoal, can prevent the with the wind drift of these Litters, causes the heavy metal diffusion.
When (2) the enriching heavy metal plant was fired into charcoal, heavy metal was fixed in the charcoal with regard to chelating; When adding charcoal to the mine tailing district, the fixing heavy metal of chelating can be with the charcoal prolonged preservation in mine tailing matrix, the diffusion of can not migrating.
(3) contain a large amount of mineral nutritions in the farmyard manure, can be plant-growth nutrient is provided.
(4) adsorbable the holding of charcoal stayed soil nutrient, increases soil water holding capacity, Promoting plant growth.
(5) charcoal can reduce the bio-toxicity of heavy-metal contaminated soil, Promoting plant growth and soil microorganisms breeding.
(6) utilize the enriching heavy metal plant of mining area growth to fire farmyard manure, with farmyard manure improvement mine pollution matrix and Promoting plant growth, realized the safe recycle of phytoremediation cutting again.
(7) Chinese tallow tree (
Sapium sebiferum), paulownia (
Paulownia fortunei) and fragrant camphor tree (
Cinnamomum camphora) have Important Economic value, uncorrelated with the human foods chain.
(8) present technique is drawn materials conveniently, and is simple.
Embodiment
Below in conjunction with embodiment the present invention is described in detail.
Embodiment 1
Test in the Xiangtan Manganese Mine district year October in August, 2007 to 2009.
In August, (1) 2007, collect straw, bamboo branch and bamboo bar, the bamboo bar cuts into the long thick bamboo tube of 1m, shines dry rice straw, bamboo branch and thick bamboo tube.
(2) in the soil of the long weeds of uranium Tailings Dam periphery selection, be with soil to shovel together weeds and dig, make lump zone soil turf, dry.
(3) collect the periphery zone of pollution growth of uranium tail storehouse enriching heavy metal plant dyers' grapes (
Phytolacca americana), dry.
(4) place mat straw and bamboo branch on a small area of ground of reservoir area, lay thick bamboo tube on straw and the bamboo branch, cover dyers' grapes on the thick bamboo tube, build up rick with this, cover tape soil turf on the rick, the rick bottom is exposed, light rick from the bottom, smoulder, fire extinguishes rear collection, and these burn soil and charcoal, sieve, make the farmyard manure that contains charcoal.
In March, (5) 2008, select 1 sample ground at the uranium mining tailing wasteland, dig the plantation hole, plantation hole specification is: long 50cm, wide 30cm, dark 50cm.The fragrant camphor tree of transplanting in the hole (
Cinnamomum camphora) seedling, add the 6kg farmyard manure in each hole, with tailings overburden soil miscellaneous fertilizers.
In September, (6) 2008, sample ground to be investigated, fragrant camphor tree survival rate is 92%, the plant height rate of increase is 15%.Investigate in October, 2009, and fragrant camphor tree survival rate is 88%, and the plant height rate of increase is 23%.
Embodiment 2
Test in the Xiangtan Manganese Mine district year October in September, 2008 to 2010.
In September, (1) 2008, collect straw, bamboo branch and bamboo bar, the bamboo bar cuts into the long thick bamboo tube of 1m, shines dry rice straw, bamboo branch and thick bamboo tube.
(2) in the soil of the long weeds of manganese ore surrounding area selection, be with soil to shovel together weeds and dig, make lump zone soil turf, dry.
(3) collect the growth of manganese ore zone of pollution enriching heavy metal plant Pinnate Beggarticks (
Bidens maximowicziana), dry.
(4) place mat straw and bamboo branch on the Manganese Ore District a small area of ground, lay thick bamboo tube on straw and the bamboo branch, cover Pinnate Beggarticks on the thick bamboo tube, build up rick with this, cover tape soil turf on the rick, the rick bottom is exposed, light rick from the bottom, smoulder, fire extinguishes rear collection, and these burn soil and charcoal, sieve, make the farmyard manure that contains charcoal.
In March, (5) 2009, select 1 sample ground at manganese ore tailings accumulation area, dig the plantation hole, plantation hole specification is: long 50cm, wide 30cm, dark 50cm.In the hole, transplant Chinese tallow tree (
Sapium sebiferum) seedling, add the 6kg farmyard manure in each hole, with tailings overburden soil miscellaneous fertilizers.
In September, (6) 2009, sample ground to be investigated, the Chinese tallow tree survival rate is 87%, the plant height rate of increase is 18%.Investigate in October, 2010, and the Chinese tallow tree survival rate is 84%, and the plant height rate of increase is 19%.
Embodiment 3
Test in the Xiangtan Manganese Mine district year October in September, 2008 to 2010.
In September, (1) 2008, collect straw, bamboo branch and bamboo bar, the bamboo bar cuts into the long thick bamboo tube of 1m, shines dry rice straw, bamboo branch and thick bamboo tube.
(2) in the soil of the long weeds of manganese ore surrounding area selection, be with soil to shovel together weeds and dig, make lump zone soil turf, dry.
(3) collect the growth of manganese ore zone of pollution the enriching heavy metal plant black nightshade (
Solanum nigrum), dry.
(4) place mat straw and bamboo branch on the Manganese Ore District a small area of ground, lay thick bamboo tube on straw and the bamboo branch, cover black nightshade on the thick bamboo tube, build up rick with this, cover tape soil turf on the rick, the rick bottom is exposed, light rick from the bottom, smoulder, fire extinguishes rear collection, and these burn soil and charcoal, sieve, make the farmyard manure that contains charcoal.
In March, (5) 2009, select 1 sample ground at manganese ore tailings accumulation area, dig the plantation hole, plantation hole specification is: long 50cm, wide 30cm, dark 50cm.In the hole, transplant paulownia (
Paulownia fortunei) seedling, add the 6kg farmyard manure in each hole, with tailings overburden soil miscellaneous fertilizers.
In September, (6) 2009, sample ground to be investigated, the paulownia survival rate is 91%, the plant height rate of increase is 16%.Investigate in October, 2010, and paulownia survival rate 87%, plant height rate of increase are 26%.
The invention is not restricted to above-mentioned three kinds of embodiment, can also collect mine pollution district growth enriching heavy metal plant dyers' grapes (
Phytolacca americana), Pinnate Beggarticks (
Bidens maximowicziana) and black nightshade (
Solanum nigrum) in any two or three, dry the other the same as in Example 1 or embodiment 2 or embodiment 3.
Claims (1)
1. one kind is the method that contains the charcoal farmyard manure of recovering plant cover of mine special use with the enriching heavy metal Plant Transformation, it is characterized in that, may further comprise the steps:
(1) collects straw, dry;
(2) collect bamboo branch and bamboo bar, the bamboo bar is cut into thick bamboo tube, dry bamboo branch and thick bamboo tube;
(3) collect the enriching heavy metal plant that grows in the mine pollution district, dry;
(4) soil of the long weeds of selection is with soil to shovel together weeds and is dug, and makes lump zone soil turf, dries;
(5) select a small area of ground, place mat straw and bamboo branch cover thick bamboo tube on straw and the bamboo branch, cover the enriching heavy metal plant on the thick bamboo tube, build up rick with this, cover tape soil turf on the rick, the rick bottom is exposed, lights rick from the bottom, smoulder, fire extinguishes rear collection, and these burn soil and charcoal, sieve, and make the farmyard manure that is rich in charcoal;
Described enriching heavy metal plant be dyers' grapes (
Phytolacca americana), black nightshade (
Solanum nigrum) and Pinnate Beggarticks (
Bidens maximowicziana) in one or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103812021A CN102515939B (en) | 2011-11-26 | 2011-11-26 | Method for converting heavy metal-enriched plant into miscellaneous fertilizer containing biological carbon special for mine vegetation recovery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103812021A CN102515939B (en) | 2011-11-26 | 2011-11-26 | Method for converting heavy metal-enriched plant into miscellaneous fertilizer containing biological carbon special for mine vegetation recovery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102515939A CN102515939A (en) | 2012-06-27 |
| CN102515939B true CN102515939B (en) | 2013-05-29 |
Family
ID=46287083
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103812021A Expired - Fee Related CN102515939B (en) | 2011-11-26 | 2011-11-26 | Method for converting heavy metal-enriched plant into miscellaneous fertilizer containing biological carbon special for mine vegetation recovery |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102515939B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102792801B (en) * | 2012-08-27 | 2015-11-25 | 王光敏 | Stalk, turf are boiled in a covered pot over a slow fire soil and are returned field method |
| CN103922822B (en) * | 2014-03-03 | 2016-04-20 | 上田环境修复股份有限公司 | A kind of manganese ultraproduct that utilizes tires out the method for rehabilitation plant Phytolacca acinosa making containing manganese organic fertilizer |
| CN106311146A (en) * | 2016-09-20 | 2017-01-11 | 中国环境科学研究院 | Biological charcoal prepared by countryside heavy-metal-enriched plant biomass and preparation method and application of biological charcoal |
| CN109529773B (en) * | 2019-01-17 | 2021-11-02 | 三峡大学 | Preparation method and application of iris manganese-enriched biochar |
| CN109987973B (en) * | 2019-03-13 | 2022-08-26 | 南京师范大学 | Method for producing rare earth micro-fertilizer by using remediation plant dicranopteris pedata, dicranopteris pedata ash rare earth micro-fertilizer produced by method and application of dicranopteris pedata ash rare earth micro-fertilizer |
| CN115591926A (en) * | 2022-09-26 | 2023-01-13 | 重庆大学（Cn） | Ecological restoration method for soil polluted by perfluorinated polyfluoroalkyl compound |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005013786A (en) * | 2003-06-23 | 2005-01-20 | Gifu Prefecture | Estimation method and estimation program of amount of heavy metal flowing out of soil |
| JP2006075821A (en) * | 2004-08-09 | 2006-03-23 | Kochi Univ | Method for removing and recovering heavy metal in soil |
| EP1795273A1 (en) * | 2004-09-10 | 2007-06-13 | Chubu Electric Power Co., Inc. | Method of purifiying heavy metal-containing soil |
| CN101283661A (en) * | 2008-06-05 | 2008-10-15 | 湖南科技大学 | A method for increasing the plant tolerance to heavy metal |
| CA2272849C (en) * | 1996-08-30 | 2011-11-01 | University Of Maryland | Method for phytomining of nickel, cobalt and other metals from soil |
-
2011
- 2011-11-26 CN CN2011103812021A patent/CN102515939B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2272849C (en) * | 1996-08-30 | 2011-11-01 | University Of Maryland | Method for phytomining of nickel, cobalt and other metals from soil |
| JP2005013786A (en) * | 2003-06-23 | 2005-01-20 | Gifu Prefecture | Estimation method and estimation program of amount of heavy metal flowing out of soil |
| JP2006075821A (en) * | 2004-08-09 | 2006-03-23 | Kochi Univ | Method for removing and recovering heavy metal in soil |
| EP1795273A1 (en) * | 2004-09-10 | 2007-06-13 | Chubu Electric Power Co., Inc. | Method of purifiying heavy metal-containing soil |
| CN101283661A (en) * | 2008-06-05 | 2008-10-15 | 湖南科技大学 | A method for increasing the plant tolerance to heavy metal |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102515939A (en) | 2012-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Mirck et al. | Development of short-rotation willow coppice systems for environmental purposes in Sweden | |
| CN103736721B (en) | Method by biological restoration water body with soil and comprehensive utilization of resources | |
| CN104529668B (en) | Metal mine soil conditioner, and mine ecological remediation method using metal mine soil conditioner. | |
| CN104289506B (en) | Cadmium, zinc, lead, copper ion contaminated soil biological renovation method | |
| US6250237B1 (en) | Method for using tree crops as pollutant control | |
| CN102515939B (en) | Method for converting heavy metal-enriched plant into miscellaneous fertilizer containing biological carbon special for mine vegetation recovery | |
| CN103894401B (en) | A kind of plant restoration method administering the plumbous arsenic combined contamination soil of cadmium | |
| CN102513341B (en) | Chemical-giant reed combined ecological recovery method of polymetal polluted soil in mining and metallurgy zones | |
| Panda et al. | Impact of fly ash on soil properties and productivity | |
| CN110915336A (en) | Ecological system treatment method | |
| CN104289504A (en) | Comprehensive heavy metal contaminated soil remediation method | |
| CN105903760A (en) | Animal and plant comprehensive utilization and restoration method for heavy metal contaminated soil | |
| CN107159694A (en) | A kind of heavy metal pollution of soil restorative procedure | |
| CN106694541A (en) | Method for repairing heavy metal pollution tailings with charcoal-based slow release fertilizer and imperata cylindrica | |
| CN101695711B (en) | Chemical fixation material suitable for arsenic in soil and application thereof | |
| CN101670362A (en) | Application of grain amaranth in repairing mine soil and sludge polluted by heavy metal cadmium | |
| CN102513338A (en) | Method for restoring copper-polluted soil by plants | |
| CN105149341A (en) | Method for restoring sludge land heavy metal contaminated soil | |
| CN110452067A (en) | A kind of charcoal and its method for repairing karst mine soil | |
| CN107226758A (en) | A kind of garden waste biomass carbon base biogas slurry fertilizer and preparation method and application | |
| CN104759455A (en) | Applications of perennial herb hydrocotyle sibthorpioides in enrichment and extraction of cadmium and other heavy metals in polluted soil | |
| CN103039150B (en) | A kind of cost effective discarded tailing vegetation repair method fast | |
| CN102659279B (en) | Sewage treatment system for constructed wetland and application | |
| CN104646404A (en) | Method for assisting ecological restoration of tailings by utilizing urban excess sludge | |
| CN107737805A (en) | A kind of ecological restoring method of zinc cadmium heavy-metal contaminated soil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130529 Termination date: 20161126 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |