CN102513726A - Silver-based flux-cored wire and manufacturing method thereof - Google Patents

Silver-based flux-cored wire and manufacturing method thereof Download PDF

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Publication number
CN102513726A
CN102513726A CN2011104351732A CN201110435173A CN102513726A CN 102513726 A CN102513726 A CN 102513726A CN 2011104351732 A CN2011104351732 A CN 2011104351732A CN 201110435173 A CN201110435173 A CN 201110435173A CN 102513726 A CN102513726 A CN 102513726A
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flux
cored wire
silver
consumption
potassium fluoride
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CN102513726B (en
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李国赣
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Foshan Yihong Welding Co Ltd
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Foshan Yihong Welding Co Ltd
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Abstract

Provided are a silver-based flux-cored wire and a manufacturing method thereof. The manufacturing method of the silver-based flux-cored wire includes the following steps: 1 placing soldering flux powder in a soldering flux jar, heating up to 580-600 DEG C, and smelting soldering flux to liquid state for use; 2 smelting proportioned silver, copper and zinc to be cast to bars, then turning the cast bars to remove scale, and cutting the cast bars to ingots for use; 3 enabling a flux-cored wire extrusion device to be heated to 520-530 DEG C; 4 placing the ingots in a muffle furnace for preheating with the preheating temperature at 560-580 DEG C; 5 placing the preheated ingots in a mould drum of the flux-cored wire extrusion device, starting a press of the flux-cored wire extrusion device to extrude an extrusion rod into an upper mould drum, and enabling alloy to be extruded into a material leading cone, enter an upper mould, a mould core and a lower mould through split-flow and then form a hollow pipe; and 6 opening an air inlet valve of the soldering flux jar, pressurizing, and enabling the liquid-state soldering flux in the soldering flux jar to be pressed into a feeding port to enter the mould core and be injected to the alloy hollow pipe to be solidified after heat dissipation. Thus, the silver-based flux-cored wire is produced. Compared with the prior art, the silver-based flux-cored wire and the manufacturing method thereof have the advantages of being simple in soldering process, high in production efficiency, low in cost, easy in controlling use level of soldering flux accurately, capable of meeting the requirement for alloy welding temperature matching, easy in cleaning after welding, good in welding performance, not prone to moisture absorption of solder wires, and long in storage time of solder wires.

Description

Money base flux-cored wire and manufacturing approach
Technical field
The present invention relates to welding wire and manufacturing approach thereof.
Background technology
Existing soldering processes generally adopt and dip in brazing flux after the heating and use, and this kind soldering processes complicacy, production efficiency is low, cost is high, be not easy accurately to control the consumption of brazing flux.
Summary of the invention
That goal of the invention of the present invention is is simple through a kind of soldering processes, production efficiency is high, cost is low, accurately the money base flux-cored wire and the manufacturing approach of the consumption of control brazing flux easily.
The present invention is achieved in that and comprises the flux cored wire that is made up of silver, copper, kirsite, is filled in the brazing flux in the welding wire pipe that the consumption of brazing flux is 10-15wt%; Silver, copper, kirsite consumption 85-90wt%, silver content is 15-65wt% in silver, copper, the kirsite, copper content is 15-65wt%; Zinc content is 15-65wt%; Brazing flux comprises potassium fluoride, borax, boric acid composition, and wherein potassium fluoride content is 15-60 weight portions, and borax, boric acid content are 40-85 weight portions.The present invention's employing is filled in brazing flux in the pipe of flux cored wire, and like this, soldering processes are simple, production efficiency is high, cost is low, welding wire surface cleaned when accurately consumption, the welding wire of control brazing flux were not easy the moisture absorption, welding easily, guaranteed welding quality.And solder fusion temperature scope is at 710-760 ℃, and welding temperature is 760-800 ℃, can adapt to the requirement of high temperature brazing.
Here; Also include boric anhydride, potassium fluoborate in the brazing flux, potassium fluoride, boric anhydride, potassium fluoborate constitute the potassium fluoride mixture, and the consumption of potassium fluoride mixture is 40-60 weight portions in the brazing flux; Borax, boric acid consumption are 40-60 weight portions; The potassium fluoride consumption is the 30-40 weight portion in the potassium fluoride mixture, and the boric anhydride consumption is the 25-45 weight portion, and the potassium fluoborate consumption is the 15-35 weight portion.The rare earth oxide that also contains 0.1-3 weight portions in the potassium fluoride mixture.Adopt boric anhydride, potassium fluoborate and rare earth oxide to cooperate potassium fluoride, can satisfy gold alloy solder jointing temp coupling, postwelding is prone to clean.
The manufacturing approach of money base flux-cored wire of the present invention is to realize like this; puts into the brazing flux jar with the brazing flux powder and is warming up to 580-600 ℃; It is for use to treat that brazing flux is fused into liquid state; will pacify silver, copper, the zinc fusing that proportioning prepares and be cast into rod; The excellent turning scale removal of will casting then; And it is for use to be cut into spindle; is with being warming up to 520-530 ℃ in the flux-cored wire pressurizing unit system;
Figure 445208DEST_PATH_IMAGE004
places preheating in the Muffle furnace with spindle; Preheat temperature 560-580 ℃;
Figure 337072DEST_PATH_IMAGE005
spindle that preheating is good is put into the mould tube of flux-cored wire pressurizing unit system; The press that starts flux-cored wire pressurizing unit system is got into the patrix tube with pressure ram; Alloy clamp-oned draw material awl, flow into patrix, core rod through dividing; Counterdie; Form hollow pipe then,
Figure 897366DEST_PATH_IMAGE006
opens brazing flux jar upper inlet valve, pressurization; Liquid brazing flux in the brazing flux jar is pressed into charging aperture gets into core rod; Inject in the alloy blank pipe, the heat radiation after coagulation is so just produced the money base flux-cored wire.Adopt seamless extruding to irritate the core production technology, guarantee that the scaling powder ratio is even in the welding wire, welding wire is difficult for the moisture absorption, and the welding wire holding time is longer, and can obtain good welding performance.
The present invention compared with present technology, have that soldering processes are simple, production efficiency is high, cost is low, easily accurately the consumption of control brazing flux, can satisfy gold alloy solder jointing temp coupling, postwelding is prone to clean, have good welding performance, welding wire to be difficult for long advantage of the moisture absorption, welding wire holding time.
Description of drawings:
Fig. 1 is the structural representation of money base flux-cored wire of the present invention.
The specific embodiment:
Combine accompanying drawing and embodiment that the present invention is done describes in further detail at present:
As shown in the figure, money base flux-cored wire of the present invention comprises the flux cored wire 1 that is made up of silver, copper, kirsite, is filled in the brazing flux 2 in the welding wire pipe, and the consumption of brazing flux is 10-15wt%; Silver, copper, kirsite consumption 85-90wt%, silver content is 15-65wt% in silver, copper, the kirsite, copper content is 15-65wt%; Zinc content is 15-65wt%; Brazing flux comprises potassium fluoride, borax, boric acid composition, and wherein potassium fluoride content is 15-60 weight portions, and borax, boric acid content are 40-85 weight portions.Also include boric anhydride, potassium fluoborate in the brazing flux; Potassium fluoride, boric anhydride, potassium fluoborate constitute the potassium fluoride mixture; The consumption of potassium fluoride mixture is 40-60 weight portions in the brazing flux, and borax, boric acid consumption are 40-60 weight portions, and the potassium fluoride consumption is the 30-40 weight portion in the potassium fluoride mixture; The boric anhydride consumption is the 25-45 weight portion, and the potassium fluoborate consumption is the 15-35 weight portion.The potassium fluoride consumption is preferably the 35-37 weight portion in the potassium fluoride mixture, and the boric anhydride consumption is preferably the 29-41 weight portion, and the potassium fluoborate consumption is preferably the 17-29 weight portion.The rare earth oxide that also contains 0.1-3 weight portions in the potassium fluoride mixture.
Money base method for manufacturing flux-cored wire of the present invention is to realize like this;
Figure 669013DEST_PATH_IMAGE001
puts into the brazing flux jar with the brazing flux powder and is warming up to 580-600 ℃; It is for use to treat that brazing flux is fused into liquid state;
Figure 370384DEST_PATH_IMAGE002
will pacify silver, copper, the zinc fusing that proportioning prepares and be cast into rod; The excellent turning scale removal of will casting then; And it is for use to be cut into spindle;
Figure 128255DEST_PATH_IMAGE003
is with being warming up to 520-530 ℃ in the flux-cored wire pressurizing unit system;
Figure 480739DEST_PATH_IMAGE004
places preheating in the Muffle furnace with spindle; Preheat temperature 560-580 ℃;
Figure 236337DEST_PATH_IMAGE005
spindle that preheating is good is put into the mould tube of flux-cored wire pressurizing unit system; The press that starts flux-cored wire pressurizing unit system is got into the patrix tube with pressure ram; Alloy clamp-oned draw material awl, flow into patrix, core rod through dividing; Counterdie; Form hollow pipe then,
Figure 674271DEST_PATH_IMAGE006
opens brazing flux jar upper inlet valve, pressurization; Liquid brazing flux in the brazing flux jar is pressed into charging aperture gets into core rod; Inject in the alloy blank pipe, the heat radiation after coagulation is so just produced the money base flux-cored wire.

Claims (5)

1. money base flux-cored wire is characterized in that comprising the flux cored wire that is made up of silver, copper, kirsite, is filled in the brazing flux in the welding wire pipe, and the consumption of brazing flux is 10-15wt%; Silver, copper, kirsite consumption 85-90wt%, silver content is 15-65wt% in silver, copper, the kirsite, copper content is 15-65wt%; Zinc content is 15-65wt%; Brazing flux comprises potassium fluoride, borax, boric acid composition, and wherein potassium fluoride content is 15-60 weight portions, and borax, boric acid content are 40-85 weight portions.
2. money base flux-cored wire according to claim 1; It is characterized in that also including in the brazing flux boric anhydride, potassium fluoborate, potassium fluoride, boric anhydride, potassium fluoborate constitute the potassium fluoride mixture, and the consumption of potassium fluoride mixture is 40-60 weight portions in the brazing flux; Borax, boric acid consumption are 40-60 weight portions; The potassium fluoride consumption is the 30-40 weight portion in the potassium fluoride mixture, and the boric anhydride consumption is the 25-45 weight portion, and the potassium fluoborate consumption is the 15-35 weight portion.
3. money base flux-cored wire according to claim 2 is characterized in that also containing in the potassium fluoride mixture rare earth oxide of 0.1-3 weight portions.
4. according to claim 2 or 3 described money base flux-cored wires, it is characterized in that the potassium fluoride consumption is the 35-37 weight portion in the potassium fluoride mixture, the boric anhydride consumption is the 29-41 weight portion, and the potassium fluoborate consumption is the 17-29 weight portion.
5. money base method for manufacturing flux-cored wire; It is characterized in that
Figure 73559DEST_PATH_IMAGE001
puts into the brazing flux jar with the brazing flux powder and is warming up to 580-600 ℃; It is for use to treat that brazing flux is fused into liquid state; will pacify silver, copper, the zinc fusing that proportioning prepares and be cast into rod; The excellent turning scale removal of will casting then; And it is for use to be cut into spindle;
Figure 990699DEST_PATH_IMAGE003
is with being warming up to 520-530 ℃ in the flux-cored wire pressurizing unit system;
Figure 2011104351732100001DEST_PATH_IMAGE004
places preheating in the Muffle furnace with spindle; Preheat temperature 560-580 ℃;
Figure 708120DEST_PATH_IMAGE005
spindle that preheating is good is put into the mould tube of flux-cored wire pressurizing unit system; The press that starts flux-cored wire pressurizing unit system is got into the patrix tube with pressure ram; Alloy clamp-oned draw material awl; Flow into patrix through dividing; Core rod, counterdie forms hollow pipe then; opens brazing flux jar upper inlet valve; Pressurization is pressed into charging aperture with liquid brazing flux in the brazing flux jar and gets into core rod, injects in the alloy blank pipe; The heat radiation after coagulation is so just produced the money base flux-cored wire.
CN201110435173.2A 2011-12-22 2011-12-22 Silver-based flux-cored wire and manufacturing method thereof Active CN102513726B (en)

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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103551757A (en) * 2013-10-31 2014-02-05 北京工业大学 Aluminum-silicon alloy seamless flux-cored wire for brazing as well as preparation and application
CN104384744A (en) * 2014-09-28 2015-03-04 杭州华光焊接新材料股份有限公司 Preparation method for flux-cored electrode
CN104625488A (en) * 2014-12-23 2015-05-20 苏州龙腾万里化工科技有限公司 Manufacture method for tin bar with core
CN104708235A (en) * 2015-02-09 2015-06-17 郑州机械研究所 Spring-shaped flux-cored solder preparing method and dedicated device adopted in method
CN104741835A (en) * 2015-04-17 2015-07-01 郑州机械研究所 Seamless silver flux-cored wire
CN104741817A (en) * 2015-03-12 2015-07-01 西安理工大学 Ag-Ni welding wire for welding titanium-pipeline-steel composite plate and preparing method thereof
CN104907727A (en) * 2015-05-25 2015-09-16 郑州机械研究所 Flux-cored silver solder and preparation method thereof
CN104907724A (en) * 2015-05-25 2015-09-16 郑州机械研究所 Reed-type environment-friendly coated silver brazing filler metal ring
CN104907723A (en) * 2015-05-25 2015-09-16 郑州机械研究所 Flux-cored silver brazing filler metal with toughening alloy
CN105014259A (en) * 2015-07-13 2015-11-04 江西金世纪特种焊接材料有限公司 Seamless flux-cored wire and processing method thereof
CN105414807A (en) * 2015-12-31 2016-03-23 广州汉源新材料有限公司 Core filling method for solder wire soldering flux
CN106312371A (en) * 2016-11-07 2017-01-11 株洲硬质合金集团有限公司 Welding flux for large hard alloy cutter welding
WO2018045528A1 (en) * 2016-09-08 2018-03-15 江西理工大学 Flux cored welding rod forming module, preparation device and preparation method thereof
CN108326475A (en) * 2018-02-07 2018-07-27 郑州机械研究所有限公司 A kind of preparation method of coating silver solder ring
CN108406162A (en) * 2018-02-07 2018-08-17 郑州机械研究所有限公司 A kind of fabricated in situ metal coating coating silver brazing item and preparation method thereof
CN109093288A (en) * 2018-11-01 2018-12-28 南京航空航天大学 The medicine core silver solder of easy processing
WO2019119281A1 (en) * 2017-12-19 2019-06-27 郑州机械研究所有限公司 Solder outer skin and preparation method thereof, in-situ synthesized metallic coated flux-cored silver solder and preparation method thereof, soldering method and connector
CN112059474A (en) * 2020-09-07 2020-12-11 郑州机械研究所有限公司 Flux-cored brazing filler metal, preparation method thereof and device for preparing flux-cored brazing filler metal
CN113084390A (en) * 2021-04-12 2021-07-09 郑州机械研究所有限公司 Multilayer flux-cored silver solder and preparation method thereof
CN113414517A (en) * 2021-04-25 2021-09-21 郑州机械研究所有限公司 Brazing welding wire, brazing welding wire forming method and brazing welding wire forming die
CN114769945A (en) * 2022-06-14 2022-07-22 中机智能装备创新研究院(宁波)有限公司 High-activity flux-cored brazing filler metal for improving brazing strength of heterogeneous material and preparation method

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CN103551757B (en) * 2013-10-31 2015-11-11 北京工业大学 Soldering alusil alloy seamless flux-cored wire, preparations and applicatio
CN103551757A (en) * 2013-10-31 2014-02-05 北京工业大学 Aluminum-silicon alloy seamless flux-cored wire for brazing as well as preparation and application
CN104384744A (en) * 2014-09-28 2015-03-04 杭州华光焊接新材料股份有限公司 Preparation method for flux-cored electrode
CN104625488A (en) * 2014-12-23 2015-05-20 苏州龙腾万里化工科技有限公司 Manufacture method for tin bar with core
CN104708235A (en) * 2015-02-09 2015-06-17 郑州机械研究所 Spring-shaped flux-cored solder preparing method and dedicated device adopted in method
CN104708235B (en) * 2015-02-09 2017-01-04 郑州机械研究所 The preparation method of spring shape medicated core solder
CN104741817A (en) * 2015-03-12 2015-07-01 西安理工大学 Ag-Ni welding wire for welding titanium-pipeline-steel composite plate and preparing method thereof
CN104741835A (en) * 2015-04-17 2015-07-01 郑州机械研究所 Seamless silver flux-cored wire
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CN104907723A (en) * 2015-05-25 2015-09-16 郑州机械研究所 Flux-cored silver brazing filler metal with toughening alloy
CN104907724A (en) * 2015-05-25 2015-09-16 郑州机械研究所 Reed-type environment-friendly coated silver brazing filler metal ring
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WO2021228286A3 (en) * 2020-09-07 2022-01-06 郑州机械研究所有限公司 Flux-cored brazing filler material and preparation method therefor, and apparatus for preparing flux-cored brazing filler material
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CN113084390A (en) * 2021-04-12 2021-07-09 郑州机械研究所有限公司 Multilayer flux-cored silver solder and preparation method thereof
CN113414517A (en) * 2021-04-25 2021-09-21 郑州机械研究所有限公司 Brazing welding wire, brazing welding wire forming method and brazing welding wire forming die
CN114769945A (en) * 2022-06-14 2022-07-22 中机智能装备创新研究院(宁波)有限公司 High-activity flux-cored brazing filler metal for improving brazing strength of heterogeneous material and preparation method
WO2023240816A1 (en) * 2022-06-14 2023-12-21 中国机械总院集团宁波智能机床研究院有限公司 High-activity flux-cored brazing filler metal for improving brazing strength between heterogeneous materials, and preparation method

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Denomination of invention: Silver based flux cored wire and its manufacturing method

Effective date of registration: 20201126

Granted publication date: 20141112

Pledgee: Guangdong Nanhai Rural Commercial Bank branch branch of Limited by Share Ltd.

Pledgor: FOSHAN YIHONG WELDING Co.,Ltd.

Registration number: Y2020440000364