CN105734611A - Preparation method for novel energy-saving anode steel claw - Google Patents

Preparation method for novel energy-saving anode steel claw Download PDF

Info

Publication number
CN105734611A
CN105734611A CN201510457676.8A CN201510457676A CN105734611A CN 105734611 A CN105734611 A CN 105734611A CN 201510457676 A CN201510457676 A CN 201510457676A CN 105734611 A CN105734611 A CN 105734611A
Authority
CN
China
Prior art keywords
welding
fusion
anode steel
steel claw
claw
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201510457676.8A
Other languages
Chinese (zh)
Other versions
CN105734611B (en
Inventor
张贵才
姜彦平
赵玉春
孙剑
张平
李海燕
郑拥军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INNER MONGOLIA SHIXING NEW MATERIAL SCIENCE & TECHNOLOGY CO., LTD.
Original Assignee
Inner Mongolia Shixing New Material Science & Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inner Mongolia Shixing New Material Science & Technology Co Ltd filed Critical Inner Mongolia Shixing New Material Science & Technology Co Ltd
Priority to CN201510457676.8A priority Critical patent/CN105734611B/en
Publication of CN105734611A publication Critical patent/CN105734611A/en
Application granted granted Critical
Publication of CN105734611B publication Critical patent/CN105734611B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The invention discloses a novel energy-saving anode steel claw. The novel energy-saving anode steel claw comprises a cross arm and claw heads, and is characterized in that the cross arm and the claw heads are bonded and fixed together through electroslag fusion-welding. A preparation method comprises the following steps: arranging pre-prepared claw head and cross arm matrix blanks Q235 in a water-cooling model cavity corresponding to an anode steel claw structure, and assembling, locating and connecting the blanks; pouring a flux which is already melted into the water-cooling model cavity, starting a power supply, and carrying out the processes of melting refining and metallurgical bonding welding between the cuboid claw head matrixes and the cylindrical metal cross arm matrix which are subjected to fusion-welding through the flux. Rare-earth active element Ce in the flux is subjected to a chemical reduction reaction, and enters a metal fusion-welding area to be alloyed, thus the material is purified. On the other hand, liquid metals are omni-directionally gradually ascended and solidified in a volume fusion-welding area, thus the generation of casting defects of shrinkage cavities and air holes is avoided. According to the preparation method disclosed by the invention, the overall electroslag fusion-welding is adopted, a fusion-welding temperature field is uniform, the fusion-welding quality is optimized, the performance, strength and toughness of the product are high, and the conductive performance is excellent.

Description

A kind of preparation method of novel energy-conserving anode steel claw
Technical field
The invention belongs to electrolytic aluminum anodic steel claw and manufacturing technology field thereof, be especially the anode steel claw of a kind of new structure.
Background technology
Electrolytic aluminum anodic steel claw structure manufacture require dense structure, without casting flaw, chemical composition is uniformly accurate, and it is cumbersome that traditional casting method makes anode steel claw processing step, it is easy to causes the secondary oxidation of molten steel, degree of purity can not be guaranteed, and the controllability of scaling loss elemental composition is poor.It is extremely difficult to electrolytic aluminum anodic steel claw resistivity low, the making requirement conducted electricity very well.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of method that special electroslag metallurgy welding process method prepares Novel anode steel claw component, it is possible to increase the compactness of Novel anode steel claw melting welding, obtains high-quality, high performance anode steel claw product.
It is an object of the invention to be accomplished by:
A kind of novel energy-conserving anode steel claw, including transverse arm 1 and pawl head 2, is characterized in that;Transverse arm 1 and pawl head 2 are fixed together by electroslag molten welding 3;
The preparation method of above-mentioned a kind of novel energy-conserving anode steel claw is as follows:
(1) previously prepared cuboid pawl head and cylinder metal transverse arm parent blank, blank material is Q235, and these 2 kinds of metal carrier body stocks are placed in the water cooled mo(u)ld die cavity that anode steel claw structure is corresponding, is assembled location and couples;
(2) pouring in water cooled mo(u)ld die cavity by the flux melted, start power supply, described melting welding flux is by CeO2、CaF2、CaCO3、AL2O3, composition, wherein each composition by weight/mass percentage composition is: CeO25-18%、CaF243-58%、CaCO35-15%、AL2O318-25%;
(3) cosolvent is being exported from transformator with secondary low-voltage and electric current between cuboid pawl head and the cylinder metal transverse arm parent of fusion welding, the slag bath that cosolvent is formed is formed loop, the electric energy of loop input produces high resistance, highly active heat in slag bath, and cosolvent slag bath temperature is 1600--18500C, causes that parent that chemical composition material is identical and consumable consumable electrode form melting refinement and metallurgical binding welding;
(4) the active rare-earth Elements C e in cosolvent being carried out chemical reduction reaction, reducing agent is Si-Ca alloy, and wherein Si:Ca is 30:70 by mass percentage, makes rare earth element ce enter region, fusion welding metal alloying, purifies material.Liquid metal is comprehensive in melting welding volumetric region on the other hand gradually rises and solidifies, thus avoiding the generation of shrinkage cavity, pore casting flaw.
The present invention, compared with the anode steel claw work of existing conventional preparation techniques fabrication techniques, has the advantage that
1, avoid traditional handicraft or the existing welding procedure to there is " pollution " of metallurgical quality in metallic object, it is to avoid due in preparation technology series of temperature uneven affect welding quality, the deficiency of obdurability and bring anode steel claw potential safety hazard in Aluminum Electrolysis Production running.
In anode steel claw entirety electroslag molten welding process process, active rare-earth chemical reaction handling novel technique makes melting welding uniform temperature fields, fusion welding quality optimization, properties of product intensity and toughness high, and electric conductivity is superior.
Prepare with tradition compared with anode steel claw technique and existing welding procedure, hence it is evident that be in that the long-pending loop process method of electroslag molten welding rare earth slag cell body is simple, scientific and reasonable, effective.Fully phase out existing irrational metallurgical method conventional cast, human weld's technique.Electroslag molten welding new technology more meets the carrying out of melting welding product, has many, fast, good, province, scientific and reasonable.Because weldering territory, melting zone increases reaction interface, it it is the completely metallurgical fusion process of verity.
Apparatus and process is easy and simple to handle, applied widely, can the type of antianode steel pawl product flexible and changeable, just reach to meet the steel pawl diameter of different size and the technology requirement of height by changing melting welding frock.
The novel technique melting welding activity duration is short, and producing cost is lower than traditional handicraft, saves cost and avoids waste.The economic benefit that product is energy-saving and cost-reducing after using simultaneously is more notable.
Accompanying drawing explanation
Fig. 1 is prior art Anodic steel claw structure schematic diagram;
Fig. 2 is anode steel claw structural representation of the present invention.
Detailed description of the invention
Embodiment 1
A kind of novel energy-conserving anode steel claw, including transverse arm 1 and pawl head 2, is characterized in that;Transverse arm 1 and pawl head 2 are fixed together by electroslag molten welding 3;
The preparation method of above-mentioned a kind of novel energy-conserving anode steel claw is as follows:
(1) previously prepared cuboid pawl head and cylinder metal transverse arm parent blank, blank material is Q235, and these 2 kinds of metal carrier body stocks are placed in the water cooled mo(u)ld die cavity that anode steel claw structure is corresponding, is assembled location and couples;
(2) pouring in water cooled mo(u)ld die cavity by the flux melted, start power supply, described melting welding flux is by CeO2、CaF2、CaCO3、AL2O3, composition, wherein each composition by weight/mass percentage composition is: CeO25-18%、CaF243-58%、CaCO35-15%、AL2O318-25%;
(3) cosolvent is being exported from transformator with secondary low-voltage and electric current between cuboid pawl head and the cylinder metal transverse arm parent of fusion welding, the slag bath that cosolvent is formed is formed loop, the electric energy of loop input produces high resistance, highly active heat in slag bath, and cosolvent slag bath temperature is 1600--18500C, causes that parent that chemical composition material is identical and consumable consumable electrode form melting refinement and metallurgical binding welding;
(4) the active rare-earth Elements C e in cosolvent being carried out chemical reduction reaction, reducing agent is Si-Ca alloy, and wherein Si:Ca is 30:70 by mass percentage, makes rare earth element ce enter region, fusion welding metal alloying, purifies material.Liquid metal is comprehensive in melting welding volumetric region on the other hand gradually rises and solidifies, thus avoiding the generation of shrinkage cavity, pore casting flaw.
Anode steel claw of the present invention adopts overall electroslag molten welding slag welding, melting welding uniform temperature fields, fusion welding quality optimization, and properties of product intensity and toughness are high, and electric conductivity is superior.

Claims (1)

1. a novel energy-conserving anode steel claw, including transverse arm and pawl head, is characterized in that: transverse arm and pawl head are fixed together by electroslag molten welding;
The preparation method of above-mentioned a kind of novel energy-conserving anode steel claw is as follows:
(1) previously prepared cuboid pawl head and cylinder metal transverse arm parent blank, blank material is Q235, and these 2 kinds of metal carrier body stocks are placed in the water cooled mo(u)ld die cavity that anode steel claw structure is corresponding, is assembled location and couples;
(2) pouring in water cooled mo(u)ld die cavity by the flux melted, start power supply, described melting welding flux is by CeO2、CaF2、CaCO3、AL2O3, composition, wherein each composition is CeO by weight/mass percentage composition25-18%、CaF243-58%、CaCO35-15%、AL2O318-25%;
(3) cosolvent is being exported from transformator with secondary low-voltage and electric current between cuboid pawl head and the cylinder metal transverse arm parent of fusion welding, the slag bath that cosolvent is formed is formed loop, the electric energy of loop input produces high resistance, highly active heat in slag bath, and cosolvent slag bath temperature is 1600--18500C, causes that parent that chemical composition material is identical and consumable consumable electrode form melting refinement and metallurgical binding welding;
(4) the active rare-earth Elements C e in cosolvent being carried out chemical reduction reaction, reducing agent is Si-Ca alloy, and wherein Si:Ca is 30:70 by mass percentage, makes rare earth element ce enter region, fusion welding metal alloying, purifies material.
CN201510457676.8A 2015-07-30 2015-07-30 A kind of preparation method of novel energy-conserving anode steel claw Active CN105734611B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510457676.8A CN105734611B (en) 2015-07-30 2015-07-30 A kind of preparation method of novel energy-conserving anode steel claw

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510457676.8A CN105734611B (en) 2015-07-30 2015-07-30 A kind of preparation method of novel energy-conserving anode steel claw

Publications (2)

Publication Number Publication Date
CN105734611A true CN105734611A (en) 2016-07-06
CN105734611B CN105734611B (en) 2018-09-07

Family

ID=56296021

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510457676.8A Active CN105734611B (en) 2015-07-30 2015-07-30 A kind of preparation method of novel energy-conserving anode steel claw

Country Status (1)

Country Link
CN (1) CN105734611B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105177626A (en) * 2015-09-22 2015-12-23 内蒙古世星新材料科技有限公司 Method for manufacturing novel energy-saving anode steel jaw
CN108500241A (en) * 2018-05-10 2018-09-07 饶云福 Anode steel claw row's weldering one-step shaping manufacturing process
CN110079830A (en) * 2018-01-26 2019-08-02 洛阳富兴管业有限公司 Electrolytic aluminum anode pawl and the electrolytic aluminium equipment for using the anode claw
CN110170624A (en) * 2019-06-04 2019-08-27 甘肃酒钢集团西部重工股份有限公司 A kind of steel pawl crystallizer and its manufacturing method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709384A (en) * 2009-11-26 2010-05-19 上海大学 Novel slag system for improving quality of electroslag remelted steel ingots
CN102534677A (en) * 2012-01-04 2012-07-04 饶云福 Device for repairing electrolytic aluminium anode steel claw by total cross-section fusion welding
CN102560552A (en) * 2012-01-04 2012-07-11 饶云福 Fusing agent for electrolytic aluminium anodic steel claws repairing
CN103769772A (en) * 2014-01-15 2014-05-07 王会智 Welding agent and welding method for welding anode steel claw
CN104139253A (en) * 2014-07-31 2014-11-12 新昌县雷凯科技有限公司 Welding agent formula and process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709384A (en) * 2009-11-26 2010-05-19 上海大学 Novel slag system for improving quality of electroslag remelted steel ingots
CN102534677A (en) * 2012-01-04 2012-07-04 饶云福 Device for repairing electrolytic aluminium anode steel claw by total cross-section fusion welding
CN102560552A (en) * 2012-01-04 2012-07-11 饶云福 Fusing agent for electrolytic aluminium anodic steel claws repairing
CN103769772A (en) * 2014-01-15 2014-05-07 王会智 Welding agent and welding method for welding anode steel claw
CN104139253A (en) * 2014-07-31 2014-11-12 新昌县雷凯科技有限公司 Welding agent formula and process

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105177626A (en) * 2015-09-22 2015-12-23 内蒙古世星新材料科技有限公司 Method for manufacturing novel energy-saving anode steel jaw
CN110079830A (en) * 2018-01-26 2019-08-02 洛阳富兴管业有限公司 Electrolytic aluminum anode pawl and the electrolytic aluminium equipment for using the anode claw
CN108500241A (en) * 2018-05-10 2018-09-07 饶云福 Anode steel claw row's weldering one-step shaping manufacturing process
CN110170624A (en) * 2019-06-04 2019-08-27 甘肃酒钢集团西部重工股份有限公司 A kind of steel pawl crystallizer and its manufacturing method
CN110170624B (en) * 2019-06-04 2023-10-13 甘肃酒钢集团西部重工股份有限公司 Crystallizer for steel claw and manufacturing method thereof

Also Published As

Publication number Publication date
CN105734611B (en) 2018-09-07

Similar Documents

Publication Publication Date Title
CN102240860B (en) Method and equipment for manufacturing gradient material mould
CN101219508A (en) Seamless explosive core aluminium welding wire and manufacturing method thereof
CN104313363B (en) A kind of method of smelting of titanium-niobium alloy ingot casting
CN105734611A (en) Preparation method for novel energy-saving anode steel claw
CN102225496A (en) Preparation method of zinc-aluminium seamless flux-cored wire
CN103706967B (en) A kind of welding compound and welding method
CN110042273A (en) A kind of copper alloy with high strength and high conductivity pipe and preparation method thereof
CN110317970A (en) A kind of Cu-Cr-Zr alloy, preparation method and applications
CN108188542A (en) Metal component filament electric smelting increasing material manufacturing method and metal component
CN1120245C (en) Technological process for producing chromium-zirconium-copper rod material containing oxide dispersed and reinforced copper
CN102392205B (en) Method for preparing precision copper part
CN105177626A (en) Method for manufacturing novel energy-saving anode steel jaw
CN1772960A (en) Method for thermite welding aluminium electrolytic cell cathode steel bar
CN101347858A (en) Arc assisted activating gas tungsten arc welding method
CN106271191B (en) A kind of high-strength low temperature composite soldering of green and preparation method thereof
CN103692100A (en) Transition-free welding device for anode guide rod and anode yoke and welding method
CN105063662A (en) Method for manufacturing anode steel stud through electro-slag fusion welding
CN203761612U (en) Titanium electrode combination comprising refractory metal core rod
CN104981040A (en) Preparation method of titanium electrode containing metal mandrel difficult to melt
CN104630541A (en) Chromium-zirconium-copper alloy profiled material production technology
CN102848101A (en) Bi-component powder thermit for resistance welding of aluminum alloy
CN203700548U (en) Anode guide rod and anode steel claw connecting structure
RU2410194C2 (en) Method of producing consumable electrodes
CN207858031U (en) The increasing material manufacturing equipment of metal component
CN107267768B (en) A kind of metal component fast shaping apptss

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Jiang Yanping

Inventor before: Zhang Guicai

Inventor before: Jiang Yanping

Inventor before: Zhao Yuchun

Inventor before: Sun Jian

Inventor before: Zhang Ping

Inventor before: Li Haiyan

Inventor before: Zheng Yongjun

CB03 Change of inventor or designer information
TA01 Transfer of patent application right

Effective date of registration: 20180306

Address after: 014000 Inner Mongolia Baotou city rare earth mansion Huafeng Garden No. 26

Applicant after: INNER MONGOLIA SHIXING NEW MATERIAL SCIENCE & TECHNOLOGY CO., LTD.

Applicant after: Jiang Yanping

Address before: 014010 the Inner Mongolia Autonomous Region Baotou Kunqu District 4 on the east side of friendship

Applicant before: INNER MONGOLIA SHIXING NEW MATERIAL SCIENCE & TECHNOLOGY CO., LTD.

Applicant before: Zhang Guicai

Applicant before: Jiang Yanping

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant