CN105734611B - A kind of preparation method of novel energy-conserving anode steel claw - Google Patents

A kind of preparation method of novel energy-conserving anode steel claw Download PDF

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Publication number
CN105734611B
CN105734611B CN201510457676.8A CN201510457676A CN105734611B CN 105734611 B CN105734611 B CN 105734611B CN 201510457676 A CN201510457676 A CN 201510457676A CN 105734611 B CN105734611 B CN 105734611B
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welding
transverse arm
pawl head
cosolvent
anode steel
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CN105734611A (en
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姜彦平
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INNER MONGOLIA SHIXING NEW MATERIAL SCIENCE & TECHNOLOGY CO., LTD.
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Inner Mongolia Shixing New Material Science & Technology Co Ltd
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Abstract

A kind of novel energy-conserving anode steel claw, including transverse arm and pawl head, it is characterized in that;Transverse arm and pawl head are fixed together by electroslag molten welding;Preparation method is:It pawl head well prepared in advance and transverse arm parent Q235 blanks, is placed in the corresponding water cooling model cavity of anode steel claw structure, assembling positioning connection;The fluxing agent melted is poured into water cooling model cavity, startup power supply, cosolvent is by the process of melting refinement between the cuboid pawl head of fusion welding and cylinder metal transverse arm parent and metallurgical binding welding.Active rare-earth Elements C e in cosolvent carries out chemical reduction reaction, and rare earth element ce is made to enter fusion welding metal region alloying, purifies material.Another aspect liquid metal is comprehensive in melting welding volumetric region to be gradually risen and solidifies, to avoid shrinkage cavity, the generation of stomata casting flaw.The present invention is welded using whole electroslag molten welding, melting welding uniform temperature fields, fusion welding quality optimization, and properties of product intensity and toughness are high, and electric conductivity is superior.

Description

A kind of preparation method of novel energy-conserving anode steel claw
Technical field
The invention belongs to electrolytic aluminum anodic steel claw and its manufacturing technology fields, are especially a kind of new structural anode steel Pawl.
Background technology
The making of electrolytic aluminum anodic steel claw component requires dense structure, without casting flaw, and chemical composition is uniformly accurate, traditional Casting method making anode steel claw processing step is cumbersome, easily causes the secondary oxidation of molten steel, and degree of purity cannot be guaranteed, and The controllability of scaling loss elemental composition is poor.It is extremely difficult to the making requirement that electrolytic aluminum anodic steel claw resistivity is low, conducts electricity very well.
Invention content
The technical problem to be solved by the present invention is to provide a kind of special electroslag metallurgy welding process method and prepare Novel anode The method of steel claw component can improve the compactness of novel anode steel claw melting welding, obtain high quality, the production of high performance anode steel claw Product.
The purpose of the present invention is what is be accomplished by the following way:
A kind of novel energy-conserving anode steel claw, including transverse arm 1 and pawl head 2, it is characterized in that;Transverse arm 1 and pawl head 2 are molten by electroslag Weldering 3 is fixed together;
A kind of preparation method of above-mentioned novel energy-conserving anode steel claw is as follows:
(1)Previously prepared cuboid pawl head and cylinder metal transverse arm parent blank, blank material Q235, this 2 kinds Metal carrier body stock is placed in the corresponding water cooling model cavity of anode steel claw structure, is assembled positioning connection;
(2)The fluxing agent melted is poured into water cooling model cavity, startup power supply, the melting welding fluxing agent is by CeO2、 CaF2、CaCO3、AL2O3, composition, wherein each ingredient is by mass percentage:CeO2 5-18%、CaF2 43-58%、CaCO3 5- 15%、AL2O3 18-25%;
(3)Cosolvent is being exported two between the cuboid pawl head of fusion welding and cylinder metal transverse arm parent by transformer Secondary low-voltage and electric current cooperation, are formed into a loop in the slag bath that cosolvent is formed, and the electric energy of circuit input generates height in slag bath The heat of resistance, high activity, cosolvent slag bath temperature are 1600--18500C leads to the identical parent of chemical composition material and oneself It consumes consumable electrode and forms melting refinement and metallurgical binding welding;
(4)Chemical reduction reaction is carried out to the active rare-earth Elements C e in cosolvent, reducing agent is Si-Ca alloys, wherein Si:Ca is 30 by mass percentage:70, so that rare earth element ce is entered fusion welding metal region alloying, purifies material.On the other hand Liquid metal is comprehensive in melting welding volumetric region to be gradually risen and solidifies, to avoid shrinkage cavity, the generation of stomata casting flaw.
The present invention has the following advantages compared with the anode steel claw work that existing conventional preparation techniques technology makes:
1, traditional handicraft or existing welding procedure are avoided there are " pollution " of metallurgical quality in metallic object, is avoided due to system Uneven the influences welding quality of series of temperature in standby technique, the deficiency of obdurability and bring anode steel claw in Aluminum Electrolysis Production fortune Security risk during row.
During anode steel claw entirety electroslag molten welding process, active rare-earth chemical reaction handling novel technique makes melting welding Uniform temperature fields, fusion welding quality optimization, properties of product intensity and toughness are high, and electric conductivity is superior.
Compared with tradition prepares anode steel claw technique and existing welding procedure, hence it is evident that be that electroslag molten welding rare earth slag pond body is accumulated Loop process method is simple, scientific and reasonable, effective.Fully phase out existing unreasonable metallurgical method conventional cast, human weld Technique.Electroslag molten welding new process more meets the progress of melting welding product, has more, fast, good, province, scientific and reasonable.Because welding melting zone domain Reaction interface is increased, is the complete metallurgical fusion process of authenticity.
Apparatus and process is easy to operate, applied widely, can be flexible and changeable to the type of anode steel claw product, molten by changing Mounted welder just reaches the technology requirement of the steel pawl diameter and height that meet different size.
The novel technique melting welding activity duration is short, and producing cost is lower than traditional handicraft, cost-effective to avoid wasting.It produces simultaneously Product are more notable using rear energy-saving economic benefit.
Description of the drawings
Fig. 1 is anode steel claw structural schematic diagram in the prior art;
Fig. 2 is anode steel claw structural schematic diagram of the present invention.
Specific implementation mode
Embodiment 1
A kind of novel energy-conserving anode steel claw, including transverse arm 1 and pawl head 2, it is characterized in that;Transverse arm 1 and pawl head 2 are molten by electroslag Weldering 3 is fixed together;
A kind of preparation method of above-mentioned novel energy-conserving anode steel claw is as follows:
(1)Previously prepared cuboid pawl head and cylinder metal transverse arm parent blank, blank material Q235, this 2 kinds Metal carrier body stock is placed in the corresponding water cooling model cavity of anode steel claw structure, is assembled positioning connection;
(2)The fluxing agent melted is poured into water cooling model cavity, startup power supply, the melting welding fluxing agent is by CeO2、 CaF2、CaCO3、AL2O3, composition, wherein each ingredient is by mass percentage: CeO2 5-18%、CaF2 43-58%、CaCO3 5-15%、AL2O3 18-25%;
(3)Cosolvent is being exported two between the cuboid pawl head of fusion welding and cylinder metal transverse arm parent by transformer Secondary low-voltage and electric current cooperation, are formed into a loop in the slag bath that cosolvent is formed, and the electric energy of circuit input generates height in slag bath The heat of resistance, high activity, cosolvent slag bath temperature are 1600--18500C leads to the identical parent of chemical composition material and oneself It consumes consumable electrode and forms melting refinement and metallurgical binding welding;
(4)Chemical reduction reaction is carried out to the active rare-earth Elements C e in cosolvent, reducing agent is Si-Ca alloys, wherein Si:Ca is 30 by mass percentage:70, so that rare earth element ce is entered fusion welding metal region alloying, purifies material.On the other hand Liquid metal is comprehensive in melting welding volumetric region to be gradually risen and solidifies, to avoid shrinkage cavity, the generation of stomata casting flaw.
Anode steel claw of the present invention is using whole electroslag molten welding slag welding, melting welding uniform temperature fields, fusion welding quality optimization, product Performance Strength and toughness are high, and electric conductivity is superior.

Claims (1)

1. a kind of energy-conserving anode steel pawl, including transverse arm and pawl head, it is characterized in that:Transverse arm and pawl head are combined by electroslag molten welding to be fixed Together;
A kind of preparation method of above-mentioned energy-conserving anode steel pawl is as follows:
(1)Previously prepared cuboid pawl head and cylinder metal transverse arm parent blank, blank material Q235, this 2 kinds of metals Parent stock is placed in the corresponding water cooling model cavity of anode steel claw structure, is assembled positioning connection;
(2)The fluxing agent melted is poured into water cooling model cavity, startup power supply, the melting welding fluxing agent is by CeO2、CaF2、 CaCO3、AL2O3Composition, wherein each ingredient is CeO by mass percentage25-18%、CaF243-58%、CaCO35-15%、 AL2O318-25%;
(3)Cosolvent exported by transformer between the cuboid pawl head of fusion welding and cylinder metal transverse arm parent it is secondary low Voltage and current coordinate, cosolvent formed slag bath in be formed into a loop, circuit input electric energy generated in slag bath high resistance, The heat of high activity, cosolvent slag bath temperature are 1600--1850 DEG C so that the identical parent of chemical composition material and consumable are molten Polarizing electrode forms melting refinement and metallurgical binding welding;
(4)Chemical reduction reaction is carried out to the active rare-earth Elements C e in cosolvent, reducing agent is Si-Ca alloys, wherein Si:Ca It is 30 by mass percentage:70, so that rare earth element ce is entered fusion welding metal region alloying, purifies material.
CN201510457676.8A 2015-07-30 2015-07-30 A kind of preparation method of novel energy-conserving anode steel claw Active CN105734611B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108500241A (en) * 2018-05-10 2018-09-07 饶云福 Anode steel claw row's weldering one-step shaping manufacturing process

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105177626A (en) * 2015-09-22 2015-12-23 内蒙古世星新材料科技有限公司 Method for manufacturing novel energy-saving anode steel jaw
CN110079830A (en) * 2018-01-26 2019-08-02 洛阳富兴管业有限公司 Electrolytic aluminum anode pawl and the electrolytic aluminium equipment for using the anode claw
CN110170624B (en) * 2019-06-04 2023-10-13 甘肃酒钢集团西部重工股份有限公司 Crystallizer for steel claw and manufacturing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709384A (en) * 2009-11-26 2010-05-19 上海大学 Novel slag system for improving quality of electroslag remelted steel ingots
CN102534677A (en) * 2012-01-04 2012-07-04 饶云福 Device for repairing electrolytic aluminium anode steel claw by total cross-section fusion welding
CN102560552A (en) * 2012-01-04 2012-07-11 饶云福 Fusing agent for electrolytic aluminium anodic steel claws repairing
CN103769772A (en) * 2014-01-15 2014-05-07 王会智 Welding agent and welding method for welding anode steel claw
CN104139253A (en) * 2014-07-31 2014-11-12 新昌县雷凯科技有限公司 Welding agent formula and process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709384A (en) * 2009-11-26 2010-05-19 上海大学 Novel slag system for improving quality of electroslag remelted steel ingots
CN102534677A (en) * 2012-01-04 2012-07-04 饶云福 Device for repairing electrolytic aluminium anode steel claw by total cross-section fusion welding
CN102560552A (en) * 2012-01-04 2012-07-11 饶云福 Fusing agent for electrolytic aluminium anodic steel claws repairing
CN103769772A (en) * 2014-01-15 2014-05-07 王会智 Welding agent and welding method for welding anode steel claw
CN104139253A (en) * 2014-07-31 2014-11-12 新昌县雷凯科技有限公司 Welding agent formula and process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108500241A (en) * 2018-05-10 2018-09-07 饶云福 Anode steel claw row's weldering one-step shaping manufacturing process

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