CN102504988A

CN102504988A - A solid particulate laundry detergent composition comprising perfume particle

Info

Publication number: CN102504988A
Application number: CN2011103200260A
Authority: CN
Inventors: P·R·莫特三世; N·P·索默维尔罗伯茨; M·E·万兹特拉特; G·G·斯彭塔克; J·艾利斯; J·D·哈特乔普洛斯
Original assignee: Procter and Gamble Ltd
Current assignee: Procter and Gamble Ltd; Procter and Gamble Co
Priority date: 2006-04-20
Filing date: 2007-04-19
Publication date: 2012-06-20
Anticipated expiration: 2027-04-19
Also published as: CA2647429A1; RU2008138395A; JP2009532577A; EP2007866A1; US20170275576A1; US20070249512A1; BRPI0710543A2; CN101426896A; CA2645501A1; WO2007124370A1; WO2007146491A3; ZA200808683B; MX336769B; US20070249513A1; CN103446963A; MX2008013357A; CN103446963B; CN101443438B; RU2424283C2; CN101426896B

Abstract

The present invention relates to a solid particulate laundry detergent composition comprising: (a) from 0.1 wt % to 50 wt % of aesthetic particle; and (b) to 100 wt % of the remainder of the solid particulate laundry detergent composition, wherein the ratio of the median particle size in micrometers of the aesthetic particle (D50bead) to the median particle size in micrometers of the remainder of the solid particulate laundry detergent composition (D50base) is greater than 2.0:1, and wherein the relative jamming onset of the aesthetic particle (RJObead) is less than 9.0.

Description

Flowable particulates

The application is to be on April 19th, 2007, denomination of invention the applying date be the dividing an application of the application for a patent for invention of the PCT/US2007/066984 of " flowable particulates ", the one Chinese patent application of original application number is 200780013778.4.

Technical field

The present invention relates to flowable particulates and comprise this type of grains of composition; And the method for making and use this type of particle and product.

Background technology

Concerning most products, flowability is a kind of desired characteristics, because the facility that it provides branch to mix, thereby allow accurate and controlled dosing.Solid phase prod can not provide stable product perfusion or drainage rate in narrow whole streamer, especially when streamer width and product granularity narrow.Because solid phase prod can not provide required flowability, so product adopts especially liquid form of fluid usually.Regrettably, this type of fluid needs complicated feeding device, and perhaps they are dirty and messy, because they can drip behind feed, therefore can pollute the surface like vessel port or supporting feeding device.In addition, this type of pollution can cause container to be difficult to open again, because product can be adhered to the shedding motion of container on the tank body of container.In addition, for example carrying out liquid feeding the rigid container from container need add steam and flow out displacement volume to fill because of liquid.Therefore, if dosing carries out through narrow outlet, possibly need additional entrance.

Therefore, although disclose particle, referring to for example WO 2006/048142 A2; WO 2007/014601 A1 and USP 5,324,649, but what need is to flow right but do not have the particle of fluidic shortcoming to be similar to the fluidic mode.The particulate that this paper proposes has satisfied this type of demand.

Summary of the invention

The present invention relates to comprise the flowable particulates of some particulate and comprise this type of grains of composition; And the method for preparing and use this type of particle and product.

Detailed Description Of The Invention

Definition

Except as otherwise noted, term used herein " cleaning compsns " comprises granule type or powder-type is multi-functional or " heavy duty type " washing composition, especially cleaning detergent; The washing composition of detergent for washing dishware with hand or light-duty dishwashing agent, especially those high alveolitoids; The machine washing dish washing detergent; Collutory, denture cleanser, automobile or carpet lotion, bathroom detergent; Shampoo and hair conditioner; Bath gels and foam bath lotion and metal detergent; And cleaning assistant agent such as bleaching assistant or pre-treatment type auxiliary agent.

As used herein, the article " a kind of " that claims use and " one " are understood that to be meant one or more claims protection or described things of receiving.

As used herein, term " layer " is meant that bedded substance is on the microparticle surfaces or cover coatings part or whole that form on the said coating surfaces of at least a portion.

As used herein, term " product growth factor " is meant the ratio of quality product and initial seed quality.

As used herein, term " stratification speed " is defined as:

Stratification speed=M _Product/ (M _Seed* t _{Stratification})

M wherein _ProductBe the product total mass; M _SeedBe the initial seed total mass; t _{Stratification}For the stratification material is used the time.Under the situation of batch methods, t _{Stratification}Be the required time of stratification, comprise tackiness agent and stratification powder additive.Under the situation of continuation method, t _{Stratification}For the material total mass in stratification method unit operation divided by overall yield.

As used herein, term " product yield " is meant the ratio of net products quality and total product quality.The net products quality is measured after the back stratification is handled, back stratification processing such as but be not limited to drying, elutriation and classification.The total product quality be after the stratification but the quality product before the back stratification is handled.

As used herein, term " earning rate " is meant the product of stratification speed and product yield: earning rate=(product yield) * (stratification speed).

As used herein, term " seed " is meant any particulate that the ability tegillum applies or part applies.Therefore, " seed " can be made up of the initial seed particulate, or is made up of the seed of the first Front-coating mirror with any amount.

As used herein, term " critical gap size " is meant the circular diameter of the maximum that can connect in fully with open plane porose area, and said plane porose area is vertical with the product flow direction in the said hole of flowing through.

As used herein, term " independent streamer " is meant that said streamer is physically separated and/or isolating in time.In an example, independent streamer is meant the charging streamer of isolating tackiness agent and stratification powder.In mixing process, tackiness agent and stratification powder at one time but spatially isolating position add.And for example, in the mixing process of using one or more entrance location, tackiness agent and stratification powder add at different time.

As used herein, term " swept volume " is meant the volume that during the whole process rotation of axle, was swept away by the mixing tool that is connected to rotating shaft.

As used herein, term " hydration material " is meant and can reacts to form the solid matter of solid hydrate with water or aqueous compsn.

Should be appreciated that when these inventions and describe and receive claims when protection in this article, must use in the application's the Test Methods section disclosed testing method to measure each parameter value that the applicant invents.

Except as otherwise noted, all components or composition levels all relate to the activity substance content of that component or compsn, and do not comprise the impurity that possibly be present in the commercially available source, for example residual solvent or by product.

Except as otherwise noted, all per-cents and ratio are all calculated by weight.Except as otherwise noted, all per-cents and ratio all calculate based on total compsn.

Should be appreciated that each the greatest measure limit that in whole specification sheets, provides comprises the numerical value limit that each is lower, write out the same in this article clearly with regard to low numerical value limit like this.Each the minimum value limit that in whole specification sheets, provides comprises each high value limit, is write out the same in this article clearly with regard to high value limit like this.Each numerical range that in whole specification sheets, provides comprises each the narrower numerical range that drops in this broader numerical, is write out the same in this article clearly with regard to narrower numerical range like this.

Particle

Particle disclosed herein can provide controlled dosage, and does not have the shortcoming relevant with fluid product.Because many products all expect to have mobile beneficial effect, therefore in one aspect, said particle can be an industrial chemical; Edible food, instant drinks mixture, medicine or nutritious prod; Pet food and/or pet nursing particle; Or washing composition, fabric treating, personal cleanliness, hair-care and/or fertiliser granulates.Applicant's particle form can be used for any application, and especially its desired has mobile application, for example cleans and/or treat product, industrial chemical, fertilizer, medicine, food, pet food, instant drinks and nutritious prod.

In one aspect, applicant's particle has about 2 to about 14, about 2.5 to about 12, about 3 to about 10, or even the about 4 relative obstruction starting points to about 8 particulates.On the other hand, applicant's particle has about 250 microns to about 4,000 microns, about 300 microns to about 1,200 micron, about 400 microns to about 1000 microns, about 500 microns to about 850 microns, or even about 600 microns to about 750 microns median particle.On the other hand, applicant's particle has about 1.0 to about 1.75, about 1.05 to about 1.6, about 1.1 to about 1.45, or even about 1.1 to about 1.3 size-grade distribution span.On the other hand, applicant's particle has about 350 grams per liters to about 2000 grams per liters, about 500 grams per liters to about 1200 grams per liters, about 600 grams per liters to about 1100 grams per liters, or even the bulk density of about 700 grams per liters to about 1000 grams per liters.On the other hand, applicant's particle has about 1.0 to about 1.4, about 1.05 to about 1.3 or even about 1.1 to about 1.25 intermediate value particle aspect ratios.In one aspect, applicant's particle can comprise the particulate that comprises seed and coating, and said coating applies said seed at least in part.In one aspect, applicant's particle can comprise the particulate that comprises seed and coating, and said coating comprises tackiness agent and stratification powder and said coating and applies said seed at least in part.On the other hand, applicant's particle can comprise the particulate that comprises a plurality of seeds, has enumerated 1,2,3,4,5,6,7,8,9 or even 10 seeds through limiting examples.On the other hand, applicant's particle can comprise the particulate that comprises a plurality of discrete coatings, has enumerated 1,2,3,4,5,6,7,8,9 or even 10 coatings through limiting examples.On the other hand, applicant's particle can comprise the particulate that comprises multiple binder substance, has enumerated 1,2,3,4,5,6,7,8,9 or even 10 kinds of binder substances through limiting examples.On the other hand, applicant's particle can comprise the particulate that comprises multiple stratification powder, has enumerated 1,2,3,4,5,6,7,8,9 or even 10 kinds of stratification powder through limiting examples.In one aspect, applicant's particulate tackiness agent can comprise a kind of oil, for example spice oil, nutritional oil and/or local flavor oil.

In one aspect, applicant's particle comprises acidity and alkaline matter.Effervesce when in one aspect, applicant's particle contacts with water.

The suitable material that is used to make above-mentioned particulate depends on the application of end product.This type of material is that the technician is known, yet they can comprise that such as seed material, binder substance and stratification powder mass-every kind above-mentioned substance can be active substance or nonreactant.

Seed material generally can be used the feed material of particle grades.Said feed can be the starting material available from supplier, or the intermediate particle of being produced by the granulating process of any amount.Suitable seed can have about 150 microns to about 1700 microns, about 200 microns to about 1200 microns, about 250 microns to about 850 microns, or even about 300 microns about 600 microns median particle diameters extremely; About 50 grams per liters are to about 2000 grams per liters, about 200 grams per liters to about 1650 grams per liters, about 350 to about 1200 grams per liters or even the seed bulk density of about 400 grams per liters to about 850 grams per liters; About alternatively 1.0 to about 2.0, about 1.05 to about 1.7, or even about 1.1 to about 1.5 size-grade distribution span; About alternatively 1 to about 2, about 1 to about 1.5, or even about 1 to about 1.3 intermediate value particle aspect ratios.When as washing composition, suitable active seed material includes but not limited to be selected from the material by the following group of forming: tensio-active agent, washing assistant, buffer reagent, soluble polymeric thing, white dyes and their mixture.In some applications, active oil base component can be mixed in fusing carrier such as Tristearoylglycerol or wax, and granulating is to form the solid seed then.Can in active seed, mix stablizer, inhibitor and sanitas.Suitable inertia seed material includes but not limited to be selected from the material by the following group of forming: salt, two salt, starch, sugar and their mixture.In one aspect, the porous seed can be used as the carrier of other active substance, and said other active substance includes but not limited to spices, flavour agent, VITAMINs, nutritional oil and their microcapsule.In one aspect, said active substance is not a tensio-active agent.In one aspect, hollow minute particle can be used as seed.In one aspect, capsule can be used as seed, and said capsule comprises the wall of encapsulating substance, and said material is such as being spices, flavour agent, VITAMINs, nutritional oil and their mixture.

The disclosed seed of this specification sheets can have median particle diameter, seed bulk density, size-grade distribution span, intermediate value particle aspect ratios and the preceding text of arbitrary combination and component type and the number that present patent application full text (comprising claim and embodiment) details.

Suitable reactive adhesive material includes but not limited to be selected from the material by the following group of forming: acid surfactant precursor, tensio-active agent, polymers soln or its acidic precursor, organosilicon, chelating agent solution, silicate solutions, cellulosic solution or dispersion-s, dye solution, pigment dispersion, melt polymer, fusing wax, melting fatty acid, nutritional oil and their mixture.Suitable inert binder material includes but not limited to be selected from the material by the following group of forming: water, salts solution, sugar soln and their mixture.Suitable tackiness agent can include but not limited to be in solution, dispersion-s or the milk sap of the active substance in activity or the inertia base-material.The instance of active substance includes but not limited to oily solvend such as mixed tocopherol, BHT, gallate, ubiquinone, xitix aliphatic ester, beta carotene and polyphenol.Suitable sticker can have about 0.5cp to about 4000cp, and about 1cp is to about 2000cp, and about 2cp is about 1000cp extremely, and about 5cp is about 600cp extremely, or even about 20cp viscosity of about 400cp extremely.Do not accept the constraint of opinion; It is believed that suitable tackiness agent can play following effect in applicant's method: the surface of at first wetting seed particle; Make the viscosity of seed particle be enough to the stratification powder is attached on the kernel texture; Most preferably pass through chemistry or physical conversion then, change solid phase or half solid phase into from liquid.In one aspect, liquid adhesive can be transformed into solid phase via chemical reaction with the stratification powder.In one aspect, need the stratification powdered reaction thing of molar excess to transform completely basically to realize the adhesive reaction thing.In one aspect, liquid adhesive can be transformed into solid phase from the heat fusing state via cooling curing.In one aspect; The active liquid tackiness agent can at first mix with melt adhesive; The mixed adhesive system is through combination changes into solid phase with the cooling agglomerative with the chemical reaction of stratification powder then, the excessive stratification powdered reaction thing that possibly need when therefore reducing reactive adhesive and using separately.In one aspect, liquid adhesive can be via being transformed into solid phase with another kind of binder compsn generation chemical reaction.In one aspect, liquid adhesive can be transformed into solid phase via solvent evaporation.In one aspect, tackiness agent can comprise liquid.

Suitable active stratification powder mass includes but not limited to be selected from the material by the following group of forming: tensio-active agent, soluble polymeric thing, washing assistant, buffer reagent, starch, white dyes, dyestuff, pigment and their mixture.Suitable inertia stratification powder mass includes but not limited to be selected from the material by the following group of forming: salt, two salt, sugar, starch, polymkeric substance, pigment, dyestuff and their mixture.Can other active substance, stablizer, sanitas or inhibitor be incorporated in the exsiccant stratification powder, comprise xitix, saccharosonic acid, ascorbic acid fatty acid ester, hydrosulphite, pyrophosphate salt, hydroxy ethylene diphosphonic acid tetra-na salt (HEDP), EDDS trisodium salt (EDDS), sequestrant such as Hydrocerol A, ethyloic L-glutamic acid tetra-na salt (Dissolvine

or GLDA), methylglycine oxalic acid trisodium salt (Trilon

M or MGDA), NSC 446 five acetic acid (DTPA) and YD 30 (EDTA) and herbage extract such as rosemary extract.In one aspect, the stratification powder composition comprises at least a hydration material.Suitable stratification powder can have about 1 micron to about 100 microns, and about 2 to about 50 microns or even about 3 microns about 30 microns median particle extremely.Aspect of applicant's invention, can use the drying solid kibbler that the granularity of stratification material is reduced to required granularity.Suitable kibbler can be available from Hosokawa Alpine Aktiengesellschaft & Co.OHG, Augsburg, Germany; Netzsch-Feinmahltechnik GmbH, Selb/Bayern, Germany; RSG Incorporated, Sylacauga, Alabama, USA.In one aspect, can use prototype on a small scale.For example, can use desk-top pulverizing mill to reduce the granularity of stratification powder; Suitable desk-top pulverizing mill can derive from Retsch GmbH, Haan, Germany.

In one aspect, the seed of particulate can comprise active substance and one deck coating at least, and said seed comprises active substance such as reactive adhesive, active stratification powder or their mixture.On the other hand, particulate can comprise inertia seed and one deck coating at least, and said seed can comprise active substance such as reactive adhesive, active stratification powder or their mixture.On the other hand, said particulate can comprise seed, and said seed can comprise active substance and one or more inert layer.

In one aspect, the activeconstituents of particulate can comprise hygroscopic material.

On the other hand described, said hygroscopic material is arranged in seed or endothecium structure, and is outer relatively low or do not have hygroscopic material and form by water absorbability.In one aspect, applicant's particle has about 2 to about 18, about 2 to about 14, about 2.5 to about 12, about 3 to about 10, or even about 4 blocks starting point relatively to the fast and stable property of about 8 particulates.

Use according to it, the suitable material that is used for seed, tackiness agent and/or stratification powder can be available from a plurality of suppliers.For the selected application that comprises washing composition and cleaning formulation, food, pet food, medicine, nutritious prod and agricultural chemicals, material can be available from Innophos, Incorporated, Cranbury, NJ, USA; Rhodia, Paris, France; FMC Corporation, Philadelphia, Pennsylvania, U.S.A.; Jost Chemicals, St.Louis, Missouri, U.S.A.; General Chemical Corporation, Parsippany, New Jersey, U.S.A.; Ulrich Chemicals, Indianapolis, Indiana, U.S.A.; Jones-Hamilton Company, Walbridge, Ohio, U.S.A.; Sigma Aldrich Corporation, St.Louis, Missouri, U.S.A., Cargill Incorporated, Minneapolis, Minnesota, U.S.A.; International Ingredient Corporation, St.Louis, Missouri, U.S.A.; National Starch Corporation, Bridgewater, New Jersey, U.S.A.; PQ Corporation, Philadelphia, Pennsylvania, U.S.A.; BASF, Ludwigshafen, Germany; Dow Chemical Company, Midland, Michigan, U.S.A.; Hercules Incorporated, Wilmington, Delaware, U.S.A.; Shell Chemical LP, Houston, Texas, U.S.A.; Procter & Gamble Chemicals, Cincinnati, Ohio, U.S.A.; Rohm and Hass Company, Philadelphia, Pennsylvania, U.S.A.; Akzo Nobel, Arnhem, NL; Ciba Specialty Chemicals Corporation, Newport, Delaware, U.S.A.; Clariant Corporation, Charlotte, North Carolina, U.S.A.; And Milliken Chemical Company, Spartanburg, South Carolina, U.S.A.

The disclosed particle of this specification sheets can have relative obstruction starting point, median particle, size-grade distribution span, bulk density, intermediate value particle aspect ratios and the preceding text of arbitrary combination and component type and the number that present patent application full text (comprising claim and embodiment) details.

The particulate method of manufacture

Particulate of the present invention and/or other particulate can be made as follows:

In one aspect; Particulate can be made through in counter-rotating twin shaft paddle stirrer, particulate is contacted with the tackiness agent that comprises liquid; The orientation of wherein said axle and the oar level that is connected to reversing shaft, and said tackiness agent is introduced in said whisking appliance through the import that is arranged in said twin shaft paddle stirrer bottom.

In one aspect, said counter-rotating twin shaft paddle stirrer has the convergent flow zone between anti-rotary propeller type axle.In one aspect, the sweep volume of said anti-rotary propeller type axle is at the convergent flow region overlapping.In one aspect, the sweep volume of said anti-rotary propeller type axle is not overlapping in the convergent flow zone.In one aspect, there is the gap in the convergent flow zone between the sweep volume of said anti-rotary propeller type axle.

In one aspect, said tackiness agent is introduced in the said counter-rotating twin shaft paddle stirrer, makes said tackiness agent upwards get into the convergent flow zone between anti-rotary propeller type axle.In one aspect; Said counter-rotating twin shaft paddle stirrer has the convergent flow zone between anti-rotary propeller type axle; And the swept volume of said anti-rotary propeller type axle is not overlapping in the convergent flow zone, and said tackiness agent is introduced in the gap between said anti-rotary propeller type axle swept volume.

In one aspect, said tackiness agent has about 1cp to about 100000cp, and about 20cp is to about 10000cp, and about 50cp is about 5000cp extremely, or even about 100cp viscosity of about 2000cp extremely.

In one aspect, said import comprises the distribution piping of the below, convergent flow zone that is positioned at anti-rotary propeller type axle, and said distribution piping comprises one or more holes.

Disclosed particulate also can prepare through guidance disclosed herein and embodiment among the application.Although possibly only need the independent unit of mixing, still can adopt a plurality of whisking appliances, for example increase the cascade whisking appliance of volume capacity gradually.Of the present invention any above-mentioned aspect, said tackiness agent can comprise liquid.

In one aspect, particulate disclosed herein can be produced through the method that may further comprise the steps:

A.) seed of stratification certain mass, said seed has:

(i) about 150 microns to about 1700 microns, about 200 microns to about 1200 microns, about 250 microns to about 850 microns or even about 300 microns to about 600 microns median particle diameter;

(ii) randomly about 1.0 to about 2.0, about 1.05 to about 1.7, or even about 1.1 to about 1.5 size-grade distribution span;

(iii) about 50 grams per liters are to about 2000 grams per liters, about 200 grams per liters to about 1650 grams per liters, about 350 grams per liters to about 1200 grams per liters or even the seed bulk density of about 400 grams per liters to about 850 grams per liters; With

(iv) randomly about 1 to about 2, about 1 to about 1.5, or even about 1 to about 1.3 intermediate value particle aspect ratios;

Said stratification method comprises that the seed that makes said quality independently contacts with the stratification powder with liquid adhesive; And randomly repeat said stratification step; Wherein said stratification powder has about 1 micron to about 100 microns, about 2 microns to about 50 microns or even about 3 microns to about 30 microns median particle;

B.) randomly, handling said particulate anyly will cause said particulate to have the material greater than about 14 relative obstruction starting point to remove.

A.) seed of stratification certain mass, said seed has:

(ii) randomly about 1.0 to about 2.0, about 1.05 to about 1.7, or even about 1.1 to about 1.5 size-grade distribution span.

(iv) randomly, about 1 to about 2, about 1 to about 1.5, or even about 1 to about 1.3 intermediate value particle aspect ratios;

B.) said stratification method comprises that independently the seed with said quality contacts with the stratification powder with tackiness agent, and randomly repeats said stratification step, and wherein said tackiness agent has about 0.5cp to about 4000cp; About 1cp is to about 2000cp; About 2cp is to about 1000cp, and about 5cp is about 600cp extremely, or even about 20cp viscosity of about 400cp extremely; Said stratification powder has about 1 micron to about 100 microns, about 2 to about 50 microns or even about 3 microns to about 30 microns median particle;

C.) randomly, with greater than 0 to about 10, about 0.001 to about 10, or even about 0.01 to about 5 stratification stokes number carry out said method;

D.) randomly, with at least 0.5, about 1 to about 1000, or even about 2 to about 1000 coalescence stokes number carry out said method;

E.) randomly, handling said particulate anyly will cause said particulate to have the material greater than about 14 relative obstruction starting point to remove.

On the other hand, particulate disclosed herein can be produced through the method that may further comprise the steps:

A.) seed of stratification certain mass and tackiness agent and stratification powder; Said method comprises that independently the seed with said quality contacts with said stratification powder with said tackiness agent; Said method is with greater than 0 to about 10; About 0.001 to about 10, or even about 0.01 to about 5 stratification stokes number carry out; And with at least 0.5, about 1 to about 1000, or even about 2 to about 1000 coalescence stokes number carry out; With

B.) randomly according to above a.) method parameter with the seed stratification one or many of said quality; With

C.) randomly, handling said particulate anyly will cause said particulate to have the material greater than about 14 relative obstruction starting point to remove.

In one aspect, handle said particulate to remove excessive binder liq.In one aspect, said tackiness agent is the aqueous solution or dispersion-s, and excessive binder liq is a water.In one aspect, said processing comprises that convection current is air-dry.In one aspect, said convection current is air-dry carries out after the stratification process.In one aspect, said stratification process is divided into several timed intervals, and said convection current is air-dry to be carried out when each finishes at interval.In one aspect, said convection current is air-dry carries out during the stratification process.Suitable convection current apparatus for drying comprises fluidized-bed or fluid bed dryer, derives from Niro Inc., Columbia, Maryland, USA; Kason Corporation, Millburn, New Jersey, USA; Allgaier Werke GmbH, Uhingen, Germany; Glatt Ingenieurtechnik GmbH, Weimar, Germany; With Bepex International LLC, Minneapolis, Minnesota, U.S.A..Can be through deriving from Forberg International AS, Larvik, Norway and Dynamic Air Inc.; St.Paul; Minnesota increases one or more stratification powdering inlets in the equipment of USA, revise the whisking appliance that obtains suiting; Said suitable whisking appliance has the convection current apparatus for drying of one, is used for carrying out drying or even in the stratification process, carrying out drying in the timed interval of stratification process.

In one aspect; The said independently seed of said quality and the tackiness agent that comprises liquid contacts with the stratification powder comprises and makes said tackiness agent get into counter-rotating twin shaft paddle stirrer; Make said tackiness agent upwards get into the convergent flow zone between anti-rotary propeller type axle, said counter-rotating twin shaft paddle stirrer has the convergent flow zone between anti-rotary propeller type axle.

In one aspect; The said seed that makes said amount independently and the tackiness agent that comprises liquid contact with the stratification powder and comprise and make said stratification powder get into counter-rotating twin shaft paddle stirrer and mix oar; Make said stratification powder get into a plurality of said positions that are arranged in the descending path that mixes oar; Said whisking appliance has a plurality of stratification powder inlet position, and said mixing oar has descending path.

In one aspect, the stratification speed of said method be greater than about 5% quality/minute, greater than about 10% quality/minute, greater than about 20% quality/minute, greater than about 30% quality/minute, or even greater than about 40% quality/minute.

In one aspect, the stratification speed of said method is about 5% quality/minute to about 200% quality/PM.

It is favourable that too small and/or excessive product is minimized, however this type of too small and/or excessive product still can occur, can handle to remove too small and excessive product said particulate.In one aspect, can this type of too small and excessive product be removed, be recovered to then in this process and further process.In one aspect, said excessive product was somebody's turn to do the Cheng Qian and can processes through the cage shredder reclaiming back.The suitable shredder that is used for excessive product can derive from Stedman Machine Company, Aurora, Indiana, USA and Otsuka Iron Works, Ltd., Tokyo, Japan.In one aspect, can be through at equipment such as vibration screen, fluidized-bed, gas lift equipment and/or have in the additional air fluidizing whisking appliance screening and/or miscellaneous goods such as wear debris is crossed in elutriation and excessive non-absorption stratification powder removed miscellaneous goods.In one aspect, in air elutriation step, can combine the gas heated convection air-dry.

In one aspect, the said miscellaneous goods of crossing is crossed the Cheng Qian and can be processed through high-speed grinder going into this as the stratification Powder Recovery.Suitable high-speed grinder can derive from Hosokawa Alpine Aktiengesellschaft & Co.OHG, Augsburg, Germany; Netzsch-Feinmahltechnik GmbH, Selb/Bayern, Germany; RSG Incorporated, Sylacauga, Alabama, USA.

In one aspect, can use excessive particulate to be screened out and handle said particulate such as the such equipment of vibration screen.Be suitable for screening out vibration screen excessive and small particle excessively and can derive from Sweco, Florence, Kentucky, USA; Kason Corporation, Millburn, New Jersey, USA; Mogensen GmbH, Wedel/Hamburg, Germany.

In one aspect, comprise that independently the seed with said quality is selected from following method with the said stratification method that tackiness agent contacts with the stratification powder: the seed of certain mass is contacted with the independent streamer of said tackiness agent and said stratification powder; The seed of said quality is contacted with the streamer of said tackiness agent in first location, said seed-binder blend is contacted in the second position with the streamer of said stratification powder; The seed of certain mass is contacted in first location with the streamer of said stratification powder, said seed-powdered mixture is contacted, perhaps their combination with the streamer of said tackiness agent in the second position.When a plurality of coating of needs, can repeat said contact process one or many.In one aspect, said stratification method can include but not limited to randomly that air elutriation step to remove any excessive small particle excessively, makes it not mix coating.

In one aspect, use the colter whisking appliance of band cutting knife, said cutting knife is between colter, and wherein the tackiness agent import is positioned the below of cutter location, and the stratification powder inlet is positioned at the top of cutter location.Suitable colter whisking appliance can available from: Lodige GmbH (Paderborn, Germany); Littleford Day, and Inc. (Florence, Kentucky, U.S.A.).Aspect this, the circumference convection current that is caused by main colter impeller makes seed replace contact adhesive and stratification powder.In one aspect, use the wherein entrance location colter whisking appliance separated from one another in the axial direction of tackiness agent and stratification powder.In one aspect, use tackiness agent and stratification powder at continuous colter whisking appliance axial and/or that circumferential direction is separated from one another.

In one aspect, use counter-rotating twin shaft paddle stirrer, wherein said reversing shaft is a horizontal alignment, moves along up path in the space of oar between parallel reversing shaft of rotating shaft and be connected to, and descending path returns in the axle outer.Suitable counter-rotating twin shaft paddle stirrer can be available from Forberg International AS, Larvik, Norway; And Dynamic Air Inc., St.Paul, Minnesota, USA.The motion of oar between axle forms the convergent flow zone, causes the basic fluidisation at the particulate at whisking appliance center.At the whisking appliance on period, the inclination of the oar on each can cause relative stream field in the axial direction, thereby in the convergent flow zone, produces additional shear field.The descending path of the oar outside axle forms descending convection current.

In one aspect, below the horizontal plane of oar axle, has a narrow docking point, for example less than the gap docking point of about 2cm at the blade tip end and the gap of stirring between the wall.In one aspect, below said horizontal plane, crooked stirring wall has formed the volume that only is slightly larger than the swept volume of oar.In one aspect, narrow gap docking point is extensible to the top of horizontal axis plane, for example through extending the bend that stirs wall or passing through to increase lining such as coverture.Do not accept the constraint of opinion, the applicant believes that Froude number is especially worked as greater than for the moment in the said shear field that provides more consistent in the whisking appliance that extends in of close clearance docking point, that is, and and when the inertial acceleration of oar surpasses terrestrial attraction.Do not accept the constraint of opinion, the applicant believes, alleviated material in the said extension of the close clearance docking point above the horizontal axis plane and accumulated in the possibility on the wall, thereby increased product yield.

In one aspect, use counter-rotating twin shaft paddle stirrer, wherein the tackiness agent import is via the top-spray device in the fluidisation area of center, and the stratification powder inlet is positioned at the side or the turning of whisking appliance, and they get into descending convection current.In one aspect; Use counter-rotating twin shaft paddle stirrer; The tackiness agent import wherein is provided so that upwards add tackiness agent, and the stratification powder inlet is positioned at side or corner location, so that the stratification powder is joined in the descending convection current of whisking appliance to the zone of the convergent flow between the anti-rotary propeller type axle.In one aspect, can the import of tackiness agent or stratification powder be provided through stirring interior opening of wall or the opening in the whisking appliance lining (such as coverture).In one aspect; The said tackiness agent that upwards adds can be accomplished through the increase and the adhesive dispense pipe of the axially parallel of whisking appliance to the moving zone of converging streams; Said distribution piping has one or more holes, and wherein said whisking appliance has carried out revising to allow the said distribution piping of butt joint below the convergent flow zone.In one aspect, tackiness agent can upwards add in the convergent flow zone through one or more tackiness agents interpolation pipes or nozzle, and wherein said whisking appliance has carried out revising to allow the lower position in the convergent flow zone to pass through to stir wall butt tube or nozzle.In one aspect, the decoration form of said stratification powder inlet makes said powder get into the descending oar path of twin shaft paddle stirrer.In these cases, the convection current that causes of blade impeller makes seed can replace contact adhesive and stratification powder in the separation point position of whisking appliance.The entrance location of a plurality of stratification powder is provided in one aspect.Do not accept the constraint of opinion, the applicant believes that these type of a plurality of positions form a plurality of convective loops, and seed replaces contact adhesive and stratification powder in these loops.In addition, do not accept the constraint of opinion, the applicant believes that the quantity that increases convective loop helps the expansion of stratification method.Do not accept the constraint of opinion, the applicant believes that the selection of whisking appliance can be depending on the seed intensity with respect to the shearing resistance in the whisking appliance.

In one aspect, the number of times that can repeat said stratification step sufficient amount to be increasing granular mass, and quality increases the factor to be compared with initial seed quality approximately greater than two times, approximately greater than four times, or even approximately greater than six times.

In one aspect, the number of times that can repeat said stratification step sufficient amount is to increase granular mass, and quality increases the factor and is in a ratio of about 2 to about 100 with initial seed quality.

In one aspect, said stratification step can be carried out in an independent whisking appliance batch methods.

In one aspect, said stratification step can be carried out in two or more batch methods sequences.

In one aspect, said stratification step can be carried out in the batch methods whisking appliance sequence of two or more volume capacities with increase with the product volume that adapts to increase.

In one aspect, said stratification method can use a series of one or more whisking appliance to carry out.In one aspect, the product particle with first whisking appliance is used as the seed grain of whisking appliance thereafter.In one aspect, can remove excessive material through screening, this type of excessive material can reduce size through grinding, and this type of abrasive material can be sent to one or more process whisking appliances through for example circulation loop, and therein as seed material.In one aspect, said whisking appliance series is arranged to continuation method, said method has the inflow of successive seed and product particle flows out.

In one aspect, said stratification method is processed acceptable product particle, and said particle does not have excessive or too small tailing.In one aspect, said tailing comprises the material of processing that is lower than 20% quality, is lower than 10% quality or even is lower than 5% the material of processing.In one aspect, product yield is greater than 80% quality, greater than 90% quality or even greater than 95% quality.In one aspect, said earning rate greater than about 4% quality/minute, greater than about 8% quality/minute, greater than about 16% quality/minute, greater than about 24% quality/minute, greater than about 32% quality/minute, or even greater than about 40% quality/minute.

In one aspect, the seed of said quality and stratification powder still get into said method at substantially the same physical location in different time.

In one aspect, said method can have approximately greater than 0 minute to about 60 minutes, and about 1 minute to about 60 minutes, about 1 minute to 30 minutes, or even about 2 minutes to 15 minutes average particle residence time.

On the other hand, applicant's particulate can prepare through the method that need not the certain mass seed.In one aspect, can use extrude/spheronization prepares composite particles.Extrude/rolling circle equipment can derive from LCI Corporation, Charlotte, North Carolina, U.S.A.On the other hand, material can be processed, spray from melted state, condenses into solia particle with granulating-coagulation method then.On the other hand, can use granulating-drying means to form particulate, use small these particulates of stratification powder coating then around the droplet template.Granulating-condense and granulating-drying plant can derive from GEA/Niro, Columbia, Maryland, U.S.A.

The technician will understand that, all respects of aforesaid method and being seen aspect those in full at this specification sheets comprise embodiment, can make up through required any way to obtain the particulate of required type and quality.

The applicant recognizes, can use the stokes number to define the parameter in stratification and the agglomeration process.Likewise, applicant's method can be implemented according to following processing parameter: stratification stokes number is less than 10, about 0.001 to about 10 or even about 0.001 to about 5, and coalescence stokes number is greater than 0.5, about 1 to about 1000 or even about 2 to about 1000.Above-mentioned stokes number can calculate as follows:

St _{Whisking appliance}=(0.0001) NR ρ δ/η

Variable in the above-mentioned formula can offer some clarification on following unit:

N is the velocity of rotation (rotations per minute is abbreviated as RPM) of main paddle wheel shaft in the whisking appliance;

R is the radius scanning distance of main paddle wheel, promptly from center to the impeller instrument of the impeller shaft tip (rice is abbreviated as m) of oar or colter impeller instrument for example;

ρ is the bulk density (grams per liter is abbreviated as g/L) of seed particle;

η is adhesive viscosities (centipoise is abbreviated as cp); With

δ is used to describe stratification or agglomerant effective size of grain (micron is abbreviated as um), wherein:

δ _{Stratification}Be defined as 2 (d _SeedD _{Stratification})/(d _Seed+ d _{Stratification}), and

δ _CoalescenceBe defined as d _SeedWherein

d _SeedBe the median particle diameter of seed material, and

d _{Stratification}Median particle diameter for the stratification powder mass.

Based on mentioned above, two sub-forms of definable stokes formula, one is used to describe the combination (St of stratification powder on seed particle _{Stratification}), and another is used to describe the coalescence (St of seed particle and other seed _Coalescence).

Stratification stokes number, St _{Stratification}=(0.0001) NR ρ δ _{Stratification}/ η

Coalescence stokes number, St _Coalescence=(0.0001) NR ρ δ _Coalescence/ η

In order to calculate said stokes number, the correlation properties of seed, stratification powder and tackiness agent are based on it and add the measured value that the Cheng Qian is crossed in stratification.In two or more whisking appliance level sequences, carry out compound stratification process aspect, the stokes number of each grade be based on the beginning or import or in each grade place with the characteristic bulk density and the size of seed material.Use the stratification process add more than a kind of tackiness agent simultaneously aspect, use the volume-weighted mean of tackiness agent to calculate the stokes number.Use the stratification process add more than a kind of stratification powder simultaneously aspect, use the quality-weighted mean of stratification powder median particle to calculate the stokes number.

The suitable equipment that is used to carry out method disclosed herein comprises paddle stirrer, transverse axis paddle stirrer, twin shaft paddle stirrer, counter-rotating twin shaft paddle stirrer, colter formula mixing tank, ribbon-type blender, Z-axis nodulizer and rotating cylinder whisking appliance, and both having can be in batch, method construct also can be continuation method structure (but when time spent).This kind equipment can available from Lodige GmbH (Paderborn, Germany), Littleford Day, Inc. (Florence, Kentucky; U.S.A.), and Dymanic Air (St.Paul, Minnesota, USA); S.Howes, and Inc. (Silver Creek, NY, USA); Forberg AS (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany).

In one aspect, use said method to produce prototype on a small scale.Can use desk-top Z-axis whisking appliance to make this type of prototype.The suitable equipment that is used to carry out said method disclosed herein comprises culinary whisk, blade culinary whisk, food processor, blade food processor and speed change food processor.This kind equipment comprises Braun, Kenwood, Bosch, Delonghi, Robot Coupe and other commercial brand, can derive from retail store, department store, electrical appliance shop and equipment shop, restaurant.

Comprise the particulate finished product

Finished product of the present invention is included in disclosed particulate embodiment in the present patent application.Although the accurate level of the particulate that adopts depend on finished product type and end-use; But aspect of applicant invention, finished product can comprise in total product weight minimum 50,60,70,80 or even the particle of the present invention-said particle of 90 mass percents can comprise the particulate that one or more are different.

In one aspect, said finished product can have about 2 to about 14, about 2.5 to about 12, about 3 to about 10, or even the about 4 relative obstruction starting points to about 8 particulates.

In one aspect, said finished product can have about 2 to about 14, about 2.5 to about 12; About 3 to about 10; Or even about 4 relative obstruction starting points and about 2 to about 18, about 2 to about 14, about 2.5 to about 12 to about 8 particulates; About 3 to about 10, or even about 4 block starting point relatively to the fast and stable property of about 8 particulates.In one aspect, said finished product is: industrial chemical; Edible food, instant drinks mixture, medicine or nutritious prod; Pet food and/or pet care product; Or washing composition, fabric treating, personal cleanliness, hair-care and/or fertilizer product.In one aspect, this type of finished product can be that the inventory dishwashing is washed product.

When said finished product was cleaning compsns, the disclosed said cleaning compsns of this paper was formulated into usually during being used for aqueous clean operation and makes washing water have the pH value between about 6.5 and about 12 or between about 7.5 and 10.5.Can prepare the particle dish cleaning product preparation that can be used for the dish hand washing, so that the washing liq with the pH value between about 6.8 and about 9.0 to be provided.Cleaning article is configured to usually has about 7 to about 12 pH value.Be used for pH regulator to the technology of recommending usage level is included but not limited to use buffer reagent, alkali, acid etc., and be that those skilled in the art knows.

Wrapped product

In one aspect, applicant's invention can comprise wrapped product, and said wrapped product comprises the finished product that can comprise particulate embodiment disclosed herein.Said wrapped product can comprise said particulate at least a portion and hole with critical gap size, and said critical gap is of a size of approximately greater than the absolute obstruction starting point of said finished product but less than four times, less than 3 times or less than 2 times said absolute obstruction starting point.In one aspect, the present invention can comprise wrapped product, and said wrapped product comprises the finished product that has greater than 14 relative obstruction starting point.In one aspect, the present invention can comprise wrapped product, and said wrapped product comprises and has about 2 to about 20; About 2 to about 18; About 2 to about 16, or even about 2 products to the relative obstruction starting point of about 15 particulates, and have about 2mm to about 11mm; About 3mm is to about 9mm, and about 4mm is about 8mm or even about 5mm product feed well of the critical gap size of about 7mm extremely extremely.In one aspect, said wrapped product can comprise a container, such as bottle, sack or a carton.In one aspect, at least a portion of said container is transparent.In one aspect, at least 5%, 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90%, or even 100% container surface area can be transparent.The material that can be used to make said transparent part includes but not limited to: Vestolen PP 7052 (PP), Vilaterm (PE), polycarbonate (PC), polyamide (PA) and/or polyethylene terephthalate (PETE), SE (PVC); And PS (PS).The transparent part of said container can have in the spectral range of 410nm to 800nm greater than 25%, 30%, 40%, 50%, 60% or even greater than 70% transmittance.For purposes of the invention, as long as a wavelength in visible-range has the transmittance greater than 25%, think that promptly it is transparent.Therefore, the transparent part of container can have color.The container of this aspect can be any form or the size that is applicable to preservation and packaging household cleaning compsn.For example, container can have virtually any size, but usually container will have 0.05 to 15L, and 0.1 to 5L, and 0.2 to 3L or even 1 to 2L maximum capacity.Preferably, said container easy handling.For example said container can have the parts of shank or suitable size, makes container be easy to one hand and lifts or carry.Said container can have and is applicable to hold the device of material in the infusion containers and be used to reclose and closes the device of said container.Closing device can be any form or size, but will be threadingly attached to or block usually by to container with unopened container.Closing device can be can isolating from container top cover.As other a kind of selection, no matter container is that open or closed, and top cover can both be connected on the container.Closing device also can be incorporated in the container.In one aspect, said wrapped product can be packed according to the instruction content of the U.S. Patent application No.2006/0032872A1 that announces.

The washing auxiliary detergent material

Though it is optional for the present invention; But hereinafter the non-limiting tabulation of illustrational promoter material be applicable to the present composition; And can advantageously it be mixed in certain embodiments of the present invention; For example helping or to improve the clean-up performance of handling substrate to be cleaned, or under the situation that contains spices, tinting material, dyestuff etc., change the aesthetic property of cleaning compsns.The physical form that the definite character of these annexing ingredients and incorporation thereof will depend on compsn with and the character of the clean operation that will be used for.Suitable promoter material includes but not limited to tensio-active agent; Washing assistant; Sequestrant; Dye transfer inhibitor; Dispersion agent; Enzyme and enzyme stabilizers; Catalytic specie; Bleach-activating agent; Hydrogen peroxide; Hydrogen peroxide cource; Preformed peracid; The dispersion agent of polymkeric substance; Structural agent; Clay soil removes/anti-redeposition agent; Increase from agent; Suds suppressor; Dyestuff; Fabric hueing agent; Spices; The structural elasticity agent; Fabric softener; Carrier; Hydrotropic agent; Processing aid; Solvent and/or pigment.Except the following discloses content, the suitable embodiment and the consumption of these other auxiliary agents also are present in USP 5,576, and 282,6,306,812 B1 and 6,326, among 348 B1, said document is introduced for your guidance.

Such as statement, ancillary component is not that applicant's compsn is necessary.Therefore, some embodiment of applicant's compsn does not comprise one or more following promoter materials: tensio-active agent, washing assistant, sequestrant, dye transfer inhibitor, dispersion agent, enzyme and enzyme stabilizers, catalytic specie, bleach-activating agent, hydrogen peroxide, hydrogen peroxide cource, preliminary shaping peracid, polymeric dispersant, clay soil remove/and anti-redeposition agent, whitening agent, suds suppressor, dyestuff, spices, structural elasticity agent, fabric softener, carrier, hydrotropic agent, processing aid, solvent and/or pigment.Yet when having one or more auxiliary agents, these one or more auxiliary agents can detail existence as follows:

SYNTHETIC OPTICAL WHITNER-cleaning compsns of the present invention can comprise one or more SYNTHETIC OPTICAL WHITNER.The suitable SYNTHETIC OPTICAL WHITNER that is different from bleaching catalyst includes but not limited to optical white, bleach-activating agent, hydrogen peroxide, hydrogen peroxide cource, preliminary shaping peracid and their mixture.Usually, when using SYNTHETIC OPTICAL WHITNER, compsn of the present invention can comprise by weight of this theme cleaning compsns about 0.1% to about 50% or even about 0.1% to about 25% SYNTHETIC OPTICAL WHITNER.The instance of suitable SYNTHETIC OPTICAL WHITNER includes but not limited to:

(1) preformed peracid: suitable preliminary shaping peracid includes but not limited to be selected from the compound by the following group of forming: percarboxylic acids and salt thereof; Percarbonic acid and salt thereof; Cross imidic acid and salt thereof; Peroxy-monosulfuric acid and salt thereof (for example Oxone

); And their mixture.Suitable percarboxylic acids includes but not limited to have hydrophobicity and the wetting ability peracid of molecular formula R-(C=O) O-O-M, and wherein R is an alkyl, optional branched-chain alkyl, and when peracid was hydrophobicity, it had 6 to 14 carbon atoms or 8 to 12 carbon atoms; When peracid is wetting ability, its have less than 6 carbon atoms or even less than 4 carbon atoms; And M is counter ion, for example sodium, potassium or hydrogen;

(2) hydrogen peroxide cource, for example inorganic over hydrogenation adduct salt comprises following an alkali metal salt such as sodium salt: perborate (being generally monohydrate or tetrahydrate), percarbonate, persulphate, perphosphate, persilicate and their mixture.In one aspect of the invention, inorganic over hydrogenation adduct salt is selected from the group of being made up of following material: peroxyboric acid sodium salt, percarbonic acid sodium salt and their mixture.If be used, inorganic over hydrogenation adduct salt exists with 0.05% to 40% weight of total compsn or the content of 1% to 30% weight usually, and usually as can coated crystalline solid being incorporated in this compsn.Suitable coating includes but not limited to: inorganic salt such as alkalimetal silicate, carbonate or borate or their mixture, or organism such as water-soluble or dispersible polymer, wax, oil or fatty soap; With

(3) has the bleach-activating agent of R-(C=O)-L; Wherein R is an alkyl; Optional branched-chain alkyl, when bleach-activating agent was hydrophobicity, it had 6 to 14 carbon atoms or 8 to 12 carbon atoms; When bleach-activating agent is wetting ability, its have less than 6 carbon atoms or even less than 4 carbon atoms; And L is a leavings group.The instance of suitable leavings group is the benzene sulfonate of phenylformic acid and verivate thereof-especially.Suitable bleach-activating agent includes but not limited to dodecyl acyl-oxygen base benzene sulfonate, last of the ten Heavenly stems acyloxy benzene sulfonate, caprinoyl aminobenzoic acid and salt, 3 thereof; 5,5-trimethyl acetyl oxygen base benzene sulfonate, tetra acetyl ethylene diamine (TAED) and nonanoly acyloxy benzene sulfonate (NOBS).Suitable bleach-activating agent also is disclosed among the WO 98/17767.Although can adopt any suitable bleach-activating agent, in one aspect of the invention, the cleaning compsns of this theme can comprise NOBS, TAED or their mixture.

If exist, peracid and/or bleach-activating agent usually with based on said compsn about 0.1% to about 60% weight, about 0.5% to about 40% weight or even about 0.6% content to about 10% weight be present in the said compsn.One or more hydrophobicity peracid or its precursor can be united use with one or more wetting ability peracid or its precursor.

Can select the amount of hydrogen peroxide cource and peracid or bleach-activating agent, make that the mol ratio of available oxygen (from peroxide source) and peracid is 1: 1 to 35: 1, perhaps even 2: 1 to 10: 1.

Tensio-active agent-can comprise tensio-active agent or surfactant system like cleaning compsns of the present invention, wherein said tensio-active agent can be selected from nonionogenic tenside, AS, cats product, amphoterics, zwitterionics, semi-polar nonionic surfactants and their mixture.If exist, tensio-active agent usually in by the weight of this theme composition about 0.1% to about 60%, about 1% to about 50% or even about 5% to about 40% content exist.

Washing assistant-cleaning compsns of the present invention can comprise one or more detergent builder or builder system.When using washing assistant, this theme composition will comprise weight by this theme composition usually at least about 1%, and about 5% to about 60% or even about 10% to about 40% washing assistant.

Washing assistant includes but not limited to: the multipolymer, 1 of poly-phosphate, alkalimetal silicate, earth alkali metal and the alkaline carbonate of basic metal, ammonium and alkanol ammonium, silico-aluminate washing assistant and polycarboxylic acid salt compound, ether hydroxy-polycarboxylate, maleic anhydride and ethene or vinyl methyl ether; 3; 5-trihydroxybenzene-2; 4; 6-trisulfonic acid and ethyloic oxysuccinic acid, polynary acetate (like YD 30 and nitrilotriacetic acid(NTA)) and polycarboxylic acid are (like mellitic acid, succsinic acid, Hydrocerol A, oxygen di-succsinic acid, polynary toxilic acid, 1; 3,5-three phenylformic acid, ethyloic oxysuccinic acid) various an alkali metal salts, ammonium salt and substituted ammonium salt and their soluble salt.

Sequestrant-cleaning compsns of the present invention can comprise sequestrant.Suitable sequestrant includes but not limited to copper, iron and/or manganese sequestrant and their mixture.When using sequestrant, this theme composition can comprise by weight of this theme composition about 0.005% to about 15% or even about 3.0% to about 10% sequestrant.

Dye transfer inhibitor-cleaning compsns of the present invention also can include but not limited to one or more dye transfer inhibitors.Suitable polymeric dye transfer inhibitor includes but not limited to: polyvinyl pyrrolidone polymers; Polyamine N-oxide pllymers; The multipolymer of N-vinyl pyrrolidone and N-vinyl imidazole; Polyvinyl

oxazolidone and polyvinyl imidazol; Or their mixture.In the time of in being present in this theme composition, dye transfer inhibitor can by the weight of said compsn about 0.0001% to about 10%, about 0.01% to about 5% or even about 0.1% to about 3% content exist.

Whitening agent-cleaning compsns of the present invention also can comprise the annexing ingredient that can be institute's cleaning article colouring, like white dyes.Suitable fluorescent brightener levels comprises from about 0.01% weight, about 0.05% weight, about 0.1% weight, or even lower aq to 0.5% weight of about 0.2% weight or even the high level of 0.75% weight.

Dispersion agent-compsn of the present invention also can comprise dispersion agent.Suitable water soluble organic substance includes but not limited to homopolymerization or co-polymeric acids or its salt, and wherein polycarboxylic acid comprises at least two and is separated by and is no more than the carboxyl of two carbon atoms.

Enzyme-said cleaning compsns can comprise one or more enzymes, and said enzyme provides clean-up performance and/or fabric care benefit effect.The embodiment of suitable enzyme includes but not limited to: hemicellulase, px, proteolytic enzyme, cellulase, zytase, lypase, Phospholipid hydrolase, esterase, at, polygalacturonase, mannase, pectin lyase, M-Zyme, reductase enzyme, oxydase, phenol oxidase, lipoxygenase, ligninase, Starch debranching enzyme, tannase, pentosanase, malanases, beta-glucanase, arabinase, Unidasa, chondroitinase, laccase and glycase or their mixture.Typical combination is that the enzyme that for example can comprise with glycase bonded proteolytic enzyme and lypase makes up.In the time of in being present in cleaning compsns, above-mentioned enzyme can be by the weight of said compsn about 0.00001% to about 2%, about 0.0001% to about 1% or even about 0.001% exist to the content of about 0.5% zymoprotein.

Enzyme stabilizers-can stablize the enzyme that is used for washing composition through multiple technologies.The enzyme that the present invention uses can be stablized by the water-soluble sources of calcium in the final composition and/or mg ion, and said water-soluble sources offers enzyme with this ion.Comprising under the aqueous compsn situation of proteolytic enzyme, for example boron cpd is stable with further improvement can to add reversible protease inhibitors.

Catalytic metal complexes-applicant's cleaning compsns can comprise catalytic metal complexes.One type of metallic bleaching catalyst is such catalyst system; This system comprises and has the active transition-metal cation of definite bleach catalyst, like copper positively charged ion, iron positively charged ion, titanium positively charged ion, ruthenium positively charged ion, tungsten positively charged ion, molybdenum positively charged ion or manganese positively charged ion; Comprise and have very low or do not have the active assistant metal positively charged ion of bleach catalyst, like zinc cation or aluminium cations; And comprise and with auxiliary metallic cation sequestrant, especially YD 30, ethylenediamine tetraacetic (methylene phosphonic acid) and their water-soluble salt of definite stability constant are arranged for catalytic.Above-mentioned catalyzer is disclosed in USP 4,430, in 243.

If desired, compsn of the present invention can carry out catalysis by manganic compound.Above-claimed cpd and consumption are well known in the art and include but not limited to for example be disclosed in USP 5,576,282 the catalyzer based on manganese.

To can be used for cobalt bleaching catalyst of the present invention be known and for example be described in USP 5,597,936, the USP 5,595,967.Above-mentioned cobalt catalyst is easy to through the preparation of known method, and for example USP 5,597,936 with USP 5,595,967 in the method that proposed.

The compsn of this paper also can comprise the transition metal complex of part aptly, and said part for example is bispidones (WO 05/042532 A1) and/or encircles rigid ligand (being abbreviated as " MRL ") mostly.As implementing item; And it is unrestricted; The compsn of adjustable this paper and method, making provides approximately at least one 1/100000000th active MRL material in the aqueous cleaning medium, and in washing liq, will be provided as about 0.005ppm usually to about 25ppm; About 0.05ppm is to about 10ppm, or even about 0.1ppm MRL of about 5ppm extremely.

In transition metal bleach catalyzer of the present invention, suitable transition metal includes but not limited to for example manganese, iron and chromium.Suitable MRL includes but not limited to 5,12-diethylammonium-1,5,8,12-four azabicyclos [6.6.2] n-Hexadecane.

Be easy to prepare suitable transition metal M RL through known steps, for example step through in WO 00/32601 and USP 6,225,464, being proposed.

The preparation method for compositions

Compsn of the present invention can be formulated into any suitable form and any method preparation of adopting formulator to select, in applicant's instance and at U.S.4, and 990,280, U.S.20030087791A1; U.S.20030087790A1; U.S.20050003983A1; U.S.20040048764A1; U.S.4,762,636; U.S.6,291,412; U.S.20050227891A1; EP1070115A2; U.S.5,879,584; U.S.5,691,297; U.S.5,574,005; U.S.5,569,645; U.S.5,565,422; U.S.5,516,448; U.S.5,489,392; U.S.5 has narrated its limiting examples in 486,303, and these patents are all incorporated this paper into way of reference.

Use the method for cleaning compsns

The present invention includes a kind of method that cleans and/or handle a certain position, particularly surface or fabric.Aforesaid method may further comprise the steps: applicant's cleaning compsns embodiment (with pure form or be diluted in the washing liq) is contacted with part surface or fabric at least, then randomly above-mentioned surface of rinsing or fabric.Can before above-mentioned rinse step, carry out washing step to said surface or fabric.For the purpose of the present invention, washing includes but not limited to clean and mechanical stirring.As those skilled in the art approved, cleaning compsns of the present invention was ideally suited for the purposes of doing washing.Therefore; The present invention includes a kind of method that is used for laundering of textile fabrics; Said method can may further comprise the steps: fabric that will be to be washed contacts with said cleaning washing soln, and said cleaning washing soln comprises at least one embodiment of applicant's cleaning compsns, cleaning additive or their mixture.Fabric can comprise most of any fabric that can under the normal consumer working conditions, wash.Said solution preferably has about 8 to about 10.5 pH value.Said compsn can solution in about 500ppm to about 15, the concentration of 000ppm is used.Water temperature is generally about 5 ℃ to about 90 ℃.The ratio of water and fabric is generally about 1: 1 to about 30: 1.

Testing method

1.) The test of stratification powder median particle

Must use this testing method to measure the median particle diameter of stratification powder.Decide the testing graininess of stratification powder according to ISO8130-13 " Coating powders-Part 13:Particle size analysis by laser diffraction ".The suitable laser diffraction granularity analyser of being furnished with the dry powder feeder can derive from Horiba Instruments Incorporated of Irvine, California, U.S.A.; Malvern Instruments Ltd of Worcestershire, UK; Sympatec GmbH of Clausthal-Zellerfeld, Germany; With Beckman-Coulter Incorporated of Fullerton, California, U.S.A.

According to ISO 9276-1:1998 " Representation of results of particle size analysis-Part 1:Graphical Representation " figure A.4, " Cumulative distribution Q ₃Plotted on graph paper with a logarithmic abscissa " come ecbatic.Median particle is defined as cumulative distribution (Q ₃) equal the abscissa value of the point at percent 50 places.

2.) The binder ingredients viscosity test

Must use this testing method to measure the viscosity of binder ingredients.

The AV that use records through the Brookfield testing method is carried out the mensuration of binder ingredients viscosity.Suitable viscometer, for example with the Brookfield type LV (LVT or LVDV series) of UL adaptor, can be available from Brookfield Engineering Laboratories, Inc., Middleboro, Massachusetts, USA.According to Brookfield Operating Manual; According to the ISO2555 second edition; Be published on February 1st, 1989, revision was reprinted February 1 nineteen ninety, " Plastics-resins in the liquid state or as emulsions or dispersions-Determination of apparent viscosity by the Brookfield Test method; " Guide rule carry out the viscosity test of binder ingredients, subsidiary following condition:

A.) use the Brookfield LV series viscometer of being with the UL adaptor.

B.) use 60 rev/mins rotational frequency.Clause 4 specified permission working ranges according to ISO2555 are selected rotor.If the working range according to allowing can not be used 60 rev/mins rotation frequency, then should use the maximum speed that is lower than 60 rev/mins and meets the allowed band of clause 4.

Temperature when the binder ingredients temperature when c.) carrying out viscosity measurement is added into the stratification process with binder ingredients is identical.

3.) Seed material median particle diameter and the test of distribution span

Must use this testing method to measure the median particle diameter of seed material.

Use the ASTM D502-89 that also has used sieve mesh specification sheets in the analysis " Standard Test Method for particle Size of Soaps and Other Detergents " of approval on May 26th, 1989 to implement the test of seed material particle diameter, to measure the median particle diameter of seed material.According to the 7th part " Procedure using machine-sieving method ", need comprise the clean exsiccant sieve of a cover of USS (ASTM E11) sieve #8 (2360um), #12 (1700um), #16 (1180um), #20 (850um), #30 (600um), #40 (425um), #50 (300um), #70 (212um), #100 (150um).Above-mentioned machine-sieve is used for specified method for sieving.Seed material is as sample.Suitable sieve shaking machine can derive from W.S.Tyler Company, Mentor, Ohio, U.S.A.

Micron opening size with each sieve is made the logarithm X-coordinate, mass accumulation per-cent (Q ₃) make linear vertical, data are depicted as semilog plot.At ISO 9276-1:1998, " Representation of results of particle size analysis-Part1:Graphical Representation ", figure is the given instance of above-mentioned data representation in A.4.For the present invention, with seed material median particle (D ₅₀) be defined as the abscissa value that mass accumulation per-cent equals the point at percent 50 places, and through method of linear interpolation to (a50) directly over 50% value and under data point between (b50) calculate, use following formula:

D ₅₀＝10^[Log(D _a50)-(Log(D _a50)-Log(D _b50))*(Q _a50-50％)/(Q _a50-Q _b50)]

Q wherein _A50And Q _B50Be respectively directly over percent 50 with under the mass accumulation fraction values of data; And D _A50And D _B50It is sieve mesh micron value corresponding to these data.

If percent 50 values are lower than minimum sieve mesh (150um) or are higher than maximum sieve mesh (2360um), must follow being not more than 1.5 geometric progression and in this cover sieve, adding additional sieve, up to intermediate value be in two survey between the sieve mesh.

The distribution span of seed material is that near the width that seed granularity distributes the intermediate value is measured.Can calculate according to following formula:

Span=(D ₈₄/ D ₅₀+ D ₅₀/ D ₁₆)/2

D wherein ₅₀Be median particle, and D ₈₄And D ₁₆, mass accumulation per-cent is respectively 1 16 and 80 percent everywhere granularity on keeping figure line.

If D ₁₆Value is lower than dusting cover order (150um), then according to the computes span:

Span=(D ₈₄/ D ₅₀).

If D ₈₄Value is higher than scalping order (2360um), then according to the computes span:

Span=(D ₅₀/ D ₁₆).

If D ₁₆Value is lower than minimum sieve mesh (150um) and D ₈₄Value is higher than maximum sieve mesh (2360um), then gets the distribution span and be 5.7 peak.

4.) The bulk density test

Measure the bulk density of seed material according to the testing method B " Loose-fill Density of Granular Materials " among the ASTM Standard E727-02 " Standard Test Methods for Determining Bulk Density of Granular Carriers and Granular Pesticides " that is included in approval on October 10th, 2002.

5.) The test of mobile particle mass base cumulative particle size distribution

Must use this test determines median particle (D ₅₀) and percent 30 granularity (D of flow particles ₃₀).Indicated method is identical in the method that this test accordings to and above-mentioned " test of seed material median particle diameter ", and different is that this method is used for test:

A) flow particles through the granularity percentage selected and

B) comprise the granularity percentage through selecting of the full blend compositions of flow particles.

The part (a) in, use mobile particulate instead the sample of seed material carry out " test of seed material median particle diameter ".Make and calculate median particle (D in the same way ₅₀).In addition, with percent 30 granularity (D ₃₀) be defined as the abscissa value that mass accumulation per-cent equals the point at percent 30 places, and through method of linear interpolation to (a30) directly over 30% value and under data point between (b30) calculate, use following formula:

D ₃₀＝10^[Log(D _a30)-(Log(D _a30)-Log(D _b30))*(Q _a30-30％)/(Q _a30-Q _b30)]

Q wherein _A30And Q _B30Be respectively directly over percent 30 with under the mass accumulation fraction values of data; And D _A30And D _B30It is sieve mesh micron value corresponding to these data.

If percent 30 values are lower than minimum sieve mesh (150um), must follow being not more than 1.5 geometric progression and in this cover sieve, adding additional sieve, up to percent 30 values be in two survey between the sieve mesh.

(b) in the part, the program of above-mentioned (a) part uses full blend compositions to replace flowable particulates.

6.) Block the starting point test

Use Flodex ^TMApparatus measures is blocked starting point, and said instrument is by Hanson Research Corporation, Chatsworth, California, USA supply.The term that uses in the testing method " hopper " is meant Flodex ^TMThe roller assemblies of instrument; Term " hole " is meant the central hole of mobile dish that is used for flowing test; Symbol " B " is meant the bore dia in the mobile dish that uses in the test; And symbol " b " is meant nondimensional hole dimension, and it is defined as bore dia and percent 30 granularity (D ₃₀) ratio, at applicant's testing method #5, stipulate b=B/D in " Flowable Particle Mass Based Cumulative Particle Size Distribution Test " ₃₀

According to Flodex ^TMThe directions for use that comprises in the operational manual, operation Flodex ^TMInstrument, operational manual version number is 21-101-000C 2004-03, the following steps exception:

A.) appropriate vessel that is used to collect test substances is carried out taring with the precision of 0.01 gram before beginning to test, subsequently with among the following step c of this container measurement from the particulate quality of hopper discharging.

B.) sample preparation.The batch sample of particulate is carried out suitable desanding fill out the subsample of volume so that the 150ml pine to be provided.Can multiply by target volume (150ml) then and measure suitable sample quality through measuring specified loose filling density in testing method #4 " bulk density test ".The quality (sample quality) of record sample before each thermometrically begins.Because test is nondestructive, same sample is reusable.Must discharge whole samples through for example Turnover bunker, before each the measurement, add sample once more then.

C.) begin to measure from smallest cell dimension (common 4mm is only if need littler hole), each hole dimension carries out three replicate measurements.Sample is added in the hopper during each the measurement, according to Flodex ^TMProgram described in the operational manual, opening before in the hole, permission stops about 30 seconds time period of stay.Permission is discharged into sample in the gas-mixing balance container at least 60 seconds time.After 60 seconds; Stop in case flowing and keep halted state to reach 30 seconds (promptly; The material that stops at interval discharging through 30 seconds is no more than 0.1% quality), just measure the quality of institute's emission of substance, close closed pore and through the Turnover bunker subassembly or remove the dish that flows and come fully turned letter hopper.Attention: if flow stop and subsequently 30 seconds stop at interval in begin again, stop then that interval timer must to restart when stopping be zero flowing next time.The mass percent of discharging is according to computes during each the measurement: (discharge quality per-cent %)=100* (discharge quality)/(sample quality).With the MV of the mass percent of three discharge measurings with non-dimensional hole dimension (b=B/D ₃₀) functional form draw coordinate diagram, be ordinate zou with the mass percent of discharging, be X-coordinate with the non-dimensional hole dimension.Hole dimension that use increases progressively repeats this program, up to according to Flodex ^TMIn the operational manual the said hopper of the explanation of " positive findings " discharge continuous three times clog-free till.

D.) data of painting are carried out linear interpolation then to find blocking starting point (J relatively _Rel), it is defined as the non-dimensional hole dimension value at 25% quality average emission place.This confirms through the interior abscissa value (b) that equals 25% mass discharge place that pushes away.If above 25%, must obtaining, the average percentage by mass discharging in beginning hole has than the mobile dish of aperture and to begin repeated test than aperture.Have mobile dish than aperture, such as 3.5,3.0,2.5 or even the mobile dish in 2.0mm hole, can obtain from Hanson Research Corporation with the form of customization accessory.

E.) definitely block starting point (J _Abs) be defined as relative obstruction starting point and D ₃₀The product of granularity, J _Abs=J _Rel* D ₃₀

7.) Fast and stable property is blocked the starting point test relatively

It is to measure when the physical stability that is exposed to warm moist environment particle flow characteristics of following time that fast and stable property is blocked the starting point test relatively.This test " is blocked the starting point test " according to method #6 and is carried out subsidiary following condition:

A) increase the environmental aging step, the 150ml sample of testing method #6 is placed the 250ml beaker, the sample that will not be capped then placed 27 degrees centigrade, the environmental testing case of 60% relative humidity 48 hours.The 250ml beaker is straight mouthful, has open top, and its internal diameter is about 6.5cm.Suitable climatic chamber can be available from Lunaire Environmental Products, New Columbia, Pennsylvania, USA; Weiss-Gallenkamp, Loughborough, UK, ESPEC, Hudsonville, Michigan, USA.

B) use aging sample to carry out ensuing obstruction starting point test.After aging sample shifts out, can be used for blocking the starting point test being no more than in time of 20 minutes from environmental cabinet.The additional if desired time is accomplished said test, must many parts of aging samples of preparation.It should be noted that aging latter stage possibly knock beaker or even use scraper to smash aging particle specimens, from beaker, to take out sample.

C), use the particle D that before environmental aging in 48 hours test, measures according to the method for calculation of blocking starting point relatively ₃₀Value is obtained fast and stable property obstruction starting point.

8.) The particle aspect ratios test

Particle aspect ratios is defined as the major diameter (d of particulate _{Major axis}) with respect to the minor axis diameter (d of particulate _{Minor axis}) ratio, wherein said major diameter and minor axis diameter are long limit of orthogonal and minor face, said rectangle makes 2 dimension images of the external particulate in rectangle minor face minimized turning point place.Use suitable microscopy technology to obtain 2 dimension images.For this method, the particulate area is defined as the area of 2 dimension micro particle image.

In order to measure aspect ratio distribution and intermediate value particle aspect ratios, must obtain and analyze the representational 2 dimension micro particle image of suitable number.For this test, need minimum 5000 micro particle image.For collection and the image analysis that helps this quantity particulate, recommend to use automated imaging and analytical system.This type systematic can be available from Malvern Instruments Ltd., Malvern, Worcestershire, United Kingdom; Beckman Coulter, Inc., Fullerton, California, USA; JM Canty, Inc., Buffalo, New York, USA; Retsch Technology GmbH, Haan, Germany; With Sympatec GmbH, Clausthal-Zellerfeld, Germany.

Obtain suitable particulate sample through desanding method.Handle and analyzing samples through ias then, so that a series of particulates that comprise major axis and minor axis attribute to be provided.According to the ratio of particulate major axis and minor axis, calculate the long-width ratio (AR) of each particulate,

AR=d _{Major axis}/ d _{Minor axis}

Then the data sequence of particle aspect ratios is classified by ascending order, according to the existing of the particulate area in the sorted sequence and calculating cumulative particulate area.Particle aspect ratios is plotted as X-coordinate, and accumulation particulate area is plotted as ordinate zou.The intermediate value particle aspect ratios equals the abscissa value at total particulate area 50% place for accumulation particulate area.

Embodiment

Embodiment 1: seed material

Seed material generally can be used the feed material of particle grades, has described granularity, size-grade distribution, long-width ratio and density in the specification sheets of the present invention.Suitable single component seed comprises tripoly phosphate sodium STPP, sodium sulfate, yellow soda ash, water glass, monocalcium phosphate, Lin Suanergai, sodium pyrosulfate, Trisodium Citrate, Hydrocerol A, lactose, sugar, whey and the starch granules of particle grades.This type of seed has widely to be used.

The embodiment that is used as the composite composition of washing composition seed is showing 1A and 1B, and middle detergent composition is given among the row a to x.This type of compound seed is through separate wash agent granulation process preparation, such as mechanical agglomeration, spraying drying or extrude, classify then to reach the seed granularity specification.These class methods that are used to prepare the intermediate particle compsn are well known to those skilled in the art.

In one aspect, middle detergent composition (for example, according to table 1) can be divided into two portions: a part is suitable for as seed, and second section is unwanted or is inappropriate for as seed.Can second section be ground to form the fine powder that is applicable to stratification then.By this method, can in the stratification process, consume whole intermediate composition, it is used as seed or stratification powder.In addition, become seed and stratification that control to the stratification process-with respect to the ratio of tackiness agent and stratification powder partly is provided the intermediate material portioning, and to the control of product attribute, for example stratification granulometric facies are for initial seed sizes.

^*Table 1A composition tabulation: 1) tripoly phosphate sodium STPP; 2) sodium silicoaluminate, zeolite structured; 3) yellow soda ash; 4) sodium sulfate; 5) water glass; 6) sodium alkyl benzene sulfonate; 7) sodium alkyl sulfate; 8) alkyl ethoxy sodium sulfate; 9) ROHM sodium polymer; 10) vinylformic acid-maleic acid sodium salt; 11) Macrogol 4000; 12) linear alcohol alcoxylates; 13) white dyes; 14) Walocel MT 20.000PV; 15) moisture and starting material by product.

^*Table 1B composition tabulation: 1) tripoly phosphate sodium STPP; 2) sodium silicoaluminate, zeolite structured; 3) yellow soda ash; 4) sodium sulfate; 5) water glass; 6) alkyl ethoxy sodium sulfate; 7) ROHM sodium polymer; 8) vinylformic acid-maleic acid sodium salt; 9) linear alcohol alcoxylates; 10) Walocel MT 20.000PV; 11) nonionogenic tenside; 12) Trisodium Citrate; 13) MGDA; 14) GLDA; 15) HEDP; 16) moisture and starting material by product.

Embodiment 2: the stratification powder

Although suitable stratification powder can directly use the starting material of powder grade, according to full specification sheets of the present invention, the pulverizing that possibly still need replenish granularity is reduced to required size range, for example, is used high speed bearing pin kibbler.

The composition of stratification powder depends on the application of product.The stratification powder can provide physics and/or the chemisorption of liquid adhesive in layer structure.When using activity or aqueous binder, preferably make at least a component of stratification powder comprise a kind of can with the material of adhesive reaction; In this case, tackiness agent is changed into solid phase or half solid phase.For example, the stratification powder can be participated in acid-alkali or hydration reaction with other material or midbody in the stratification process.For example, when using aqueous binder, expectation makes the stratification powder comprise at least a hydration material.

The instance of suitable stratification material includes but not limited to be selected from the material by the following group of forming: sugar, acetate, Citrate trianion, vitriol, carbonate, borate, phosphoric acid salt, acidic precursor and their mixture.The instance of sugar and glucide salt includes but not limited to lactose, lactic acid ca and trehalose.The instance of acetate includes but not limited to magnesium acetate, Mg (CH ₃COO) ₂And sodium-acetate, NaCH ₃COO.The instance of Citrate trianion includes but not limited to Trisodium Citrate, C ₆H ₅O ₇Na ₃And Hydrocerol A, C ₆H ₈O ₇The instance of vitriol includes but not limited to sal epsom, MgSO ₄And sodium sulfate, Na ₂SO ₄The instance of carbonate includes but not limited to yellow soda ash, Na ₂CO ₃Salt of wormwood, K ₂CO ₃Boratory instance includes but not limited to Sodium Tetraborate, Na ₂B ₄O ₇Phosphatic instance includes but not limited to Sodium phosphate, dibasic, Na ₂HPO ₄And tripoly phosphate sodium STPP, Na ₅P ₃O ₁₀Can the stratification powder that comprise this type of material be introduced the stratification process as substantially anhydrous salt.Do not accept the constraint of opinion, it is believed that they provide the method for removing tackiness agent moisture to the conversion of stabilize water compound phase, and make processing have the control of improvement.If material has enough hydratabilities, said method drying-free step.

The additional activity stratification powder mass that is used to wash application includes but not limited to be selected from the material by the following group of forming: tensio-active agent, soluble polymeric thing, washing assistant, buffer reagent, white dyes and their mixture.In one aspect, the stratification powder is made through detergent composition in the middle of grinding, and for example, given compsn is used for 7 to 15 row of production table 2A and shows the compsn that 12 to 16 of 2B goes among table 1A and the 1B.

^*Table 2A composition tabulation: 1) tripoly phosphate sodium STPP; 2) sodium silicoaluminate, zeolite structured; 3) yellow soda ash; 4) sodium sulfate; 5) Walocel MT 20.000PV; 6) white dyes powder; 7) abrasive composition table 1A row (b); 8) abrasive composition table 1A row (d); 9) abrasive composition table 1A row (e); 10) abrasive composition table 1A row (g); 11) abrasive composition table 1A row (h); 12) abrasive composition table 1A row (i); 13) abrasive composition table 1A row (j); 14) abrasive composition table 1A row (k); 15) abrasive composition table 1A row (l); 16) moisture and starting material by product.

^*Table 2B composition tabulation: 1) yellow soda ash; 2) sodium sulfate; 3) Trisodium Citrate; 4) MGDA; 5) GLDA; 6) water glass; 7) vinylformic acid-maleic acid sodium salt; 8) sodium alkyl benzene sulfonate; 9) di 2 ethylhexyl phosphonic acid; 10) EDDS; 11) sal epsom; 12) pulverize compositions table 1B row (o); 13) pulverize compositions table 1B row (p); 14) pulverize compositions table 1B row (r); 15) pulverize compositions table 1B row (s); 16) pulverize compositions table 1B row (v); 17) moisture and starting material by product.

Embodiment 3: tackiness agent

Although its application is depended in the selection of tackiness agent, the preferred adhesive system should comprise at least a binder ingredients, and said at least a binder ingredients can become solid phase or half solid phase from liquid through chemistry or physics conversion.Under the situation of chemical conversion, tackiness agent preferably with the component reaction of stratification powder.Can use suitable nonactive tackiness agent, it can physically be adsorbed in the laminate structure.The instance of suitable nonactive tackiness agent includes but not limited to spice oil, local flavor oil and nutritional oil.

The suitable active binder material that is used for washing composition includes but not limited to be selected from the material by the following group of forming: the polymkeric substance of the tensio-active agent of acid surfactant precursor, liquid or fusing or negatively charged ion, positively charged ion, nonionic or zwitterionics solution, liquid or fusing, polymers soln, acidic polymer, silicate solutions, cellulosic solution or dispersion-s, melting fatty acid or alcohol, wax and their mixture.Suitable inert binder material includes but not limited to be selected from the material by the following group of forming: water, salts solution, sugar soln and their mixture.

Embodiment 4: isolating tackiness agent and the manufacturing of stratification powder streamer are used for automatic dish on the usage space The stratification particulate method of washing composition

Use Sweco24 Vibro-Energy Round Separator, will screen available from the seed particle compsn in the table 1A row (a) of Procter & Gamble Co., to obtain the particulate of granularity between about 300 and 850 microns.With the about 75kg of quality, the seed particle of about 1.07 kg/liter of bulk density joins (Bella in the twin shaft counter-rotating paddle stirrer then ^TMB-120XN derives from Dynamic Air, St.Paul, and MN, USA), said twin shaft counter-rotating paddle stirrer is modified to and uses the distribution piping that is positioned at below, convergent flow zone to add tackiness agent.Turn on agitator, twin shaft reverses with about 100RPM.Each axle has 14 oars, is mounted to 7 pairs of oars of each axle.With quality is the viscosity of the alcohol alkoxylates liquid heat of about 0.6kg to about 40cp; Under the speed of about 200lbs/hr, add whip topping then via the press atomization mouth; So that formation atomised droplets; Then make said droplet contact particulate, fluidisation seed particle herein in whisking appliance central authorities.Through being installed in the nozzle of whip topping central authorities, the about 30% weight solid ZX-I polymer binder solution of beginning atomized spray is so that adhesive droplets is at whisking appliance central authorities contact fluidizing seed particle then.Polymers soln sprayed about 6 minutes with the speed of about 75lbs/hr.Simultaneously, through near above the descending oar path position of whisking appliance end wall, be positioned at diagonal two imports of whisking appliance, the stratification powder that will show 2A row (a) with the speed of about 900lbs/hr is on average shunted and was added whip topping 6 minutes.Simultaneously, add about 34% weight solid sodium silicate binder solution through distribution piping, said binder solution upwards flows into the convergent flow zone through four holes that stride across three oar positions of central authorities, about 2mm diameter.Speed with about 175lbs/hr adds sodium silicate solution approximately

Minute before draining into second whisking appliance, allow in whisking appliance, in 6 to 7 minutes the residence time, to carry out said whole process, second whisking appliance is the Bella that has carried out similar repacking in order to add tackiness agent ^TMB-200XN.The product that uses first whisking appliance then is as seed; In second whisking appliance, repeat said process; The residence time is similar with first whisking appliance and comprise all the stratification compositions except that the straight chain alcoxylates, and the adding speed of stratification powder, silicate and polymers soln is respectively about 1450,260 and 110 Pounds Per Hours.

Gained criticizes and discharges, screen with remove any excessive particulate (＞1.2mm), and the surperficial gas speed processing 3 to 7 minutes of air and about 0.8m/s of environment for use temperature in fluidized-bed.Product yield is about 90%; Residue carries out milled processed and recycling is used as seed or stratification powder.The time that does not comprise fluidized bed processing, the cumulative stratification process residence time is about 14 minutes.Free water content in the binder solution during the stratification process basically with the phosphoric acid salt of stratification powder and CARBONATE COMPONENT reaction, cause the equivalent of the crystal carbonate of about 80% tripoly phosphate sodium STPP and about 50% to transform.Product does not need other drying process.The product growth factor is about 2.8 times of initial seed grain amount.The stratification rate be about 20% quality/minute.Product granularity is characterised in that D ₅₀=630 microns, span=1.3, D ₃₀=540 microns.It is about 6.9 particulates that product blocks starting point relatively.

Embodiment 5: isolating tackiness agent and the manufacturing of stratification powder streamer are used for automatic dish on duration of service The stratification particulate method of washing composition

Use Sweco 24 " Vibro-Energy Round Separator, will screen to obtain the particulate of granularity between about 300 and 850 microns available from the seed particle compsn in the table 1A row (a) of Procter & Gamble Co..With the about 320g of quality, the seed particle of about 1.07 kg/liter of bulk density adds high-shear food processed-type culinary whisk (Robot Coupe, R302V type) then.Whisking appliance is opened down so that make seed particle produce centrifugal " rope stream " low the setting, and seed particle rotates with centrifugal flow pattern with respect to stirring wall.The liquid alcohol alkoxylates that the syringe that enters the mouth via the top adds about 4.6 grams is in whisking appliance, so that the liquid streamer is with the about vertical angle contact seed particle in convection surface.Next, the stratification powder composition that adds about 60 grams given in the table 2A row (a) through whip topping.Next, through whip topping, add the about 36% weight solid sodium silicate binder solution of about 60 grams with the about vertical angle in convection surface.Next, the stratification powder composition that adds about 145 grams given in the table 2A row (a) through whip topping.Next, through whip topping, add the about 26% weight solid ZX-I polymer binder solution of about 27 grams with the about vertical angle in convection surface.At last, the stratification powder composition that adds about 100 grams given in the table 2A row (a) through whip topping.During batch methods, increase agitator speed gradually and move with centrifugal flow pattern with respect to stirring wall to keep material.

Embodiment 6: isolating tackiness agent and the manufacturing of stratification powder streamer are used for medium-sized clothing on duration of service The effervesce stratification particulate method of washing composition

Obtain seed particle through the sodium pyrosulfate particle of screening rank between 500 and 1000 microns.Use the stratification powder of table 2A row (c).The LABS (HLAS) of mixing about 85% and about 15% fusing tallow alcohol ethoxylate (TAE80) prepare tackiness agent under about 60 ℃.Then even binder blend is preserved down at about 60 ℃.

With quality is that the seed material of 203 grams adds in the FP370 type food processor, and turn on agitator to speed is provided with #2, in whisking appliance, to produce centrifugal flow pattern.Carry out a series of eight continuous stratification steps then, alternately add about 15 gram tackiness agents and about 35 to 45 gram stratification powder, add more tackiness agent, add stratification powder or the like, up to forming lamellated product composition around the hydrosulfate seed.

The combination of solidifying of the TAE80 of chemical reaction and the fusing of tackiness agent through yellow soda ash in HLAS tackiness agent and the stratification powder changes into solid phase.Do not accept the constraint of opinion, it is believed that the mixed adhesive system extends to the lower too much yellow soda ash of content in the stratification powder with this type of ability of processing.In addition, nonaqueous basically process can form the composite particles with acid core core structure (sodium pyrosulfate) and alkaline layer, makes effervesce when said particle adds in the entry.

Embodiment 7: isolating tackiness agent and the manufacturing of stratification powder streamer comprise the little glue of spices on duration of service The stratification heavy-duty laundry detergent particulate method of capsule

Through spray drying process, the intermediate particle compsn that at first provides in the preparation table 1A row (k) obtains seed particle.The spray-dired particle of gained is classified the seed of preferred dimension between 425 microns and 850 microns through screening.The gained seed has the bulk density and the porous microtexture of about 300 grams per liters.

With quality is that the seed material of 200 grams adds in Braun CombiMax 600 food processors of 3205 types with blade impeller, and turn on agitator makes its speed be enough in whisking appliance, cause centrifugal flow pattern, and for example speed is provided with #4.According to USP 4; The aqueous slurry of 100,103 preparations, nine gram perfume microcapsules, it comprises the active spice oil of about 30% weight; Then through syringe with its adding so that the streamer of the streamer of said slurries contact porous seed makes microcapsule get into the porous microgranular texture.

In table 2A row (k), the stratification powder composition is provided.Use two kinds of isolating tackiness agents: 1) acid surfactant precursor such as alkyl benzene sulphonate(ABS) (HLAS) and/or alkyl 3-oxyethyl group sulfonic acid (HAE3S) and 2) about 30% weight solid sodium polyacrylate solution.Acid surfactant precursor contacts the sodium salt that is converted into it behind the tiny yellow soda ash in the stratification powder.Polyacrylate solution is also solidified through the hydration of yellow soda ash.

Carry out a series of 6 continuous stratification steps then; Alternately add about 11 gram acid surfactant precursor tackiness agents through syringe; Add about 45 gram stratification powder through teaspoon; Add about 1 gram polyacrylate solution through syringe then, all materials are sent through whip topping continuously, the particle streamer in the contact whisking appliance.Discharge total material then, and use screen cloth that it is classified, obtain granularity between about 300 microns and 1180 microns 330 gram products and send whisking appliance back to.

Repeat the stratification method of a series of 6 continuous stratification steps then; Alternately add about 10 gram acid surfactant precursor tackiness agents through syringe; Add about 50 gram stratification powder through teaspoon; Add about 1 gram polyacrylate solution through syringe then, all materials are sent through whip topping continuously, the particle streamer in the contact whisking appliance.

From whisking appliance, discharge said material, and it is classified to obtain the product of granularity between about 300 microns and 1180 microns through screening.The gained bulk density of product is about 800 grams per liters.

Embodiment 8: isolating tackiness agent and stratification powder streamer and spray-dired kind on the usage space Son is made stratification heavy-duty laundry detergent particulate method

Use Sweco 24 " Vibro-Energy Round Separator, through spraying drying system and the particulate of category filter between 300 microns and 850 microns that carry out subsequently, the seed particle compsn of preparation table 1A row (e).Use Netzsch CUM-150 bearing pin kibbler that the tiny tailing of above-mentioned spray-dried material and yellow soda ash is ground to about 20 microns median particle, prepare the stratification powder composition of table 2A row (e).Use two kinds of isolating tackiness agents: LABS (HLAS) and be with about 30% weight solid vinylformic acid-maleic acid aqueous solution.

Seed particle with about 8kg of quality and about 0.45 kg/liter of bulk density adds twin shaft counter-rotating paddle stirrer (Bella then ^TMB-32XN) in.Turn on agitator, twin shaft reverses with about 160RPM.Each axle has 22 oars, is mounted to 11 pairs of oars of each axle.Through whip topping, the about 30% weight solid ZX-I polymer binder solution of atomized spray, so that adhesive droplets contacts particulate in whisking appliance central authorities, said seed particle obtains fluidisation herein.Use 4 hole distribution pipings to add the HLAS tackiness agent through the whisking appliance bottom, tackiness agent upwards flows into the convergent flow zone, crosses over three oar positions of central authorities.Through near above the descending oar path position of whisking appliance end wall, be positioned at diagonal two imports of whisking appliance, the shunting of stratification powder is added whip topping.According to the feed timetable, " step 1 " part of table 3 adds tackiness agent and stratification powder simultaneously.

After step 1 timetable is accomplished, quality is put into identical whisking appliance for step 1 particulate product of about 11.55kg be used as seed, according to table 3, step 2 repeats said process.Gained criticizes and discharges, screen with remove any excessive particle (＞1.2mm), and about 4 minutes of the surperficial gas speed processing of air and about 0.8m/s of environment for use temperature in fluidized-bed.Tackiness agent is converted to solid phase on basically in the stratification process, does not need other drying process.Product yield is about 90%.Bulk density is about 0.82 kg/liter.According to table 3, step 3, this product carries out further stratification with a small amount of spice oil tackiness agent (about 0.2% mass percent) and zeolite stratification powder (about 0.8% mass percent) then.Use identical whisking appliance; And use step 2 product after about 20kg handles to make seed, and accomplish spices stratification step, add the finer atomization spraying of spices through whip topping; Make the spraying droplet at whisking appliance central authorities contact particulate, said seed particle obtains fluidisation herein.Product is about 5.5 with respect to the growth factor based on total mass of initial seed.Blocking starting point relatively is about 7.3 particulates.

In making production decision, the whisking appliance that two tandems of the scalable one-tenth operation of this process are arranged, second whisking appliance comprise and double the first whisking appliance working volume approximately.In this scheme, the granular product of step 1 is drained into the whisking appliance 2 from whisking appliance 1, as the seed of step 2.The process of step 2 can be accomplished in the substantially the same time with step 1, so that two whisking appliances can move in synchronized batch of timetable the idle mixing time with minimum.In order to keep the similar batch time, the tackiness agent of step 2 and stratification powder feed rate can be amplified according to batch size in proportion.In this production decision, stratification speed can for about 60% mass percent/minute or even higher.Earning rate can greater than 50% mass percent/minute.

Embodiment 9: use isolating tackiness agent and stratification powder streamer and grain seed to make stratification and weigh The method of dirt type detergent particles

This embodiment makes up a layer material through three steps continuously, and each step is by batch in the paddle stirrer of pilot scale, carrying out.Use Sweco 24 " Vibro-Energy Round Separator, select the particulate between 380 microns and 850 microns, the particulate state seed particle compsn of preparation table 1A row (j) through the mechanical agglomeration method and the classifying screen of carrying out subsequently.Through micronization soda ash content and the zeolite A powder that mixes 2: 1 mass ratioes, preparation stratification powder composition.Use two kinds of isolating tackiness agents: LABS (HLAS) and be with about 30% weight solid ZX-I aqueous solutions of polymers.

With the about 10kg of quality, the seed particle of about 0.8 kg/liter of bulk density adds twin shaft counter-rotating paddle stirrer (Bella then ^TMB-20XE).Turn on agitator, twin shaft reverses with about 120RPM.Each axle has 14 oars, is mounted to 7 pairs of oars of each axle.In successive stage, add tackiness agent.At first, be heated to about 60 ℃ and viscosity HLAS tackiness agent, make adhesive droplets contact the fluidisation seed particle in whisking appliance central authorities for about 150cp through the whip topping atomized spray.Then, also use isolating nozzle to spray the polymers soln tackiness agent to identical central fluidisation area top from whip topping.With the spray adhesive while, through an import that is positioned at top, whip topping turning the stratification powder is added whip topping, splash into the top of outer (moving downward) position of oar.According to the prescription of embodiment 9, " step 1 " of table 4 part adds tackiness agent and stratification powder.After step 1 timetable is accomplished, quality is put into identical whisking appliance for step 1 particulate product of about 11.16kg, repeat said process according to the step 2 of table 4.After step 2 timetable is accomplished, quality is put into identical whisking appliance for step 2 particulate product of about 11.65kg, repeat said process according to the step 3 of table 4.According to the stage of this method, in the scope of coalescence stokes number between about 7 and 9, and in the scope of stratification stokes number between 0.5 and 0.7.The discharging gained criticize go forward side by side row filter with the particle that removes any too volume particle size (＞1.2mm).Product yield is about 95%.Bulk density is about 950 grams per liters.Product is about 5.3 with respect to the growth factor based on quality of seed.Blocking starting point relatively is about 6.1 particulates.The intermediate value particle aspect ratios is about 1.22.

Embodiment 10: use isolating tackiness agent and stratification powder streamer and vitriol seed to make layer Change heavy-duty laundry detergent particulate method

This embodiment makes up a layer material through three steps continuously, and each step is by batch in 20 liters pilot scale colter whisking appliance, carrying out.Suitable colter whisking appliance can be available from Lodige GMBH.Seed particle obtains with the form of coarse particles sodium sulfate, and median particle is about 600um.Use Netzsch CUM-150A bearing pin kibbler to obtain median particle and be about 20 microns particulate, the stratification powder composition of preparation table 2A row (g).Use zeolite powder in a small amount to replenish the stratification powder.Tackiness agent is LABS (HLAS).

Shear colter whisking appliance (Lodige M-20-G Lab Plow Mixer has the about 0.15 meter colter whipping appts of radial scan) during product uses, like table 5, a series of three batches of steps of the said process of the prescription of embodiment 10 are carried out the manufacturing of product.Turn on agitator, main stir shaft rotates with about 175RPM, and cutting knife moves with about 3000RPM.Add HLAS tackiness agent (the about 60 ℃) streamer that heats through the supply pipe below cutting knife, its viscosity is about 150cp.The stratification powder is added the whip topping that is positioned at the cutter location top.Coalescence stokes number (St _Coalescence) be about 17, and stratification stokes number (St _{Stratification}) be about 1.1.

The discharging gained criticize go forward side by side row filter with the particle that removes any too volume particle size (＞1.4mm).Product yield is about 95%.Bulk density is about 1.05 grams per liters.Product is about 4.5 with respect to the growth factor based on quality of seed.D ₃₀Granularity is about 895um, and blocking starting point relatively is about 5.8 particles.

Embodiment 11: isolating tackiness agent and stratification powder streamer and grain seed on duration of service Mixture is made stratification heavy-duty laundry detergent particulate method

Through spraying drying and mechanical agglomeration method, the seed particle compsn in preparation table 1A row (l) and the table 1B row (m) carries out classifying screen subsequently and selects the particle between 425 microns and 1400 microns respectively.As show 2A row (l) said preparation stratification powder composition.The binder blend of preparation LABS (HLAS) and ethoxylation hexanediamine quaternary salt (EHDQ), its mass ratio are about 86% HLAS and 14% EHDQ.The heated adhesive mixture is to about 60 ℃, and its viscosity is about 150cp.

The seed particle of the about 0.28kg of quality; By mass ratio is table 1B row (m) granulometric composition of about 25% table 1A row A (l) particle and 75%; Combination bulk density with about 0.8 kg/liter; It is added among the Kenwood Food Processor Model FP370, and turn on agitator to speed is provided with #2 in whisking appliance, to produce centrifugal flow pattern.Carry out a series of four continuous stratification steps then; The adhesive droplets that alternately adds about 15 grams via syringe; In whisking appliance, contact seed particle, contact also through about 15 to 25 gram stratification powder of whip topping adding, adds more tackiness agent then; More stratification powder or the like is until making up lamellated product composition around seed particle.

Embodiment 12: block starting point and measure

In this embodiment, the stratification particulate that is provided for measuring embodiment 9 blocks starting point and absolute detailed method of blocking starting point relatively.

At first, according to method 5, " Flowable Particle Mass Based Cumulative Particle Size Distribution Test " measures percent 30 granularity (D ₃₀).30% mass accumulation is between 600um and the 850um, like table 6, " Particle Size Data ".Can obtain Log (D with respect to pushing away percent 30 in Log (size) data ₃₀) be 2.8542 and D ₃₀Be 715um.

According to method 6, " obstruction starting point " measured relatively and the absolute starting point of blocking.At table 7, the data that provide test to obtain in " obstruction starting point data ".In order to obtain nondimensional relative obstruction starting point, with D ₃₀Granularity is converted into the unit identical with hole dimension.Required 25% mass discharge falls between non-dimensional hole dimension (b) 5.59 and 6.99.Pushing away in carrying out with respect to the mass percent emissions data and can obtaining measured relative obstruction starting point is 6.07 particulates, is 4.34 millimeters and definitely block starting point.

Embodiment 13: isolating tackiness agent and the manufacturing of stratification powder streamer are used for inventory on the usage space The stratification particulate method of dish washing composition

Use Sweco 24 " Vibro-Energy Round Separator, will be screened by the seed particle compsn in the table 1B row (p) of spray drying process preparation, to obtain the particulate of granularity between about 300 and 850 microns.Quality is that about 350kg and the seed particle with bulk density of about 0.6 kg/liter are added into twin shaft counter-rotating paddle stirrer (Bella then ^TMB-1000XN), said whisking appliance has carried out reequiping the distribution piping adding tackiness agent that is positioned at below, convergent flow zone with use.Turn on agitator, twin shaft reverses with about 45RPM.Each axle has 14 oars, is mounted to 7 pairs of oars of each axle.With alcohol alkoxylates liquid heat to the viscosity about 40cp of quality for about 20kg; Under the speed of about 10 kg/min, add whip topping then via the press atomization mouth; So that the formation atomised droplets then makes said droplet contact fluidizing seed particle in whisking appliance central authorities.After adding alcohol alkoxylates, add the combination of successive tackiness agent and stratification powder, to form the internal layer that has more the water absorbability chemical property relatively that centers on by the skin that contains less hygroscopic material.Total stratification time behind the adding alcoxylates is about 8 minutes.

The continuous stratification powder packets that adds is drawn together two kinds of stratification powder.Through near above the descending oar path position of whisking appliance end wall, be positioned at diagonal two imports of whisking appliance, the first stratification powder that will show 2B row (x) with the speed of about 45 kg/min is on average shunted and was added whip topping 5 minutes.After accomplish adding the first stratification powder,, add the second stratification powder 3 minutes and 15 seconds of table 2B row (p) with the speed of about 40 kg/min through identical import.

With begin to add the stratification powder simultaneously, use 4 hole distribution pipings to add about 41% weight solid sodium silicate binder solution through the whisking appliance bottom, tackiness agent upwards flows into the convergent flow zone, crosses over three oar positions of central authorities.Speed with about 11 kg/min added sodium silicate solution about 8 minutes.With the adding sodium silicate binder while; Through being installed in the nozzle of whip topping central authorities; The about 32% weight solid ZX-I polymer binder solution of atomized spray, so that adhesive droplets contacts particulate in whisking appliance central authorities, said seed particle is fluidized herein.Polymers soln sprayed about 8 minutes with the speed of about 3 kg/min.

Gained criticizes and discharges, screen with remove any excessive particle (＞1.2mm), and in fluidized-bed, use about 10 minutes of the air stream drying of the about 130 ℃ air of temperature in and about 260 kg/min.Product yield is about 90%; Residue carries out milled processed and recycling is used as seed or stratification powder.

Its relative obstruction starting point of acceptable particle is about 7.2 particulates, and product fast and stable property obstruction starting point is about 8.0 particulates.

Embodiment 14: manufacturing is used for the stratification particulate continuation method that the inventory dishwashing is washed

Use multilayer Mogensen Sizer , to carrying out step sizing to obtain to be in the granularity between about 420 and 1000 microns through the seed particle compsn in the 1B row (s) of mechanical agglomeration method preparation.The tailing of screening method suits to return agglomeration process and carries out recycling.With about 650 kilograms/hour speed, the seed material of classification is added continuously the main-inlet of Lodige KM-600 whisking appliance.The KM-600 whisking appliance is furnished with the colter agitation elements with the tip speed rotation of about 2 meter per seconds.Two high speed cutters along stirrer shaft to the colter position between.Two tube inlets through cutter belows add 41% sodium silicate aqueous solution continuously to the KM-600 whisking appliance.The combined flow of silicate solutions is about 75 kilograms/hour.Use Netzsch-Condux CUM-150 bearing pin kibbler that the yellow soda ash anhydrous powder is carried out micronization to form tiny stratification powder, then it is added continuously two positions of whisking appliance cutting knife top.The stratification powder adds with about 275 kilograms/hour group speed.Total percent of pass of stratification method is about 1 tonne/hour continuously.Water in the silicate solutions is basically by the hydration of yellow soda ash stratification powder.Do not need further drying.

Dimension disclosed herein and numerical value should not be construed as strictness and are confined to the accurate numerical value quoted.On the contrary, except as otherwise noted, each such dimension be meant the numerical value of quoting and the scope that is equal on the function of this numerical value.For example, the dimension that is disclosed as " 40mm " is intended to expression " about 40mm ".

The All Files of in detailed Description Of The Invention, quoting is all introduced this paper for your guidance in relevant portion.Should not be interpreted as for quoting of any file and to admit that it is relevant prior art of the present invention.When any implication of term in any implication of term among the present invention or definition and the file of introducing for your guidance or when defining contradiction, should obey the implication or the definition of giving this term in the present invention.

Though illustrated and described specific embodiments of the present invention, it will be apparent to one skilled in the art that and under the situation that does not deviate from spirit and scope of the invention, can make a plurality of other changes and modification.Therefore, claims are intended to comprise within the scope of the present invention all such changes and modification.

Claims

1. particle that comprises particulate; Said particulate comprises at least a seed and at least one layer; Said layer is coated on the said seed at least in part, said particle have about 2 to about 14 relative obstruction starting point and about 250 microns to about 4,000 microns median particle.

2. particle as claimed in claim 1, said particle have about 600 microns to about 750 microns median particle.

3. particle as claimed in claim 1, said particle have the bulk density of about 350 grams per liters to about 2000 grams per liters.

4. particle as claimed in claim 1, said particle have about 1.0 to about 1.4 intermediate value particle aspect ratios.

5. particle as claimed in claim 1, at least a group of forming by following that is selected from wherein said one or more seeds: hollow minute particle, the seed that contains the hole, capsule encapsulation object, comprise active substance contain hole seed and their mixture.

6. particle as claimed in claim 1 wherein has in said seed:

(i) about 150 microns to about 1700 microns median particle diameter;

(ii) randomly about 1.0 to about 2.0 size-grade distribution span;

The seed bulk density of (iii) about 50 grams per liters to about 2000 grams per liters; With

(iv) randomly, about 1 to about 2 intermediate value particle aspect ratios.

7. particle as claimed in claim 1, said particle have about 2 to about 18 fast and stable property and block starting point relatively.

8. finished product, said finished product comprises particle as claimed in claim 1.

9. finished product as claimed in claim 8, said finished product have about 2 to about 14 relative obstruction starting point.

10. finished product, said finished product comprises particle as claimed in claim 6.

11. finished product as claimed in claim 10, said finished product have about 2 to about 14 relative obstruction starting point.

12. a finished product, said finished product comprises particle as claimed in claim 5, and said finished product has about 2 to about 14 relative obstruction starting point.

13. a finished product, said finished product comprises particle as claimed in claim 7, and said finished product has about 2 to about 18 fast and stable property and blocks starting point relatively.

14. a method of handling and/or cleaning, said method comprises:

A.) randomly the washing and/or a certain zone of rinsing;

B.) make this regional at least a portion contact particle as claimed in claim 1 and/or finished product as claimed in claim 8; With

C.) the randomly washing and/or the said part in said zone of rinsing or said zone subsequently.

15. wrapped product; Said wrapped product comprises finished product as claimed in claim 9; Said wrapped product comprises the product feed well, and said product feed well has approximately greater than the absolute obstruction starting point of said finished product but less than the critical gap size of four times said absolute obstruction starting point.

16. wrapped product as claimed in claim 15, said wrapped product are contained in the packing of partially transparent at least.

17. one kind is used to produce the particulate method; Said method is included in the counter-rotating twin shaft paddle stirrer particulate is contacted with the tackiness agent that comprises liquid, and wherein said tackiness agent is introduced in said whisking appliance through the import that is arranged in said twin shaft paddle stirrer bottom.

18. method as claimed in claim 17 is wherein introduced said tackiness agent, makes said tackiness agent orientation upwards enter into the convergent flow zone between said anti-rotary propeller type axle.

19. method as claimed in claim 17; Wherein said counter-rotating twin shaft paddle stirrer has the convergent flow zone between said anti-rotary propeller type axle; And the swept volume of said anti-rotary propeller type axle is not overlapping in said convergent flow zone, and said tackiness agent orientation enters into the gap between the swept volume of said anti-rotary propeller type axle.

20. method as claimed in claim 17, wherein said tackiness agent have the viscosity of about 1cp to about 100000cp.

21. method as claimed in claim 17, wherein said import comprise the distribution piping of the below, convergent flow zone that is positioned at said anti-rotary propeller type axle, said distribution piping comprises one or more holes.

22. particle as claimed in claim 1, effervesce when wherein said particle contacts with water.

23. particle as claimed in claim 1, wherein said particle is:

A.) industrial chemical;

B.) edible food, instant drinks mixture, medicine or nutritious prod;

C.) pet food and/or pet nursing particle; Or

D.) washing composition, fabric treating, personal cleanliness, hair-care and/or fertiliser granulates.

24. finished product as claimed in claim 8, wherein said finished product is:

A.) industrial chemical;

B.) edible food, instant drinks mixture, medicine or nutritious prod;

C.) pet food and/or pet care product; Or

D.) washing composition, fabric treating, personal cleanliness, hair-care and/or fertilizer product.