CN102504725A - Book side glue and production method thereof - Google Patents
Book side glue and production method thereof Download PDFInfo
- Publication number
- CN102504725A CN102504725A CN2011103058053A CN201110305805A CN102504725A CN 102504725 A CN102504725 A CN 102504725A CN 2011103058053 A CN2011103058053 A CN 2011103058053A CN 201110305805 A CN201110305805 A CN 201110305805A CN 102504725 A CN102504725 A CN 102504725A
- Authority
- CN
- China
- Prior art keywords
- eva
- vinyl acetate
- side glue
- parts
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention designs book side glue which comprises 10 to 20 parts of paraffin, 0 to 10 parts of polyethylene wax, 5 to 30 parts of EVA (ethylene vinyl acetate copolymer) with VA (vinyl acetate) content of 28 percent and melt index of 25, 5 to 30 parts of EVA (Ethylene vinyl acetate Copolymer) with VA (vinyl acetate) content of 28 percent and melt index of 400, 5 to 30 parts of EVA (Ethylene vinyl acetate Copolymer) with VA (vinyl acetate) content of 33 percent and melt index of 25, 0.1 to 1.5 parts of antioxidant, 0 to 5 parts of plasticizer, 2 to 10 parts of stuffing, 5 to 20 parts of polyolefin, 5 to 30 parts of abietic resin, 5 to 30 parts of petroleum resin and 0.1 to 1 part of coupling agent. The book side glue can be used for adhering a book, of which a cover is coated with a film or a special ink system, the bonding intensity is high, and the phenomenon of degumming is difficult to generate, etc. Moreover, the book side glue also has high bonding strength for a special material, so that the book side glue has wider bonding application range. The book side glue has curing time of 7 to 14 seconds. A formula of the book side glue can be regulated, so that the book side glue meets the requirements on different types of equipment and different operating speeds.
Description
Technical field
The present invention relates to the production field of hot melt adhesive, especially a kind of books and periodicals side glue and working method thereof.
Background technology
Hot melt adhesive can be applicable to aspect of social life, mainly contains: building and finishing industry, electronic enterprises, packaging industry, carpentry, paper conversion and bookbinding industry, shoemaking industry, sanitary material and medical industry or the like.For example in the packaging industry, beverage industries, milk industry, beer industry etc. since the use heat melten gel has promptly been taken leave of the history of tying up, are directly used the spreadometer automatic glue-spraying, are packed, and have realized at a high speed, automatically, stably maybe.Adhesive bookbinding industry for another example uses the adhesive bookbinding quality of wireless perfrct binding good, and process velocity is fast, and is applied widely, applies rapidly in China in recent years.Wireless perfrct binding substitutes the old technology of iron wire flat stitching basically.
Safety and environmental protection, the hot melt adhesive that is suitable for high-speed automated production has become the main tackiness agent kind of developed country, and in the five-year, hot melt adhesive will be one of global fastest-rising kind.Wherein adhesive bookbinding is used hot melt adhesive; Especially books and periodicals side glue require increasingly high; This mainly is because the used paper type of books and periodicals is various, model is complicated, and also has multiple overlay film, and book and periodical printing often uses printing ink in addition; And ink thickness is different, system is various, and the existing common books and periodicals side of the EVA single mass system glue in market can not satisfy widely-used requirement.
Common books and periodicals side glue his-and-hers watches mask has overlay film system or surface poor for the bonding intensity of the books and periodicals of special ink system, and the phenomenon that often occurs coming unstuck, being backless is also firm inadequately to the bonding of specialties, influences the adhesive bookbinding quality.
Summary of the invention
The objective of the invention is provides a kind of bonding suitability wide for the deficiency that solves above-mentioned technology, and to printing ink, books and periodicals side glue and working method thereof that overlay film system bonding intensity is high.
In order to achieve the above object, the books and periodicals side glue that the present invention designed, it comprises paraffin 10-20 part, polyethylene wax 0-10 part; VA (vinyl acetate between to for plastic) content is 28%, and melting index is EVA (Injecatable EVA Copolymer) 5-30 part of 25, and VA (vinyl acetate between to for plastic) content is 28%, and melting index is EVA (Injecatable EVA Copolymer) 5-30 part of 400; VA (vinyl acetate between to for plastic) content is 33%, and melting index is EVA (Injecatable EVA Copolymer) 5-30 part of 25, oxidation inhibitor 0.1-1.5 part, softening agent 0-5 part; Filler 2-10 part, polyolefine 5-20 part, Gum Rosin 5-30 part; Petroleum resin 5-30 part, coupling agent 0.1-1 part more than is mass fraction.
Above-mentioned oxidation inhibitor is chain-transfer agent or is the resistance phenols; Filler is talcum powder or clay or lime carbonate.
The working method of described books and periodicals side glue: at first, reaction kettle is heated to 150 degrees centigrade and temperature control, adds paraffin and polyethylene wax; After treating to dissolve fully, three kinds of EVA, comprising: VA (vinyl acetate between to for plastic) content is 28%; Melting index is 25 EVA (Injecatable EVA Copolymer), and VA (vinyl acetate between to for plastic) content is 28%, and melting index is that 400 EVA (Injecatable EVA Copolymer) and VA (vinyl acetate between to for plastic) content are 33%; Melting index is 25 EVA (ethylene vinyl acetate); After oxidation inhibitor, filler, softening agent and coupling agent are mixed thoroughly, progressively add in the reaction kettle, treat to be cooled to 130 degrees centigrade and temperature control after all dissolvings, progressively add polyolefine, Gum Rosin, petroleum resin more successively; Treat to be cooled to 120 degrees centigrade and temperature control after all dissolvings; Pressure-controlling: keep normal pressure in the reinforced process, reinforced accomplish and be cooled to 120 degrees centigrade after vacuumized 10-15 minute, be adjusted into normal pressure again; Churning time: in reinforced process, keep stirring, slow down after reinforced the completion and stir, stirring was controlled at 2-3 hour total time; Last discharging, cooling obtains books and periodicals side glue finished product after the granulation.
The present invention's resulting books and periodicals side glue and working method thereof, the books and periodicals side glue that it obtains can carry out bonding to the books and periodicals of front cover overlay film or special ink system, and bonding intensity is high, difficult phenomenon such as come unstuck.In addition, this books and periodicals side glue also has higher bonding strength to extraordinary material, makes its adherent scope of application wider.Be 7-14 second the set time of this books and periodicals side glue, can adjust prescription and make it satisfy different model equipment, different travelling speed requirement.
Embodiment
Through embodiment the present invention is done further description below.
Embodiment 1:
The books and periodicals side glue that present embodiment is described, it comprises paraffin 10-20 part, polyethylene wax 0-10 part, VA (vinyl acetate between to for plastic) content is 28%; Melting index is EVA (Injecatable EVA Copolymer) 5-30 part of 25, and VA (vinyl acetate between to for plastic) content is 28%, and melting index is EVA (Injecatable EVA Copolymer) 5-30 part of 400, and VA (vinyl acetate between to for plastic) content is 33%; Melting index is EVA (Injecatable EVA Copolymer) 5-30 part of 25, oxidation inhibitor 0.1-1.5 part, softening agent 0-5 part; Filler 2-10 part, polyolefine 5-20 part, Gum Rosin 5-30 part; Petroleum resin 5-30 part, coupling agent 0.1-1 part more than is mass fraction.
Above-mentioned oxidation inhibitor is chain-transfer agent or is the resistance phenols; Filler is talcum powder or clay or lime carbonate.
The working method of described books and periodicals side glue: at first, reaction kettle is heated to 150 degrees centigrade and temperature control, adds paraffin and polyethylene wax; After treating to dissolve fully, three kinds of EVA, comprising: VA (vinyl acetate between to for plastic) content is 28%; Melting index is 25 EVA (Injecatable EVA Copolymer), and VA (vinyl acetate between to for plastic) content is 28%, and melting index is that 400 EVA (Injecatable EVA Copolymer) and VA (vinyl acetate between to for plastic) content are 33%; Melting index is 25 EVA (ethylene vinyl acetate); After oxidation inhibitor, filler, softening agent and coupling agent are mixed thoroughly, progressively add in the reaction kettle, treat to be cooled to 130 degrees centigrade and temperature control after all dissolvings, progressively add polyolefine, Gum Rosin, petroleum resin more successively; Treat to be cooled to 120 degrees centigrade and temperature control after all dissolvings; Pressure-controlling: keep normal pressure in the reinforced process, reinforced accomplish and be cooled to 120 degrees centigrade after vacuumized 10-15 minute, be adjusted into normal pressure again; Churning time: in reinforced process, keep stirring, slow down after reinforced the completion and stir, stirring was controlled at 2-3 hour total time; Last discharging, cooling, granulation can obtain books and periodicals side glue finished product.
Claims (3)
1. a books and periodicals side glue is characterized in that it comprises paraffin 10-20 part, polyethylene wax 0-10 part, and VA (vinyl acetate between to for plastic) content is 28%; Melting index is EVA (Injecatable EVA Copolymer) 5-30 part of 25, and VA (vinyl acetate between to for plastic) content is 28%, and melting index is EVA (Injecatable EVA Copolymer) 5-30 part of 400, and VA (vinyl acetate between to for plastic) content is 33%; Melting index is EVA (Injecatable EVA Copolymer) 5-30 part of 25, oxidation inhibitor 0.1-1.5 part, softening agent 0-5 part; Filler 2-10 part, polyolefine 5-20 part, Gum Rosin 5-30 part; Petroleum resin 5-30 part, coupling agent 0.1-1 part more than is mass fraction.
2. books and periodicals side glue according to claim 1 is characterized in that described oxidation inhibitor is chain-transfer agent or is the resistance phenols; Filler is talcum powder or clay or lime carbonate.
3. the working method of a books and periodicals side glue as claimed in claim 1 is characterized in that reaction kettle is heated to 150 degrees centigrade and temperature control, adds paraffin and polyethylene wax; After treating to dissolve fully, three kinds of EVA, comprising: VA (vinyl acetate between to for plastic) content is 28%; Melting index is 25 EVA (Injecatable EVA Copolymer), and VA (vinyl acetate between to for plastic) content is 28%, and melting index is that 400 EVA (Injecatable EVA Copolymer) and VA (vinyl acetate between to for plastic) content are 33%; Melting index is 25 EVA (Injecatable EVA Copolymer); After oxidation inhibitor, filler, softening agent and coupling agent are mixed thoroughly, progressively add in the reaction kettle, treat to be cooled to 130 degrees centigrade and temperature control after all dissolvings, progressively add polyolefine, Gum Rosin, petroleum resin more successively; Treat to be cooled to 120 degrees centigrade and temperature control after all dissolvings; Pressure-controlling: keep normal pressure in the reinforced process, reinforced accomplish and be cooled to 120 degrees centigrade after vacuumized 10-15 minute, be adjusted into normal pressure again; Churning time: in reinforced process, keep stirring, slow down after reinforced the completion and stir, stirring was controlled at 2-3 hour total time; Last discharging, cooling, granulation can obtain books and periodicals side glue finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110305805.3A CN102504725B (en) | 2011-10-11 | 2011-10-11 | Book side glue and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110305805.3A CN102504725B (en) | 2011-10-11 | 2011-10-11 | Book side glue and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102504725A true CN102504725A (en) | 2012-06-20 |
| CN102504725B CN102504725B (en) | 2014-04-09 |
Family
ID=46216862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110305805.3A Expired - Fee Related CN102504725B (en) | 2011-10-11 | 2011-10-11 | Book side glue and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102504725B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838949A (en) * | 2012-09-27 | 2012-12-26 | 浙江固特热熔胶有限公司 | Back glue for books and magazines and production method thereof |
| CN105778826A (en) * | 2016-03-25 | 2016-07-20 | 日邦树脂(无锡)有限公司 | Preparation method of hot melt adhesive for low-temperature high-compatibility package |
| CN106318277A (en) * | 2016-08-30 | 2017-01-11 | 浙江固特热熔胶有限公司 | High-speed linkage line bookbinding gum |
| CN106398591A (en) * | 2015-07-31 | 2017-02-15 | 浙江固特热熔胶有限公司 | High-strength transparent back adhesive and preparation method thereof |
| CN106433517A (en) * | 2015-08-07 | 2017-02-22 | 浙江固特热熔胶有限公司 | High-strength hardcover book flat spreading back adhesive and preparation method thereof |
| CN107652920A (en) * | 2017-09-25 | 2018-02-02 | 浙江固特热熔胶有限公司 | A kind of picture album bands bookbinding glue and preparation method thereof |
| CN109096950A (en) * | 2018-06-29 | 2018-12-28 | 浙江固特热熔胶有限公司 | A kind of low-temperature environment-friendly packaging glue and preparation method thereof |
| CN109852291A (en) * | 2018-12-25 | 2019-06-07 | 广州聚才新材料有限公司 | Adhesive bookbinding carries on the back the universal hot melt adhesive in side and production method |
| CN110819267A (en) * | 2018-08-08 | 2020-02-21 | 佛山市南海骏驰新材料有限公司 | Book back glue suitable for high-gram coated paper |
| CN116694090A (en) * | 2023-07-28 | 2023-09-05 | 苏州泰尔航空材料有限公司 | Environment-friendly low-temperature molding material and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280162A (en) * | 2008-05-29 | 2008-10-08 | 同济大学 | Preparation of low-cost hot-melt adhesive |
-
2011
- 2011-10-11 CN CN201110305805.3A patent/CN102504725B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280162A (en) * | 2008-05-29 | 2008-10-08 | 同济大学 | Preparation of low-cost hot-melt adhesive |
Non-Patent Citations (3)
| Title |
|---|
| 李佩瑾等: "书刊装订用EVA热熔胶的研制", 《化学工程师》 * |
| 赵竹仙: "书刊装订用热熔胶性能及其应用", 《印刷世界》 * |
| 邸明伟等: "热熔型纸塑复合预涂膜的研制", 《中国胶粘剂》 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838949A (en) * | 2012-09-27 | 2012-12-26 | 浙江固特热熔胶有限公司 | Back glue for books and magazines and production method thereof |
| CN106398591A (en) * | 2015-07-31 | 2017-02-15 | 浙江固特热熔胶有限公司 | High-strength transparent back adhesive and preparation method thereof |
| CN106398591B (en) * | 2015-07-31 | 2018-04-17 | 浙江固特热熔胶有限公司 | High-strength transparence gum and preparation method thereof |
| CN106433517A (en) * | 2015-08-07 | 2017-02-22 | 浙江固特热熔胶有限公司 | High-strength hardcover book flat spreading back adhesive and preparation method thereof |
| CN105778826A (en) * | 2016-03-25 | 2016-07-20 | 日邦树脂(无锡)有限公司 | Preparation method of hot melt adhesive for low-temperature high-compatibility package |
| CN105778826B (en) * | 2016-03-25 | 2018-01-23 | 日邦树脂(无锡)有限公司 | A kind of preparation method of low temperature high-compatibility hot fusible adhesive for package |
| CN106318277A (en) * | 2016-08-30 | 2017-01-11 | 浙江固特热熔胶有限公司 | High-speed linkage line bookbinding gum |
| CN107652920A (en) * | 2017-09-25 | 2018-02-02 | 浙江固特热熔胶有限公司 | A kind of picture album bands bookbinding glue and preparation method thereof |
| CN109096950A (en) * | 2018-06-29 | 2018-12-28 | 浙江固特热熔胶有限公司 | A kind of low-temperature environment-friendly packaging glue and preparation method thereof |
| CN110819267A (en) * | 2018-08-08 | 2020-02-21 | 佛山市南海骏驰新材料有限公司 | Book back glue suitable for high-gram coated paper |
| CN109852291A (en) * | 2018-12-25 | 2019-06-07 | 广州聚才新材料有限公司 | Adhesive bookbinding carries on the back the universal hot melt adhesive in side and production method |
| CN116694090A (en) * | 2023-07-28 | 2023-09-05 | 苏州泰尔航空材料有限公司 | Environment-friendly low-temperature molding material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102504725B (en) | 2014-04-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102504725B (en) | Book side glue and production method thereof | |
| CN102153968B (en) | Hot melt adhesive for medical dialyzing paper | |
| CN102181246B (en) | Heat-resistant hot melt adhesive and preparation method and application thereof | |
| CN101928530A (en) | Edge sealing hot melt adhesive for furniture and preparation method thereof | |
| CN102838949A (en) | Back glue for books and magazines and production method thereof | |
| CN108395854A (en) | A kind of hot fusible adhesive for package | |
| CN100558839C (en) | Hot-melt adhesive composition | |
| CN111019559A (en) | EVA hot melt adhesive for rapid box sealing and preparation method thereof | |
| CN105349088A (en) | Novel hot-melt adhesive and preparation method thereof | |
| CN103666369A (en) | Hot-melt adhesive with excellent heat resistance and hot-melt adhesive tape | |
| JP4605521B2 (en) | Hot melt adhesive composition | |
| CN108239494A (en) | Hot melt adhesive for sticking pipes to dairy products | |
| CN102618194A (en) | Hot melt pressure sensitive adhesive for high speed automatic labeling and preparation method thereof | |
| CN110240883A (en) | Domestic air filter filter paper hot melt adhesive and preparation method thereof | |
| CN103242782A (en) | Circular-to-circular high-speed hot gold stamping gum | |
| CN104762032A (en) | High and low temperature-resistant and fat oil-resistant hot melt adhesive and preparation method thereof | |
| CN102618212B (en) | Hot melt adhesive and preparation process and application thereof | |
| CN106833514B (en) | A kind of hot melt adhesive and preparation method thereof | |
| CN108864987A (en) | Hot melt adhesive for air conditioner internal unit | |
| CN105419655B (en) | A kind of holography electrochemical aluminium thermoprinting glue and preparation method thereof | |
| CN112322234A (en) | Low-cost quick-binding hot melt adhesive and preparation method thereof | |
| CN110819267A (en) | Book back glue suitable for high-gram coated paper | |
| CN104745122A (en) | Hot melt adhesive and preparation process thereof | |
| CN101759909A (en) | Coating-free directly combined film additive | |
| CN109280512A (en) | A kind of low grams art paper gum and its production technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140409 Termination date: 20161011 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |