CN102477505A - Aluminum alloy doped with strontium element and manufacturing method thereof - Google Patents
Aluminum alloy doped with strontium element and manufacturing method thereof Download PDFInfo
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- CN102477505A CN102477505A CN2010105659553A CN201010565955A CN102477505A CN 102477505 A CN102477505 A CN 102477505A CN 2010105659553 A CN2010105659553 A CN 2010105659553A CN 201010565955 A CN201010565955 A CN 201010565955A CN 102477505 A CN102477505 A CN 102477505A
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- Prior art keywords
- strontium
- alloy
- silicon
- mass percent
- percent concentration
- Prior art date
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- 229910052712 strontium Inorganic materials 0.000 title claims abstract description 53
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 229910000838 Al alloy Inorganic materials 0.000 title abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 35
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910001278 Sr alloy Inorganic materials 0.000 claims abstract description 32
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 25
- 239000010703 silicon Substances 0.000 claims abstract description 25
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052802 copper Inorganic materials 0.000 claims abstract description 23
- 239000010949 copper Substances 0.000 claims abstract description 23
- 238000003756 stirring Methods 0.000 claims abstract description 15
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011777 magnesium Substances 0.000 claims abstract description 14
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 14
- 238000007872 degassing Methods 0.000 claims abstract description 13
- 238000005266 casting Methods 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 8
- 239000011572 manganese Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 229910000737 Duralumin Inorganic materials 0.000 claims description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 26
- 239000004411 aluminium Substances 0.000 claims description 23
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 13
- 229910052742 iron Inorganic materials 0.000 claims description 13
- 229910052759 nickel Inorganic materials 0.000 claims description 13
- 229910052718 tin Inorganic materials 0.000 claims description 13
- 239000011701 zinc Substances 0.000 claims description 13
- 229910052725 zinc Inorganic materials 0.000 claims description 13
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
- 239000011135 tin Substances 0.000 claims description 6
- 239000000956 alloy Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 229910045601 alloy Inorganic materials 0.000 abstract description 3
- 239000013078 crystal Substances 0.000 abstract description 2
- YNDGDLJDSBUSEI-UHFFFAOYSA-N aluminum strontium Chemical compound [Al].[Sr] YNDGDLJDSBUSEI-UHFFFAOYSA-N 0.000 abstract 3
- 229910000881 Cu alloy Inorganic materials 0.000 abstract 2
- -1 aluminum-silicon-copper Chemical compound 0.000 abstract 2
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
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- Manufacture And Refinement Of Metals (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
Abstract
The invention relates to the field of aluminum-based alloy with silicon as a secondary main component, in particular to strontium-doped aluminum-silicon-copper alloy and a manufacturing method thereof. The strontium doped aluminum-silicon-copper alloy comprises aluminum, silicon, copper, manganese and magnesium and is characterized in that: also comprises strontium, and the mass percent concentration of the strontium is 0.015-0.035%. The manufacturing method of the strontium-doped aluminum alloy comprises the following 5 steps of material mixing, melting, stirring, degassing and casting in sequence, and is characterized in that: the method also comprises adding the aluminum strontium alloy, wherein the adding of the aluminum strontium alloy is carried out between stirring and degassing, and the temperature of the aluminum liquid is controlled between 720 ℃ and 750 ℃ when the aluminum strontium alloy is added. The casting of the invention has refined crystal grains and high mechanical property.
Description
Technical field
The present invention relates to silicon and do the aluminum base alloy field of time staple, be specially a kind of duraluminum and method of manufacture thereof of supporting by the arm strontium element.
Background technology
Duraluminum is with its light weight, corrosion resistant characteristic and be used widely at aviation, automotive field.Be applied as with cast aluminium alloy in the mechanical manufacturing field many, but present cast aluminium alloy, it is excessive also to exist behind the alloy graining crystal grain of material, metallographic structure is undesirable, influences the mechanical property of foundry goods.
Summary of the invention
In order to overcome the defective of prior art, a kind of cast aluminium alloy that contraction speed is fast, the foundry goods mechanical property is high is provided, the invention discloses a kind of duraluminum and method of manufacture thereof of supporting by the arm strontium element.
The present invention reaches goal of the invention through following technical scheme:
A kind of duraluminum of supporting by the arm strontium element comprises aluminium, silicon and copper, and the mass percent concentration of each component is respectively:
Component | Mass percent concentration (%) |
Silicon | 10.5~12 |
Copper | 1.5~3.5 |
Magnesium | 0~0.3 |
Zinc | 0~1.0 |
Iron | 0~1.3 |
Manganese | 0~0.5 |
Nickel | 0~0.5 |
Tin | 0~0.3 |
Aluminium | Surplus |
It is characterized in that: also comprise strontium, the mass percent concentration of strontium is: 0.015%~0.035%.
A kind of method of manufacture of supporting by the arm the duraluminum of strontium element comprises these 5 steps of batching, fusing, stirring, degasification and casting of carrying out successively, during batching, with silicon, copper, magnesium, zinc, iron, manganese, nickel, tin and aluminium in following ratio uniform mixing:
Component | Mass percent concentration (%) |
Silicon | 10.5~12 |
Copper | 1.5~3.5 |
Magnesium | 0~0.3 |
Zinc | 0~1.0 |
Iron | 0~1.3 |
Manganese | 0~0.5 |
Nickel | 0~0.5 |
Tin | 0~0.3 |
Aluminium | Surplus |
It is characterized in that: also comprise adding al-sr alloy, the mass percent concentration of strontium is 0.015%~0.035%, adds al-sr alloy and between stirring and degasification, carries out, and when adding al-sr alloy, the control temperature of aluminum liquid is between 720 ℃~750 ℃.
Described method of manufacture of supporting by the arm the duraluminum of strontium element is characterized in that: when adding al-sr alloy, the mass percent concentration of added its strontium of al-sr alloy is 8%~12%.
When the present invention used, these 6 steps in sequence of al-sr alloy, degasification and casting carried out making the duraluminum that contains strontium according to preparing burden, melt, stir, adding.The present invention makes the material metallographic structure become excellent through in duraluminum, adding an amount of strontium element with the refinement material grains, to improve the mechanical property of duraluminum, has especially strengthened fatigue resistance, can be used for automotive wheel.
Original aluminum alloy materials that does not contain strontium, when adopting die cast, tensile strength is 225N/mm
2, elongation is 2.0%, HB hardness is 85.The duraluminum that adopts the present invention to make, when adopting die cast, tensile strength is 256N/mm
2, having improved 13.8%, elongation is 2.57%, has improved 28.5%, HB hardness is 88, has improved 3.5%.
The invention has the beneficial effects as follows: the casting crystalline grain refinement, fatigue resistance is high, and mechanical property is high.
Embodiment
Below further specify the present invention through specific embodiment.
Embodiment 1
A kind of duraluminum of supporting by the arm strontium element comprises aluminium, silicon and copper, and the mass percent concentration of each component is respectively:
Component | Mass percent concentration (%) |
Silicon | 10.5 |
Copper | 1.5 |
Strontium | 0.015 |
Aluminium | Surplus |
A kind of method of manufacture of supporting by the arm the duraluminum of strontium element comprises batching, the fusing carried out successively, stirs, adds these 6 steps of al-sr alloy, degasification and casting, during batching, with silicon, copper, strontium and aluminium in ratio uniform mixing shown in the last table; During fusing, with accomplish raw material after the batching at the stove internal heating to molten state; During stirring, stir aluminium liquid with splash bar; Add al-sr alloy constantly, the control temperature of aluminum liquid is at 720 ℃, and the mass percent concentration of added its strontium of al-sr alloy is 8%.
Embodiment 2
A kind of duraluminum of supporting by the arm strontium element comprises aluminium, silicon and copper, and the mass percent concentration of each component is respectively:
Component | Mass percent concentration (%) |
Silicon | 11 |
Copper | 2.5 |
Strontium | 0.025 |
Aluminium | Surplus |
A kind of method of manufacture of supporting by the arm the duraluminum of strontium element; Comprise batching, the fusing carried out successively, stir, add these 6 steps of al-sr alloy, degasification and casting; Add al-sr alloy constantly, the control temperature of aluminum liquid is at 735 ℃, and the mass percent concentration of added its strontium of al-sr alloy is 10%.Other steps are all same with embodiment 1.
Embodiment 3
A kind of duraluminum of supporting by the arm strontium element comprises aluminium, silicon and copper, and the mass percent concentration of each component is respectively:
Component | Mass percent concentration (%) |
Silicon | 12 |
Copper | 3.5 |
Strontium | 0.035 |
Aluminium | Surplus |
A kind of method of manufacture of supporting by the arm the duraluminum of strontium element; Comprise batching, the fusing carried out successively, stir, add these 6 steps of al-sr alloy, degasification and casting; Add al-sr alloy constantly, the control temperature of aluminum liquid is at 750 ℃, and the mass percent concentration of added its strontium of al-sr alloy is 12%.Other steps are all same with embodiment 1.
Embodiment 4
A kind of duraluminum of supporting by the arm strontium element comprises silicon, copper, magnesium, zinc, iron, manganese, nickel, tin, strontium and aluminium, and the mass percent concentration of each component is respectively:
Component | Mass percent concentration (%) |
Silicon | 10.5 |
Copper | 1.5 |
Magnesium | 0.01 |
Zinc | 0.01 |
Iron | 0.01 |
Manganese | 0.01 |
Nickel | 0.01 |
Tin | 0.01 |
Strontium | 0.015 |
Aluminium | Surplus |
A kind of method of manufacture of supporting by the arm the duraluminum of strontium element; Comprise batching, the fusing carried out successively, stir, add these 6 steps of al-sr alloy, degasification and casting; During batching, with silicon, copper, magnesium, zinc, iron, manganese, nickel, tin, strontium and aluminium in ratio uniform mixing shown in the last table; Add al-sr alloy constantly, the control temperature of aluminum liquid is at 720 ℃, and the mass percent concentration of added its strontium of al-sr alloy is 8%.Other steps are all same with embodiment 1.
Embodiment 5
A kind of duraluminum of supporting by the arm strontium element comprises silicon, copper, magnesium, zinc, iron, manganese, nickel, tin, strontium and aluminium, and the mass percent concentration of each component is respectively:
Component | Mass percent concentration (%) |
Silicon | 11 |
Copper | 2.5 |
Magnesium | 0.15 |
Zinc | 0.5 |
Iron | 0.65 |
Manganese | 0.25 |
Nickel | 0.25 |
Tin | 0.15 |
Strontium | 0.025 |
Aluminium | Surplus |
A kind of method of manufacture of supporting by the arm the duraluminum of strontium element; Comprise batching, the fusing carried out successively, stir, add these 6 steps of al-sr alloy, degasification and casting; Add al-sr alloy constantly, the control temperature of aluminum liquid is at 735 ℃, and the mass percent concentration of added its strontium of al-sr alloy is 8%.Other steps are all same with embodiment 4.
Embodiment 6
A kind of duraluminum of supporting by the arm strontium element comprises silicon, copper, magnesium, zinc, iron, manganese, nickel, tin, strontium and aluminium, and the mass percent concentration of each component is respectively:
Component | Mass percent concentration (%) |
Silicon | 12 |
Copper | 3.5 |
Magnesium | 0.3 |
Zinc | 1.0 |
Iron | 1.3 |
Manganese | 0.5 |
Nickel | 0.5 |
Tin | 0.3 |
Strontium | 0.035 |
Aluminium | Surplus |
A kind of method of manufacture of supporting by the arm the duraluminum of strontium element; Comprise batching, the fusing carried out successively, stir, add these 6 steps of al-sr alloy, degasification and casting; Add al-sr alloy constantly, the control temperature of aluminum liquid is at 750 ℃, and the mass percent concentration of added its strontium of al-sr alloy is 12%.Other steps are all same with embodiment 4.
Claims (3)
1. a duraluminum of supporting by the arm strontium element comprises aluminium, silicon and copper, and the mass percent concentration of each component is respectively:
It is characterized in that: also comprise strontium, the mass percent concentration of strontium is 0.015%~0.035%.
2. a method of manufacture of supporting by the arm the duraluminum of strontium element comprises these 5 steps of batching, fusing, stirring, degasification and casting of carrying out successively, during batching, with silicon, copper, magnesium, zinc, iron, manganese, nickel, tin and aluminium in following ratio uniform mixing:
It is characterized in that: also comprise adding al-sr alloy, the mass percent concentration of strontium is 0.015%~0.035%, adds al-sr alloy and between stirring and degasification, carries out, and when adding al-sr alloy, the control temperature of aluminum liquid is between 720 ℃~750 ℃.
3. method of manufacture of supporting by the arm the duraluminum of strontium element as claimed in claim 2 is characterized in that: when adding al-sr alloy, the mass percent concentration of added its strontium of al-sr alloy is 8%~12%.
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CN2010105659553A CN102477505A (en) | 2010-11-30 | 2010-11-30 | Aluminum alloy doped with strontium element and manufacturing method thereof |
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CN2010105659553A CN102477505A (en) | 2010-11-30 | 2010-11-30 | Aluminum alloy doped with strontium element and manufacturing method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102485927A (en) * | 2010-12-01 | 2012-06-06 | 上海万泰铝业有限公司 | Strontium doped Al-Si-Cu alloy and manufacture method thereof |
CN102676862A (en) * | 2012-05-31 | 2012-09-19 | 无锡格莱德科技有限公司 | Process for manufacturing aluminum alloy ingot |
CN102994823A (en) * | 2012-11-20 | 2013-03-27 | 无锡常安通用金属制品有限公司 | Aluminium alloy structural material |
CN109338177A (en) * | 2018-11-13 | 2019-02-15 | 苏州仓松金属制品有限公司 | A kind of rotten aluminum alloy materials of AlSi10Mg system and its rotten production technology |
CN109423564A (en) * | 2017-08-28 | 2019-03-05 | 昭和电工株式会社 | Magnetic recording media aluminium alloy base plate, magnetic recording media substrate, magnetic recording media and hard disk drive |
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CN1410572A (en) * | 2002-10-01 | 2003-04-16 | 西南铝业(集团)有限责任公司 | High silicon cast aluminium spectrum standard sample and its preparation method |
CN101392340A (en) * | 2008-11-14 | 2009-03-25 | 周岳健 | Method for producing water meter case by cast aluminum alloy and products thereof |
WO2009132388A1 (en) * | 2008-04-30 | 2009-11-05 | Commonwealth Scientific And Industrial Research Organisation | Improved aluminium based casting alloy |
CN100577835C (en) * | 2008-01-16 | 2010-01-06 | 无锡海特铝业有限公司 | A kind of method of producing high-silicon aluminum alloy |
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2010
- 2010-11-30 CN CN2010105659553A patent/CN102477505A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1410572A (en) * | 2002-10-01 | 2003-04-16 | 西南铝业(集团)有限责任公司 | High silicon cast aluminium spectrum standard sample and its preparation method |
CN100577835C (en) * | 2008-01-16 | 2010-01-06 | 无锡海特铝业有限公司 | A kind of method of producing high-silicon aluminum alloy |
WO2009132388A1 (en) * | 2008-04-30 | 2009-11-05 | Commonwealth Scientific And Industrial Research Organisation | Improved aluminium based casting alloy |
CN101392340A (en) * | 2008-11-14 | 2009-03-25 | 周岳健 | Method for producing water meter case by cast aluminum alloy and products thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102485927A (en) * | 2010-12-01 | 2012-06-06 | 上海万泰铝业有限公司 | Strontium doped Al-Si-Cu alloy and manufacture method thereof |
CN102676862A (en) * | 2012-05-31 | 2012-09-19 | 无锡格莱德科技有限公司 | Process for manufacturing aluminum alloy ingot |
CN102994823A (en) * | 2012-11-20 | 2013-03-27 | 无锡常安通用金属制品有限公司 | Aluminium alloy structural material |
CN102994823B (en) * | 2012-11-20 | 2015-12-02 | 江苏高博智融科技有限公司 | A kind of Aluminium alloy structural material |
CN109423564A (en) * | 2017-08-28 | 2019-03-05 | 昭和电工株式会社 | Magnetic recording media aluminium alloy base plate, magnetic recording media substrate, magnetic recording media and hard disk drive |
CN109338177A (en) * | 2018-11-13 | 2019-02-15 | 苏州仓松金属制品有限公司 | A kind of rotten aluminum alloy materials of AlSi10Mg system and its rotten production technology |
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Application publication date: 20120530 |