CN102444055A - Decorative wallpaper material for environmentally-friendly wall and preparation method thereof - Google Patents
Decorative wallpaper material for environmentally-friendly wall and preparation method thereof Download PDFInfo
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- CN102444055A CN102444055A CN2011102585196A CN201110258519A CN102444055A CN 102444055 A CN102444055 A CN 102444055A CN 2011102585196 A CN2011102585196 A CN 2011102585196A CN 201110258519 A CN201110258519 A CN 201110258519A CN 102444055 A CN102444055 A CN 102444055A
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- Prior art keywords
- wallpaper material
- plastics
- wall fitting
- environmental protection
- environmentally
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- 239000000463 material Substances 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000004033 plastic Substances 0.000 claims abstract description 34
- 229920003023 plastic Polymers 0.000 claims abstract description 34
- 229920002943 EPDM rubber Polymers 0.000 claims abstract description 24
- 239000003063 flame retardant Substances 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 230000007613 environmental effect Effects 0.000 claims description 23
- 238000003851 corona treatment Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000004698 Polyethylene Substances 0.000 abstract 3
- 239000011247 coating layer Substances 0.000 abstract 3
- 239000010410 layer Substances 0.000 abstract 3
- 229920001169 thermoplastic Polymers 0.000 abstract 2
- 239000004416 thermosoftening plastic Substances 0.000 abstract 2
- 239000004636 vulcanized rubber Substances 0.000 abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 238000004040 coloring Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 238000004500 asepsis Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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Abstract
The invention belongs to the technical field of wallpaper and specifically discloses a decorative wallpaper material for an environmentally-friendly wall and a preparation method thereof. The structure for constituting the decorative wallpaper material for the environmentally-friendly wall comprises a base paper layer and a coating layer or coating layers adhered on the single side or the double sides of the base paper layer, wherein each coating layer comprises 60-90 parts by weight of PE (polyethylene) plastic and 15-25 parts by weight of thermoplastic ethylene-propylene-diene monomer dynamic vulcanized rubber. The decorative wallpaper material for the environmentally-friendly wall is prepared by uncoiling base paper, performing corona, heating the PE plastic containing the thermoplastic ethylene-propylene-diene monomer dynamic vulcanized rubber and a flame retardant for forming a liquid, then forming a film on the paper surface through flowing for forming a covering layer, drying and then coiling. The decorative wallpaper material for the environmentally-friendly wall has the characteristics of no toxicity and environment friendliness and has great coloring and printing performances.
Description
Technical field
The invention belongs to the wallpaper technical field, promptly relate to a kind of environmental protection wall fitting wallpaper material and preparation method thereof.
Background technology
The wall fitting wallpaper is a wall decorative material commonly used such as household, hotel.But at present the widely used decorative wall paper of institute is on the paper of body paper, to be coated with to scrape last layer PVC emulsion, again through strickling, embossing formation.But because characteristics---the one of which of PVC material itself, quality is hard and be difficult to paintedly, so when emulsion is processed in heating, must add a large amount of DEP or DOP plasticizer and dyeing auxiliaries therein and can make that made wallpaper deliquescing is painted; And plasticizer DEP or DOP are noxious materials, contain heavy metal lead and chromium in the dyeing auxiliaries, live in for a long time in the environment that contains DEP or DOP plasticizer and heavy metal lead and chromium wallpaper and can cause great harm to people healthy.Its two, aging cracking own, therefore service life is shorter, must add age resister therein in order to improve its ageing resistace, can the healthy of people be worked the mischief equally and contain ageing-resistant wallpaper, causes the inaccessible environmental requirement of wallpaper.
Summary of the invention
The object of the invention just provides wall fitting wallpaper material of a kind of environmental protection and preparation method thereof.
Realize that the technical scheme that above-mentioned purpose of the present invention adopted is:
A kind of environment-friendly type wall fitting wallpaper material is characterized in that: be made up of original paper layer and the coat that adheres on its single or double; Described coat includes the PE plastics of 60-90 weight portions and the thermoplasticity EPDM dynamic perduren of 15-25 weight portions.
The additional technical feature that constitutes above-mentioned a kind of environmental protection wall fitting wallpaper material comprises:
Described coat contains the fire retardant of 0.1-0.5 weight portion;
The density of said PE plastics is between 0.88-0.92 gram/cubic centimetre;
The thickness of said coat be 55-65 the gram/square metre.
The method for preparing above-mentioned environmental protection wall fitting wallpaper material comprises the following steps:
Body paper is unreeled, and through the sided corona treatment paper, the PE plastics that will contain thermoplasticity EPDM dynamic perduren and fire retardant are heated to 340-380 ℃ and form and flow film on paper after liquid and form cover layer, oven dry back rolling.
A kind of environmental protection wall fitting wallpaper material provided by the present invention and preparation method thereof compared with prior art has the following advantages: one of which; Because constituting the coat of the structure of this its wall fitting wallpaper material is to be made up of the PE plastics that added thermoplasticity EPDM dynamic perduren therein; These PE plastics are a kind of asepsis environment-protecting materials, and the decorative wall paper material that is therefore constituted has the characteristics of asepsis environment-protecting; They are two years old; Owing to itself be mixed with the starch that to degrade in the PE plastics; Therefore, the decorative wall paper material that is constituted accomplish the fixing use age can natural degradation after being eliminated, solved a large amount of waste and old decorative wall paper materials in back that update and caused environmental pollution problems; Its three comprised PE plastics that molecular weight is moderate and an amount of TPV macromolecular elastomer material in the material of above-mentioned environmental protection wall fitting wallpaper material coat owing to constitute, make that the direct colour print performance of wall fitting wallpaper material is better.
Description of drawings
Fig. 1 is the structural representation of single face environmental protection wall fitting wallpaper material;
Fig. 2 is the structural representation of two-sided environmental protection wall fitting wallpaper material.
The specific embodiment
Below in conjunction with accompanying drawing the structure and the use principle of environmental protection wall fitting wallpaper material provided by the present invention are done further to specify:
As depicted in figs. 1 and 2 is the structural representation of environmental protection wall fitting wallpaper material provided by the invention.The structure that promptly constitutes this environmental protection wall fitting wallpaper material comprise by original paper layer 1 with adhere to its lip-deep coat 2 that constitutes by PE plastics and thermoplasticity EPDM dynamic perduren and constitute; Or coat 2 is coated on the coat 2 on original paper layer 1 two sides.
The preparation technology of above-mentioned environmental protection wall fitting wallpaper material may further comprise the steps:
1, body paper unreels, and handles the body paper first surface through corona technology;
The PE plastics that 2, will contain thermoplasticity EPDM dynamic perduren and fire retardant be heated to 340-380 ℃ form liquid back through the stream membrane process through form on the paper of sided corona treatment thickness 55-65 grams/square metre coat;
3, oven dry;
4, rolling.
When the second surface at body paper prepares coat; Repeat first and second operations after second step in above-mentioned operation; Promptly at first handle the body paper second surface through corona technology; The PE plastics that will contain thermoplasticity EPDM dynamic perduren and fire retardant then be heated to 340-380 ℃ form liquid back through the stream membrane process through form on second paper of sided corona treatment thickness 55-65 grams/square metre coat, get final product through oven dry, rolling again.
In above-mentioned preparation technology, are continuous scopes to the heating-up temperature scope of the PE plastics that contain thermoplasticity EPDM dynamic perduren and fire retardant, and adjust according to the content of various compositions is different.
The formation that constitutes above-mentioned environmental protection wall fitting wallpaper material coat is that embodiment is:
1, density is 60 weight portions at the PE of 0.88-0.90 gram/cubic centimetre plastics, thermoplasticity EPDM dynamic perduren 25 weight portions.
2, density is 90 weight portions at the PE of 0.88 gram/cubic centimetre plastics, thermoplasticity EPDM dynamic perduren 15 weight portions.
3, density is 75 weight portions at the PE of 0.90 gram/cubic centimetre plastics, thermoplasticity EPDM dynamic perduren 20 weight portions.
4, density is 80 weight portions at the PE of 0.88-0.90 gram/cubic centimetre plastics, the Firemaster CA 117 of thermoplasticity EPDM dynamic perduren 18 weight portions and 0.5 weight portion.
5, density is 70 weight portions at the PE of 0.88-0.90 gram/cubic centimetre plastics, the fire retardant BS5852 of thermoplasticity EPDM dynamic perduren 20 weight portions and 0.1 weight portion.
6, density is 65 weight portions at the PE of 0.88-0.90 gram/cubic centimetre plastics, the fire retardant that the LM-BS1 flame-proof environmental protection particle of thermoplasticity EPDM dynamic perduren 22 weight portions and 0.3 weight portion (Foshan be full of intelligence chemistry Co., Ltd produce) constitutes.
7, density is 65 weight portions at the PE of 0.92 gram/cubic centimetre plastics, thermoplasticity EPDM dynamic perduren 20 weight portions.
8, density is 75 weight portions at the PE of 0.90 gram/cubic centimetre plastics, thermoplasticity EPDM dynamic perduren 18 weight portions.
9, density is 85 weight portions at the PE of 0.90-0.92 gram/cubic centimetre plastics, thermoplasticity EPDM dynamic perduren 23 weight portions.
10, density is 80 weight portions at the PE of 0.90-0.92 gram/cubic centimetre plastics, the fire retardant that the flame-proof environmental protection particle of U.S.'s mark fireproof powder of thermoplasticity EPDM dynamic perduren 21 weight portions and 0.4 weight portion (Hunan shakes and contains the production of polyurethane material Co., Ltd) constitutes.
11, density is 90 weight portions at the PE of 0.90-0.92 gram/cubic centimetre plastics, the Firemaster CA 117 of thermoplasticity EPDM dynamic perduren 15 weight portions and 0.2 weight portion.
12, density is 70 weight portions at the PE of 0.90-0.92 gram/cubic centimetre plastics, the fire retardant BS5852 of thermoplasticity EPDM dynamic perduren 25 weight portions and 0.3 weight portion.
What fire retardant adopted in the above-described embodiments is the agent of polyurethanes fire retardant.
In the material of above-mentioned environmental protection wall fitting wallpaper material coat constituted, thermoplasticity EPDM dynamic perduren was a kind of macromolecular elastomer material, and its English name is Thermal Plastic Vulcanizate, was called for short TPV.
In the material of above-mentioned environmental protection wall fitting wallpaper material coat constitutes, select the PE plastics of its density for use, i.e. the moderate PE plastics of molecular weight in 0.88-0.92 gram/cubic centimetre scope.Because the molecular weight of the PE plastics of being selected for use is big, density is less; Adding an amount of TPV macromolecular elastomer material; Can make the soft more and high resilience of wall fitting wallpaper material of prepared one-tenth, and solve the adaptability of the direct colour print of wall fitting wallpaper material.If select the PE plastics of density big (also being that molecular weight is less) for use,, also be not enough to make formed coat deliquescing although also add TPV macromolecular elastomer material; The PE plastics of density big (also being that molecular weight is less) heat melt form institute to form colloidal liquid after on stream film to the body paper paper time, can make formed wallpaper material take place to roll up to stick up and be difficult to use.
Claims (5)
1. an environment-friendly type wall fitting wallpaper material is characterized in that: be made up of original paper layer and the coat that adheres on its single or double; Described coat includes the PE plastics of 60-90 weight portions and the thermoplasticity EPDM dynamic perduren of 15-25 weight portions.
2. a kind of environmental protection wall fitting wallpaper material according to claim 1 is characterized in that described coat contains the fire retardant of 0.1-0.5 weight portion.
3. a kind of environmental protection wall fitting wallpaper material according to claim 1 is characterized in that the density of said PE plastics is between 0.88-0.92 gram/cubic centimetre.
4. a kind of environmental protection wall fitting wallpaper material according to claim 1 and 2 is characterized in that, the thickness of said coat be 55-65 the gram/square metre.
5. prepare the method that aforesaid right requires 1 said a kind of environmental protection wall fitting wallpaper material; May further comprise the steps; Body paper is unreeled; Through the sided corona treatment paper, the PE plastics that will contain thermoplasticity EPDM dynamic perduren and fire retardant are heated to 340-380 ℃ and form and flow film on paper after liquid and form cover layer, oven dry back rolling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110258519 CN102444055B (en) | 2011-09-03 | 2011-09-03 | Decorative wallpaper material for environmentally-friendly wall and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110258519 CN102444055B (en) | 2011-09-03 | 2011-09-03 | Decorative wallpaper material for environmentally-friendly wall and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102444055A true CN102444055A (en) | 2012-05-09 |
| CN102444055B CN102444055B (en) | 2013-04-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110258519 Expired - Fee Related CN102444055B (en) | 2011-09-03 | 2011-09-03 | Decorative wallpaper material for environmentally-friendly wall and preparation method thereof |
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| Country | Link |
|---|---|
| CN (1) | CN102444055B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106269447A (en) * | 2016-08-27 | 2017-01-04 | 苏州雅晟建筑装饰工程有限公司 | A kind of waterproof anti-aging decoration wallpaper material |
| CN106758506A (en) * | 2016-12-09 | 2017-05-31 | 湖北恒昊包装科技有限公司 | A kind of corrugated case freeze proof maceration extract of waterproof and its preparation and application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07278504A (en) * | 1994-04-12 | 1995-10-24 | Keiwa Shoko Kk | Application tape for wallpaper |
| CN1789556A (en) * | 2004-12-16 | 2006-06-21 | 三星Total株式会社 | Burning-resistent wallpaper for reducing new house syndrome |
| US20070293640A1 (en) * | 2002-10-15 | 2007-12-20 | Peijun Jiang | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| CN101391203A (en) * | 2007-09-21 | 2009-03-25 | 叶正涛 | Compound powder capable of releasing negative ion with high efficiency and adhesive material thereof |
| CN101443199A (en) * | 2005-02-11 | 2009-05-27 | 浦瑞玛柯Rwp控股公司 | Self-adhesive flaky material |
-
2011
- 2011-09-03 CN CN 201110258519 patent/CN102444055B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07278504A (en) * | 1994-04-12 | 1995-10-24 | Keiwa Shoko Kk | Application tape for wallpaper |
| US20070293640A1 (en) * | 2002-10-15 | 2007-12-20 | Peijun Jiang | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| CN1789556A (en) * | 2004-12-16 | 2006-06-21 | 三星Total株式会社 | Burning-resistent wallpaper for reducing new house syndrome |
| CN101443199A (en) * | 2005-02-11 | 2009-05-27 | 浦瑞玛柯Rwp控股公司 | Self-adhesive flaky material |
| CN101391203A (en) * | 2007-09-21 | 2009-03-25 | 叶正涛 | Compound powder capable of releasing negative ion with high efficiency and adhesive material thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106269447A (en) * | 2016-08-27 | 2017-01-04 | 苏州雅晟建筑装饰工程有限公司 | A kind of waterproof anti-aging decoration wallpaper material |
| CN106758506A (en) * | 2016-12-09 | 2017-05-31 | 湖北恒昊包装科技有限公司 | A kind of corrugated case freeze proof maceration extract of waterproof and its preparation and application |
| CN106758506B (en) * | 2016-12-09 | 2019-07-09 | 湖北恒昊包装科技有限公司 | A kind of freeze proof maceration extract of corrugated case waterproof and its preparation and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102444055B (en) | 2013-04-03 |
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