CN102433565A - Petroleum sulfonate corrosion inhibitor and preparation method thereof - Google Patents

Petroleum sulfonate corrosion inhibitor and preparation method thereof Download PDF

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Publication number
CN102433565A
CN102433565A CN2011104501369A CN201110450136A CN102433565A CN 102433565 A CN102433565 A CN 102433565A CN 2011104501369 A CN2011104501369 A CN 2011104501369A CN 201110450136 A CN201110450136 A CN 201110450136A CN 102433565 A CN102433565 A CN 102433565A
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CN
China
Prior art keywords
parts
petroleum sulfonate
sulfonated petro
leum
corrosion inhibitor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2011104501369A
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Chinese (zh)
Inventor
杨冬峰
胡志清
杨荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI JIU'AN WATER QUALITY STABILIZER PLANT
Original Assignee
SHANGHAI JIU'AN WATER QUALITY STABILIZER PLANT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by SHANGHAI JIU'AN WATER QUALITY STABILIZER PLANT filed Critical SHANGHAI JIU'AN WATER QUALITY STABILIZER PLANT
Priority to CN2011104501369A priority Critical patent/CN102433565A/en
Publication of CN102433565A publication Critical patent/CN102433565A/en
Pending legal-status Critical Current

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  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Lubricants (AREA)

Abstract

The invention relates to the technical field of water treatment chemicals and particularly relates to a petroleum sulfonate corrosion inhibitor and a preparation method thereof. The petroleum sulfonate corrosion inhibitor comprises the following components in parts by weight: 10-20 parts of petroleum sulfonate, 10-15 parts of hydroxyethylidene diphosphonic acid, 5-15 parts of barium petroleum sulfonate, 3-8 parts of sodium lignin sulfonate and 60-80 parts of distilled water. The product provided by the invention has good antirusting property and low-temperature dissolubility.

Description

A kind of sulfonated petro-leum inhibiter and method of manufacture thereof
Technical field
The present invention relates to the water treatment agent technical field, especially a kind of sulfonated petro-leum inhibiter and method of manufacture thereof.
Background technology
People are for preventing metallic corrosion, getting rusty in the past, often vegetable and animals oils, MO, lubricated wet goods directly are coated on the metallic surface, and these greases are to stabilized metal, can corroding metal, and they have water, O in certain air-isolation 2Ability, but stop H 2O, O 2Limited in one's ability to metallic surface migration.Someone did experiment, found to be coated with the thick oil-bound film of 5ram in the metallic surface, and the moisture that sees through oil film after 5 days is 0.34~0.45g, and the moisture that sees through the antirust oil film of same thickness has only 0.005~0.008g.In addition, these greases can not stop SO 2, H 2Penetrating of corrosive deposits such as S.Grease itself also can cause metallic corrosion because of oxidation produces free acid.
Summary of the invention
The object of the present invention is to provide a kind of sulfonated petro-leum inhibiter and method of manufacture thereof, mainly solve above-mentioned existing in prior technology technical problem, it has rust-preventing characteristic and dissolution in low temperature property preferably.
For realizing above-mentioned purpose, the present invention realizes like this.
A kind of sulfonated petro-leum inhibiter is characterized in that: it is 10~20 parts of sulfonated petro-leums according to the composition of parts by weight, 10~15 parts of HEDPs, 5~15 parts of barium mahogany sulfonates, 3~8 parts of sodium lignosulfonates, 60~80 parts of zero(ppm) water.
A kind of method of manufacture of aforesaid sulfonated petro-leum inhibiter; It is characterized in that: zero(ppm) water is put in the reaction vessel; Add sulfonated petro-leum, HEDP, barium mahogany sulfonate, sodium lignosulfonate in the reaction vessel successively then; After stirring, get product.
The advantage that prescription of the present invention and method can embody is:
1, employed HEDP in the disclosed a kind of sulfonated petro-leum inhibiter of the present invention, it can form stable complex compound with multiple metals ions such as iron, copper, zinc, can the surperficial oxide compound of dissolution of metals.Can belong to ion with underwater gold, especially calcium ion forms six annulus inner complexs, and tool is scale inhibition effect and the significantly molten limit effect of tool preferably.
2, employed sodium lignosulfonate is to heavy metal in the disclosed a kind of sulfonated petro-leum inhibiter of the present invention, and especially iron, copper, stannous ion have sequestering power preferably, play corrosion inhibition.
3, employed barium mahogany sulfonate has good anti-embroidery, antiseptic property to ferrous metal, non-ferrous metal copper and alloy thereof in the disclosed a kind of sulfonated petro-leum inhibiter of the present invention, and oil soluble is good.
4, in use it has rust-preventing characteristic and dissolution in low temperature property preferably to the disclosed a kind of sulfonated petro-leum inhibiter of the present invention.
Embodiment
Embodiment 1: 60 parts of zero(ppm) water are put in the reaction vessel, then 10 parts of sulfonated petro-leums, 10 parts of HEDPs, 5 parts of barium mahogany sulfonates, 3 parts of sodium lignosulfonates are added in the reaction vessel successively, after stirring, get product.
Embodiment 2: 70 parts of zero(ppm) water are put in the reaction vessel, then 15 parts of sulfonated petro-leums, 12 parts of HEDPs, 10 parts of barium mahogany sulfonates, 5 parts of sodium lignosulfonates are added in the reaction vessel successively, after stirring, get product.
Embodiment 3: 80 parts of zero(ppm) water are put in the reaction vessel, then 20 parts of sulfonated petro-leums, 15 parts of HEDPs, 15 parts of barium mahogany sulfonates, 8 parts of sodium lignosulfonates are added in the reaction vessel successively, after stirring, get product.
Being merely preferred embodiment of the present invention in sum, is not to be used for limiting practical range of the present invention.Be that all equivalences of doing according to the content of claim of the present invention change and modification, all should be technological category of the present invention.

Claims (2)

1. sulfonated petro-leum inhibiter, it is characterized in that: it is 10~20 parts of sulfonated petro-leums according to the composition of parts by weight, 10~15 parts of HEDPs, 5~15 parts of barium mahogany sulfonates, 3~8 parts of sodium lignosulfonates, 60~80 parts of zero(ppm) water.
2. the method for manufacture of a sulfonated petro-leum inhibiter as claimed in claim 1; It is characterized in that: zero(ppm) water is put in the reaction vessel; Add sulfonated petro-leum, HEDP, barium mahogany sulfonate, sodium lignosulfonate in the reaction vessel successively then; After stirring, get product.
CN2011104501369A 2011-12-29 2011-12-29 Petroleum sulfonate corrosion inhibitor and preparation method thereof Pending CN102433565A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011104501369A CN102433565A (en) 2011-12-29 2011-12-29 Petroleum sulfonate corrosion inhibitor and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011104501369A CN102433565A (en) 2011-12-29 2011-12-29 Petroleum sulfonate corrosion inhibitor and preparation method thereof

Publications (1)

Publication Number Publication Date
CN102433565A true CN102433565A (en) 2012-05-02

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011104501369A Pending CN102433565A (en) 2011-12-29 2011-12-29 Petroleum sulfonate corrosion inhibitor and preparation method thereof

Country Status (1)

Country Link
CN (1) CN102433565A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104099615A (en) * 2014-06-20 2014-10-15 黄河三角洲京博化工研究院有限公司 Imidazoline type neutralization corrosion inhibitor and preparation method thereof
CN112778869A (en) * 2019-11-05 2021-05-11 宜兴汉光高新石化有限公司 Water-based two-component epoxy anticorrosive paint for storage tank weld joint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104099615A (en) * 2014-06-20 2014-10-15 黄河三角洲京博化工研究院有限公司 Imidazoline type neutralization corrosion inhibitor and preparation method thereof
CN112778869A (en) * 2019-11-05 2021-05-11 宜兴汉光高新石化有限公司 Water-based two-component epoxy anticorrosive paint for storage tank weld joint and preparation method thereof

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Application publication date: 20120502